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We propose a state preparation protocol based on sequential measurements of a central spin coupled with a spin ensemble, and investigate the usefulness of the generated multi-spin states for quantum enhanced metrology. Our protocol is shown to generate highly entangled spin states, devoid of the necessity for non-linear spin interactions. The metrological sensitivity of the resulting state surpasses the standard quantum limit, reaching the Heisenberg limit under symmetric coupling strength conditions. We also explore asymmetric coupling strengths, identifying specific preparation windows in time for optimal sensitivity. Our findings introduce a novel method for generating large-scale, non-classical, entangled states, enhancing quantum-enhanced metrology within current experimental capabilities., Comment: Figure 1 updated

Parahydrogen-Induced Polarization (PHIP) is a potent technique for generating target molecules with high nuclear spin polarization. The PHIP process involves a chemical reaction between parahydrogen and a target molecule, followed by the transformation of nuclear singlet spin order into magnetization of a designated nucleus through magnetic field manipulations. Although the singlet-to-magnetization polarization transfer process works effectively at moderate concentrations, it is observed to become much less efficient at high molar polarization, defined as the product of polarization and concentration. This strong dependence on the molar polarization is attributed to interference from the field produced by the sample's magnetization during polarization transfer, which leads to complex dynamics and can severely impact the scalability of the technique. We address this challenge with a pulse sequence that negates the influence of the distant dipolar field, while simultaneously achieving singlet-to-magnetization polarization transfer to the desired target spins, free from restrictions on the molar polarization.

We present a group theoretical and ab-initio analysis of lattice point defects in fluorographene, with a focus on neutral and negative $\text{V}_{\text{CF}}$ vacancies. By using a combination of density functional theory calculations and group theory analysis, we investigate the many-body configurations of the defects and calculate the vertical absorption and zero-phonon line energies of the excited states and their dependence with strain. The description of the defects is extended by computing their formation energy, as well as further relevant parameters as the Jahn-Teller energy for neutral $\text{V}_{\text{CF}}$ and the zero field splitting for negative $\text{V}_{\text{CF}}$ vacancies. Based on our results, we discuss possible quantum applications of these color centers when coupled to mechanical oscillation modes of the hosting two-dimensional material. The symmetry and active orbitals of the defects exhibit a parallelism with those of the extensively studied NV centers in diamond. In this context, the studied defects emerge as interesting candidates for the development of two-dimensional quantum devices based on fluorographene.

The active driving of the electron spin of a color center is known as a method for the hyperpolarization of the surrounding nuclear spin bath and to initialize a system with large number of spins. Here, we investigate the efficiency of this approach for various spin coupling schemes in a one-dimensional Heisenberg chain coupled to a central spin. To extend our study to the realistic systems with a large number of interacting spins, we employ an approximate method based on Holstein-Primakoff transformation. The validity of the method for describing spin polarization dynamics is benchmarked by the exact numerics for a small lattice, where the accuracy of the bosonic Holstein-Primakoff approximation approach is confirmed. We, thus, extend our analysis to larger spin systems where the exact numerics are out of reach. The results prove the efficiency of the active driving method when the central spin interaction with the spin bath is long range and the inter-spin interactions in the bath spins is large enough. The method is then applied to the realistic case of optically active negatively charged boron vacancy centers ($V_B$) in hexagonal boron nitride. Our results suggest that a high degree of hyperpolarization in the boron and nitrogen nuclear spin lattices is achievable even starting from a fully thermal bath. As an initialization, our work provides the first step toward the realization of a two-dimensional quantum simulator based on natural nuclear spins and it can prove useful for extending the coherence time of the $V_B$ centers.

We determine the conditions for the equivalence between the multi-time expectation values of a general finite-dimensional open quantum system when interacting with, respectively, an environment undergoing a free unitary evolution or a discrete environment under a free evolution fixed by a proper Gorini-Kossakowski-Lindblad-Sudarshan generator. We prove that the equivalence holds if both environments are bosonic and Gaussian and if the one- and two-time correlation functions of the corresponding interaction operators are the same at all times. This result leads to a non-perturbative evaluation of the multi-time expectation values of operators and maps of open quantum systems interacting with a continuous set of bosonic modes by means of a limited number of damped modes, thus setting the ground for the investigation of open-system multi-time quantities in fully general regimes., Comment: 16 pages, 1 figure. Submission to a special issue of 'Open Systems and Information Dynamics' devoted to the memory of Prof. Andrzej Kossakowski

