Search

Water remediation has become a hot subject of study due to textile, pharmaceutical, and agricultural discharge to the water bodies. Photocatalysis with photocatalyst having favorable structure, reduced charge carrier recombination and ability to harness UV–Visible spectrum has emerged as efficient way to completely mineralize the persistent organic pollutants (POPs) (Sharma et al. in J Environ Chem Eng 9(5):105812, 2021; Chawla et al. in Coord Chem Rev 491:215246, 2023). In this research, we reported the synthesis of SnO2/Fe2O3/MoS2 ternary composite. The motive of the composite formation is to harvest the entire solar spectrum with prolonged electron–hole recombination. The band gap has reduced from 3.46 to 2.30 eV with the formation of SnO2/Fe2O3/MoS2 ternary composite. The ternary composite exhibited an excellent photocatalytic activity of 95% against Congo red after 80 min at a rate constant of 0.018 min−1. Moreover, the composite showed a photocatalytic activity of 85% and 93% against diclofenac sodium and pendimethalin at a rate constant of 0.017 min−1 and 0.02 min−1 respectively. Through trapping experiments, we determined that hydroxyl radicals scavenging had reduced the photocatalytic degradation of Congo red, diclofenac sodium and pendimethalin to 25%, 22%, and 15% respectively. Beyond its exceptional photocatalytic degradation capabilities, the SnO2/Fe2O3/MoS2 ternary composite also ushered in new possibilities for utilizing wide band gap materials reinforced with visible light active materials along with 2-D materials. [ABSTRACT FROM AUTHOR]

Herbicides are often detected in aquatic ecosystems due to residential and agricultural applications and can harm aquatic organisms once deposited into water systems. Pendimethalin is part of the dinitroaniline chemical family and is applied to crops like corn, legumes, potatoes, and soybeans. The potential toxicity of pendimethalin to aquatic species is understudied compared to other widely studied herbicides, like atrazine and glyphosate. The objectives of this review were to (1) collate information on sub-lethal responses to pendimethalin exposure in fish, (2) evaluate how exposure studies relate to environmental concentrations, and (3) identify putative bioindicators for exposure studies. Overall, studies reporting pendimethalin in water systems worldwide indicate a range of 100–300 ng/L, but levels have been reported as high as ~15 µg/g in sediment. In teleost fish, studies demonstrate developmental toxicity, immunotoxicity, and behavioral disruptions. The strongest evidence for pendimethalin-induced toxicity involves oxidative stress, although studies often test toxicity at higher concentrations than environmentally relevant levels. Using the Comparative Toxicogenomics Database, pathway analysis reveals linkages to neurotoxicity and mechanisms of neurodegeneration like "Ubiquitin Dependent Protein Degradation", "Microtubule Cytoskeleton", "Protein Oxidation and Aggregation in Aging", and "Parkinson's Disease". Other prominent pathways included those related to mTOR signaling and reproduction. Thus, two potential mechanisms underlying pendimethalin-induced toxicity in fish include the neural and reproductive systems. This review synthesizes current data regarding environmental fate and ecotoxicology of pendimethalin in teleost fish and points to some putative physiological and molecular responses that may be beneficial for assessing toxicity of the herbicide in future investigations. [ABSTRACT FROM AUTHOR]

A field trial was conducted to investigate the ‘Phytotoxicity of pendimethalin on the emergence of seedlings in direct seeded rice (DSR) across different concentrations’ during the Kharif season of 2022 at the experimental farm of the School of Agriculture, Lovely Professional University, Phagwara, Punjab. The experiment was conducted using a randomized block design with five treatments using different doses of pendimethalin (1600, 1800, 2000, and 2200 gram active ingredient per hectare (g ai per ha), and control (untreated)). Application of pendimethalin at 1600 g ai per ha resulted in a significantly higher number of seedlings than other treatment groups. The lowest number of seedlings was observed in the 2200 g ai per ha treatment group. The number of microbes present was optimal during the treatment with 1600 g ai per ha pendimethalin. With an increase in the dosage of pendimethalin, a decrease in the count of soil microbes was observed, with the lowest microbial count observed with the highest dose of pendimethalin, i.e., 2200 g ai per ha. No phytotoxic effect was observed in the DSR treated with pendimethalin at 1600 g ai per ha. Therefore the present study has to be obtain the appropriate use of dosage to inhibit the toxicity of herbicide as well as maintain the soil fertility and microbial growth.

Traditional pesticide emulsion formulation may exert deleterious effects on the environment and even induce stress on nontarget crops in the vicinity. In this study, γ-cyclodextrin (γ-CD)-encapsulated azobenzene derivative nanovesicles were synthesized and loaded with pendimethalin to obtain pendimethalin-loaded γ-CD/azobenzene derivative nanovesicles. Upon exposure to ultraviolet irradiation or sunlight, the azobenzene derivatives are converted from the trans- to cis- configuration, leading to the dissociation of the ternary host–guest complexes, resulting in the vesicle rupture and the subsequent release of pendimethalin. Further investigations were conducted on the γ-CD/azobenzene nanovesicles. According to the release characteristics of herbicides, the release rate of pendimethalin under ultraviolet light (365 nm) or sunlight conditions reached 88.3 ± 3%, which was 4.3 times higher than that under dark conditions, demonstrating excellent photocontrolled release behavior. Pot experiments showed that the herbicidal activity of pendimethalin-loaded nanovesicles against Portulaca oleracea (L.) and Echinochloa crusgalli (L.) Beauv. at the recommended dose was comparable to that of the pendimethalin technical under illuminated conditions. Furthermore, genotoxicity experiments reveal a notable increase in the mitotic index of onion root tip cells treated with pendimethalin-loaded nanovesicles, indicating that it had minimal inhibitory effect on cell metabolism and the genotoxicity was lower than that of pendimethalin technical. Pendimethalin-loaded nanovesicles exhibited favorable stability and photoresponsive performance. These findings reveal a promising avenue for responsive material design and release modulation using such nanovesicle systems, providing insights into their potential applications in targeted pesticide delivery systems. [ABSTRACT FROM AUTHOR]

