Search

Fluvial sediment samples (river bottom sediment, suspended sediment and active floodplain/overbank) were collected in 2 baseline stations of the Transnational Monitoring Network for each of the 12 countries in the Danube Basin Region: Austria, Bosnia and Herzegovina, Bulgaria, Croatia, Czech Republic, Hungary, Republic of Moldavia, Montenegro, Romania, Republic of Serbia, Slovakia and Slovenia, according to a harmonized methodology. The sediment samples were analyzed for selected hazardous substances (HSs):8 metals, 8 polycyclic aromatic hydrocarbons (PAHs) and 6 pesticides in an accredited laboratory selected as reference laboratory, as well as in national laboratories. Risk ratios were computed in order to compare the results to the Environmental Quality Standards listed in the European Directives, to the national threshold values in the Danube Basin, and to other available international European and American quality standards, and the risk ratios were classified as background, alert and intervention values for readily evaluation. Results show widespread metal(oid) (As, Cd, Cu, Hg, Pb, and Zn) contamination in the Danube Basin, most often associated with historic mining. Concentration values of Ni and Cr exceeding the thresholds are caused by the geological background (ultrabasic and metamorphic rocks in Bosnia and Herzegovina, Republic of Serbia and Romania). Concentration values higher than the thresholds for some of the PAHs (e.g. Fluoranthene) and sometimes for Total PAHs were also noted almost in every countries, caused by industrial activities, wastewater discharges or navigation on the Danube River. Pesticides were below the detection limit or below the legislative intervention thresholds at all national baseline sampling sites.

Discharge of hazardous substances (HSs) in hydrographic basins represent a danger to aquatic biological activity and water supplies and can severely pollute surface water sediments. The increase of pollution in the Danube Basin requires the implementation of systematic monitoring and evaluation of the sediments quality as dictated by the EU Water Framework Directive. For this system development, applicable in mountainous conditions, the Upper Tisa region in the northwest part of Romania on the border with Ukraine, Hungary and Slovakia was selected as a test area. Sampling of overbank (floodplain) sediment, river bottom sediment and suspended sediment was carried out at 10 locations in the test area in order to analyze the concentration and distribution of eight metal(oid)s (Cu, Pb, Zn, Cd, Hg, Ni, Cr and As), in addition to 3 organic components (anthracene, fluoranthene, benzo(e)pyrene) as hazardous substances (HSs). The sediment quality assessment was carried out according to the 2013/39/EU Directive and EU Water Framework Directive standards. Most of the analyzed HS concentrations in river bottom sediment and overbank (floodplain) sediments fall within the limits of environmental quality standards (EQS). As, Cu, Pb, and Zn tend to exceed the EQS at some locations. The highest exceedances were recorded for Pb, for which contents of up to 987 mg/kg were detected. The highest contents were found in the overbank sediments sampled, and the lowest in river bottom sediments, which may indicate historical pollution. Mercury contents in overbank sediment samples exceed all standards, while cadmium content is below the international standards. Anthracene, fluoranthene and benzo(e)pyrene concentrations in overbank and bottom sediments comply with international standards. A few samples in suspended sediments slightly exceed the lowest environmental standard value (i.e., Romanian normal value). HS concentrations remain low in the suspended sediments showing that it is not the main transport route for pollution in this area. HS contents decrease gradually from upstream to downstream due to dilution along the river course. In the last testing point at Someș Aciua, the concentration of metal(oid)s measured in the sediments remain below the EQS limit values, thus there is no risk of transboundary pollution. The main source of metal(oid) contamination is historic base-metal ore mining and the associated mine waste sites in the Baia Mare and other mining areas scattered around the whole region. The main source of the studied organic compounds is the incomplete or low-temperature coal combustion processes that occur in households in rural areas.

The EU Water Framework Directive requires the monitoring and evaluation of surface water sediment quality based on the assessment of risk posed by contamination on the biotic receptors. Fluvial sediments are important receptors of hazardous substances (HSs) pollution from the upstream catchment areas in the Danube River Basin (DRB). For the development of systematic sediment quality monitoring and evaluation, the Drava River region on the border of Hungary and Croatia was selected as a test area representative of lowland hydromorphological conditions. Overbank (floodplain) sediments and river bottom sediments (stream sediments) were sampled at two depths at 9 locations in the test area. Eight heavy metal(oid)s were analyzed As, Cd, Cr, Cu, Hg, Ni, and Zn as hazardous substances. The sediment quality assessment was carried out according to the 2013/39/EU Directive and EU Water Framework Directive standards. Most of the analysed HS concentrations in river bottom sediment and overbank (floodplain) sediments fall within the limits of environmental quality standards (EQS). Results show that there is no significant differences in metal(oid) HS concentrations among the various sediment types and between shallow (0- 5cm) and deeper (stream sediment: 5-10cm ; floodplain sediment: 40-50cm) sediment which suggests that the large lowland Drava River fluvial system is an extensive single fluvial system with homogeneous distribution of sediments and the associated contaminants. Specifically, the studied sediments in the tributaries of the Drava River do not seem to be contaminated with metal(oid) hazardous substances but at certain sites concentrations are elevated above the environmental limit values, especially for As and Zn, and to lesser extent for Cr. The data analysis techniques used enabled the identification of sites with anthropogenic pollution and the recognition of regional pattern in HSs distribution.

Europe shows an inevitably growing and accelerating consumption of mineral commodities and the high import dependence of strategic and critical raw materials has a serious impact on the sustainability of the EU manufacturing industry. The European Commission has long recognized the challenge of sustainable supply of mineral raw materials and steps are implemented to try to deal with this. In this context, EuroGeoSurveys and its Mineral Resources Expert Group (MREG) serve as one of the contact points for the Commission. The MREG is a group of earth scientists, experts in Economic Geology that act under the umbrella body of EuroGeoSurveys. The group acts upon requests and queries received by member states and the European Commission and provides the best available mineral expertise and information based on the knowledge of member Geological Surveys, for policy, communication, public awareness and education purposes at European level. RESUMO: A Europa mostra um inevitável e acelerado aumento de consumo de recursos minerais. A alta dependência das importações de matérias-primas estratégicas e críticas tem um forte impacto na sustentabilidade da indústria transformadora da UE. A produção de muitas matérias primas depende apenas de alguns países. O desafio do abastecimento sustentável tem sido reconhecido pela Comissão Europeia e foram implementadas etapas no sentido de tal ser assegurado. Neste contexto, o EuroGeoSurveys e o seu Grupo de Peritos em Recursos Minerais (MREG) servem como um dos pontos de contacto para a Comissão. O MREG dos EuroGeoSurveys é um grupo de Geocientistas, especialistas em Geologia Económica que trabalham sobre a tutela dos EuroGeoSurveys. O grupo atua com base em solicitações e consultas recebidas pelos Estados membros e pela Comissão Europeia e fornece os melhores conhecimentos e informações disponíveis com base no conhecimento geológico dos recursos minerais, nas esferas da política, e de comunicação, conscientização pública e educação a nível europeu. info:eu-repo/semantics/publishedVersion