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Intentional binding (IB) is the experience of temporal interval compression between voluntary actions and subsequent events when the latter are perceived to be caused on purpose by the agent's actions. It can be measured experimentally by comparing the judgments of temporal intervals between either a voluntary act or an external event, and a later sensory consequence. Evidence suggests this might be modulated by the emotional valence of the consequence. However, controversies have arisen over the consistency of the results and the methodology they were obtained with. Here, we aimed to measure this affective modulation using a two-interval forced-choice (2AFC) discrimination task and word stimuli. Three factors were employed: agency (agency and passive), emotional valence (neutral, positive, and negative words), and interval duration ratio determined based on individual values of just noticeable differences (JND). Participants had to judge which of two intervals presented in each trial was shorter. Generalized linear mixed model analysis indicated that there was an effect of IB, but no affective modulation. Dissociation of component mechanisms of SoA are discussed to better understand results and suggest further directions.

The 18 O/16 O ratio of the subcontinental mantle has decreased by 0.2‰, while crustal values increased by 4‰ via fluid transfer since the Archean due to the initiation of plate tectonics and subduction, in line with the crust-upper mantle mass balance

Changes in the control of developmental gene expression patterns have been implicated in the evolution of animal morphology. However, the genetic mechanisms underlying complex morphological traits remain largely unknown. Here we investigated the molecular mechanisms that induce the pigmentation gene yellow in a complex color pattern on the abdomen of Drosophila guttifera. We show that at least five developmental genes may collectively activate one cis-regulatory module of yellow in distinct spot rows and a dark shade to assemble the complete abdominal pigment pattern of Drosophila guttifera. One of these genes, wingless, may play a conserved role in the early phase of spot pattern development in several species of the quinaria group. Our findings shed light on the evolution of complex animal color patterns through modular changes of gene expression patterns.

Abstract The water solubility in olivine C H 2 O $$ \left({C}_{{\mathrm{H}}_2\mathrm{O}}\right) $$ has been investigated at 1050 °C and 3 GPa as a function of water activity a H 2 O $$ \left({a}_{{\mathrm{H}}_2\mathrm{O}}\right) $$ at subsolidus conditions in the piston-cylinder apparatus, with a H 2 O $$ {a}_{{\mathrm{H}}_2\mathrm{O}} $$ varied using H2O–NaCl fluids. Four sets of experiments were conducted to constrain the effect of a H 2 O $$ {a}_{{\mathrm{H}}_2\mathrm{O}} $$ on the four main substitution mechanisms. The experiments were designed to grow olivine in situ and thus achieve global equilibrium (G-type), as opposed to hydroxylating olivine with a pre-existing point-defect structure and impurity content (M-type). Olivine grains from the experiments were analysed with polarised and unpolarised FTIR spectroscopy, and where necessary, the spectra have been deconvoluted to quantify the contribution of each substitution mechanism. Olivine buffered with magnesiowüstite produced absorbance bands at high wavenumbers ranging from 3566 to 3612 cm−1. About 50% of the total absorbance was found parallel to the a-axis, 30% parallel to the b-axis and 20% parallel to the c-axis. The total absorbance and hence water concentration in olivine follows the relationship of C H 2 O ∝ a H 2 O 2 $$ {C}_{{\mathrm{H}}_2\mathrm{O}}\propto {a_{{\mathrm{H}}_2\mathrm{O}}}^2 $$ , indicating that the investigated defect must involve four H atoms substituting for one Si atom (labelled as [Si]). Forsterite buffered with enstatite produced an absorbance band exclusively aligned parallel the c-axis at 3160 cm−1. The band position, polarisation and observed C H 2 O ∝ a H 2 O $$ {C}_{{\mathrm{H}}_2\mathrm{O}}\propto {a}_{{\mathrm{H}}_2\mathrm{O}} $$ are consistent with two H substituting for one Mg (labelled as [Mg]). Ti-doped, enstatite-buffered olivine displays absorption bands, and polarisation typical of Ti-clinohumite point defects where two H on the Si-site are charge-balanced by one Ti on a Mg-site (labelled as [Ti]). This is further supported by C H 2 O ∝ a H 2 O $$ {C}_{{\mathrm{H}}_2\mathrm{O}}\propto {a}_{{\mathrm{H}}_2\mathrm{O}} $$ and a 1:1 relationship of molar H2O and TiO2 in these experiments. Sc-doped, enstatite-buffered experiments display a main absorption band at 3355 cm−1 with C H 2 O ∝ a H 2 O 0.5 $$ {C}_{{\mathrm{H}}_2\mathrm{O}}\propto {a_{{\mathrm{H}}_2\mathrm{O}}}^{0.5} $$ and a positive correlation of Sc and H, indicating the coupled substitution of a trivalent cation plus a H for two Mg (labelled as [triv]). Our data demonstrate that extreme care has to be taken when inferences from experiments conducted at a H 2 O = 1 $$ {a}_{{\mathrm{H}}_2\mathrm{O}}=1 $$ are applied to the mantle, where in most cases, a low a H 2 O $$ {a}_{{\mathrm{H}}_2\mathrm{O}} $$ persists. In particular, the higher exponent of the [Si] substitution mechanism means that the contribution of this hydrous defect to total water content will decrease more rapidly with decreasing a H 2 O $$ {a}_{{\mathrm{H}}_2\mathrm{O}} $$ than the contributions of the other substitution mechanisms. The experiments confirm previous results that the [Mg] mechanism holds an almost negligible amount of water under nearly all T-P-fO2-fH2O conditions that may be anticipated in nature. However, the small amounts of H2O we find in substituting by this mechanism are similar in the experiments on forsterite doped with either Sc or Ti to those in the undoped forsterite at equivalent a H 2 O $$ {a}_{{\mathrm{H}}_2\mathrm{O}} $$ (all buffered by enstatite), confirming the assumption that, thermodynamically, C H 2 O $$ {C}_{{\mathrm{H}}_2\mathrm{O}} $$ substituting by each mechanism does not depend on the water concentration that substitutes by other mechanisms.

