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Mercury (Hg) is a naturally occurring element that bonds with organic matter and, when converted to methylmercury, is a potent neurotoxicant. Here we estimate potential future releases of Hg from thawing permafrost for low and high greenhouse gas emissions scenarios using a mechanistic model. By 2200, the high emissions scenario shows annual permafrost Hg emissions to the atmosphere comparable to current global anthropogenic emissions. By 2100, simulated Hg concentrations in the Yukon River increase by 14% for the low emissions scenario, but double for the high emissions scenario. Fish Hg concentrations do not exceed United States Environmental Protection Agency guidelines for the low emissions scenario by 2300, but for the high emissions scenario, fish in the Yukon River exceed EPA guidelines by 2050. Our results indicate minimal impacts to Hg concentrations in water and fish for the low emissions scenario and high impacts for the high emissions scenario., Permafrost locks away the largest reservoir of mercury on the planet, but climate warming threatens to thaw these systems. Here the authors use models to show that unconstrained fossil fuel burning will dramatically increase the amount of mercury released into future ecosystems.

Arctic Indigenous communities have been classified as highly vulnerable to climate change impacts. The remoteness of Arctic communities, their dependence upon local species and habitats, and the historical marginalization of Indigenous peoples enhances this characterization of vulnerability. However, vulnerability is a result of diverse historical, social, economic, political, cultural, institutional, natural resource, and environmental conditions and processes and is not easily reduced to a single metric. Furthermore, despite the widespread characterization of vulnerability, Arctic Indigenous communities are extremely resilient as evidenced by subsistence institutions that have been developed over thousands of years. We explored the vulnerability of subsistence systems in the Cup’ik village of Chevak and Yup’ik village of Kotlik through the lens of the strong seasonal dimensions of resource availability. In the context of subsistence harvesting in Alaska Native villages, vulnerability may be determined by analyzing the exposure of subsistence resources to climate change impacts, the sensitivity of a community to those impacts, and the capacity of subsistence institutions to absorb these impacts. Subsistence resources, their seasonality, and perceived impacts to these resources were investigated via semi-structured interviews and participatory mapping-calendar workshops. Results suggest that while these communities are experiencing disproportionate impacts of climate change, Indigenous ingenuity and adaptability provide an avenue for culturally appropriate adaptation strategies. However, despite this capacity for resiliency, rapid socio-cultural changes have the potential to be a barrier to community adaptation and the recent, ongoing shifts in seasonal weather patterns may make seasonally specific subsistence adaptations to landscape particularly vulnerable.

This review documents recent advances in terrestrial mercury cycling. Terrestrial mercury (Hg) research has matured in some areas, and is developing rapidly in others. We summarize the state of the science circa 2010 as a starting point, and then present the advances during the last decade in three areas: land use, sulfate deposition, and climate change. The advances are presented in the framework of three Hg "gateways" to the terrestrial environment: inputs from the atmosphere, uptake in food, and runoff with surface water. Among the most notable advances: These and other advances reported here are of value in evaluating the effectiveness of the Minamata Convention on reducing environmental Hg exposure to humans and wildlife.

Permafrost on the Qinghai-Tibetan Plateau (QTP) has been degrading in the past decades. While the degradation may mobilize previously protected material from the permafrost profile, little is known about the stocks and stability of mercury (Hg) in the QTP permafrost. Here we measured total soil Hg in 265 samples from 15 permafrost cores ranging from 3 to 18 m depth, and 45 active layer (AL) soil samples from different land cover types on the QTP. Approximately 21.7 Gg of Hg was stored in surficial permafrost (0–3 m), with 16.58 Gg of Hg was stored in the active layer. Results from six permafrost collapse areas showed that much of the thawed Hg is mobile, with decreases in total Hg mass of 17.6–30.9% for the AL (top 30 cm) in comparison with non-thermokarst surfaces. We conclude that the QTP permafrost region has a large mercury pool, and the stored mercury is sensitive to permafrost degradation.