We present a protocol that detects molecular conformational changes with two nitroxide electron-spin labels and a nitrogen-vacancy (NV) center in diamond. More specifically, we demonstrate that the NV can detect energy shifts induced by the coupling between electron-spin labels. The protocol relies on the judicious application of microwave and radiofrequency pulses in a range of parameters that ensures stable nitroxide resonances. Furthermore, we demonstrate that our scheme is optimized by using nitroxides with distinct nitrogen isotopes. We use detailed numerical simulations and Bayesian inference techniques to demonstrate that our method enables the detection of conformational changes under realistic conditions including strong NV dephasing rates as a consequence of the diamond surface proximity and nitroxide thermalization mechanisms. Finally, we show that random molecular tumbling can be exploited to extract the inter-label distance., Comment: 6 pages plus supplemental material

The primary steps of photosynthesis rely on the generation, transport, and trapping of excitons in pigment-protein complexes (PPCs). Generically, PPCs possess highly structured vibrational spectra, combining many discrete intra-pigment modes and a quasi-continuous of protein modes, with vibrational and electronic couplings of comparable strength. The intricacy of the resulting vibronic dynamics poses significant challenges in establishing a quantitative connection between spectroscopic data and underlying microscopic models. Here we show how to address this challenge using numerically exact simulation methods by considering two model systems, namely the water-soluble chlorophyll-binding protein of cauliflower and the special pair of bacterial reaction centers. We demonstrate that the inclusion of the full multi-mode vibronic dynamics in numerical calculations of linear spectra leads to systematic and quantitatively significant corrections to electronic parameter estimation. These multi-mode vibronic effects are shown to be relevant in the longstanding discussion regarding the origin of long-lived oscillations in multidimensional nonlinear spectra., Comment: 10+26 pages, 5+9 figures

A scheme for the enhanced generation of higher photon-number states is realized, using an optical time-multiplexing setting that exploits a parametric down-conversion source for an iterative state generation. We use a quantum feedback mechanism for already generated photons to induce self-seeding of the consecutive nonlinear process, enabling us to coherently add photons to the light that propagates in the feedback loop. The addition can be carried out for any chosen number of round trips, resulting in a successive buildup of multiphoton states. Our system is only limited by loop losses. The looped design is rendered possible by a carefully engineered waveguide source that is compatible with and preserves the shape of the propagating mode. We compare the fidelities and success probabilities of our protocol with the common direct heralding of photon-number states. This comparison reveals that, for same the fidelity, our feedback-based setup significantly enhances success probabilities, being vital for an efficient utilization in quantum technologies. Moreover, quantum characteristics of the produced states are analyzed, and the flexibility of producing higher photon-number states with our setup beyond the common direct heralding is demonstrated., Comment: 10 pages. Comments are welcome

Squeezing is a resource that enables precision enhancements in quantum metrology and can be used as a basis for the generation of entanglement by linear optics. While strong squeezing is challenging to generate in optical fields, here we present simple periodic modulation protocols in optomechanical systems that can generate large squeezing of their mechanical degrees of freedom for realistic system parameters. We then proceed to show how such protocols can serve to improve the measurement precision of weak forces and enhance the generation of entanglement between test masses that are subject to any kind of weak interaction. Moreover, these protocols can be reverted to reduce the amount of injected energy, while preserving the generated entanglement and making it more resilient to noise. We present the principle at work, discuss its application in a variety of physical settings, including levitated and tethered mechanical harmonic oscillators, and present example applications to Casimir and gravitational forces., Comment: 11 pages, 4 figures

We use a combination of microwave fields and free precession to drive the spin of a nitrogen-vacancy (NV) center in diamond on different trajectories on the Bloch sphere, and investigate the physical significance of the frame-dependent decomposition of the total phase into geometric and dynamic parts. The experiments are performed on a two-level subspace of the spin-1 ground state of the NV, where the Aharonov-Anandan geometric phase manifests itself as a global phase, and we use the third level of the NV ground state triplet to detect it. We show that while the geometric Aharonov-Anandan phase retains its connection to the solid angle swept out by the evolving spin, it is generally accompanied by a dynamic phase that suppresses the geometric dependence of the system dynamics. These results offer insights into the physical significance of frame-dependent geometric phases., Comment: 10 pages, 5 figures

Quantum sensors typically translate external fields into a periodic response whose frequency is then determined by analyses performed in Fourier space. This allows for a linear inference of the parameters that characterize external signals. In practice, however, quantum sensors are able to detect fields only in a narrow range of amplitudes and frequencies. A departure from this range, as well as the presence of significant noise sources and short detection times, lead to a loss of the linear relationship between the response of the sensor and the target field, thus limiting the working regime of the sensor. Here we address these challenges by means of a Bayesian inference approach that is tolerant to strong deviations from desired periodic responses of the sensor and is able to provide reliable estimates even with a very limited number of measurements. We demonstrate our method for an $^{171}$Yb$^{+}$ trapped-ion quantum sensor but stress the general applicability of this approach to different systems., Comment: 6+15 pages, 3+11 figures. Close to published version; comments welcome

