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Dry deposition of ozone is an important sink of ozone in near surface air. When dry deposition occurs through plant stomata, ozone can injure the plant, altering water and carbon cycling and reducing crop yields. Quantifying both stomatal and nonstomatal uptake accurately is relevant for understanding ozone's impact on human health as an air pollutant and on climate as a potent short-lived greenhouse gas and primary control on the removal of several reactive greenhouse gases and air pollutants. Robust ozone dry deposition estimates require knowledge of the relative importance of individual deposition pathways, but spatiotemporal variability in nonstomatal deposition is poorly understood. Here we integrate understanding of ozone deposition processes by synthesizing research from fields such as atmospheric chemistry, ecology, and meteorology. We critically review methods for measurements and modeling, highlighting the empiricism that underpins modeling and thus the interpretation of observations. Our unprecedented synthesis of knowledge on deposition pathways, particularly soil and leaf cuticles, reveals process understanding not yet included in widely-used models. If coordinated with short-term field intensives, laboratory studies, and mechanistic modeling, measurements from a few long-term sites would bridge the molecular to ecosystem scales necessary to establish the relative importance of individual deposition pathways and the extent to which they vary in space and time. Our recommended approaches seek to close knowledge gaps that currently limit quantifying the impact of ozone dry deposition on air quality, ecosystems, and climate.

The emission, dispersion, and photochemistry of isoprene (C5H8) and related chemical species in the convective boundary layer (CBL) during sunlit daytime were studied over a mixed forest in the southeastern United States by combining ground-based and aircraft observations. Fluxes of isoprene and monoterpenes were quantified at the top of the forest canopy using a high-resolution proton transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS). Snapshot (2 min sampling duration) vertical profiles of isoprene, methyl vinyl ketone (MVK)Cmethacrolein (MACR), and monoterpenes were collected from aircraft every hour in the CBL (100-1000 m). Both ground-based and airborne collected volatile organic compound (VOC) data are used to constrain the initial conditions of a mixed-layer chemistry model (MXLCH), which is applied to examine the chemical evolution of the O3-NOx-HOx-VOC system and how it is affected by boundary layer dynamics in the CBL. The chemical loss rate of isoprene (1 h) is similar to the turbulent mixing timescale (0.1-0.5 h), which indicates that isoprene concentrations are equally dependent on both photooxidation and boundary layer dynamics. Analysis of a modelderived concentration budget suggests that diurnal evolution of isoprene inside the CBL is mainly controlled by surface emissions and chemical loss; the diurnal evolution of O3 is dominated by entrainment. The NO to HO2 ratio (NO :HO2) is used as an indicator of anthropogenic impact on the CBL chemical composition and spans a wide range (1-163). The fate of hydroxyl-substituted isoprene peroxyl radical (HOC5H8OO q; ISOPOO) is strongly affected by NO:HO2, shifting from NO-dominant to NO-HO2-balanced conditions from early morning to noontime. This chemical regime change is reflected in the diurnal evolution of isoprene hydroxynitrates (ISOPN) and isoprene hydroxy hydroperoxides (ISOPOOH).

The Canopy Horizontal Array Turbulence Study (CHATS) experimental study was conducted at a Cilker Orchards's walnut blocks in Dixon, California, before and after leaves emerged, to help improve understanding, simulation capabilities, and modeling of coupled vegetation-atmosphere-land surface interactions. The campaign took place over 12 weeks in the spring of 2007 and was broken into three 4-week phases. Canopy-induced mechanical and thermodynamical vertical variation of turbulence transport characteristics and the linkages between canopy-scale motions and the larger scale planetary boundary layer (PBL) turbulence were measured. The observations focused on measurements characterizing stratification influences on the spatial structure of canopy-induced turbulence, the trace gas source/sink distribution associated with vegetation, and the overall impact of canopy-induced processes on trace gas transport.

This manuscript describes numerical experiments investigating the influence of 2-30-km striplike heterogeneity on wet and dry convective boundary layers coupled to the land surface. The striplike heterogeneity is shown to dramatically alter the structure of the convective boundary layer by inducing significant organized circulations that modify turbulent statistics. The impact, strength, and extent of the organized motions depend critically on the scale of the heterogeneity A relative to the boundary layer height [z.sub.i]. The coupling with the land surface modifies the surface fluxes and hence the circulations resulting in some differences compared to previous studies using fixed surface forcing. Because of the coupling, surface fluxes in the middle of the patches are small compared to the patch edges. At large heterogeneity scales ([lambda][z.sub.i] ~18) horizontal surface-flux gradients within each patch are strong enough to counter the surface-flux gradients between wet and dry patches allowing the formation of small cells within the patch coexisting with the large-scale patch-induced circulations. The strongest patch-induced motions occur in cases with 4 < [lambda]/[z.sub.i] Velocity and scalar fields respond differently to variations of heterogeneity scale. The patch-induced motions have little influence on total vertical scalar flux, but the relative contribution to the flux from organized motions compared to background turbulence varies with heterogeneity scale. Patch-induced motions are shown to dramatically impact point measurements in a free-convective boundary layer. The magnitude and sign of this impact depends on the location of the measurement within the region of heterogeneity.