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A planet's albedo is a fundamental property that sets its energy budget by dictating the fraction of incident radiation absorbed versus reflected back to space. Generally, optical eclipse observations have revealed the majority of hot, giant planets to have low albedos, indicating dayside atmospheres dominated by absorption instead of reflection. However, there are several exceptions to this rule, including the ultra-hot-Neptune LTT 9779b, which have been found to have high geometric albedos. We observed four eclipses of LTT 9779b with the G280 grism of the Hubble Space Telescope's WFC3 UVIS mode; targeting the scattering signatures of the cloud condensate species causing the planet's elevated reflectivity. However, we do not definitively detect the planet's eclipse in our observations, with injection-recovery tests yielding a 3-$\sigma$ upper limit of 113 ppm on the eclipse depth of LTT 9779b in the 0.2-0.8$\mu$m waveband. We create reflectance spectrum grids for LTT 9779b's dayside using VIRGA/PICASO and compare to our UVIS limit, as well as previously published CHEOPS and TESS eclipse photometry. We find that silicate condensates are best able to explain LTT 9779b's highly-reflective dayside. Our forward model grids only enable weak constraints on vertical mixing efficiency, and suggest that, regardless of their particular composition, the clouds are likely composed of smaller and more reflective particles. Our work facilitates a deeper understanding of the reflectance properties of LTT 9779b as well as the UVIS spectroscopic mode itself, which will remain the community's primary access to UV wavelengths until next-generation telescopes like the Habitable Worlds Observatory., Comment: Accepted to MNRAS

GJ 436b is the archetype warm Neptune exoplanet. The planet's thermal emission spectrum was previously observed via intensive secondary eclipse campaigns with Spitzer. The atmosphere has long been interpreted to be extremely metal-rich, out of chemical equilibrium, and potentially tidally heated. We present the first panchromatic emission spectrum of GJ 436b observed with JWST's NIRCAM (F322W2 and F444W) and MIRI (LRS) instruments between 2.4 and 11.9 $\mu$m. Surprisingly, the JWST spectrum appears significantly fainter around 3.6 $\mu$m than that implied by Spitzer photometry. The molecular absorption features in the spectrum are relatively weak, and we only find tentative evidence of CO$_2$ absorption at 2$\sigma$ significance. Under the assumption of a day-side blackbody, we find $T_{\rm day}$=662.8$\pm$5.0 K, which is similar to the zero Bond albedo equilibrium temperature. We use it to obtain a 3$\sigma$ upper limit on the Bond albedo of $A_B{\le}$0.66. To understand the spectrum we employ 1D radiative-convective models but find that atmospheric constraints depend strongly on model assumptions. If thermochemical equilibrium is assumed, we find a cloudy metal-enriched atmosphere (metallicity $\ge$ 300$\times$solar). We employ 1D photochemical modeling to show that the observed spectrum is also consistent with a cloud-free, relatively lower-metallicity atmosphere (metallicity $\ge$ 80$\times$solar) with a cold internal temperature ($T_{\rm int}$$\sim$60 K). These are much lower metallicities and internal temperatures than inferences from Spitzer photometry. The low $T_{\rm day}$ and non-detection of transmission features at high spectral resolution does suggest a role for cloud opacity, but this is not definitive., Comment: Accepted for publication in ApJL, 27 Pages, 17 Figures

Ultra-hot Jupiters, an extreme class of planets not found in our solar system, provide a unique window into atmospheric processes. The extreme temperature contrasts between their day- and night-sides pose a fundamental climate puzzle: how is energy distributed? To address this, we must observe the 3D structure of these atmospheres, particularly their vertical circulation patterns, which can serve as a testbed for advanced Global Circulation Models (GCM) [e.g. 1]. Here, we show a dramatic shift in atmospheric circulation in an ultra-hot Jupiter: a unilateral flow from the hot star-facing side to the cooler space-facing side of the planet sits below an equatorial super-rotational jet stream. By resolving the vertical structure of atmospheric dynamics, we move beyond integrated global snapshots of the atmosphere, enabling more accurate identification of flow patterns and allowing for a more nuanced comparison to models. Global circulation models based on first principles struggle to replicate the observed circulation pattern [3], underscoring a critical gap between theoretical understanding of atmospheric flows and observational evidence. This work serves as a testbed to develop more comprehensive models applicable beyond our Solar System as we prepare for the next generation of giant telescopes., Comment: Accepted for publication in Nature on 16th January 2025, published with DOI 10.1038/s41586-025-08664-1, 5 main figures, 12 main pages plus methods. This work has a companion paper on the same dataset: Prinoth et al. 2025, A&A, DOI: 10.1051/0004-6361/202452405