We develop a unified theoretical framework for the efficient description of multiphoton states generated and propagating in loop-based optical networks which contain nonlinear elements. These active optical components are modeled as nonlinear media, resembling a two-mode squeezer. First, such nonlinear components can be seeded to manipulate quantum states of light, as such enabling photon addition protocols. And, second, they can function as an amplifying medium for quantum light. To prove the practical importance of our approach, the impact of multiple round trips is analyzed for states propagating in experimentally relevant loop configurations of networks, such as time-multiplexed driven quantum walks and iterative photon-number state generation protocols. Our method not only enables us to model such complex systems but also allows us to propose alternative setups that overcome previous limitations. To characterize the systems under study, we provide exact expressions for fidelities with target states, success probabilities of heralding-type measurements, and correlations between optical modes, including many realistic imperfections. Moreover, we provide an easily implementable numerical approach by devising a vector-type representation of photonic states, measurement operators, and passive and active processes.

We present a method that combines continuous and pulsed microwave radiation patterns to achieve robust interactions among hyperfine trapped ions placed in a magnetic field gradient. More specifically, our scheme displays continuous microwave drivings with modulated phases, phase flips, and $\pi$ pulses. This leads to high-fidelity entangling gates which are resilient against magnetic field fluctuations, changes on the microwave amplitudes, and crosstalk effects. Our protocol runs with arbitrary values of microwave power, which includes the technologically relevant case of low microwave intensities. We demonstrate the performance of our method with detailed numerical simulations that take into account the main sources of decoherence., Comment: 4 pages, 3 figures + supplemental material

In the present work we discuss the propagation of excitons across a one-dimensional Su-Schrieffer-Heeger lattice, which possesses both harmonic oscillations and weak quartic anharmonicities. When quantizing these vibrational degrees of freedom we identify several phonon-conserving nonlinearities, each one with a different impact on the excitonic transport. Our analysis identifies a dominant nonlinear correction to the phonon hopping which leads to a strong enhancement of exciton conduction compared to a purely linear vibrational dynamics. Thus quartic lattice nonlinearities can be exploited to induce transitions from localized to delocalized transport, even for very weak amplitudes., Comment: 9 pages, 9 figures

The measured multi-dimensional spectral response of different light harvesting complexes exhibits oscillatory features which suggest an underlying coherent energy transfer. However, making this inference rigorous is challenging due to the difficulty of isolating excited state coherences in highly congested spectra. In this work, we provide a coherent control scheme that suppresses ground state coherences, thus making rephasing spectra dominated by excited state coherences. We provide a benchmark for the scheme using a model dimeric system and numerically exact methods to analyze the spectral response. We argue that combining temporal and spectral control methods can facilitate a second generation of experiments that are tailored to extract desired information and thus significantly advance our understanding of complex open many-body structure and dynamics.

The polarisation dynamics of nuclear spins weakly coupled to an NV center is highly sensitive to the parameters of the microwave control and the nuclear Larmor frequency. What is commonly regarded as a challenge, we propose here as a resource for quantum sensing. By varying a single experimental parameter in a suitable set-up, i.e., the Rabi frequency of a continual microwave driving or the nuclear Larmor frequency, we predict periodic reversals of the steady-state polarisation of the nuclear spin. Crucially, interference between the transverse and longitudinal dipolar interaction of electron and nuclear spins results in remarkably sharp steady-state polarisation reversals of nuclear spins within only a few tens of Hz change in the nuclear Larmor frequency. Our method is particularly robust against imperfections such as decoherence of the electron spin and the frequency resolution of the sensor is not limited by the coherence time $T_2$ of the electron sensor.

We develop energy efficient, continuous microwave schemes to couple electron and nuclear spins, using phase or amplitude modulation to bridge their frequency difference. These controls have promising applications in biological systems, where microwave power should be limited, as well as in situations with high Larmor frequencies due to large magnetic fields and nuclear magnetic moments. These include nanoscale NMR where high magnetic fields achieves enhanced thermal nuclear polarisation and larger chemical shifts. Our controls are also suitable for quantum information processors and nuclear polarisation schemes., Comment: 5 pages + Supplemental Material (2 + 4 figures)

The realisation of optically detected magnetic resonance via nitrogen vacancy centers in diamond faces challenges at high magnetic fields which include growing energy consumption of control pulses as well as decreasing sensitivities. Here we address these challenges with the design of shaped pulses in microwave control sequences that achieve orders magnitude reductions in energy consumption and concomitant increases in sensitivity when compared to standard top-hat microwave pulses. The method proposed here is general and can be applied to any quantum sensor subjected to pulsed control sequences., Comment: 7 pages, 4 figures