A field trial was conducted to investigate the ‘Phytotoxicity of pendimethalin on the emergence of seedlings in direct seeded rice (DSR) across different concentrations’ during the Kharif season of 2022 at the experimental farm of the School of Agriculture, Lovely Professional University, Phagwara, Punjab. The experiment was conducted using a randomized block design with five treatments using different doses of pendimethalin (1600, 1800, 2000, and 2200 gram active ingredient per hectare (g ai per ha), and control (untreated)). Application of pendimethalin at 1600 g ai per ha resulted in a significantly higher number of seedlings than other treatment groups. The lowest number of seedlings was observed in the 2200 g ai per ha treatment group. The number of microbes present was optimal during the treatment with 1600 g ai per ha pendimethalin. With an increase in the dosage of pendimethalin, a decrease in the count of soil microbes was observed, with the lowest microbial count observed with the highest dose of pendimethalin, i.e., 2200 g ai per ha. No phytotoxic effect was observed in the DSR treated with pendimethalin at 1600 g ai per ha. Therefore the present study has to be obtain the appropriate use of dosage to inhibit the toxicity of herbicide as well as maintain the soil fertility and microbial growth. [ABSTRACT FROM AUTHOR]

Alternanthera bettzickiana is an invasive weed which has now attained the status of a major weed in several upland crops in Kerala. Field experiments were conducted in 2021 and 2022 to study the efficacy of various pre- emergence and post- emergence herbicides in controlling the weed in oriental pickling melon. Ten treatments included pre-emergence spray of oxyfluorfen and pendimethalin, post-emergence application of 2,4-D and metsulfuron methyl+ chlorimuron ethyl, oxyfluorfen and pendimethalin followed by 2,4-D and metsulfuron methyl+ chlorimuron ethyl, hand weeding at 20 and 40 DAS and unweeded control. Randomized block design was adopted and all the treatments were replicated thrice. Results indicated that dry matter production of A. bettzickiana, total weed dry matter production and nutrient uptake by weeds were significantly lower with pre-emergence application of oxyfluorfen followed by post-emergence application of 2,4-D or metsulfuron methyl+ chlorimuron ethyl and were on par with hand weeding at 20 DAS and 40 DAS. These treatments also resulted in higher crop growth, mean fruit weight and fruit yield. At 30 DAS, the same treatments as well as pre- emergence oxyfluorfen resulted in higher weed control efficiency, while at 60 DAS, only the combined pre- and post- emergence application of oxyfluorfen followed by 2,4-D or metsulfuron methyl+ chlorimuron ethyl resulted in higher weed control efficiency. The combinations also recorded lower weed index and higher net return and B: C ratio. [ABSTRACT FROM AUTHOR]

Weeds are a major cause of yield and quality loss in sunflower (Helianthus annuus L.) crops. Therefore, weed control is important in sunflower production. In this context, the study was conducted in 2023 to determine the effectiveness of pre-emergence and post-emergence herbicides with different modes of action on weed population, dry weight of weeds and sunflower yield and yield components in sunflower. Four herbicides with different modes of action, three pre-emergence (aclonifen (A), pendimethalin (P), linuron (L) and one post-emergence (quizalofop-p-ethyl) (Q) and combinations of these herbicides were used in the study. To determine the effects of herbicides on weed populations and species, four different assessments were conducted at regular intervals. As a result of the study, a total of 10 weed species belonging to 5 families were detected in the trial area. The weed species with the highest density were Sorghum halepense (L.) Pers., Xanthium strumarium L., Convolvulus arvensis L. and Chenopodium album L. The study found that the effects of herbicides on weed populations and species varied. In the study, the highest rates of weed control were achieved in plots where both pre-emergence and post-emergence herbicides were used together. The highest weed control rate was observed in plots P+Q (96.66%). The highest effect on weed dry weight was obtained in plot L+Q with a rate of 89.63%. The highest weed dry weight was recorded in the weedy control plots. In the study, the highest yield (287.53 kg da-1) was obtained in the weed-free (hoe) control plot. Yield increases of 18% to 45% can be achieved by controlling weeds in sunflowers. As a result, herbicide efficacy on weed population and dry weight of weeds increased when herbicides were used in combination. Some herbicides have been shown to increase yields when used alone. However, it is important to use herbicides in combination to control more weed populations and prevent a potential resistance problem. [ABSTRACT FROM AUTHOR]

