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1. New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air

Author

Per-Fredrik Larsson, Peter Astvik, and Per-Ola Norrby

Subjects
copper, cross coupling, hyperactivity, kinetics, ligands, Science, Organic chemistry, QD241-441
Abstract

A new efficient ligand, N,N’’-dimethyldiethylene triamine (DMDETA), has been synthesized and evaluated for sub-mol % copper-catalyzed C–N cross-coupling reactions. The efficiency of the ligand was determined by kinetic methods. DMDETA proved to display efficiency similar to DMEDA and, in addition, the resulting catalyst was tolerant to air.

Published
2012
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