Due to its superior coherent and optical properties at room temperature, the nitrogen-vacancy (N-V ) center in diamond has become a promising quantum probe for nanoscale quantum sensing. However, the application of N-V containing nanodiamonds to quantum sensing suffers from their relatively poor spin coherence times. Here we demonstrate energy efficient protection of N-V spin coherence in nanodiamonds using concatenated continuous dynamical decoupling, which exhibits excellent performance with less stringent microwave power requirement. When applied to nanodiamonds in living cells we are able to extend the spin coherence time by an order of magnitude to the $T_1$-limit of up to $30\mu$s. Further analysis demonstrates concomitant improvements of sensing performance which shows that our results provide an important step towards in vivo quantum sensing using N-V centers in nanodiamond.

Ultra-thin layers of liquids on a surface behave differently from bulk liquids due to liquid-surface interactions. Some examples are significant changes in diffusion properties and the temperature at which the liquid-solid phase transition takes place. Indeed, molecular dynamics simulations suggest that thin layers of water on a diamond surface may remain solid even well above room temperature. However, because of the small volumes that are involved, it is exceedingly difficult to examine these phenomena experimentally with current technologies. In this context, shallow NV centers promise a highly sensitive tool for the investigation of magnetic signals emanating from liquids and solids that are deposited on the surface of a diamond. Moreover, NV centers are non-invasive sensors with extraordinary performance even at room-temperature. To that end, we present here a theoretical work, complemented with numerical evidence based on bosonization techniques, that predicts the measurable signal from a single NV center when interacting with large spin baths in different configurations. We therefore propose single NV centers as sensors capable to resolve structural water features at the nanoscale and even sensitive to phase transitions.

We devise an all-optical scheme for the generation of entangled multimode photonic states encoded in temporal modes of light. The scheme employs a nonlinear down-conversion process in an optical loop to generate one- and higher-dimensional tensor network states of light. We illustrate the principle with the generation of two different classes of entangled tensor network states and report on a variational algorithm to simulate the ground-state physics of many-body systems. We demonstrate that state-of-the-art optical devices are capable of determining the ground-state properties of the spin-1/2 Heisenberg model. Finally, implementations of the scheme are demonstrated to be robust against realistic losses and mode mismatch., Comment: 6 pages main text plus 6 pages Supplementary Material and many figures. Updated to published version. Comments welcome

We propose a quantum control scheme aimed at interacting systems that gives rise to highly selective coupling among their near-to-resonance constituents. Our protocol implements temporal control of the interaction strength, switching it on and off again adiabatically. This soft temporal modulation significantly suppresses off-resonant contributions in the interactions. Among the applications of our method we show that it allows us to perform an efficient rotating-wave approximation in a wide parameter regime, the elimination of side peaks in quantum sensing experiments, and selective high-fidelity entanglement gates on nuclear spins with close frequencies. We apply our theory to nitrogen-vacancy centers in diamond and demonstrate the possibility for the detection of weak electron-nuclear coupling under the presence of strong perturbations.

Efficient polarization of organic molecules is of extraordinary relevance when performing nuclear magnetic resonance (NMR) and imaging. Commercially available routes to dynamical nuclear polarization (DNP) work at extremely low-temperatures, thus bringing the molecules out of their ambient thermal conditions and relying on the solidification of organic samples. In this work we investigate polarization transfer from optically-pumped nitrogen vacancy centers in diamond to external molecules at room temperature. This polarization transfer is described by both an extensive analytical analysis and numerical simulations based on spin bath bosonization and is supported by experimental data in excellent agreement. These results set the route to hyperpolarization of diffusive molecules in different scenarios and consequently, due to increased signal, to high-resolution NMR., Comment: 6 pages, 3 figures

We propose a pulsed dynamical decoupling protocol as the generator of tunable, fast, and robust quantum phase gates between two microwave-driven trapped ion hyperfine qubits. The protocol consists of sequences of $\pi$-pulses acting on ions that are oriented along an externally applied magnetic field gradient. In contrast to existing approaches, in our design the two vibrational modes of the ion chain cooperate under the influence of the external microwave driving to achieve significantly increased gate speeds. Our scheme is robust against the dominant noise sources, which are errors on the magnetic field and microwave pulse intensities, as well as motional heating, predicting two-qubit gates with fidelities above $99.9\%$ in tens of microseconds., Comment: 11 pages + Supplemental Material, (6 + 1 figures)