Water isotopes in precipitation provide new insight on the controlling factors for moisture source variations on the Tibetan Plateau. However, understanding the intra-annual water isotope cycle is difficult for a region lack of winter precipitation. Here, we reported water vapor δ18O and δ2H time series over two and half years at Lhasa on the southern Tibetan Plateau. We compare our values with concurrent daily precipitation isotopes to assess the seasonal controls of vapor isotopes and possible correlation to precipitation isotopes. Results show an intra-seasonal dependence of water vapor δ18O on large scale meteorological regime. During the winter months, vapor water δ18O shows positive dependence on regional-scale temperature, confirming a Rayleigh-distillation controlling moisture transport. During the summer months, lower vapor δ18O is weekly in association with the heavy precipitation over tropical Indian Ocean and on the Tibetan Plateau, and this relation is further enhanced by the evaporation of precipitation at the sampling site. We also found a weak seasonal variation of vapor d-excess, likely resulted from climate seasonality over the large moisture sources region. Moreover, the isotope dataset contains a high-frequency of fluctuations for both δ18O and d-excess lasting several days during the summer monsoon season. These high frequency fluctuations are in phase with precipitation events, confirming significant local evaporation effects on the short-term water cycle, which further complicated the control of near surface water vapor isotopes. These findings improve our regional scale understanding of hydrological cycle on the southern Tibetan Plateau, and will potentially improve our understanding of isotope variations in proxy archives in the Tibetan Plateau.

This paper examines the quality of data collected by the Indigenous Observation Network, a community-based water-quality project in the Yukon River Basin of Alaska and Canada. The Indigenous Observation Network relies on community technicians to collect surface-water samples from as many as fifty locations to achieve their goals of monitoring the quality of the Yukon River and major tributaries in the basin and maintaining a long-term record of baseline data against which future changes can be measured. This paper addresses concerns about the accuracy, precision, and reliability of data collected by non-professionals. The Indigenous Observation Network data are examined in the context of a standard data life cycle: plan, collect, assure, and describe; as compared to professional scientific activities. Field and laboratory protocols and procedures of the Indigenous Observation Network are compared to those utilized by professional scientists. The data of the Indigenous Observation Network are statistically compared to those collected by professional scientists through a retrospective analysis of a set of water-quality parameters reported by all three projects over a number of years. No statistical differences were found among the three projects for pH, Calcium, Magnesium, or Alkalinity, although statistically significant differences were found for Sodium, Chloride, Sulfate, and Potassium concentrations. The statistical differences found were small and likely not significant in terms of interpreting the data for a variety of uses. Our results suggest that Indigenous Observation Network data are of high quality, and with consistent protocols and participant training, community based monitoring projects can collect data that are accurate, precise, and reliable.

Boreal soils in permafrost regions contain vast quantities of frozen organic material that is released to terrestrial and aquatic environments via subsurface flow paths as permafrost thaws. Longer flow paths may allow chemical reduction of solutes, nutrients, and contaminants, with implications for greenhouse gas emissions and aqueous export. Predicting boreal catchment runoff is complicated by soil heterogeneities related to variability in active layer thickness, soil type, fire history, and preferential flow potential. By coupling measurements of permeability, infiltration potential, and water chemistry with a stream chemistry end-member mixing model, we tested the hypothesis that organic soils and burned slopes are the primary sources of runoff, and that runoff from burned soils is greater due to increased hydraulic connectivity. Organic soils were more permeable than mineral soils, and 25% of infiltration moved laterally upon reaching the organic-mineral soil boundary on unburned hillslopes. A large portion of the remaining water infiltrated into deeper, less permeable soils. In contrast, burned hillslopes displayed poorly defined soil horizons, allowing rapid, mineral-rich runoff through preferential pathways at various depths. On the catchment scale, mineral/organic runoff ratios averaged 1.6 and were as high as 5.2 for an individual storm. Our results suggest that burned soils are the dominant source of water and solutes reaching the stream in summer, whereas unburned soils may provide longer term storage and residence times necessary for production of anaerobic compounds. These results are relevant to predicting how boreal catchment drainage networks and stream export will evolve given continued warming and altered fire regimes.

Responses of near-surface permafrost and glacial ice to climate change are of particular significance for understanding long-term effects on global carbon cycling and carbon export by high-latitude northern rivers. Here we report Δ14C-dissolved organic carbon (DOC) values and dissolved organic matter optical data for the Yukon River, 15 tributaries of the Yukon River, glacial meltwater, and groundwater and soil water end-member sources draining to the Yukon River, with the goal of assessing mobilization of aged DOC within the watershed. Ancient DOC was associated with glacial meltwater and groundwater sources. In contrast, DOC from watersheds dominated by peat soils and underlain by permafrost was typically enriched in Δ14C indicating that degradation of ancient carbon stores is currently not occurring at large enough scales to quantitatively influence bulk DOC exports from those landscapes. On an annual basis, DOC exported was predominantly modern during the spring period throughout the Yukon River basin and became older through summer-fall and winter periods, suggesting that contributions of older DOC from soils, glacial meltwaters, and groundwater are significant during these months. Our data indicate that rapidly receding glaciers and increasing groundwater inputs will likely result in greater contributions of older DOC in the Yukon River and its tributaries in coming decades.