Copyright of Xinjiang Agricultural Sciences is the property of Xinjiang Agricultural Sciences Editorial Department and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Losses caused by the presence of weeds in an agricultural business are often associated with the ability of weeds as strong competitors for plants to obtain water, nutrients, sunlight, and growing space. A mixture of metolachlor and pendimethalin herbicides is expected to control important weeds of various classes in coffee plants. The purpose of the research was to determine the effect of two herbicide mixtures at different doses on weeds in coffee plantations. This research used a 4 X 4 factorial randomized block design with 2 repetitions, resulting in 32 experimental plots. The first factor was metolachlor herbicide and the second was pendimethalin herbicide, each factor consisting of 4 levels with 0.00, 0.75, 1.75 and 2.25 kg ha-1 doses. The observed parameters consisted of (1) dominance count value, (2) percentage of controlled weeds, (3) weed coverage, (4) weed population, and (5) weed dry weight. The results showed that there was a very significant effect on the combined interaction of metolachlor and pendimethalin herbicide mixtures on the percentage of controlled weeds, percentage of weed closure at 21 and 28 DAA, and weed dry weight at 28 and 42 DAA with the best dose combination at b.a. 1.50 kg ha-1 which could increase the efficiency of weed control. Meanwhile, the percentage of controlled weeds, percentage of weed cover at 14 DAA, and weed population at 28 and 42 DAA showed very significant results independently with a dose of b.a. 2.25 kg ha-1. [ABSTRACT FROM AUTHOR]

Field experiments were carried out during Rabi season 2020–21 and 2021–22 at Agronomy Research Farm, CCS HAU, Hisar, for the management of multiple herbicide-resistant Phalaris minor in wheat. Experiment was performed using randomized block design and replicated thrice with a total number of 15 treatment consisting of different combination of pre (PRE) and post-emergence (POST) herbicides. Herbicides selected in this study have different modes of action, i.e. clodinafop and pinoxaden are acetyl-CoA carboxylase (ACCase) inhibitors, sulfosulfuron, mesosulfuron, iodosulfuron and metsulfuron belongs to acetolactate synthase (ALS)/Acetohydroxy acid synthase (AHS) inhibitor group, pendimethalin and pyraxosulfone inhibits the microtubule assembly and long chain fatty acids synthesis, respectively, while metribuzin is Photosystem-II (PS-II) inhibitor and flumioxazin is from protoporphyrinogen oxidase (PPO) inhibitor group. Among different treatments, application of flumioxazin + pendimethalin fb clodinafop propargyl + metribuzin (RM) resulted in significantly lower density and dry weight of P. minor and broadleaved weeds and maximum weed control efficiency at 60 DAS. It was statistically comparable to application of flumioxazin, flumioxazin + pendimethalin, pyroxasulfone + pendimethalin fb mesosulfuron + iodosulfuron (RM), or pinoxaden + metsulfuron (TM) or clodinafop propargyl + metribuzin. Sequential application of pyroxasulfone + pendimethalin (TM) fb mesosulfuron + iodosulfuron (RM) resulted in significantly higher grain yield (5847 and 5369 kg/ha) when compared to rest of the treatments. It was statistically comparable to PRE pyroxasulfone + pendimethalin (TM) fb POST pinoxaden + metsulfuron (TM) or clodinafop propargyl + metribuzin (RM). In conclusion, pre-emergence application of pyroxasulfone + pendimethalin (TM) followed by post-emergence application of either mesosulfuron + iodosulfuron (RM), pinoxaden + metsulfuron (TM) or clodinafop propargyl + metribuzin resulted in better control of resistant P. minor and broadleaved weeds along with higher grain yield. [ABSTRACT FROM AUTHOR]

Limited preemergence herbicides are registered for new blackberry (Rubus subgenus Rubus) plantings. This greenhouse experiment was designed to investigate the effects of a broad selection of preemergence herbicides at multiple rates on blackberry transplants. Screening was initiated Aug 2021 and repeated Mar 2022 in Fayetteville, AR, USA, in a greenhouse at the Milo J. Shult Agricultural Research and Extension Center. ‘Ouachita’ blackberry plugs were transplanted into utility pots that contained field soil and growth media treated with preemergence herbicides. After transplanting, plant height was measured from the substrate to the highest apical meristem of 25 representative plants. Initial blackberry plant heights were 13.5 and 9.2 cm in 2021 and 2022, respectively. Twenty-five treatments were evaluated, consisting of 12 preemergence herbicides at 1× and 2× field rates, and one untreated control. Herbicide treatments included diuron, flumioxazin, halosulfuron, indaziflam, mesotrione, napropamide, oryzalin, pendimethalin, rimsulfuron, S-metolachlor, simazine, and sulfentrazone applied to substrate in containers at their respective 1× or 2× field rates. Data were collected on plant height, blackberry injury ratings, internode length, leaf chlorophyll content, and destructive harvest, including leaf count, leaf dry biomass, and aboveground dry biomass. Specific leaf areas and leaf area-to-dry matter ratios were calculated. When observed, plant injury tended to increase from 7 days after treatment (DAT) until 42 DAT. Greater injury levels were observed in response to treatment with mesotrione at the 1× (78%) and 2× rates (90%), halosulfuron at the 1× rate (58%), halosulfuron at the 2× rate (68%), and diuron at the 2× rate (73%). Injury from diuron was rate dependent, with the 1× rate causing relatively low injury (19%). At both the 1× and 2× rates, flumioxazin, indaziflam, napropamide, S-metolachlor, and pendimethalin treatments exhibited similar responses to the untreated control.