The superposition principle lies at the heart of many non-classical properties of quantum mechanics. Motivated by this, we introduce a rigorous resource theory framework for the quantification of superposition of a finite number of linear independent states. This theory is a generalization of resource theories of coherence. We determine the general structure of operations which do not create superposition, find an elementary connection to unambiguous state discrimination, and propose several general quantitative superposition measures. We show that several main results from resource theories of coherence still hold in our more general setting. Of special importance are two results about the free completion of trace decreasing operations and the free probabilistic transformation between pure states that are also valid for the special case of coherence., Comment: Close to published version. Connection to entanglement theory added. 5+16 pages

The coherent high-fidelity generation of nuclear spins in long-lived singlet states which may find application as quantum memory or sensor represents a considerable experimental challenge. Here we propose a dissipative scheme that achieves the preparation of pairs of nuclear spins in long-lived singlet states by a protocol that combines the interaction between the nuclei and a periodically reset electron spin of an NV center with local rf-control of the nuclear spins. The final state of this protocol is independent of the initial preparation of the nuclei, is robust to external field fluctuations and can be operated at room temperature. We show that a high fidelity singlet pair of a 13C dimer in a nuclear bath in diamond can be generated under realistic experimental conditions.

We propose a protocol that achieves arbitrary N-qubit interactions between nuclear spins and that can measure directly nuclear many-body correlators by appropriately making the nuclear spins interact with a nitrogen vacancy (NV) center electron spin. The method takes advantage of recently introduced dynamical decoupling techniques and demonstrates that action on the electron spin is sufficient to fully exploit nuclear spins as robust quantum registers. Our protocol is general, being applicable to other nuclear spin based platforms with electronic spin defects acting as mediators as the case of silicon carbide., Comment: 7 pages, 3 figures

We propose to use a dissipatively engineered nitrogen vacancy (NV) center as a mediator of interaction between two nuclear spins that are protected from decoherence and relaxation of the NV. Under ambient conditions this scheme achieves highly selective high-fidelity quantum gates between nuclear spins in a quantum register even at large NV-nuclear distances. Importantly, this method allows for the use of nuclear spins as a sensor rather than a memory, while the NV spin acts as an ancillary system for the initialization and read out of the sensor. The immunity to the decoherence and relaxation of the NV center leads to a tunable sharp frequency filter while allowing at the same time the continuous collection of the signal to achieve simultaneously high spectral selectivity and high signal-to-noise ratio (SNR).

Quantum state tomography (QST) is the gold standard technique for obtaining an estimate for the state of small quantum systems in the laboratory. Its application to systems with more than a few constituents (e.g. particles) soon becomes impractical as the effort required grows exponentially in the number of constituents. Developing more efficient techniques is particularly pressing as precisely-controllable quantum systems that are well beyond the reach of QST are emerging in laboratories. Motivated by this, there is a considerable ongoing effort to develop new characterisation tools for quantum many-body systems. Here we demonstrate Matrix Product State (MPS) tomography, which is theoretically proven to allow the states of a broad class of quantum systems to be accurately estimated with an effort that increases efficiently with constituent number. We first prove that this broad class includes the out-of-equilbrium states produced by 1D systems with finite-range interactions, up to any fixed point in time. We then use the technique to reconstruct the dynamical state of a trapped-ion quantum simulator comprising up to 14 entangled spins (qubits): a size far beyond the reach of QST. Our results reveal the dynamical growth of entanglement and description complexity as correlations spread out during a quench: a necessary condition for future beyond-classical performance. MPS tomography should find widespread use to study large quantum many-body systems and to benchmark and verify quantum simulators and computers., Comment: 5 pages of main text with 4 figures, 40 additional pages of supplementary material

The nitrogen vacancy (NV) color center in diamond is an enormously important platform for the development of quantum sensors, including for single spin and single molecule NMR. Detection of weak single-spin signals is greatly enhanced by repeated sequences of microwave pulses; in these dynamical decoupling (DD) techniques, the key control parameters swept in the experiment are the time intervals, $\tau$, between pulses. Here we show that, in fact, the pulse duration offers a powerful additional control parameter. While previously, a non-negligible pulse-width has been considered simply a source of experimental error, here we elucidate the underlying quantum dynamics: we identify a landscape of quantum-state crossings which are usually closed (inactive) but may be controllably activated (opened) by adjusting the pulse-width from zero. We identify these crossings with recently observed but unexpected dips (so called spurious dips) seen in the quantum coherence of the NV spin. With this new understanding, both the position and strength of these sharp features may be accurately controlled; they co-exist with the usual broader coherence dips of short-duration microwave pulses, but their sharpness allows for higher resolution spectroscopy with quantum diamond sensors, or their analogues.