Cryosols contain roughly 1700 Gt of Soil organic carbon (SOC) roughly double the carbon content of the atmosphere. As global temperature rises and permafrost thaws, this carbon reservoir becomes vulnerable to microbial decomposition, resulting in greenhouse gas emissions that will amplify anthropogenic warming. Improving our understanding of carbon dynamics in thawing permafrost requires more data on carbon and nitrogen content, soil physical and chemical properties and substrate quality in cryosols. We analyzed five permafrost cores obtained from the North Slope of Alaska during the summer of 2009. The relationship between SOC and soil bulk density can be adequately represented by a logarithmic function. Gas fluxes at -5 degrees C and -5 degrees C were measured to calculate the temperature response quotient (Q(10)). Q(10) and the respiration per unit soil C were higher in permafrost-affected soils than that in the active layer, suggesting that decomposition and heterotrophic respiration in ciyosols may contribute more to global warming. (C) 2014 Published by Elsevier B.V.

Glacier-derived dissolved organic matter represents a quantitatively significant source of ancient, but bioavailable, carbon to downstream ecosystems. Anthropogenic aerosols supply glaciers with aged organic matter, according to an analysis of organic matter from glaciers in Alaska.

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.

Mercury and organic carbon concentrations vary dynamically in streamwater at the Sleepers River Research Watershed in Vermont, USA. Total mercury (THg) concentrations ranged from 0.53 to 93.8 ng/L during a 3-year period of study. The highest mercury (Hg) concentrations occurred slightly before peak flows and were associated with the highest organic carbon (OC) concentrations. Dissolved Hg (DHg) was the dominant form in the upland catchments; particulate Hg (PHg) dominated in the lowland catchments. The concentration of hydrophobic acid (HPOA), the major component of dissolved organic carbon (DOC), explained 41–98% of the variability of DHg concentration while DOC flux explained 68–85% of the variability in DHg flux, indicating both quality and quantity of the DOC substantially influenced the transport and fate of DHg. Particulate organic carbon (POC) concentrations explained 50% of the PHg variability, indicating that POC is an important transport mechanism for PHg. Despite available sources of DHg and wetlands in the upland catchments, dissolved methylmercury (DmeHg) concentrations in streamwaters were below detection limit (0.04 ng/L). PHg and particulate methylmercury (PmeHg) had a strong positive correlation (r 2 = 0.84, p

It is the nature of the scientific method to use a variety of models, procedures, techniques and data to quantify and analyse natural phenomena. Recently, in Reddy et al. (2006), we published a study in which υ18O values for precipitation, surfaceand ground-water samples from the Shingobee River Headwaters Area (SRHA) were analysed using an amplitude-attenuation (convolution integral) approach for estimating mean residence times (MRTs). This approach has been used in many small watershed studies (e.g. Stewart and McDonnell, 1991; DeWalle et al., 1997; Burns and McDonnell, 1998; McGuire et al., 2002; Rodgers et al., 2005; McGuire and McDonnell, 2006). In a comment, Criss and Winston (2006) disagree with our method and present an alternative approach for interpreting υ18O values in the SRHA. We feel that this comparison with our methodology is unfair. Criss and Winston (2006) focus their attention on the weaknesses in our method and the strengths of theirs, while overlooking our detailed evaluation of model predictions with other independent watershed hydrologic properties. The comment by Criss and Winston (2006) makes several points, some of which we agree are valid criticisms of our paper. In this response, we will address their concerns regarding (1) our interpretation of the current state of the literature, (2) the data we used in the analysis, and (3) the relative merits of the two modelling approaches. In so doing, we will update the dataset with precipitation υ18O data from 1990 to 2004, and compare the two approaches to provide a fair basis for understanding the strengths and weaknesses of both methods. Additionally, we will discuss some technical issues that arise for scientists in choosing between simple and complex models.

18O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. 18O variations (δ18O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well-instrumented research catchment in north-central Minnesota. SRHA surface waters exhibit δ18O seasonal variations similar to those of groundwaters, and seasonal δ18O variations plotted versus time fit seasonal sine functions. These seasonal δ18O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed-basin lakes. MRT variations of about 1 to 16 years have been estimated over an area covering about 9 km2 from the basin boundary to the most downgradient well. Estimated MRT error (±0·3 to ±0·7 years) is small for short MRTs and is much larger (±10 years) for a well with an MRT (16 years) near the limit of the method. Groundwater transit time estimates based on Darcy's law, tritium content, and the seasonal δ18O amplitude approach appear to be consistent within the limits of each method. The results from this study suggest that use of the δ18O seasonal variation method to determine MRTs can help assess groundwater recharge areas in small headwaters catchments. Copyright © 2005 John Wiley & Sons, Ltd.