Copyright of Modern Food Science & Technology is the property of Editorial Office of Modern Food Science & Technology and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

In this research, pendimethalin was synthesized by a two-step reaction with N-(1-Ethylpropyl)− 3,4-dimethylaniline as raw material and nitric acid as nitration reagent. The research focused on the second-step reaction, which was far more dangerous than the first-step. The effects of reaction temperature (T p), feeding time (t), stirring rate (SR) and nitric acid concentration (φ) on the yield and thermal hazard of the second step reaction were explored by experiments. The optimal process conditions were obtained. In addition, concentration variation of each component during the reaction were monitored by using HPLC for intermediate sampling. Combined with the theoretical calculation, the possible reaction mechanism was deduced. The reaction can be divided into two main paths according to the sequence of nitro substitution. In one of these paths the nitro group replaced the H first at position 2 and then at position 6, while in the other path it was completely reversed. Both paths eventually produced pendimethalin. Finally, the thermal hazard was analyzed by Stoessel criticality diagram. The risk levels for the two-step reaction were level 1 and level 3, respectively. This study provides theoretical support for the safe production of the nitration and synthesis of pendimethalin. [ABSTRACT FROM AUTHOR]

Weed control poses substantial difficulties for winter season onion (Allium cepa L.) cultivation in the north-western Indo-Gangetic Plains, primarily due to the constrained efficacy of the existing herbicides. To address this issue, a 2-year field study was conducted to assess the efficacy of pre- and post-emergence herbicides (pendimethalin, ethoxysulfuron, imazethapyr, and quizalofop-p-ethyl) individually and in combination with crop residue mulch for weed control in winter onion. The results revealed that using herbicides or mulches in isolation did not provide satisfactory weed control. However, the integration of natural mulch with pendimethalin followed by quizalofop-p-ethyl application proved to be the most effective weed control strategy, resulting in the least reduction in bulb yield (10.3%) compared to other treatments. On the contrary, combinations of pendimethalin with ethoxysulfuron or imazethapyr showed adverse effects on the onion crop and inflicted the highest yield losses among all treatments (78.6 and 83.4%, respectively). However, the combination of pendimethalin with quizalofop-p-ethyl coupled with crop mulch resulted in season-long weed control and over 80% bulb yield (36.58 t/ha) gains compared to the weed-free condition. These findings emphasize the efficacy of combining herbicides and mulches as an integrated weed management strategy for onions. By adopting such integrated approaches, farmers could improve weed control while maintaining bulb yield and quality, reducing the risks associated with herbicide resistance, and promoting sustainable onion production in the north-western Indo-Gangetic Plains. [ABSTRACT FROM AUTHOR]

Background: Time of pre-emergence herbicide application is an important factor that decides the efficiency of herbicide. If the preemergence herbicide is not applied at appropriate time, it may cause ineffective weed control or toxicity to crops. With this background, a field experiment was conducted at TNAU, Madurai to optimize the time of pre-emergence herbicides namely pendimethalin and oxyfluorfen application for effective weed management in irrigated blackgram. Methods: The experiment was laid out in randomized block design with three replication. Treatments were application of pendimethalin at 0.75 kg ha-1 and oxyfluorfen at 0.2 kg ha-1 on 1, 2, 3, 4 days after sowing, weed free check and unweeded check. Result: Results of the study revealed that oxyfluorfen gave maximum weed control efficiency as compared to pendimethalin, but toxicity to the crop was observed when oxyfluorfen was sprayed after 2 days of sowing. Yield and economics were achieved higher with application of 0.75 kg ha-1 of pendimethalin at 2 DAS, which was on par with application of 0.2 kg ha-1 of oxyfluorfen at 1 DAS due to lesser toxicity. Application of 0.75 kg ha-1 of pendimethalin and 0.2 kg ha-1 of oxyfluorfen didn’t leave any herbicide residue after harvest. Hence, application of 0.75 kg ha-1 of pendimethalin at 2 DAS and 0.2 kg ha-1 of oxyfluorfen at 1 DAS can be recommended for effective weed management in irrigated balckgram. [ABSTRACT FROM AUTHOR]

Peptidomimetic and anti-immunocomplex peptides can be easily isolated from phage display libraries, and can be used as alternatives to chemical competing haptens to improve the sensitivity of small molecule immunoassay. In this work, 16 peptidomimetics and 7 anti-immunocomplex peptides of pendimethalin (PND) were obtained from cyclic 7-, 8-, 9-, and 10-residue peptide phage libraries. Peptidomimetic EJ-2 (CMFTGTDFPC) with the highest sensitivity in competitive phage enzyme-linked immunosorbent assay (ELISA) and immunocomplex peptide EF-30 (CNPGWPPIPC) with the highest sensitivity in noncompetitive phage ELISA were selected to prepare phage-free peptides with GGGSSK-biotin at the C-terminus. Competitive and noncompetitive lateral flow immunoassays (CLFIA and NLFIA) were developed by using the phage-free peptides. After optimization, the CLFIA and NLFIA showed visual limit of detections (vLODs) of 5 ng/mL and 2.5 ng/mL, respectively, which were improved two- and fourfold compared with a LFIA based on chemical hapten. The NLFIA showed better sensitivity than CLFIA in the detection of spiked samples, and can meet the detection requirements for agro-products regulated by EU and China. The detection results of CLFIA and NLFIA for blind samples were consistent with that of ultra performance liquid chromatography/tandem mass spectrometry. [ABSTRACT FROM AUTHOR]