We present a method to identify spurious signals generated by finite-width pulses in quantum sensing experiments and apply it to recently proposed dynamical decoupling sequences for accurate spectral interpretation. We first study the origin of these fake resonances and quantify their behavior in a situation that involves the measurement of a classical magnetic field. Here we show that a change of the initial phase of the sensor or, equivalently, of the decoupling pulses leads to oscillations in the spurious signal intensity while the real resonances remain intact. Finally we extend our results to the quantum regime for the unambiguous detection of remote nuclear spins by utilization of a nitrogen vacancy sensor in diamond., Comment: 8 pages, 5 figures

Computational advantages gained by quantum algorithms rely largely on the coherence of quantum devices and are generally compromised by decoherence. As an exception, we present a quantum algorithm for graph isomorphism testing whose performance is optimal when operating in the partially coherent regime, as opposed to the extremes of fully coherent or classical regimes. The algorithm builds on continuous-time quantum stochastic walks (QSWs) on graphs and the algorithmic performance is quantified by the distinguishing power (DIP) between non-isomorphic graphs. The QSW explores the entire graph and acquires information about the underlying structure, which is extracted by monitoring stochastic jumps across an auxiliary edge. The resulting counting statistics of stochastic jumps is used to identify the spectrum of the dynamical generator of the QSW, serving as a novel graph invariant, based on which non-isomorphic graphs are distinguished. We provide specific examples of non-isomorphic graphs that are only distinguishable by QSWs in the presence of decoherence., Comment: To appear in Physical Review A, 6 pages, 3 figures

Selective control of qubits in a quantum register for the purposes of quantum information processing represents a critical challenge for dense spin ensembles in solid state systems. Here we present a protocol that achieves a complete set of selective single and two-qubit gates on nuclear spins in such an ensemble in diamond facilitated by a nearby NV center. The protocol suppresses internuclear interactions as well as unwanted coupling between the NV center and other spins of the ensemble to achieve quantum gate fidelities well exceeding 99% . Notably, our method can be applied to weakly coupled, distant, spins and therefore represents a scalable procedure that exploits the exceptional properties of nuclear spins in diamond as robust quantum memories., Comment: 5 pages + Supplemental Material, (2 + 2 figures)

Control at the interface between the classical and the quantum world is fundamental in quantum physics. In particular, how classical control is enhanced by coherence effects is an important question both from a theoretical as well as from a technological point of view. In this work, we establish a resource theory describing this setting and explore relations to the theory of coherence, entanglement and information processing. Specifically, for the coherent control of quantum systems the relevant resources of entanglement and coherence are found to be equivalent and closely related to a measure of discord. The results are then applied to the DQC1 protocol and the precision of the final measurement is expressed in terms of the available resources., Comment: 9 pages, 4 figures, final version. Discussions were improved and some points were clarified. The title was slightly changed to agree with the published version

The coherence power of a quantum channel, that is, its ability to increase the coherence of input states, is a fundamental concept within the framework of the resource theory of coherence. In this note we discuss various possible definitions of coherence power. Then we prove that the coherence power of a unitary operator acting on a qubit, computed with respect to the $l_1$-coherence measure, can be calculated by maximizing its coherence gain over pure incoherent states. We proceed to show that this result fails for dimensions N>2, that is, the maximal coherence gain is found when acting on a state with non-vanishing coherence., Comment: 5 pages, no figures

Sensing in the presence of environmental noise is a problem of increasing practical interest. In a master equation description, where the state of the environment is unobserved, the effect of signal and noise is described by system operators only. In this context it is well-known that noise that is orthogonal on an external signal can be corrected for without perturbing the signal, while similarly efficient strategies for non-orthogonal signal and noise operators are not known. Here we make use of the fact that system-environment interaction typically arises via local two-body interactions describing the exchange of quanta between system and environment, which are observable in principle. That two-body-interactions are usually orthogonal on system operators, allows us to develop error corrected sensing supported by the observation of the quanta that are emitted into the environment. We describe such schemes and outline a realistic proof-of-principle experiment in an ion trap set-up., Comment: 4 pages

In this paper, we establish a general relation which directly links the dissipated work done on a system driven arbitrarily far from equilibrium, a fundamental quantity in thermodynamics, and the R\'{e}nyi divergences, a fundamental concept in information theory. Specifically, we find that the generating function of the dissipated work under an arbitrary time-dependent driving process is related to the R\'{e}nyi divergences between a non-equilibrium state in the driven process and a non-equilibrium state in its time reversed process. This relation is a consequence of time reversal symmetry in driven process and is universally applicable to both finite classical system and finite quantum system, arbitrarily far from equilibrium., Comment: 5 pages and 2 figures