Williams Lake, Minnesota is a closed-basin lake that is a flow-through system with respect to ground water. Ground-water input represents half of the annual water input and most of the chemical input to the lake. Chemical budgets indicate that the lake is a sink for calcium, yet surficial sediments contain little calcium carbonate. Sediment pore-water samplers (peepers) were used to characterize solute fluxes at the lake-water–ground-water interface in the littoral zone and resolve the apparent disparity between the chemical budget and sediment data. Pore-water depth profiles of the stable isotopes δ18O and δ2H were non-linear where ground water seeped into the lake, with a sharp transition from lake-water values to ground-water values in the top 10 cm of sediment. These data indicate that advective inflow to the lake is the primary mechanism for solute flux from ground water. Linear interstitial velocities determined from δ2H profiles (316 to 528 cm/yr) were consistent with velocities determined independently from water budget data and sediment porosity (366 cm/yr). Stable isotope profiles were generally linear where water flowed out of the lake into ground water. However, calcium profiles were not linear in the same area and varied in response to input of calcium carbonate from the littoral zone and subsequent dissolution. The comparison of pore-water calcium profiles to pore-water stable isotope profiles indicate calcium is not conservative. Based on the previous understanding that 40–50 % of the calcium in Williams Lake is retained, the pore-water profiles indicate aquatic plants in the littoral zone are recycling the retained portion of calcium. The difference between the pore-water depth profiles of calcium and δ18O and δ2H demonstrate the importance of using stable isotopes to evaluate flow direction and source through the lake-water–ground-water interface and evaluate mechanisms controlling the chemical balance of lakes. Published in 2003 by John Wiley & Sons, Ltd.

Mercury (Hg) contamination of aquatic ecosystems and subsequent methylmercury bioaccumulation are significant environmental problems of global extent. At regional to global scales, the primary mechanism of Hg contamination is atmospheric Hg transport. Thus, a better understanding of the long-term history of atmospheric Hg cycling and quantification of the sources is critical for assessing the regional and global impact of anthropogenic Hg emissions. Ice cores collected from the Upper Fremont Glacier (UFG), Wyoming, contain a high-resolution record of total atmospheric Hg deposition (ca. 1720-1993). Total Hg in 97 ice-core samples was determined with trace-metal clean handling methods and low-level analytical procedures to reconstruct the first and most comprehensive atmospheric Hg deposition record of its kind yet available from North America. The record indicates major atmospheric releases of both natural and anthropogenic Hg from regional and global sources. Integrated over the past 270-year ice-core history, anthropogenic inputs contributed 52%, volcanic events 6%, and background sources 42%. More significantly, during the last 100 years, anthropogenic sources contributed 70% of the total Hg input. Unlike the 2-7-fold increase observed from preindustrial times (before 1840) to the mid-1980s in sediment-core records, the UFG record indicates a 20-fold increase for the same period. The sediment-core records, however, are in agreement with the last 10 years of this ice-core record, indicating declines in atmospheric Hg deposition.

Although mercury (Hg) emissions peaked in the United States over the last 20 to 40 years and are now declining, they remain well above natural background levels in soils and sediments. Only a small fraction of the Hg deposited from the atmosphere to the terrestrial landscape runs off in streamflow. However, some of this Hg is methylated in the environment and can potentially bioaccumulate to the top of food webs, posing a hazard to people who eat fish, especially children and pregnant women. What factors determine the amount of Hg that runs off in streams? During the 2000 snowmelt at Sleepers River in Vermont, strong correlations were found between dissolved and particulate mercury and the respective dissolved and particulate organic carbon fractions, even when data were pooled from 10 streams of diverse watershed size and land cover. Episodic export of particulate Hg during the highest flows appears to be the dominant mechanism of Hg movement.