Investigations in the temporal estimation domain are quite vast in the range of milliseconds, seconds, and minutes. This study aimed to determine the psychophysical function that best describes long-range time interval estimation and evaluate the effect of numerals in duration presentation on the form of this function. Participants indicated on a line the magnitude of time intervals presented either as a number + time-unit (e.g., “9 months”; Group I), unitless numerals (e.g., “9”; Group II), or tagged future personal events (e.g., “Wedding”; Group III). The horizontal line was labeled rightward (“Very short” = >“Very long”) or leftward (“Very long” = >“Very short”) for Group I and II, but only rightward for Group III. None of the linear, power, logistic or logarithmic functions provided the best fit to the individual participant data in more than 50% of participants for any group. Individual power exponents were different only between the tagged personal events (Group III) and the other two groups. When the same analysis was repeated for the aggregated data, power functions provided a better fit than other tested functions in all groups with a difference in the power function parameters again between the tagged personal events and the other groups. A non-linear mixed effects analysis indicated a difference in the power function exponent between Group III and the other groups, but not between Group I and II. No effect of scale directionality was found in neither of the experiments in which scale direction was included as independent variable. These results suggest that the judgment of intervals in a number + time-unit presentation invoke, at least in part, processing mechanisms other than those used for time-domain. Consequently, we propose the use of event-tagged assessment for characterizing long-range interval representation. We also recommend that analyses in this field should not be restricted to aggregated data given the qualitative variation between participants.

The diffusivity and diffusion mechanisms of hydrogen together with with deuterium and lithium, parallel to the c axis of quartz, were investigated experimentally at 800°C, 0.1 GPa with the activity of H2O or 2H2O ≈ 1 [2H is used throughout this work to describe deuterium rather than D, to avoid confusion with the diffusion coefficient, D]. The pH was set using mixtures of H2O (or 2H2O) and HCl. Three types of experiment were conducted: (1) H-in/Li-out; (2) 2H-in/H-out; and (3) 2H-in/H + Li out, using three different natural quartz crystals as starting materials. Profiles of H, 2H and Li were measured using Fourier-transform infrared (FTIR) spectroscopy and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). H, 2H and Li are charge-compensated by Al3+ replacing Si4+, or by excess O2–. The total atomic concentration of monovalent cations appears to remain constant over the duration of the experiments. The resulting diffusion profiles are different for the three experimental designs and three starting materials, and some show complex shapes inconsistent with simple diffusion. A multi-site diffusion–reaction model is developed, with the theory based on previous models that have been derived mainly on the basis of conductivity measurements. In these models, the monovalent cations move away from their charge-balancing ion then diffuse rapidly to another site. The mobility of the monovalent cations is described by both a diffusion coefficient and an equilibrium constant that enables dissociation of the immobile charge-balanced defects. This model can describe complex step-shaped profiles formed in H-in/Li-out experiments, profiles with local maxima ('humped' profiles) in 2H-in/H + Li out experiments, and error function-shaped profiles in 2H-in/H-out and previously published Li-in/H-out experiments. Our data provide support for models previously proposed for quartz. Studies of the lengths and forms of diffusion profiles from such experiments provide a useful complement to assertions from conductivity experiments. [ABSTRACT FROM AUTHOR]