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This case study documents a lameness control strategy in a commercial dairy goat herd with treponeme-associated non-healing white line disease (nhWLD). A similar control strategy to nhWLD in cattle was used, focusing on reducing environmental infection pressure of treponemes and culling of cases unresponsive to treatment. This case study highlights the importance of regular and accurate lameness scoring, correct lesion categorisation, and critical decision making on treatment versus culling. Over the 12 month intervention period lameness prevalence reduced from 45% to 15%. Treatment response of existing nhWLD was poor, but prevention of new cases was good. A total of 27% of the lactating herd were culled due to lameness, however total herd yield dropped by less than 1% despite nutritional management remaining broadly the same, demonstrating the wider benefits of culling in terms of farm productivity and efficiency.

A major challenge in quantum computing is to solve general problems with limited physical hardware. Here, we implement digitized adiabatic quantum computing, combining the generality of the adiabatic algorithm with the universality of the digital approach, using a superconducting circuit with nine qubits. We probe the adiabatic evolutions, and quantify the success of the algorithm for random spin problems. We find that the system can approximate the solutions to both frustrated Ising problems and problems with more complex interactions, with a performance that is comparable. The presented approach is compatible with small-scale systems as well as future error-corrected quantum computers., Comment: Main text: 7 pages, 5 figures. Supplementary: 12 pages, 9 figures

A quantum computer can solve hard problems, such as prime factoring, database searching and quantum simulation, at the cost of needing to protect fragile quantum states from error. Quantum error correction provides this protection by distributing a logical state among many physical quantum bits (qubits) by means of quantum entanglement. Superconductivity is a useful phenomenon in this regard, because it allows the construction of large quantum circuits and is compatible with microfabrication. For superconducting qubits, the surface code approach to quantum computing is a natural choice for error correction, because it uses only nearest-neighbour coupling and rapidly cycled entangling gates. The gate fidelity requirements are modest: the per-step fidelity threshold is only about 99 per cent. Here we demonstrate a universal set of logic gates in a superconducting multi-qubit processor, achieving an average single-qubit gate fidelity of 99.92 per cent and a two-qubit gate fidelity of up to 99.4 per cent. This places Josephson quantum computing at the fault-tolerance threshold for surface code error correction. Our quantum processor is a first step towards the surface code, using five qubits arranged in a linear array with nearest-neighbour coupling. As a further demonstration, we construct a five-qubit Greenberger-Horne-Zeilinger state using the complete circuit and full set of gates. The results demonstrate that Josephson quantum computing is a high-fidelity technology, with a clear path to scaling up to large-scale, fault-tolerant quantum circuits. © 2014 Macmillan Publishers Limited.

Many superconducting qubit systems use the dispersive interaction between the qubit and a coupled harmonic resonator to perform quantum state measurement. Previous works have found that such measurements can induce state transitions in the qubit if the number of photons in the resonator is too high. We investigate these transitions and find that they can push the qubit out of the two-level subspace, and that they show resonant behavior as a function of photon number. We develop a theory for these observations based on level crossings within the Jaynes-Cummings ladder, with transitions mediated by terms in the Hamiltonian that are typically ignored by the rotating wave approximation. We find that the most important of these terms comes from an unexpected broken symmetry in the qubit potential. We confirm the theory by measuring the photon occupation of the resonator when transitions occur while varying the detuning between the qubit and resonator.

© 2016 Macmillan Publishers Limited. All rights reserved. Statistical mechanics is founded on the assumption that all accessible configurations of a system are equally likely. This requires dynamics that explore all states over time, known as ergodic dynamics. In isolated quantum systems, however, the occurrence of ergodic behaviour has remained an outstanding question. Here, we demonstrate ergodic dynamics in a small quantum system consisting of only three superconducting qubits. The qubits undergo a sequence of rotations and interactions and we measure the evolution of the density matrix. Maps of the entanglement entropy show that the full system can act like a reservoir for individual qubits, increasing their entropy through entanglement. Surprisingly, these maps bear a strong resemblance to the phase space dynamics in the classical limit; classically, chaotic motion coincides with higher entanglement entropy. We further show that in regions of high entropy the full multi-qubit system undergoes ergodic dynamics. Our work illustrates how controllable quantum systems can investigate fundamental questions in non-equilibrium thermodynamics.