The aim of the research was to investigate interactions between pendimethalin (PE), an active substance of plant protection products, and the humin fraction (HM), which is the most recalcitrant component of soil organic matter. The soil material used for the study was collected from the mollic horizon of two Chernozems different in physicochemical properties. HM was obtained in the solid state after discarding humic acid (HA) and fulvic acid (FA) and digesting the mineral fraction in an HF-HCl mixture. Pure PE and two commercial products containing the substance (Penfox 330 EC and Stomp Aqua 455 SC), dissolved in hexane and added to the HM, were used in the research. The batch sorption experiment was carried out in accordance with OECD Guidelines for the Testing of Chemicals No.106. Spectroscopic methods (UV-Vis-nearIR and fluorescence) were used to assess the molecular characteristics of HM exposed to pesticides. The study showed significant differences in the molecular structures of the tested HM as a result of interactions with the pesticides used. The results revealed that PE had a different effect than the commercial products, and proved that the composition of commercial products significantly modified the strength and ability of organic matter to bind pesticides. This is probably related to the presence of adjuvants that are more competitive in forming bonds with the active sorption sites of HM, and thus strengthen or weaken the process of forming pesticide-HM complexes. As a result, the diversity of the molecular structure of HM and the presence of accompanying substances in commercial pesticide products interact, leading to different sorption mechanisms and durability of the resulting products. [ABSTRACT FROM AUTHOR]

Introduction: Pendimethalin is an herbicide that is used worldwide to attack certain wide leaf and grassy weeds in a variety of agricultural and non-crop regions, with a claimed very low toxicity to human. There have been some few reported cases of acute pendimethalin toxicity to date, around the world. We report a case of pendimethalin toxicity resembling and managed initially as organophosphorus poisoning. Case Description: A 42-year-old agricultural worker was found unresponsive in his field with profuse oral secretions. The patient presented with altered mental status, where Glasgow comma scale was 10, oxygen saturation at room air was 88 %, Blood pressure measured 125/75, pulse rate was 95 beats per minute, and temperature was 37 °C. The patient’s pupils were constricted, equal, regular, and reactive. Chest examination revealed scattered respiratory crepitations. The patient also had a distinct garlic odor very similar to that of Organophosphate compounds. The results of his laboratory investigations revealed only hypoxemia. The patient received atropine and supportive management, which prompted the chest secretions to clear up and allow him to restore consciousness without experiencing any neurological problems.Conclusion: Pendimethalin toxicity can present with manifestations mimicking acute organophosphorus poisoning. Proper supportive care is needed for the management of acute pendimethalin toxicity.

Weed control poses substantial difficulties for winter season onion (Allium cepa L.) cultivation in the north-western Indo-Gangetic Plains, primarily due to the constrained efficacy of the existing herbicides. To address this issue, a 2-year field study was conducted to assess the efficacy of pre- and post-emergence herbicides (pendimethalin, ethoxysulfuron, imazethapyr, and quizalofop-p-ethyl) individually and in combination with crop residue mulch for weed control in winter onion. The results revealed that using herbicides or mulches in isolation did not provide satisfactory weed control. However, the integration of natural mulch with pendimethalin followed by quizalofop-p-ethyl application proved to be the most effective weed control strategy, resulting in the least reduction in bulb yield (10.3%) compared to other treatments. On the contrary, combinations of pendimethalin with ethoxysulfuron or imazethapyr showed adverse effects on the onion crop and inflicted the highest yield losses among all treatments (78.6 and 83.4%, respectively). However, the combination of pendimethalin with quizalofop-p-ethyl coupled with crop mulch resulted in season-long weed control and over 80% bulb yield (36.58 t/ha) gains compared to the weed-free condition. These findings emphasize the efficacy of combining herbicides and mulches as an integrated weed management strategy for onions. By adopting such integrated approaches, farmers could improve weed control while maintaining bulb yield and quality, reducing the risks associated with herbicide resistance, and promoting sustainable onion production in the north-western Indo-Gangetic Plains.

Beneficial bacteria are used as plant growth promoters in agriculture. The off-target effects of herbicides on beneficial bacteria are needed to be investigated. This study was carried out to determine the positive or negative effects of active compounds of herbicides on the reproduction of beneficial bacteria, Bacillus cereus and Pseudomonas putida. The herbicides used in this study contained active compounds such as Fluazifop-p-buthyl, Pendimethalin and Metribuzin. Effects of the active compounds were evaluated on the bacteria under in vitro, greenhouse and field conditions. Three doses of each active compound were used: the recommended dose (N), twice the recommended dose (2N) and three folds (3N) the recommended dose. It was observed that the increased dose of Pendimethalin, Fluazifop-p-buthyl, Metribuzin had significant effects on B. cereus and P. putida under in vitro conditions. Also, the increased dose of Pendimethalin, Fluazifop-p-buthyl significantly reduced the density of both bacteria. On the other hand, increasing doses of Pendimethalin decreased the density of P. putida, but did not affect that of B. cereus. Under greenhouse conditions, the density of B. cereus was not affected with increased doses of Fluazifop-p-buthyl and Metribuzin while the bacteria concentration were increased with doses of pendimethalin. As the doses of active substances increased, P. putida bacterial density also increased in greenhouse. Under field conditions, the recommended doses of Pendimethalin, Metribuzin did not inhibit B. cereus density, while the dose of Fluazifop-p-buthyl increased the bacterial concentration. Additionally, under similar conditions, Fluazifop-p-buthyl and Metribuzin did not affect P. putida, while Pendimethalin decreased concentration of P putida. In the present study results showed that increased active substances of Pendimethalin, Fluazifop-p-buthyl and Metribuzin are decreasing or increasing the densities of P. putida and B. cereus with dependent on experimental conditions. All these active substances are not eradicating the beneficial bacterial population in soil. It would be appropriate to give some quantitative values of the obtained results in the abstract. [ABSTRACT FROM AUTHOR]