High-resolution spectroscopy has provided a wealth of information about the climate and composition of ultra-hot Jupiters. However, the 3D structure of their atmospheres makes observations more challenging to interpret, necessitating 3D forward-modeling studies. In this work, we model phase-dependent thermal emission spectra of the archetype ultra-hot Jupiter WASP-76b to understand how the line strengths and Doppler shifts of Fe, CO, H$_2$O, and OH evolve throughout the orbit. We post-process outputs of the SPARC/MITgcm global circulation model with the 3D Monte-Carlo radiative transfer code gCMCRT to simulate emission spectra at 36 orbital phases. We then cross-correlate the spectra with different templates to obtain CCF and $K_{\text{p}}$$-$$V_{\text{sys}}$ maps. For each species, our models produce consistently negative $K_{\text{p}}$ offsets in pre- and post-eclipse, which are driven by planet rotation. The size of these offsets is similar to the equatorial rotation velocity of the planet. Furthermore, we demonstrate how the weak vertical temperature gradient on the nightside of ultra-hot Jupiters mutes the absorption features of CO and H$_2$O, which significantly hampers their detectability in pre- and post-transit. We also show that the $K_{\text{p}}$ and $V_{\text{sys}}$ offsets in pre- and post-transit are not always a measure for the line-of-sight velocities in the atmosphere. This is because the cross-correlation signal is a blend of dayside emission and nightside absorption features. Finally, we highlight that the observational uncertainty in the known orbital velocity of ultra-hot Jupiters can be multiple km/s, which makes it hard for certain targets to meaningfully report absolute $K_{\text{p}}$ offsets., Comment: 23 pages, 18 figures, submitted to AAS journals

Highly-irradiated gas giant exoplanets are predicted to show circulation patterns dominated by day-to-night heat transport and a spatial distribution of clouds that is driven by advection and local heating. Hot-Jupiters have been extensively studied from broadband phase-curve observations at infrared and optical wavelengths, but spectroscopic observations in the reflected light are rare and the regime of smaller and higher-metallicity ultra-hot planets, such as hot-Neptunes, remains largely unexplored to date. Here we present the phase-resolved reflected-light and thermal-emission spectroscopy of the ultra-hot Neptune LTT 9779b, obtained through observing its full phase-curve from 0.6 to 2.8 $\mu$m with JWST NIRISS/SOSS. We detect an asymmetric dayside in reflected light (3.1$\sigma$ significance) with highly-reflective white clouds on the western dayside (A = 0.79$\pm$0.15) and a much lower-albedo eastern dayside (A = 0.41$\pm$0.10), resulting in an overall dayside albedo of A = 0.50$\pm$0.07. The thermal phase curve is symmetric about the substellar point, with a dayside effective temperature of T$_\mathrm{eff,day}$ = 2,260$^{+40}_{-50}$ K and a cold nightside (T$_\mathrm{eff,night}$ <1,330 K at 3-$\sigma$ confidence), indicative of short radiative timescales. We propose an atmospheric circulation and cloud distribution regime in which heat is transported eastward from the dayside towards the cold nightside by an equatorial jet, leading to a colder western dayside where temperatures are sufficiently low for the condensation of silicate clouds., Comment: Accepted for publication

