Search

Copper-based ternary metal oxide (i.e., Cu0.52Al0.01Fe0.47O4) impregnated reduced graphene oxide nanohybrid is verified for microbial and arsenic treatment. Growth inhibition of colonies are observed around 99.99% (E. coli), and 99.83% (S. aureus) at 10–20 μg/mL of hybrid dosage, respectively. The inhibition rates for both the colonies are increased to 99.9998% at 80 μg/mL. TEM images have shown insight of cell-content/lipid leakage behavior after inoculating with the hybrid. The efficient hindrance towards microbial colony growth is attributed to better charge transfer, reactive oxygen species generation, and metal-ion release. Maximum arsenic sorption capacities are observed around 248 and 314 mg/g for As(III), and As(V), respectively (Ci ~ 500 ppm). Surface morphology studies onto arsenic adsorption are reported with atomic force microscope, and FT-IR/Raman analysis. A detailed discussion onto individual spectra of As 3d spectra confirmed the occurrence of redox transformation in arsenic species [As(III)]. The variation in the quantity (at. %) of oxygen functional groups in O1s spectra (i.e., M–O, M-OH, and -OH2) onto the hybrid supported the ligand-exchange behavior. Cyclic voltammetry study in arsenic electrolytes (10 µM – 1 mM) provides the occurrence of various in-situ electrochemical reactions supporting the redox activity. A significant electromagnetic wave absorption characteristics of the present hybrid is proposed with plausible airborne antimicrobial-agent abilities. [ABSTRACT FROM AUTHOR]

Arsenic [As(III) and As(V)] adsorption on aluminum substituted cobalt ferrite (Co-Al-Fe) ternary metal oxide adsorbent is reported by means of qualitative and quantitative spectroscopy tools. IR and Raman active signals were observed around 810-920 cm -1 band indicate different As-OH complexed and As-O uncomplexed stretching vibrations on to the adsorbent. The adsorption behavior of arsenic (III and V) onto these adsorbents is studied as a function of contact time, different concentrations, and pH conditions. The kinetics study on adsorption were performed to understand nature of adsorption which supports the Pseudo Second Order (PSO) model. The adsorption isotherms study indicates Freundlich type of adsorption. The maximum adsorption capacity of Co-Al-Fe adsorbent is observed around 130 and 76 mg g -1 for As(III) and As(V) systems, respectively. Detailed XPS study of As 3d, Fe 2p, Co 2p, and O 1s spectra has been reported in explaining the redox behavior and ligand exchange reactions in supporting arsenic adsorption mechanism.