This study is essential for assessing the binding capacity of Prosopis wood biochar to commonly used herbicides, Pretilachlor and Pendimethalin. Understanding their sorption dynamics at varying biochar application rates and exposure times is crucial f or sustainable and effective herbicide management in intensively farming agricultural fields and for reducing environmental contamination. The Prosopis wood biochar was produced in an earthen kiln at 300-350°C. The batch experiment was conducted to study the sorption potential of biochar additions at rates of 0, 5, and 10 t ha-1. The herbicides were added to the homogenized soil-biochar mixes at zero, whole, twice, and four times the recommended dose. The sorption of the herbicides by soil biochar mixture was studied for 12 and 24 hours. The result showed that Pendimethalin sorption increased with biochar application rat e, requiring 24 hours for 95% sorption at 4X dose without biochar (77.95 mg/kg soil) and 12 hours with 10 t/ha biochar (75.82 mg/kg soil). The Kd value increased with biochar application (0.57-77.95 mg/kg soil) and decreased with pendimethalin application (77.95-3.04 mg/kg soil). Maximum sorption (95%) was attained within 12 hours for 1X and 2X rates and 24 hours for 4X rates when biochar was added. This demonstrated that although pendimethalin residue in the soil can be immobilized by adding biochar within 8 hours at lower rates, more than 24 hours were required when pendimethalin was applied at higher rates or repeatedly. Biochar can be used to reduce pendimethalin leaching in agricultural fields, especially sodic soils, at higher applicat ion rates. [ABSTRACT FROM AUTHOR]

In 35 years of routine screening for herbicide resistance, a total of 3758 seed sample/herbicide combinations were assayed. Resistance testing was done in either pots in glasshouses (chlortoluron, fenoxaprop and mesosulfuron‐methyl + iodosulfuron‐methyl sodium) or Petri‐dishes in incubators (sethoxydim, cycloxydim and pendimethalin). With all herbicides, the relationship between herbicide efficacy and year of sampling was linear, with the slope representing the annual loss of efficacy. This was higher for the ALS inhibitors mesosulfuron + iodosulfuron (3.73% year−1) and ACCase inhibitors sethoxydim/cycloxydim (1.92% year−1) and fenoxaprop (1.36% year−1) than for the substituted urea chlorotoluron (0.69% year−1) and the dinitroaniline pendimethalin (1.10% year−1). These results are consistent with other studies on the relative resistance risk associated with these different modes of action. There was also a surprisingly good correlation between results for random and non‐random resistance testing, which has also been found in studies with other weed species in Canada and Australia. This indicates that routine testing of submitted samples can replace, at least partly, the need for random surveys which tend to be both labour intensive and expensive. These results, compiled over 35 years, show the value of routine resistance screening, not only for detecting resistance at the individual field level ('micro' scale), but also the distribution, evolution and impact of resistance country‐wide ('macro' scale). However, it is important that standardised testing methods, including appropriate reference populations, are used by different testing centres to ensure consistent results. [ABSTRACT FROM AUTHOR]

The research was carried out on newly planted bare-root plants at an early stage of their cultivation. The scope of the growth responses of woody plants was verified in relation to the recommended herbicide rate, namely for herbicide solution application rates of 0.825% and 1.025%. The new increment of the longest shoot and the mortality rate were evaluated. The selective efficacy on weeds was observed. Data collection took place at 2, 4, 8, 12 and 24 weeks after application. The experiment followed the manufacturer's recommendations for application. It was conducted on an experimental area of loamy sand soil in 2019 and it was not affected by extreme weather conditions. The application of the herbicide to privet (Ligustrum vulgare) showed a small inhibitory effect, reducing the average increment of the longest plant shoot by 4.7% and 8.3%, respectively, by the end of the study period compared to the control. By contrast, in the case of the European Bladdernut (Staphylea pinnata), the application was found to have an adverse effect. The role of the application rate was secondary. The average increment of the longest shoot was reduced by 45.68% and 50.13%, respectively, and the mortality rate of the treated woody plants reached 10% at the end of the study period. The highest inhibitory effect of the herbicide on the ornamental woody plants that had been treated was observed in the first 2 and 4 weeks after treatment, respectively. The application of the herbicide proved ineffective against horseweed (Conyza canadensis) and groundsel (Senecio vulgaris). [ABSTRACT FROM AUTHOR]

Copyright of Xinjiang Agricultural Sciences is the property of Xinjiang Agricultural Sciences Editorial Department and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The constant influx of pesticides into soils is a key environmental issue in terms of their potential retention in the soil, thus reducing their negative impact on the environment. Soil organic matter (SOM) is an important factor influencing the environmental fate of these substances. Therefore, the aim of this research was to assess the chemical behavior of pesticides (flufenacet, pendimethalin, α-cypermethrin, metazachlor, acetamiprid) toward stable soil humin fractions (HNs) as a main factor affecting the formation of non-extractable residues of agrochemicals in soil. This research was conducted as a batch experiment according to OECD Guideline 106. For this purpose, HNs were isolated from eight soils with different physicochemical properties (clay content = 16–47%, pHKCl = 5.6–7.7, TOC = 13.3–49.7 g·kg−1, TN = 1.06–2.90 g·kg−1, TOC/TN = 11.4–13.7) to reflect the various processes of their formation. The extraction was carried out through the sequential separation of humic acids with 0.1 M NaOH, and then the digestion of the remaining mineral fraction with 10% HF/HCl. The pesticide concentrations were detected using GC-MS/MS. The pesticides were characterized based on the different sorption rates to HNs, according to the overall trend: metazachlor (95% of absorbed compound) > acetamiprid (94% of absorbed compound) > cypermethrin (63% of partitioning compound) > flufenacet (39% of partitioning compound) > pendimethalin (28% of partitioning compound). Cypermethrin and metazachlor exhibited the highest saturation dynamic, while the other agrochemicals were much more slowly attracted by the HNs. The obtained sorption kinetic data were congruous to the pseudo-first-order and pseudo-second-order models related to the surface adsorption and interparticle diffusion isotherm. The conducted research showed that the processes of pesticide sorption, apart from physicochemical phenomena, are also affected by the properties of the pollutants themselves (polarity, KOC) and the soil properties (SOM content, clay content, and pHKCl). [ABSTRACT FROM AUTHOR]

