Search

The paper presents the summary data of the authors' research within the framework of the OLIMPIYA project (the Russian acronym of {\bf OLI}viny iz {\bf M}eteoritov --- {\bf P}oisk tyazholykh {\bf I} sverkhtyazholykh {\bf YA}der / Olivines from meteorites: Search for heavy and superheavy nuclei) and results of track analysis for heavy cosmic ray nuclei (\emph{Z} = 26--129) in olivine crystals from meteorites using an original processing technique. A total of 21,743 tracks of nuclei heavier than iron have been identified in meteoritic matter to date to form the largest database within this charge range. The database includes three tracks of superheavy nuclei with the lifetimes of about a few decades, which can be considered as direct experimental evidence for the existence of natural superheavy nuclei from the "island of stability". Comprehensive comparative analysis of data from two meteorites with different cosmic ray exposure ages, Marjalahti (from 178 to 205 Myr) and Eagle Station (from 35 to 71 Myr), is presented for the first time. The results are discussed within the existing concepts of nuclei formation in astrophysical processes., Comment: 13 pages, 4 figures, 1 table

First-principle density-functional calculations have been applied to study the interaction of molecular chlorine with the (111) plane of copper. Using transition-state search method, we considered the elementary processes (Cl$_2$ dissociation, adsorption, diffusion, association and desorption) on the chlorinated Cu(111) surface. A systematic study of possible desorption pathways has been carried out for different species (Cl, Cl$_2$, CuCl, CuCl$_2$, and Cu) at various chlorine coverage. As a result, we concluded that chlorine monolayer irrespective of the coverage desorbs in the form of CuCl molecules from step edges.

This paper presents a DFT study for phosphine adsorption on a Si(001)-2$\times$1 surface covered by a chlorine monolayer, including adsorption on local defects, i.e. mono- and bivacancies in the adsorbate layer (Cl, Cl$_2$), and combined vacancies with removed silicon atoms (SiCl, SiCl$_2$). Activation barriers were found for the adsorbing PH$_3$ to dissociate into PH$_2$+H and PH+H$_2$ fragments; it was also established that phosphine dissociation on combined vacancies is possible at room temperature. If there is a silicon vacancy on the surface, phosphorus settles in the Si(001) lattice as PH (if the vacancy is SiCl) or as PH$_2$ (if the vacancy is SiCl$_2$). This paper suggests a method to plant a separate phosphorus atom into the silicon surface layer with atomic precision, using phosphine adsorption on defects specially created on a Si(001)-2$\times$1-Cl surface with an STM tip.