The potential to use ice cores from alpine glaciers in the midlatitudes to reconstruct paleoclimatic records has not been widely recognized. Although excellent paleoclimatic records exist for the polar regions, paleoclimatic ice core records are not common from midlatitude locations. An ice core removed from the Upper Fremont Glacier in Wyoming provides evidence for abrupt climate change during the mid-1800s. Volcanic events (Krakatau and Tambora) identified from electrical conductivity measurements (ECM) and isotopic and chemical data from the Upper Fremont Glacier were reexamined to confirm and refine previous chronological estimates of the ice core. At a depth of 152 m the refined age-depth profile shows good agreement (1736{+-}10 A.D.) with the {sup 14}C age date (1729{+-}95 A.D.). The {delta}{sup 18}O profile of the Upper Fremont Glacier (UFG) ice core indicates a change in climate known as the Little Ice Age (LIA). However, the sampling interval for {delta}{sup 18}O is sufficiently large (20 cm) such that it is difficult to pinpoint the LIA termination on the basis of {delta}{sup 18}O data alone. Other research has shown that changes in the {delta}{sup 18}O variance are generally coincident with changes in ECM variance. The ECM data set contains over 125,000 data points atmore » a resolution of 1 data point per millimeter of ice core. A 999-point running average of the ECM data set and results from f tests indicates that the variance of the ECM data decreases significantly at about 108 m. At this depth, the age-depth profile predicts an age of 1845 A.D. Results indicate the termination of the LIA was abrupt with a major climatic shift to warmer temperatures around 1845 A.D. and continuing to present day. Prediction limits (error bars) calculated for the profile ages are {+-}10 years (90% confidence level). Thus a conservative estimate for the time taken to complete the LIA climatic shift to present-day climate is about 10 years, suggesting the LIA termination in alpine regions of central North America may have occurred on a relatively short (decadal) timescale. (c) 2000 American Geophysical Union.« less

High-altitude watersheds in the Front Range of Colorado show symptoms of advanced stages of nitrogen excess, despite having less nitrogen in atmospheric deposition than other regions where watersheds retain nitrogen. In two alpine/subalpine subbasins of the Loch Vale watershed, atmospheric deposition of NO3− plus NH4+ was 3.2–5.5 kg N ha−1, and watershed export was 1.8–3.9 kg N ha−1 for water years 1992–1997. Annual N export increased in years with greater input of N, but most of the additional N was retained in the watershed, indicating that parts of the ecosystem are nitrogen-limited. Dissolved inorganic nitrogen (DIN) concentrations were greatest in subsurface water of talus landscapes, where mineralization and nitrification augment high rates of atmospheric deposition of N. Tundra landscapes had moderately high DIN concentrations, whereas forest and wetland landscapes had low concentrations, indicating little export of nitrogen from these landscapes. Between the two subbasins the catchment of Icy Brook had greater retention of nitrogen than that of Andrews Creek because of landscape and hydrologic characteristics that favor greater N assimilation in both the terrestrial and aquatic ecosystems. These results suggest that export of N from alpine/subalpine watersheds is caused by a combination of direct flushing of N from atmospheric deposition and release of N from ecosystem biogeochemical processes (N cycling). Sensitivity of alpine ecosystems in the western United States to atmospheric deposition of N is a function of landscape heterogeneity, hydrologic flow paths, and climatic extremes that limit primary productivity and microbial activity, which, in turn, control retention and release of nitrogen. Conceptual and mechanistic models of N excess that have been developed for forested ecosystems need to be modified in order to predict the response of alpine ecosystems to future changes in climate and atmospheric deposition of N.

Chemical mass balances for sodium, magnesium, chloride, dissolved organic carbon, and oxygen 18 were used to estimate groundwater seepage to and from Williams Lake, Minnesota, over a 15-month period, from April 1991 through June 1992. Groundwater seepage to the lake and seepage from the lake to groundwater were determined independently using a flow net approach using data from water table wells installed as part of the study. Hydrogeological analysis indicated groundwater seepage to the lake accounted for 74% of annual water input to the lake; the remainder came from atmospheric precipitation, as determined from a gage in the watershed and from nearby National Weather Service gages. Seepage from the lake accounted for 69% of annual water losses from the lake; the remainder was removed by evaporation, as determined by the energy budget method. Calculated annual water loss exceeded calculated annual water gain, and this imbalance was double the value of the independently measured decrease in lake volume. Seepage to the lake determined from oxygen 18 was larger (79% of annual water input) than that determined from the flow net approach and made the difference between calculated annual water gain and loss consistent with the independently measured decrease in lake volume. Although the net difference between volume of seepage to the lake and volume of seepage from the lake was 1% of average lake volume, movement of water into and out of the lake by seepage represented an annual exchange of groundwater with the lake equal to 26–27% of lake volume. Estimates of seepage to the lake from sodium, magnesium, chloride, and dissolved organic carbon did not agree with the values determined from flow net approach or oxygen 18. These results indicated the importance of using a combination of hydrogeological and chemical approaches to define volume of seepage to and from Williams Lake and identify uncertainties in chemical fluxes.