Background and Objectives: Wheat (Triticum aestivum L.) is one of the most strategic crops, which is very important in terms of level and nutritional value, and is known as one of the most important and most consumed crops in the world. According to the report of the World Food and Agriculture Organization (FAO), in 2017, the world production of wheat was about 772 million tons, of which Iran's share was reported to be about 14 million tons. Increasing the yield of wheat per unit area depends on certain factors, one of which is the correct management of weeds to reduce their damage. Therefore, the aims of this study was to use different time of application of pre and post emergence herbicide to reduce use of herbicide for improving productivity of wheat. Materials and Methods: A field experiment was conducted in a randomized complete block design with three replications in the research farm of Shahid Chamran University of Ahvaz in the year 2019-2020. Treatments in this experiment include; Uncontrolled, hand weeding, pendimethalin + atlantis, pendimethalin + metribuzin, trifluralin + atlantis, trifluralin + metribosin, pendimethalin + 2,4-D, trifluralin + 2,4-D, green mungbean + 2,4-D and 2,4-D intercropping. Wheat cv. ‘Mehregan’ was sown at 20 cm row spacing on 28 November in 2019. A seed rate of 120 kg ha-1 along with recommended fertilizer dose of 120:60:40 kg N-P2O5- K2O ha-1 was followed uniformly. Wheat matured in the 2nd week of April. Result: The control methods of hand weeding and pendimethalin+atlantis had a positive effect on increasing the weight of 1000 seeds and the treatment of trifluralin+2,4-D had a negative effect on the weight of 1000 seeds. Examining the changes in wheat grain yield among weed control levels showed that hand weeding and pendimethalin+Atlantis treatment levels had an average grain yield of 3.86 and 3.93 tons per hectare, respectively, which was more than the control, but in the rest of the experimental treatments, lower grain yield was observed. According to the obtained results, the use of pendimethalin pre-planting herbicide along with atlantis herbicide and metribuzin increased yield compared to the control treatment and the use of trifluralin herbicide. Conclusion: In general, the results of this research showed that hand weeding treatments, pendimethalin+atlantis, pendimethalin+metribuzin, improved the growth and performance characteristics of wheat by reducing the amount of weed interference and increasing the amount of absorption of nitrogen, phosphorus and potassium elements in aerial organs. [ABSTRACT FROM AUTHOR]

This article discusses a study conducted in Bihar, India, on the effects of integrated weed management practices on direct-seeded rice grown under aerobic conditions. The study examined various weed control techniques and found that hand weeding at specific intervals was significantly superior in terms of crop development and yield. The results emphasized the importance of efficient weed control for optimal growth and development of direct-seeded rice. The study also compared different weed management practices and found that weed-free plots and plots treated with pendimethalin followed by manual weedings had the highest crop growth and yield, as well as the highest gross and net returns. [Extracted from the article]

In order to investigate the effect of pre-emergence and post-emergence herbicides on nutrient depletion, weed population and nutrient uptake by wheat in sesame-wheat cropping system in Khuzestan a field experiment was conducted in randomized complete block design with three replications in the research farm of Shahid Chamran University of Ahvaz in 2019-2020. Treatments included no weeding, hand weeding, Pendimethalin+Atlantis, Pendimethalin+Metribosin, Trifluralin+Atlantis, Trifluralin+Metribozin, Pendimethalin+2,4-D, Trifluralin+2,4-D, green mungbean+2,4-D and 2,4-D in plots seeded by wheat cv. ‘Mehregan’. Weed population varied notably among the experimental treatments. At 60 days after sowing, while the mean number of weeds was 5.6 plants per m-2, it was significantly different among the weed control treatments. Moreover in this growth stage, Pendimethalin+Atlantis and Pendimethalin+Metribuzin treatments significantly reduced the weed population compared to the control no weeding condition. Generally, hand weeding and Pendimethalin+Atlantis treatments improved the growth and yield of wheat compared to Trifluralin+Atlantis, Trifluralin+Metribosin, and Trifluralin+2,4-D treatments, due apparently to reducing weed interference and increasing the uptake of nitrogen, phosphorus and potassium of the wheat plants. We concluded that the pre-emergence application of Pendimethalin herbicide along with post-emergence application of Metribozin and Atlantis herbicides at the seedling stage of wheat may increase the absorption of nutrients and grain yield.