We report the first electronic structure calculation performed on a quantum computer without exponentially costly precompilation. We use a programmable array of superconducting qubits to compute the energy surface of molecular hydrogen using two distinct quantum algorithms. First, we experimentally execute the unitary coupled cluster method using the variational quantum eigensolver. Our efficient implementation predicts the correct dissociation energy to within chemical accuracy of the numerically exact result. Second, we experimentally demonstrate the canonical quantum algorithm for chemistry, which consists of Trotterization and quantum phase estimation. We compare the experimental performance of these approaches to show clear evidence that the variational quantum eigensolver is robust to certain errors. This error tolerance inspires hope that variational quantum simulations of classically intractable molecules may be viable in the near future., Comment: 13 pages, 7 figures. This revision is to correct an error in the coefficients of identity in Table 1

The intriguing many-body phases of quantum matter arise from the interplay of particle interactions, spatial symmetries, and external fields. Generating these phases in an engineered system could provide deeper insight into their nature and the potential for harnessing their unique properties. However, concurrently bringing together the main ingredients for realizing many-body phenomena in a single experimental platform is a major challenge. Using superconducting qubits, we simultaneously realize synthetic magnetic fields and strong particle interactions, which are among the essential elements for studying quantum magnetism and fractional quantum Hall (FQH) phenomena. The artificial magnetic fields are synthesized by sinusoidally modulating the qubit couplings. In a closed loop formed by the three qubits, we observe the directional circulation of photons, a signature of broken time-reversal symmetry. We demonstrate strong interactions via the creation of photon-vacancies, or "holes", which circulate in the opposite direction. The combination of these key elements results in chiral groundstate currents, the first direct measurement of persistent currents in low-lying eigenstates of strongly interacting bosons. The observation of chiral currents at such a small scale is interesting and suggests that the rich many-body physics could survive to smaller scales. We also motivate the feasibility of creating FQH states with near future superconducting technologies. Our work introduces an experimental platform for engineering quantum phases of strongly interacting photons and highlight a path toward realization of bosonic FQH states., in Nature Physics (2016)

Weak measurement has provided new insight into the nature of quantum measurement, by demonstrating the ability to extract average state information without fully projecting the system. For single-qubit measurements, this partial projection has been demonstrated with violations of the Leggett–Garg inequality. Here we investigate the effects of weak measurement on a maximally entangled Bell state through application of the Hybrid Bell–Leggett–Garg inequality (BLGI) on a linear chain of four transmon qubits. By correlating the results of weak ancilla measurements with subsequent projective readout, we achieve a violation of the BLGI with 27 s.d.s. of certainty. Scientists in the US have developed a method to evaluate the properties of complex quantum states without causing their destruction. A team at the University of California Santa Barbara led by John Martinis verified that the properties of entangled quantum states can be probed using weak measurements. By extracting only small parts of quantum information in a single measurement, weak measurements avoid the problem whereby quantum states are destroyed when the information contained in them is measured. Although this has been successfully demonstrated for single quantum states, it remained unclear if weak measurements were compatible with more complicated entangled systems. By implementing an experimental test that verifies with high accuracy the preservation of those entangled states in measurements, the researchers have made it possible to probe the properties of qubits in complex quantum computing schemes.