Irradiated brown dwarfs offer a unique opportunity to bridge the gap between stellar and planetary atmospheres. We present high-quality $\mathit{HST}$/WFC3/G141 phase-resolved spectra of the white dwarf + brown dwarf binary GD 1400, covering more than one full rotation of the brown dwarf. Accounting for brightness variations caused by ZZ Ceti pulsations, we revealed weak ($\sim$1\%) phase curve amplitude modulations originating from the brown dwarf. Sub-band light curve exploration in various bands showed no significant wavelength dependence on amplitude or phase shift. Extracted day- and night-side spectra indicated chemically similar hemispheres, with slightly higher day-side temperatures, suggesting efficient heat redistribution or dominance of radiative escape over atmospheric circulation. A simple radiative and energy redistribution model reproduced observed temperatures well. Cloud-inclusive models fit the day and night spectra better than cloudless models, indicating global cloud coverage. We also begin qualitatively exploring atmospheric trends across six irradiated brown dwarfs, from the now complete "Dancing with Dwarfs" WD$-$BD sample. The trend we find in the day-side/night-side temperature and irradiation levels is consistent with efficient heat redistribution for irradiation levels less than $\sim$10$^9$ ergs/s/cm$^2$ and decreasing efficiency above that level., Comment: accepted to the Astrophysical Journal, 24 Dec 2024

Measuring the abundances of carbon- and oxygen-bearing molecules has been a primary focus in studying the atmospheres of hot Jupiters, as doing so can help constrain the carbon-to-oxygen (C/O) ratio. The C/O ratio can help reveal the evolution and formation pathways of hot Jupiters and provide a strong understanding of the atmospheric composition. In the last decade, high-resolution spectral analyses have become increasingly useful in measuring precise abundances of several carbon- and oxygen-bearing molecules. This allows for a more precise constraint of the C/O ratio. We present four transits of the hot Jupiter WASP-43b observed between 1.45 $-$ 2.45 $\mu$m with the high-resolution Immersion GRating InfraRed Spectrometer (IGRINS) on the Gemini-S telescope. We detected H$_2$O at a signal-to-noise ratio (SNR) of 3.51. We tested for the presence of CH$_4$, CO, and CO$_2$, but we did not detect these carbon-bearing species. We ran a retrieval for all four molecules and obtained a water abundance of $\log_{10}(\text{H}_2\text{O}) = -2.24^{+0.57}_{-0.48}$. We obtained an upper limit on the C/O ratio of C/O $<$ 0.95. These findings are consistent with previous observations from the Hubble Space Telescope and the James Webb Space Telescope., Comment: 11 pages, 6 figures

One of the outstanding goals of the planetary science community is to measure the present-day atmospheric composition of planets and link this back to formation. As giant planets are formed by accreting gas, ices, and rocks, constraining the relative amounts of these components is critical to understand their formation and evolution. For most known planets, including the Solar System giants, this is difficult as they reside in a temperature regime where only volatile elements (e.g., C, O) can be measured, while refractories (e.g., Fe, Ni) are condensed to deep layers of the atmosphere where they cannot be remotely probed. With temperatures allowing for even rock-forming elements to be in the gas phase, ultra-hot Jupiter atmospheres provide a unique opportunity to simultaneously probe the volatile and refractory content of giant planets. Here we directly measure and obtain bounded constraints on the abundances of volatile C and O as well as refractory Fe and Ni on the ultra-hot giant exoplanet WASP-121b. We find that ice-forming elements are comparatively enriched relative to rock-forming elements, potentially indicating that WASP-121b formed in a volatile-rich environment much farther away from the star than where it is currently located. The simultaneous constraint of ice and rock elements in the atmosphere of WASP-121b provides insights into the composition of giant planets otherwise unattainable from Solar System observations., Comment: 24 pages, 9 figures, 2 tables, Accepted for publication in The Astronomical Journal