Abstract Objective The toxicology of herbicides, which are currently in use is under-explored. One highly used but under investigated herbicide is pendimethalin. Here we mined high-throughput data from the US National Toxicology Program (NTP) to identify whether pendimethalin possesses an estrogenic capability in human cells. We also evaluated effects of pendimethalin and its reference commercial formulated herbicide Stomp Aqua on the transcriptome profile of three human mammary epithelial cell lines, cancerous MCF-7 and non-cancerous MCF-10 A and MCF-12 A to see whether this compound could have endocrine disrupting effects and if co-formulants present in the commercial formulation could amplify its toxicity. Results The data mined from the US NTP database suggests that pendimethalin activates estrogen receptors at a concentration of approximately 10?M. MCF-7, MCF-10A and MCF-12A cells were exposed to 10 ?M pendimethalin and Stomp Aqua at an equivalent concentration. Transcriptome analysis showed changes in gene expression patterns implying that pendimethalin affected ubiquitin-mediated proteolysis and the function of the spliceosome. The formulated pendimethalin product Stomp Aqua gave comparable effects suggesting pendimethalin was responsible for the observed transcriptome alterations. Given the lack of information on the exposure to this pesticide, our study prompts the need for biomonitoring studies, especially under occupational use scenarios, to understand if low level exposure to pendimethalin could have endocrine disrupting effects on populations exposed to this compound. A deeper understanding of the exposure and mechanisms of action of this endocrine-disrupting pesticide is needed.

Tungsten oxide (WO3), Iron and vanadium co-doped tungsten oxide (FeVWO3), and the composite of iron and vanadium co-doped tungsten oxide with graphitic carbon nitride (FeVWO3@g-C3N4) were prepared for the photocatalytic study. WO3 and FeVWO3 were synthesized by co-precipitation, and the composite FeVWO3@g-C3N4 was synthesized by an ultra-sonication approach. All the prepared materials were analyzed by different techniques. Structural study was done by XRD, functional group analysis by FTIR, and SEM was used for the morphological study of the nanoparticles. EIS measurements were done to investigate the electrical properties of fabricated materials. Photocatalysis was performed for the band gap analysis. Pendimethalin (PM) a herbicide and aspirin (pharmaceutical product) were used in photocatalysis and degraded by the prepared photocatalysts (WO3, FeVWO3, and FeVWO3@g-C3N4). WO3 and FeVWO3 have 2.62 eV and 2.34 eV Eg values of band gap, respectively. FeVWO3 has a lower Eg value than WO3. The decrease is due to the doping, and generation of further energy levels in the band gap of the pure sample, and these energy levels cause changes in the electronic structure of the sample. The composite shows a high degradation efficiency. The percentage degradation of pendimethalin and aspirin by FeVWO3@g-C3N4 was 82.26 % and 92.84 %. It is because of the presence of g-C3N4 which provides greater surface area for better degradation efficiency.

Copyright of Xinjiang Agricultural Sciences is the property of Xinjiang Agricultural Sciences Editorial Department and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Introduction: Pendimethalin is an herbicide that is used worldwide to attack certain wide leaf and grassy weeds in a variety of agricultural and non-crop regions, with a claimed very low toxicity to human. There have been some few reported cases of acute pendimethalin toxicity to date, around the world. We report a case of pendimethalin toxicity resembling and managed initially as organophosphorus poisoning. Case Description: A 42-year-old agricultural worker was found unresponsive in his field with profuse oral secretions. The patient presented with altered mental status, where Glasgow comma scale was 10, oxygen saturation at room air was 88 %, Blood pressure measured 125/75, pulse rate was 95 beats per minute, and temperature was 37 °C. The patient's pupils were constricted, equal, regular, and reactive. Chest examination revealed scattered respiratory crepitations. The patient also had a distinct garlic odor very similar to that of Organophosphate compounds. The results of his laboratory investigations revealed only hypoxemia. The patient received atropine and supportive management, which prompted the chest secretions to clear up and allow him to restore consciousness without experiencing any neurological problems. Conclusion: Pendimethalin toxicity can present with manifestations mimicking acute organophosphorus poisoning. Proper supportive care is needed for the management of acute pendimethalin toxicity. [ABSTRACT FROM AUTHOR]

Threespike goosegrass (Eleusine tristachya) is a difficult-to-control perennial grass of increasing concern for orchard production systems in the Central Valley of California, USA. This grass has a bunch-type growth habit when tillered, which can interfere with orchard operations, particularly nut pickup from the ground at harvest. From 2016 to 2019, herbicide efficacy on threespike goosegrass was evaluated in a walnut (Juglans regia) orchard in Chico, CA, USA; an almond (Prunus dulcis) orchard in Livingston, CA, USA; and a prune (Prunus domestica) orchard in Orland, CA, USA. At each location, two independent experiments were conducted to evaluate 12 preemergent (PRE) herbicide treatments and eight postemergent (POST) treatments over several years, for a total of 16 trials. PRE herbicides were applied in January according to the region’s typical winter orchard management practices. One treatment included an additional sequential application in March to extend residual activity later into the warm season when threespike goosegrass germinates or resumes growth. In separate studies, POST control of established stands of threespike goosegrass was evaluated in May and June of each year. Each trial was conducted in a randomized complete block design with four replications. Threespike goosegrass control was visually estimated monthly for 5 months after the PRE treatments or at weekly intervals for 5 weeks following POST treatments. The most effective PRE treatment was a sequential application of indaziflam in January, followed by a March application of pendimethalin, providing 90% or greater control of threespike goosegrass 5 months after treatment across all sites and all years. Of the POST treatments, the three graminicides outperformed the other treatments with 73% to 91% control overall sites and years at 5 weeks after treatment. Fluazifop had the highest control ratings (85% to 91%) among the graminicide herbicides but was not always statistically better than clethodim or sethoxydim (74% to 83% control). Glyphosate alone resulted in unacceptable control (33% to 51%) regardless of rates tested, experimental sites, or years. Together, these results confirm grower reports of poor glyphosate performance on threespike goosegrass but suggest that effective herbicide programs can be developed to manage threespike goosegrass using PRE herbicides and POST graminicides registered in California orchard crops.