Control of zero-field spin splitting is realized in a dual-gated high-quality InAs-AlSb two-dimensional electron gas. Magnetotransport experiments showed clean Shubnikov--de Haas oscillations down to low magnetic fields, and the gate-tuned electron mobility exceeded $700\phantom{\rule{0.16em}{0ex}}000\phantom{\rule{0.16em}{0ex}}\mathrm{c}{\mathrm{m}}^{2}/\mathrm{V}\phantom{\rule{0.16em}{0ex}}\mathrm{s}$. A clear beating effect was observed in magnetoresistance oscillations at large potential asymmetry between gates. Beat patterns due to zero-field spin splitting and other classes of transverse magnetoresistance oscillations were distinguished by temperature-dependent magnetoresistance measurements. Analysis of the magnetoresistance oscillations indicated that the zero-field spin splitting could be tuned via the Rashba effect while keeping the two-dimensional electron gas charge density constant.

By analyzing the dissipative dynamics of a tunable gap flux qubit, we extract both sides of its two-sided environmental flux noise spectral density over a range of frequencies around $2k_BT/h \approx 1\,\rm{GHz}$, allowing for the observation of a classical-quantum crossover. Below the crossover point, the symmetric noise component follows a $1/f$ power law that matches the magnitude of the $1/f$ noise near $1\,{\rm{Hz}}$. The antisymmetric component displays a 1/T dependence below $100\,\rm{mK}$, providing dynamical evidence for a paramagnetic environment. Extrapolating the two-sided spectrum predicts the linewidth and reorganization energy of incoherent resonant tunneling between flux qubit wells., Comment: paper + supplement

Leakage errors occur when a quantum system leaves the two-level qubit subspace. Reducing these errors is critically important for quantum error correction to be viable. To quantify leakage errors, we use randomized benchmarking in conjunction with measurement of the leakage population. We characterize single qubit gates in a superconducting qubit, and by refining our use of Derivative Reduction by Adiabatic Gate (DRAG) pulse shaping along with detuning of the pulses, we obtain gate errors consistently below $10^{-3}$ and leakage rates at the $10^{-5}$ level. With the control optimized, we find that a significant portion of the remaining leakage is due to incoherent heating of the qubit., 10 pages, 10 figures including supplement; fixed typos in metadata

A precise measurement of dephasing over a range of timescales is critical for improving quantum gates beyond the error correction threshold. We present a metrological tool, based on randomized benchmarking, capable of greatly increasing the precision of Ramsey and spin echo sequences by the repeated but incoherent addition of phase noise. We find our SQUID-based qubit is not limited by $1/f$ flux noise at short timescales, but instead observe a telegraph noise mechanism that is not amenable to study with standard measurement techniques., 11 pages, 7 figures

Simulating quantum physics with a device which itself is quantum mechanical, a notion Richard Feynman originated, would be an unparallelled computational resource. However, the universal quantum simulation of fermionic systems is daunting due to their particle statistics, and Feynman left as an open question whether it could be done, because of the need for non-local control. Here, we implement fermionic interactions with digital techniques in a superconducting circuit. Focusing on the Hubbard model, we perform time evolution with constant interactions as well as a dynamic phase transition with up to four fermionic modes encoded in four qubits. The implemented digital approach is universal and allows for the efficient simulation of fermions in arbitrary spatial dimensions. We use in excess of 300 single-qubit and two-qubit gates, and reach global fidelities which are limited by gate errors. This demonstration highlights the feasibility of the digital approach and opens a viable route towards analog-digital quantum simulation of interacting fermions and bosons in large-scale solid state systems., Main text: 5 pages, 5 figures. Supplementary: 7 pages, 6 figures