One hundred samples were collected from the surface of the Upper Fremont Glacier at equally spaced intervals defined by an 8,100 m2 snow grid to assess the significance of lateral variability in major-ion concentrations and del oxygen-18 values. For the major ions, the largest concentration range within the snow grid was sodium (0.5056 mg/l) and the smallest concentration range was sulfate (0.125 mg/l). Del oxygen-18 values showed a range of 7.45 per mil. Comparison of the observed variability of each chemical constituent to the variability expected by measurement error indicated substantial lateral variability within the surface-snow layer. Results of the nested ANOVA indicate most of the variance for every constituent is in the values grouped at the two smaller geographic scales (between 506 m2 and within 506 m2 sections). Calcium and sodium concentrations and del oxygen-18 values displayed the largest amount of variance at the largest geographic scale (between 2,025 m2 sections) within the grid and ranged from 14 to 26 per cent of the total variance. The variance data from the snow grid were used to develop equations to evaluate the significance of both positive and negative concentration/value peaks of nitrate and del oxygen-18 with depth, in a 160 m ice core. Solving the equations indicates that both the nitrate and del oxygen-18 ice-core profiles have concentration/value trends that exceed the limits expected from lateral variability. Values of del oxygen-18 in the section from 110-150 m below the surface consistently vary outside the expected limits and possibly represents cooler temperatures during the Little Ice Age from about 1810 to 1725 A.D.

A chemical budget analysis for Williams Lake, Minnesota, tracks the seasonal progression of carbon inputs and outputs. CO, exchanges with the atmosphere reverse seasonally, with uptake by the lake in summer preceded and followed by larger losses to the atmosphere. Calcium bicarbonate-rich groundwaters seep steadily into the lake, augmented by remobilization of lacustrine marls. Most of the carbon used in summer photosynthesis nevertheless derives from depletion of lake carbon stores, facilitated significantly by plant calcification. Calcification in summer reduces alkalinity and calcium inventories by 15 and 25%, respectively, while generating equal molar quantities of CO,. Marl precipitates mainly on submersed macrophytes, several of which calcify in 1 : 1 ratio to photosynthesis when incubated in Ca-supplemented lake water. Despite calcite supersaturation within the epilimnion, there is little authigenic calcification.

We measured mercury (Hg) concentrations and calculated export and yield from the Yukon River Basin (YRB) to quantify Hg flux from a large, permafrost-dominated, high-latitude watershed. Exports of Hg averaged 4400 kg Hg yr(-1). The average annual yield for the YRB during the study period was 5.17 μg m(-2) yr(-1), which is 3-32 times more than Hg yields reported for 8 other major northern hemisphere river basins. The vast majority (90%) of Hg export is associated with particulates. Half of the annual export of Hg occurred during the spring with about 80% of 34 samples exceeding the U.S. EPA Hg standard for adverse chronic effects to biota. Dissolved and particulate organic carbon exports explained 81% and 50%, respectively, of the variance in Hg exports, and both were significantly (p < 0.001) correlated with water discharge. Recent measurements indicate that permafrost contains a substantial reservoir of Hg. Consequently, climate warming will likely accelerate the mobilization of Hg from thawing permafrost increasing the export of organic carbon associated Hg and thus potentially exacerbating the production of bioavailable methylmercury from permafrost-dominated northern river basins.

Ice-core samples from Upper Fremont Glacier (UFG), Wyoming, were used as proxy records for the chemical composition of atmospheric deposition. Results of analysis of the ice-core samples for stable isotopes of nitrogen (δ15N, ) and sulfur (δ34S, ), as well as and deposition rates from the late-1940s thru the early-1990s, were used to enhance and extend existing National Atmospheric Deposition Program/National Trends Network (NADP/NTN) data in western Wyoming. The most enriched δ34S value in the UFG ice-core samples coincided with snow deposited during the 1980 eruption of Mt. St. Helens, Washington. The remaining δ34S values were similar to the isotopic composition of coal from southern Wyoming. The δ15N values in ice-core samples representing a similar period of snow deposition were negative, ranging from -5.9 to -3.2 ‰ and all fall within the δ15N values expected from vehicle emissions. Ice-core nitrate and sulfate deposition data reflect the sharply increasing U.S. emissions data from 1950 to the mid-1970s.