Nitrogen-vacancy (NV) centers in diamond have emerged as valuable tools for sensing and polarizing spins. Motivated by potential applications in chemistry, biology, and medicine, we show that NV-based sensors are capable of detecting single spin targets even if they undergo diffusive motion in an ambient thermal environment. Focusing on experimentally relevant diffusion regimes, we derive an effective model for the NV-target interaction, where parameters entering the model are obtained from numerical simulations of the target motion. The practicality of our approach is demonstrated by analyzing two realistic experimental scenarios: (i) time-resolved sensing of a fluorine nuclear spin bound to an N-heterocyclic carbene-ruthenium (NHC-Ru) catalyst that is immobilized on the diamond surface and (ii) detection of an electron spin label by an NV center in a nanodiamond, both attached to a vibrating chemokine receptor in thermal motion. We find in particular that the detachment of a fluorine target from the NHC-Ru carrier molecule can be monitored with a time resolution of a few seconds., Comment: 14 pages, 8 figures, supplemental material

Non-Markovian effects in the evolution of open quantum systems have recently attracted widespread interest, particularly in the context of assessing the efficiency of energy and charge transfer in nanoscale biomolecular networks and quantum technologies. With the aid of many-body simulation methods, we uncover and analyse an ultrafast environmental process that causes energy relaxation in the reduced system to depend explicitly on the phase relation of the initial state preparation. Remarkably, for particular phases and system parameters, the net energy flow is uphill, transiently violating the principle of detailed balance, and implying that energy is spontaneously taken up from the environment. A theoretical analysis reveals that non-secular contributions, significant only within the environmental correlation time, underlie this effect. This suggests that environmental energy harvesting will be observable across a wide range of coupled quantum systems., Comment: 5 + 4 pages, 3 + 2 figures. Comments welcome

We propose the use of non-equally spaced decoupling pulses for high-resolution selective addressing of nuclear spins by a quantum sensor. The analytical model of the basic operating principle is supplemented by detailed numerical studies that demonstrate the high degree of selectivity and the robustness against static and dynamic control field errors of this scheme. We exemplify our protocol with an NV center-based sensor to demonstrate that it enables the identification of individual nuclear spins that form part of a large spin ensemble., Comment: 5 pages, 4 figures

We present practical methods to measure entanglement for quantum simulators that can be realized with trapped ions, cold atoms, and superconducting qubits. Focussing on long- and short-range Ising-type Hamiltonians, we introduce schemes that are applicable under realistic experimental conditions including mixedness due to, e.g., noise or temperature. In particular, we identify a single observable whose expectation value serves as a lower bound to entanglement and which may be obtained by a simple quantum circuit. As such circuits are not (yet) available for every platform, we investigate the performance of routinely measured observables as quantitative entanglement witnesses. Possible applications include experimental studies of entanglement scaling in critical systems and the reliable benchmarking of quantum simulators., Comment: 9 pages, 3 figures

Here we propose and analyse in detail protocols that can achieve rapid hyperpolarization of 13C nuclear spins in randomly oriented ensembles of nanodiamonds at room temperature. Our protocols exploit a combination of optical polarization of electron spins in nitrogen-vacancy centers and the transfer of this polarization to 13C nuclei by means of microwave control to overcome the severe challenges that are posed by the random orientation of the nanodiamonds and their nitrogen-vacancy centers. Specifically, these random orientations result in exceedingly large energy variations of the electron spin levels that render the polarization and coherent control of the nitrogen-vacancy center electron spins as well as the control of their coherent interaction with the surrounding 13C nuclear spins highly inefficient. We address these challenges by a combination of an off-resonant microwave double resonance scheme in conjunction with a realization of the integrated solid effect which, together with adiabatic rotations of external magnetic fields or rotations of nanodiamonds, leads to a protocol that achieves high levels of hyperpolarization of the entire nuclear-spin bath in a randomly oriented ensemble of nanodiamonds even at room temperature. This hyperpolarization together with the long nuclear spin polarization lifetimes in nanodiamonds and the relatively high density of 13C nuclei has the potential to result in a major signal enhancement in 13C nuclear magnetic resonance imaging and suggests functionalized and hyperpolarized nanodiamonds as a unique probe for molecular imaging both in vitro and in vivo., Comment: 19 pages,13 figures