Background— The goal of this study was to determine whether the expression of vascular endothelial growth factor (VEGF) is critical for coronary collateral growth. Previous studies have provided an association between coronary collateral growth and VEGF, but none have allowed determination of a causal role. Methods and Results— We measured coronary collateral growth in rats subjected to repetitive episodes of myocardial ischemia (RI; one 40-second occlusion every 20 minutes for 2 hours 40 minutes, followed by 5 hours 20 minutes of rest, with this 8-hour cycle repeated 3 times per day for 10 days). Collateral growth was measured from blood flow (radioactive microspheres), visualization of arterial-arterial anastomoses (x-ray micro-CT), and maintenance of function during complete coronary occlusion in 3 groups of animals: sham (received instrumentation but no RI), experimental (subjected to RI), and anti–vascular endothelial growth factor (RI+anti-VEGF 0.6 mg/100 g per day) to block the endogenous actions of VEGF. In the 3 groups, native collateral flow (measurement for RI or sham protocol) averaged 0.2 to 0.3 mL · min −1 · g −1 of tissue. In the sham group, collateral flow did not increase during the protocol. Collateral flow in the control RI group increased by ≈6-fold to 1.63 mL · min −1 · g −1 tissue, but in the anti-VEGF group, collateral flow did not increase after the RI protocol (0.22 mL · min −1 · g −1 ). In acute experiments, collateral flow was unchanged during vasodilation with dipyridamole, indicating the increases in collateral flow are due to collateral growth and not vasodilation. X-ray micro-CT analysis revealed a 3-fold increase (versus sham group) in the number of arterial-arterial anastomoses per heart after RI, which was prevented by treatment with anti-VEGF. The growth of the collateral circulation was functional in the RI group because complete coronary occlusion did not induce any untoward effects on hemodynamics or arrhythmias. In the sham or anti-VEGF groups, coronary occlusion at the end of the protocol induced many arrhythmias and deterioration of function. Conclusions— From these results, we conclude that the expression of VEGF is critical to the growth of coronary collaterals.

One of the key challenges in quantum information is coherently manipulating the quantum state. However, it is an outstanding question whether control can be realized with low error. Only gates from the Clifford group -- containing $\pi$, $\pi/2$, and Hadamard gates -- have been characterized with high accuracy. Here, we show how the Platonic solids enable implementing and characterizing larger gate sets. We find that all gates can be implemented with low error. The results fundamentally imply arbitrary manipulation of the quantum state can be realized with high precision, providing new practical possibilities for designing efficient quantum algorithms., Comment: 8 pages, 4 figures, including supplementary material

Topology, with its abstract mathematical constructs, often manifests itself in physics and has a pivotal role in our understanding of natural phenomena. Notably, the discovery of topological phases in condensed-matter systems has changed the modern conception of phases of matter. The global nature of topological ordering, however, makes direct experimental probing an outstanding challenge. Present experimental tools are mainly indirect and, as a result, are inadequate for studying the topology of physical systems at a fundamental level. Here we employ the exquisite control afforded by state-of-the-art superconducting quantum circuits to investigate topological properties of various quantum systems. The essence of our approach is to infer geometric curvature by measuring the deflection of quantum trajectories in the curved space of the Hamiltonian. Topological properties are then revealed by integrating the curvature over closed surfaces, a quantum analogue of the Gauss-Bonnet theorem. We benchmark our technique by investigating basic topological concepts of the historically important Haldane model after mapping the momentum space of this condensed-matter model to the parameter space of a single-qubit Hamiltonian. In addition to constructing the topological phase diagram, we are able to visualize the microscopic spin texture of the associated states and their evolution across a topological phase transition. Going beyond non-interacting systems, we demonstrate the power of our method by studying topology in an interacting quantum system. This required a new qubit architecture that allows for simultaneous control over every term in a two-qubit Hamiltonian. By exploring the parameter space of this Hamiltonian, we discover the emergence of an interaction-induced topological phase. Our work establishes a powerful, generalizable experimental platform to study topological phenomena in quantum systems.

We present a method for optimizing quantum control in experimental systems, using a subset of randomized benchmarking measurements to rapidly infer error. This is demonstrated to improve single- and two-qubit gates, minimize gate bleedthrough, where a gate mechanism can cause errors on subsequent gates, and identify control crosstalk in superconducting qubits. This method is able to correct parameters to where control errors no longer dominate, and is suitable for automated and closed-loop optimization of experimental systems., Comment: 7 pages, 7 figures including supplementary

(Received 15 November 2013; revised manuscript received 24 January 2014; published 28 May 2014) We demonstrate a high-efficiency deterministic quantum receiver to convert flying qubits to stationary qubits. We employ a superconducting resonator, which is driven with a shaped pulse through an adjustable coupler. For the ideal “time-reversed” shape, we measure absorption and receiver fidelities at the single microwave photon level of, respectively, 99.41% and 97.4%. These fidelities are comparablewith gates and measurement and exceed the deterministic quantum communication and computation fault-tolerant thresholds, enabling new designs of deterministic qubit interconnects and hybrid quantum computers.