The small watershed approach is well-suited but underutilized in mercury research. We applied the small watershed approach to investigate total mercury (THg) and methylmercury (MeHg) dynamics in streamwater at the five diverse forested headwater catchments of the US Geological Survey Water, Energy, and Biogeochemical Budgets (WEBB) program. At all sites, baseflow THg was generally less than 1 ng L -1 and MeHg was less than 0.2 ng L -1 . THg and MeHg concentrations increased with streamflow, so export was primarily episodic. At three sites, THg and MeHg concentration and export were dominated by the particulate fraction in association with POC at high flows, with maximum THg (MeHg) concentrations of 94 (2.56) ng L -1 at Sleepers River, Vermont; 112 (0.75) ng L -1 at Rio Icacos, Puerto Rico; and 55 (0.80) ng L -1 at Panola Mt., Georgia. Filtered (

This report contains water-quality and sediment-quality data from samples collected in the Yukon River Basin from March through September during the 2005 water year (WY). Samples were collected throughout the year at five stations in the basin (three on the main stem Yukon River, one each on the Tanana and Porcupine Rivers). A broad range of physical, chemical, and biological analyses are presented. This is the final report in a series of five USGS Open-File Reports spanning five WYs, from October 2000 through September 2005.

Paleoclimatic and paleoenvironmental ice-core records are not common from mid-latitude locations in the contiguous U.S.A. Although excellent paleo-records exist for the high latitudes (Hammer, 1980; Lyons et al., 1990, Dansgaard et al., 1993, Taylor et al., 1993a; Clausen et al., 1995, Alley et al., 1997, Johnsen et al., 1997, Jouzel et al., 1997, Mayewski et al., 1997, Taylor et al., 1997, White, J.W.C, et al., 1997, Zielinski et al., 1997), icecore records from polar regions may be considered proxy indicators of climatic and environmental change in the mid latitudes. Unlike polar ice cores which are more likely to preserve visual, chemical and isotopic stratigraphy with sub-annual resolution, visual stratigraphy and sub annual isotopic resolution are generally not apparent in mid-latitude ice cores. In addition, meltwater percolation can influence chemical and isotopic stratigraphy of alpine glaciers from mid-latitude ice cores by “damping” the environmental signal (Wagenbach, 1989). Despite these problems, Naftz (1993), Naftz et al., (1994), Naftz et al. (1996) and Cecil and Vogt (1997), through chemical lines of evidence, indicated that the Upper Fremont Glacier (UFG) in the Wind River Range, Wyoming, U.S.A., (43° 07’ 37” N

[1] A detailed study of the climatic significance of δ18O in precipitation was completed on a 1500 km southwest-northeast transect of the Tibetan Plateau in central Asia. Precipitation samples were collected at four meteorological stations for up to 9 years. This study shows that the gradual impact of monsoon precipitation affects the spatial variation of δ18O-T relationship along the transect. Strong monsoon activity in the southern Tibetan Plateau results in high precipitation rates and more depleted heavy isotopes. This depletion mechanism is described as a precipitation “amount effect” and results in a poor δ18O-T relationship at both seasonal and annual scales. In the middle of the Tibetan Plateau, the effects of the monsoon are diminished but continue to cause a reduced correlation of δ18O and temperature at the annual scale. At the monthly scale, however, a significant δ18O-T relationship does exist. To the north of the Tibetan Plateau beyond the extent of the effects of monsoon precipitation, δ18O in precipitation shows a strong temperature dependence. δ18O records from two shallow ice cores and historic air temperature data were compared to verify the modern δ18O-T relationship. δ18O in Dunde ice core was positively correlated with air temperature from a nearby meteorological station in the north of the plateau. The δ18O variation in an ice core from the southern Plateau, however, was inversely correlated with precipitation amount at a nearby meteorological station and also the accumulation record in the ice core. The long-term variation of δ18O in the ice core record in the monsoon regions of the southern Tibetan Plateau suggest past monsoon seasons were probably more expansive. It is still unclear, however, how changes in large-scale atmosphere circulation might influence summer monsoon precipitation on the Tibetan Plateau.