A primary goal of exoplanet science is to measure the atmospheric composition of gas giants in order to infer their formation and migration histories. Common diagnostics for planet formation are the atmospheric metallicity ([M/H]) and the carbon-to-oxygen (C/O) ratio as measured through transit or emission spectroscopy. The C/O ratio in particular can be used to approximately place a planet's initial formation radius from the stellar host, but a given C/O ratio may not be unique to formation location. This degeneracy can be broken by combining measurements of both the C/O ratio and the atmospheric refractory-to-volatile ratio. We report the measurement of both quantities for the atmosphere of the canonical ultra hot Jupiter WASP-121 b using the high resolution (R=45,000) IGRINS instrument on Gemini South. Probing the planet's direct thermal emission in both pre- and post-secondary eclipse orbital phases, we infer that WASP-121 b has a significantly super-stellar C/O ratio of 0.70$^{+0.07}_{-0.10}$ and a moderately super-stellar refractory-to-volatile ratio at 3.83$^{+3.62}_{-1.67} \times$ stellar. This combination is most consistent with formation between the soot line and H$_2$O snow line, but we cannot rule out formation between the H$_2$O and CO snow lines or beyond the CO snow line. We also measure velocity offsets between H$_2$O, CO, and OH, potentially an effect of chemical inhomogeneity on the planet day side. This study highlights the ability to measure both C/O and refractory-to-volatile ratios via high resolution spectroscopy in the near-infrared H and K bands., Comment: 21 pages, 15 figures, accepted to AJ

GJ1214b is the archetype sub-Neptune for which thick aerosols have prevented us from constraining its atmospheric properties for over a decade. In this study, we leverage the panchromatic transmission spectrum of GJ1214b established by HST and JWST to investigate its atmospheric properties using a suite of atmospheric radiative transfer, photochemistry, and aerosol microphysical models. We find that the combined HST, JWST/NIRSpec and JWST/MIRI spectrum can be well-explained by atmospheric models with an extremely high metallicity of [M/H]$\sim$3.5 and an extremely high haze production rate of $F_{\rm haze}{\sim}10^{-8}$--$10^{-7}$ g cm$^{-2}$ s$^{-1}$. Such high atmospheric metallicity is suggested by the relatively strong CO2 feature compared to the haze absorption feature or the CH4 feature in the NIRSpec-G395H bandpass of 2.5--5 $\mu$m. The flat 5--12 $\mu$m MIRI spectrum also suggests a small scale height with a high atmospheric metallicity that is needed to suppress a prominent 6 $\mu$m haze feature. We tested the sensitivity of our interpretation to various assumptions for uncertain haze properties, such as optical constants and production rate, and all models tested here consistently suggest extremely high metallicity. Thus, we conclude that GJ1214b likely has a metal-dominated atmosphere where hydrogen is no longer the main atmospheric constituent. We also find that different assumptions for the haze production rate lead to distinct inferences for the atmospheric C/O ratio. We stress the importance of high precision follow-up observations to confirm the metal-dominated atmosphere and to constrain the C/O ratio, which provides further insights on the planet formation process. The confirmation of the metal-dominated atmosphere is particularly crucial, as it challenges the conventional understanding of interior structure and evolution of sub-Neptunes., Comment: 22 pages, 10 figures, Published in ApJL, Please also see a companion paper Schlawin et al. (2024)

Sub-Neptune planets with radii smaller than Neptune (3.9 Re) are the most common type of planet known to exist in The Milky Way, even though they are absent in the Solar System. These planets can potentially have a large diversity of compositions as a result of different mixtures of rocky material, icy material and gas accreted from a protoplanetary disk. However, the bulk density of a sub-Neptune, informed by its mass and radius alone, cannot uniquely constrain its composition; atmospheric spectroscopy is necessary. GJ 1214 b, which hosts an atmosphere that is potentially the most favorable for spectroscopic detection of any sub-Neptune, is instead enshrouded in aerosols (thus showing no spectroscopic features), hiding its composition from view at previously observed wavelengths in its terminator. Here, we present a JWST NIRSpec transmission spectrum from 2.8 to 5.1 um that shows signatures of carbon dioxide and methane, expected at high metallicity. A model containing both these molecules is preferred by 3.3 and 3.6 sigma as compared to a featureless spectrum for two different data analysis pipelines, respectively. Given the low signal-to-noise of the features compared to the continuum, however, more observations are needed to confirm the carbon dioxide and methane signatures and better constrain other diagnostic features in the near-infrared. Further modeling of the planet's atmosphere, interior structure and origins will provide valuable insights about how sub-Neptunes like GJ 1214 b form and evolve., Comment: 22 pages, 11 figures, Accepted in ApJL, Please also see a companion paper Ohno et al. (2024)