We derive rigorous truncation-error bounds for the spin-boson model and its generalizations to arbitrary quantum systems interacting with bosonic baths. For the numerical simulation of such baths the truncation of both, the number of modes and the local Hilbert-space dimensions is necessary. We derive super-exponential Lieb--Robinson-type bounds on the error when restricting the bath to finitely-many modes and show how the error introduced by truncating the local Hilbert spaces may be efficiently monitored numerically. In this way we give error bounds for approximating the infinite system by a finite-dimensional one. As a consequence, numerical simulations such as the time-evolving density with orthogonal polynomials algorithm (TEDOPA) now allow for the fully certified treatment of the system-environment interaction., Comment: 13 pages, 3 figures

When the amount of entanglement in a quantum system is limited, the relevant dynamics of the system is restricted to a very small part of the state space. When restricted to this subspace the description of the system becomes efficient in the system size. A class of algorithms, exemplified by the Time-Evolving Block-Decimation (TEBD) algorithm, make use of this observation by selecting the relevant subspace through a decimation technique relying on the Singular Value Decomposition (SVD). In these algorithms, the complexity of each time-evolution step is dominated by the SVD. Here we show that, by applying a randomized version of the SVD routine (RRSVD), the power law governing the computational complexity of TEBD is lowered by one degree, resulting in a considerable speed-up. We exemplify the potential gains in efficiency at the hand of some real world examples to which TEBD can be successfully applied to and demonstrate that for those system RRSVD delivers results as accurate as state-of-the-art deterministic SVD routines., Comment: 14 pages, 5 figures

Precision sensing, and in particular high precision magnetometry, is a central goal of research into quantum technologies. For magnetometers, often trade-offs exist between sensitivity, spatial resolution, and frequency range. The precision, and thus the sensitivity of magnetometry, scales as $1/\sqrt {T_2}$ with the phase coherence time, $T_2$, of the sensing system playing the role of a key determinant. Adapting a dynamical decoupling scheme that allows for extending $T_2$ by orders of magnitude and merging it with a magnetic sensing protocol, we achieve a measurement sensitivity even for high frequency fields close to the standard quantum limit. Using a single atomic ion as a sensor, we experimentally attain a sensitivity of $4.6$ pT $/\sqrt{Hz}$ for an alternating-current magnetic field near 14 MHz. Based on the principle demonstrated here, this unprecedented sensitivity combined with spatial resolution in the nanometer range and tunability from direct-current to the gigahertz range could be used for magnetic imaging in as of yet inaccessible parameter regimes., Comment: Replaced with final published version. Extended Supplemental Material

Based on recently introduced efficient quantum state tomography schemes, we propose a scalable method for the tomography of unitary processes and the reconstruction of one-dimensional local Hamiltonians. As opposed to the exponential scaling with the number of subsystems of standard quantum process tomography, the method relies only on measurements of linearly many local observables and either (a) the ability to prepare eigenstates of locally informationally complete operators or (b) access to an ancilla of the same size as the to-be-characterized system and the ability to prepare a maximally entangled state on the combined system. As such, the method requires at most linearly many states to be prepared and linearly many observables to be measured. The quality of the reconstruction can be quantified with the same experimental resources that are required to obtain the reconstruction in the first place. Our numerical simulations of several quantum circuits and local Hamiltonians suggest a polynomial scaling of the total number of measurements and post-processing resources., Comment: 9+2 pages, 5 figures; v2: close to published version

We introduce a detector that selectively probes the phononic excitations of a cold Bose gas. The detector is composed of a single impurity atom confined by a double-well potential, where the two lowest eigenstates of the impurity form an effective probe qubit that is coupled to the phonons via density-density interactions with the bosons. The system is analogous to a two-level atom coupled to photons of the radiation field. We demonstrate that tracking the evolution of the qubit populations allows probing both thermal and coherent excitations in targeted phonon modes. The targeted modes are selected in both energy and momentum by adjusting the impurity's potential. We show how to use the detector to observe coherent density waves and to measure temperatures of the Bose gas down to the nano-Kelvin regime. We analyze how our scheme could be realized experimentally, including the possibility of using an array of multiple impurities to achieve greater precision from a single experimental run., Comment: 11+4 pages, 7 figures

Ion Coulomb crystals are currently establishing themselves as a highly controllable test-bed for mesoscopic systems of statistical mechanics. The detailed experimental interrogation of the dynamics of these crystals however remains an experimental challenge. In this work, we show how to extend the concepts of multi-dimensional nonlinear spectroscopy to the study of the dynamics of ion Coulomb crystals. The scheme we present can be realized with state-of-the-art technology and gives direct access to the dynamics, revealing nonlinear couplings even in the presence of thermal excitations. We illustrate the advantages of our proposal showing how two-dimensional spectroscopy can be used to detect signatures of a structural phase transition of the ion crystal, as well as resonant energy exchange between modes. Furthermore, we demonstrate in these examples how different decoherence mechanisms can be identified., Comment: 5 + 11 pages, close to published version