Quantum interference is one of the most fundamental physical effects found in nature. Recent advances in quantum computing now employ interference as a fundamental resource for computation and control. Quantum interference also lies at the heart of sophisticated condensed matter phenomena such as Anderson localization, phenomena that are difficult to reproduce in numerical simulations. Here, employing a multiple-element superconducting quantum circuit, with which we manipulate a single microwave photon, we demonstrate that we can emulate the basic effects of weak localization. By engineering the control sequence, we are able to reproduce the well-known negative magnetoresistance of weak localization as well as its temperature dependence. Furthermore, we can use our circuit to continuously tune the level of disorder, a parameter that is not readily accessible in mesoscopic systems. Demonstrating a high level of control, our experiment shows the potential for employing superconducting quantum circuits as emulators for complex quantum phenomena.

We introduce a superconducting qubit architecture that combines high-coherence qubits and tunable qubit-qubit coupling. With the ability to set the coupling to zero, we demonstrate that this architecture is protected from the frequency crowding problems that arise from fixed coupling. More importantly, the coupling can be tuned dynamically with nanosecond resolution, making this architecture a versatile platform with applications ranging from quantum logic gates to quantum simulation. We illustrate the advantages of dynamical coupling by implementing a novel adiabatic controlled-z gate, with a speed approaching that of single-qubit gates. Integrating coherence and scalable control, the introduced qubit architecture provides a promising path towards large-scale quantum computation and simulation.

We present a lumped-element Josephson parametric amplifier designed to operate with strong coupling to the environment. In this regime, we observe broadband frequency dependent amplification with multi-peaked gain profiles. We account for this behaviour using the "pumpistor" model which allows for frequency dependent variation of the external impedance. Using this understanding, we demonstrate control over gain profiles through changes in the environment impedance at a given frequency. With strong coupling to a suitable external impedance we observe a significant increase in dynamic range, and large amplification bandwidth up to 700 MHz giving near quantum-limited performance.

Quantum computing becomes viable when a quantum state can be preserved from environmentally-induced error. If quantum bits (qubits) are sufficiently reliable, errors are sparse and quantum error correction (QEC) is capable of identifying and correcting them. Adding more qubits improves the preservation by guaranteeing increasingly larger clusters of errors will not cause logical failure - a key requirement for large-scale systems. Using QEC to extend the qubit lifetime remains one of the outstanding experimental challenges in quantum computing. Here, we report the protection of classical states from environmental bit-flip errors and demonstrate the suppression of these errors with increasing system size. We use a linear array of nine qubits, which is a natural precursor of the two-dimensional surface code QEC scheme, and track errors as they occur by repeatedly performing projective quantum non-demolition (QND) parity measurements. Relative to a single physical qubit, we reduce the failure rate in retrieving an input state by a factor of 2.7 for five qubits and a factor of 8.5 for nine qubits after eight cycles. Additionally, we tomographically verify preservation of the non-classical Greenberger-Horne-Zeilinger (GHZ) state. The successful suppression of environmentally-induced errors strongly motivates further research into the many exciting challenges associated with building a large-scale superconducting quantum computer., Comment: Main text 5 pages, 4 figures. Supplemental 25 pages, 31 figures

Many superconducting qubits are highly sensitive to dielectric loss, making the fabrication of coherent quantum circuits challenging. To elucidate this issue, we characterize the interfaces and surfaces of superconducting coplanar waveguide resonators and study the associated microwave loss. We show that contamination induced by traditional qubit lift-off processing is particularly detrimental to quality factors without proper substrate cleaning, while roughness plays at most a small role. Aggressive surface treatment is shown to damage the crystalline substrate and degrade resonator quality. We also introduce methods to characterize and remove ultra-thin resist residue, providing a way to quantify and minimize remnant sources of loss on device surfaces.