The extreme environments of transiting close-in exoplanets in highly-eccentric orbits are ideal for testing exo-climate physics. Spectroscopically resolved phase curves not only allow for the characterization of their thermal response to irradiation changes but also unveil phase-dependent atmospheric chemistry and dynamics. We observed a partial phase curve of the highly-eccentric close-in giant planet HAT-P-2b ($e=0.51,M=9M_{\rm{Jup}}$) with the Wide Field Camera 3 aboard the Hubble Space Telescope. Using these data, we updated the planet's orbital parameters and radius, and retrieved high-frequency pulsations consistent with the planet-induced pulsations reported in Spitzer data. We found that the peak in planetary flux occurred at $6.7\pm0.6$ hr after periastron, with a heating and cooling timescales of $9.0^{+3.5}_{-2.1}$ hr, and $3.6^{+0.7}_{-0.6}$ hr, respectively. We compare the light-curve to various 1-dimensional and 3-dimensional forward models, varying the planet's chemical composition. The strong contrast in flux increase and decrease timescales before and after periapse indicates an opacity term that emerges during the planet's heating phase, potentially due to more H$^{-}$ than expected from chemical equilibrium models. The phase-resolved spectra are largely featureless, that we interpret as indicative an inhomogeneous dayside. However, we identified an anomalously high flux in the spectroscopic bin coinciding with the hydrogen Paschen $\beta$ line and that is likely connected to the planet's orbit. We interpret this as due to shock heating of the upper atmosphere given the short timescale involved, or evidence for other star-planet interactions., Comment: In review in AJ

The Hubble Space Telescope has been a pioneering instrument for studying the atmospheres of exoplanets, specifically its WFC3 and STIS instruments. With the launch of JWST, we are able to observe larger spectral ranges at higher precision. NIRISS/SOSS covers the range 0.6--2.8 microns, and thus can serve as a direct comparison to WFC3 (0.8--1.7 microns). We perform atmospheric retrievals of WFC3 and NIRISS transmission spectra of WASP-39 b in order to compare their constraining power. We find that NIRISS is able to retrieve precise H2O abundances that do not suffer a degeneracy with the continuum level, due to the coverage of multiple spectral features. We also combine these datasets with spectra from STIS, and find that challenges associated with fitting the steep optical slope can bias the retrieval results. In an effort to diagnose the differences between the WFC3 and NIRISS retrievals, we perform the analysis again on the NIRISS data cut to the same wavelength range as WFC3. We find that the water abundance is in strong disagreement with both the WFC3 and full NIRISS retrievals, highlighting the importance of wide wavelength coverage. Finally, we carry out mock retrievals on the different instruments, which shows further evidence of the challenges in constraining water abundance from the WFC3 data alone. Our study demonstrates the vast information gain of JWST's NIRISS instrument over WFC3, highlighting the insights to be obtained from our new era of space-based instruments., Comment: 21 pages, 17 figures; Accepted for publication in MNRAS

Due to their short orbital periods and relatively high flux ratios, irradiated brown dwarfs in binaries with white dwarfs offer better opportunities to study irradiated atmospheres than hot Jupiters, which have lower planet-to-star flux ratios. WD1032+011 is an eclipsing, tidally locked white dwarf-brown dwarf binary with a 9950 K white dwarf orbited by a 69.7 M$_{Jup}$ brown dwarf in a 0.09 day orbit. We present time-resolved Hubble Space Telescope Wide Field Camera 3 spectrophotometric data of WD1032+011. We isolate the phase-dependent spectra of WD1032+011B, finding a 210 K difference in brightness temperature between the dayside and nightside. The spectral type of the brown dwarf is identified as L1 peculiar, with atmospheric retrievals and comparison to field brown dwarfs showing evidence for a cloud-free atmosphere. The retrieved temperature of the dayside is $1748^{+66}_{-67}$ K, with a nightside temperature of $1555^{+76}_{-62}$ K, showing an irradiation-driven temperature contrast coupled with inefficient heat redistribution from the dayside to the nightside. The brown dwarf radius is inflated, likely due to the constant irradiation from the white dwarf, making it the only known inflated brown dwarf in an eclipsing white dwarf-brown dwarf binary., Comment: 20 pages, 23 figures. Accepted for Publication in MNRAS

