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Direct catalytic conversion of methane to liquid oxygenates under mild conditions remains a challenge due to high bond energy of symmetric CH4. Isolated Rh atoms were supported on hydrophobic fluorine modified TS-1 (FTS-1). Single-atom Rh on FTS-1 catalyst was characterized with Ac-HAADF/STEM and CO adsorption FTIR. The aerobic selective conversion of methane to oxygenates was carried out in a fixed bed continuous flow reactor upon co-feeding CO and H2O at 423 K under relative low pressure (42.3 kPa CH4, 21.1 kPa CO, 10.6 kPa O2, 0.476 MPa H2O). Hydrophobic Rh/FTS-1 catalyst exhibits higher activity (151.9 molproducts/(molmetalh)) than the activity (36.4 molproducts/(molmetalh)) over hydrophilic Rh-ZSM-5 (Si/Al = 15) under such reaction conditions. Hydrophobicity of different catalysts were compared by water adsorption test. The catalytic activity of F modified TS-1 supported single-atom Rh (Rh/FTS-1) is higher than that of unmodified Rh/TS-1 which is due to its higher Lewis acidity as shown by pyridine adsorption FTIR and NH3-TPD. [ABSTRACT FROM AUTHOR]