Faster and more accurate state measurement is required for progress in superconducting qubit experiments with greater numbers of qubits and advanced techniques such as feedback. We have designed a multiplexed measurement system with a bandpass filter that allows fast measurement without increasing environmental damping of the qubits. We use this to demonstrate simultaneous measurement of four qubits on a single superconducting integrated circuit, the fastest of which can be measured to 99.8% accuracy in 140 ns. This accuracy and speed is suitable for advanced multiqubit experiments including surface-code error correction.

Superconducting microwave circuits based on coplanar waveguides (CPW) are susceptible to parasitic slotline modes which can lead to loss and decoherence. We motivate the use of superconducting airbridges as a reliable method for preventing the propagation of these modes. We describe the fabrication of these airbridges on superconducting resonators, which we use to measure the loss due to placing airbridges over CPW lines. We find that the additional loss at single photon levels is small, and decreases at higher drive powers., 8 pages and 7 figures including supplementary information

We demonstrate a planar, tunable superconducting qubit with energy relaxation times up to 44 microseconds. This is achieved by using a geometry designed to both minimize radiative loss and reduce coupling to materials-related defects. At these levels of coherence, we find a fine structure in the qubit energy lifetime as a function of frequency, indicating the presence of a sparse population of incoherent, weakly coupled two-level defects. This is supported by a model analysis as well as experimental variations in the geometry. Our `Xmon' qubit combines facile fabrication, straightforward connectivity, fast control, and long coherence, opening a viable route to constructing a chip-based quantum computer., Comment: 10 pages, 9 figures, including supplementary material

We demonstrate a lumped-element Josephson parametric amplifier, using a single-ended design that includes an on-chip, high-bandwidth flux bias line. The amplifier can be pumped into its region of parametric gain through either the input port or through the flux bias line. Broadband amplification is achieved at a tunable frequency $\omega/2 \pi$ between 5 to 7 GHz with quantum-limited noise performance, a gain-bandwidth product greater than 500 MHz, and an input saturation power in excess of -120 dBm. The bias line allows fast frequency tuning of the amplifier, with variations of hundreds of MHz over time scales shorter than 10 ns.

We demonstrate a superconducting resonator with variable coupling to a measurement transmission line. The resonator coupling can be adjusted through zero to a photon emission rate 1000 times the intrinsic resonator decay rate. We demonstrate the catch and release of photons in the resonator, as well as control of nonclassical Fock states. We also demonstrate the dynamical control of the release waveform of photons from the resonator, a key functionality that will enable high-fidelity quantum state transfer between distant resonators or qubits.

A quantum processor (QuP) can be used to exploit quantum mechanics to find the prime factors of composite numbers[1]. Compiled versions of Shor's algorithm have been demonstrated on ensemble quantum systems[2] and photonic systems[3-5], however this has yet to be shown using solid state quantum bits (qubits). Two advantages of superconducting qubit architectures are the use of conventional microfabrication techniques, which allow straightforward scaling to large numbers of qubits, and a toolkit of circuit elements that can be used to engineer a variety of qubit types and interactions[6, 7]. Using a number of recent qubit control and hardware advances [7-13], here we demonstrate a nine-quantum-element solid-state QuP and show three experiments to highlight its capabilities. We begin by characterizing the device with spectroscopy. Next, we produces coherent interactions between five qubits and verify bi- and tripartite entanglement via quantum state tomography (QST) [8, 12, 14, 15]. In the final experiment, we run a three-qubit compiled version of Shor's algorithm to factor the number 15, and successfully find the prime factors 48% of the time. Improvements in the superconducting qubit coherence times and more complex circuits should provide the resources necessary to factor larger composite numbers and run more intricate quantum algorithms., 5 pages, 3 figures