Although exoplanetary science was not initially projected to be a substantial part of the Spitzer mission, its exoplanet observations set the stage for current and future surveys with JWST and Ariel. We present a comprehensive reduction and analysis of Spitzer's 4.5 micron phase curves of 29 hot Jupiters on low-eccentricity orbits. The analysis, performed with the Spitzer Phase Curve Analysis (SPCA) pipeline, confirms that BLISS mapping is the best detrending scheme for most, but not all, observations. Visual inspection remains necessary to ensure consistency across detrending methods due to the diversity of phase curve data and systematics. Regardless of the model selection scheme - whether using the lowest-BIC or a uniform detrending approach - we observe the same trends, or lack thereof. We explore phase curve trends as a function of irradiation temperature, orbital period, planetary radius, mass, and stellar effective temperature. We discuss the trends that are robustly detected and provide potential explanations for those that are not observed. While it is almost tautological that planets receiving greater instellation are hotter, we are still far from confirming dynamical theories of heat transport in hot Jupiter atmospheres due to the sample's diversity. Even among planets with similar temperatures, other factors like rotation and metallicity vary significantly. Larger, curated sample sizes and higher-fidelity phase curve measurements from JWST and Ariel are needed to firmly establish the parameters governing day-night heat transport on synchronously rotating planets., Comment: 16 pages, 6 figures, submitted to AAS journal

We present a population-level analysis of the dayside thermal emission spectra of 19 planets observed with Hubble WFC3 and Spitzer IRAC 3.6 and 4.5 microns, spanning equilibrium temperatures 1200-2700 K and 0.7-10.5 Jupiter masses. We use grids of planet-specific 1D, cloud-free, radiative-convective-thermochemical equilibrium models (1D-RCTE) combined with a Bayesian inference framework to estimate atmospheric metallicity, the carbon-to-oxygen ratio, and day-to-night heat redistribution. In general, we find that the secondary eclipse data cannot reject the physics encapsulated within the 1D-RCTE assumption parameterized with these three variables. We find a large degree of scatter in atmospheric metallicities, with no apparent trend, and carbon-to-oxygen ratios that are mainly consistent with solar or subsolar values but do not exhibit population agreement. Together, these indicate either (1) formation pathways vary over the hot and ultra-hot Jupiter population and/or (2) more accurate composition measurements are needed to identify trends. We also find a broad scatter in derived dayside temperatures that do not demonstrate a trend with equilibrium temperature. Like with composition estimates, this suggests either significant variability in climate drivers over the population and/or more precise dayside temperature measurements are needed to identify a trend. We anticipate that 1D-RCTE models will continue to provide valuable insights into the nature of exoplanet atmospheres in the era of JWST., Comment: Published in The Astrophysical Journal

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ \mu$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator., Comment: Published in Nature at https://www.nature.com/articles/s41586-024-07768-4. All code to produce plots (with data) can be found at https://github.com/nespinoza/wasp39-terminators

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $\mu$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $\mu$m in the 5-12 $\mu$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$\sigma$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $\mu$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range., Comment: Published in Nature

WASP-69 b is a hot, inflated, Saturn-mass planet 0.26 Mjup with a zero-albedo equilibrium temperature of 963 K. Here, we report the JWST 2 to 12 um emission spectrum of the planet consisting of two eclipses observed with NIRCam grism time series and one eclipse observed with MIRI LRS. The emission spectrum shows absorption features of water vapor, carbon dioxide and carbon monoxide, but no strong evidence for methane. WASP-69 b's emission spectrum is poorly fit by cloud-free homogeneous models. We find three possible model scenarios for the planet: 1) a Scattering Model that raises the brightness at short wavelengths with a free Geometric Albedo parameter 2) a Cloud Layer model that includes high altitude silicate aerosols to moderate long wavelength emission and 3) a Two-Region model that includes significant dayside inhomogeneity and cloud opacity with two different temperature-pressure profiles. In all cases, aerosols are needed to fit the spectrum of the planet. The Scattering model requires an unexpectedly high Geometric Albedo of 0.64. Our atmospheric retrievals indicate inefficient redistribution of heat and an inhomogeneous dayside distribution, which is tentatively supported by MIRI LRS broadband eclipse maps that show a central concentration of brightness. Our more plausible models (2 and 3) retrieve chemical abundances enriched in heavy elements relative to solar composition by 6x to 14x solar and a C/O ratio of 0.65 to 0.94, whereas the less plausible highly reflective scenario (1) retrieves a slightly lower metallicity and lower C/O ratio., Comment: 41 pages, 19 figures, accepted to the Astronomical Journal