[1] Site-specific transfer functions relating delta oxygen 18 (δ18O) values in snow to the average air temperature (TA) during storms on Upper Fremont Glacier (UFG) were used in conjunction with δ18O records from UFG ice cores to reconstruct long-term trends in air temperature from alpine areas in the Wind River Range, Wyoming. Transfer functions were determined by using data collected from four seasonal snowpacks (1989–1990, 1997–1998, 1998–1999, and 1999–2000). The timing and amount of each storm was determined from an automated snowpack telemetry (SNOTEL) site, 22 km northeast of UFG, and ∼1060 m in elevation below UFG. Statistically significant and positive correlations between δ18O values in the snow and TA were consistently found in three of the four seasonal snowpacks. The snowpack with the poor correlation was deposited in 1997–1998 during the 1997–1998 El Nino Southern Oscillation (ENSO). An ultrasonic snow-depth sensor installed on UFG provided valuable insights into site-specific storms and postdepositional processes that occur on UFG. The timing of storms recorded at the UFG and Cold Springs SNOTEL sites were similar; however, selected storms did not correlate. Snow from storms occurring after mid-October and followed by high winds was most susceptible to redeposition of snow. This removal of lower temperature snowfall could potentially bias the δ18O values preserved in ice core records to environmental conditions reflecting higher air temperatures and lower wind speeds. Transfer functions derived from seasonal snow cover on UFG were used to reconstruct TA values from δ18O values determined from two ice cores collected from UFG. Reconstructed air temperatures from the ice core data indicate an increase in TA of ∼3.5°C from the mid-1960s to the early 1990s in the alpine areas of northwestern Wyoming. Reconstructed TA from the ice core records between the end of the Little Ice Age (LIA), mid-1800s, and the early 1990s indicate a TA increase of ∼5°C. The historically reconstructed TA values from the UFG were significantly higher than the global average observed during the 20th Century but were in agreement with TA increases observed at selected, high-altitude and high-latitude sites in other parts of the world. Additional research is required to determine if part of the observed trend toward heavier δ18O values in ice from the UFG since the LIA (and increased TA) is due to an increased proportion of snowfall from southerly storm tracks and moisture sources, as seems to have been the situation in 1997–1998.

In the past, ice-core records from mid-latitude glaciers in alpine areas of the continental United States were considered to be poor candidates for paleoclimate records because of the influence of meltwater on isotopic stratigraphy. To evaluate the existence of reliable paleoclimatic records, a 160-m ice core, containing about 250 yr of record was obtained from Upper Fremont Glacier, at an altitude of 4000 m in the Wind River Range of south-central North America. The {gamma}{sup 18}O (SMOW) profile from the core shows a -0.95{per_thousand} shift to lighter values in the interval from 101.8 to 150 m below the surface, corresponding to the latter part of the Little Ice Age (LIA). Numerous high-amplitude oscillations in the section of the core from 101.8 to 150 m cannot be explained by site-specific lateral variability and probably reflect increased seasonality or better preservation of annual signals as a result of prolonged cooler temperatures that existed in this alpine setting. An abrupt decrease in these large amplitude oscillations at the 101.8-m depth suggests a sudden termination of this period of lower temperatures which generally coincides with the termination of the LIA. Three common features in the {gamma}{sup 18}O profiles between Upper Fremont Glacier and themore » better dated Quelccaya Ice Cap cores indicate a global paleoclimate linkage, further supporting the first documented occurrence of the LIA in an ice-core record from a temperate glacier in south-central North America.« less

Mountain snowpacks are a vital natural resource for ∼1.5 billion people in the northern Hemisphere, helping to meet human and ecological demand for water in excess of that provided by summer rain. Springtime warming and aeolian dust deposition accelerate snowmelt, increasing the risk of water shortages during late summer, when demand is greatest. While climate networks provide data that can be used to evaluate the effect of warming on snowpack resources, there are no established regional networks for monitoring aeolian dust deposition to snow. In this study, we test the hypothesis that chemistry of snow, wet deposition, and aerosols can be used as a surrogate for dust deposition to snow. We then analyze spatial patterns and temporal trends in inferred springtime dust deposition to snow across the Rocky Mountains, USA, for 1993–2014. Geochemical evidence, including strong correlations (r2 ≥ 0.94) between Ca2+, alkalinity, and dust concentrations in snow deposited during dust events, indicate that carbonate minerals in dust impart a strong chemical signature that can be used to track dust deposition to snow. Spatial patterns in chemistry of snow, wet deposition, and aerosols indicate that dust deposition increases from north to south in the Rocky Mountains, and temporal trends indicate that winter/spring dust deposition increased by 81% in the southern Rockies during 1993–2014. Using a multivariate modeling approach, we determined that increases in dust deposition and decreases in springtime snowfall combined to accelerate snowmelt timing in the southern Rockies by approximately 7–18 days between 1993 and 2014. Previous studies have shown that aeolian dust emissions may have doubled globally during the 20th century, possibly due to drought and land-use change. Climate projections for increased aridity in the southwestern U.S., northern Africa, and other mid-latitude regions of the northern Hemisphere suggest that aeolian dust emissions may continue to increase, compounding the risk that climate warming poses to snowpack water resources in arid/semi-arid regions of the world.

Changing climate in northern regions is causing permafrost to thaw with major implications for the global mercury (Hg) cycle. We estimated Hg in permafrost regions based on in situ measurements of ...