Superconducting qubits probe environmental defects such as non-equilibrium quasiparticles, an important source of decoherence. We show that "hot" non-equilibrium quasiparticles, with energies above the superconducting gap, affect qubits differently from quasiparticles at the gap, implying qubits can probe the dynamic quasiparticle energy distribution. For hot quasiparticles, we predict a non-neligable increase in the qubit excited state probability P_e. By injecting hot quasiparticles into a qubit, we experimentally measure an increase of P_e in semi-quantitative agreement with the model and rule out the typically assumed thermal distribution., Comment: Main paper: 5 pages, 5 figures. Supplement: 1 page, 1 figure, 1 table. Updated to user-prepared accepted version. Key changes: Supplement added, Introduction rewritten, Figs.2,3,5 revised, Fig.4 added

We measure the dependence of qubit phase coherence and flux noise on inductor loop geometry. While wider inductor traces change neither the flux noise power spectrum nor the qubit dephasing time, increased inductance leads to a simultaneous increase in both. Using our new tomographic protocol for measuring low frequency flux noise, we make a direct comparison between the flux noise spectrum and qubit phase decay, finding agreement within 10% of theory.

Losses in superconducting planar resonators are presently assumed to predominantly arise from surface-oxide dissipation, due to experimental losses varying with choice of materials. We model and simulate the magnitude of the loss from interface surfaces in the resonator, and investigate the dependence on power, resonator geometry, and dimensions. Surprisingly, the dominant surface loss is found to arise from the metal-substrate and substrate-air interfaces. This result will be useful in guiding device optimization, even with conventional materials., Main paper: 4 pages, 4 figures, 1 table. Supplementary material: 4 pages, 2 figures, 1 table

We present a systematic study of the properties of room temperature deposited TiN films by varying the deposition conditions in an ultra-high-vacuum reactive magnetron sputtering chamber. By increasing the deposition pressure from 2 to 9 mTorr while keeping a nearly stoichiometric composition of Ti1−xNx (x = 0.5) without substrate heating, the film resistivity increases, the dominant crystal orientation changes from (100) to (111), grain boundaries become clearer, and the strong compressive in-plane strain changes to weak tensile in-plane strain. The TiN films absorb a high concentration of contaminants including hydrogen, carbon, and oxygen when they are exposed to air after deposition. With the target–substrate distance set to 88 mm the contaminant levels increase from ∼0.1% to ∼10% as the pressure is increased from 2 to 9 mTorr. The contaminant concentrations also correlate with in-plane distance from the center of the substrate and increase by roughly two orders of magnitude as the target–substrate distance is increased from 88 to 266 mm. These contaminants are found to strongly influence the properties of TiN thin films. For instance, the resistivity of stoichiometric films increases by around a factor of 5 as the oxygen content increases from 0.1% to 11%. These results strongly suggest that the energy of the sputtered TiN particles plays a crucial role in determining the TiN film properties, and that it is important to precisely control the energy of these particles to obtain high-quality TiN films. Superconducting coplanar waveguide resonators made from a series of nearly stoichiometric films grown at pressures from 2 to 7 mTorr show a substantial increase in intrinsic quality factor from ∼104 to ∼106 as the magnitude of the compressive strain decreases from nearly 3800 MPa to approximately 150 MPa and the oxygen content increases from 0.1% to 8%. Surprisingly, the films with a higher oxygen content exhibit lower loss, but care must be taken when depositing at room temperature to avoid nonuniform oxygen incorporation, which presents as a radially dependent resistivity and becomes a radially dependent surface inductance in the superconductor.

We find that quasiparticle generation from stray infrared light creates a significant loss mechanism in superconducting resonators and qubits. We show that resonator quality factors and qubit energy relaxation times are limited by a quasiparticle density of approximately 200 μm−3, induced by 4 K blackbody radiation from the environment. We demonstrate how this influence can be fully removed by isolating the devices from the radiative environment using multistage shielding.