The atmospheric properties of hot exoplanets are expected to be different between the morning and the evening limb due to global atmospheric circulation. Ground-based observations at high spectral resolution have detected this limb asymmetry in several ultra-hot (>2000 K) exoplanets, but the prevalence of the phenomenon in the broader exoplanetary population remains unexplored. Here we use JWST/NIRCam transmission spectra between 2.5 and 4.0 $\mu$m to find evidence of limb asymmetry on exoplanet WASP-107 b. With its equilibrium temperature of 770 K and low density of 0.126 gm c$^{-3}$, WASP-107 b probes a very different regime compared to ultra-hot giant planets and was not expected to exhibit substantial spatial heterogeneity according to atmospheric models. We infer instead a morning-evening temperature difference on the order of 100 K with a hotter evening limb. Further observations on other cooler exoplanets are needed to determine whether WASP-107 b is an outlier or the models underestimate the presence of limb asymmetry in exoplanets., Comment: This preprint has not undergone any significant improvements or corrections. This article's Version of Record has been published in Nature Astronomy and can be found at https://www.nature.com/articles/s41550-024-02367-9. Enclosed is the main text, 4 main text figures, methods, 3 Extended Data items, and 5 Supplementary Information items

Ultra-hot Jupiters are among the best targets for atmospheric characterization at high spectral resolution. Resolving their transmission spectra as a function of orbital phase offers a unique window into the 3D nature of these objects. In this work, we present three transits of the ultra-hot Jupiter WASP-121b observed with Gemini-S/IGRINS. For the first time, we measure the phase-dependent absorption signals of CO and H$_{\text{2}}$O in the atmosphere of an exoplanet, and we find that they are different. While the blueshift of CO increases during the transit, the absorption lines of H$_{\text{2}}$O become less blueshifted with phase, and even show a redshift in the second half of the transit. These measurements reveal the distinct spatial distributions of both molecules across the atmospheres of ultra-hot Jupiters. Also, we find that the H$_{\text{2}}$O signal is absent in the first quarter of the transit, potentially hinting at cloud formation on the evening terminator of WASP-121b. To further interpret the absorption trails of CO and H$_{\text{2}}$O, as well as the Doppler shifts of Fe previously measured with VLT/ESPRESSO, we compare the data to simulated transits of WASP-121b. To this end, we post-processes the outputs of global circulation models with a 3D Monte-Carlo radiative transfer code. Our analysis shows that the atmosphere of WASP-121b is subject to atmospheric drag, as previously suggested by small hotspot offsets inferred from phase-curve observations. Our study highlights the importance of phase-resolved spectroscopy in unravelling the complex atmospheric structure of ultra-hot Jupiters and sets the stage for further investigations into their chemistry and dynamics., Comment: 24 pages, 16 figures, accepted for publication in PASP

We report observations of the atmospheric transmission spectrum of the sub-Neptune exoplanet GJ 3470 b taken using the Near-Infrared Camera (NIRCam) on JWST. Combined with two archival HST/WFC3 transit observations and fifteen archival Spitzer transit observations, we detect water, methane, sulfur dioxide, and carbon dioxide in the atmosphere of GJ 3470 b, each with a significance of >3-sigma. GJ 3470 b is the lowest mass -- and coldest -- exoplanet known to show a substantial sulfur dioxide feature in its spectrum, at $M_{p}$=11.2${\,{\rm M}_{\oplus}}$ and $T_{eq}$=600$\,$K. This indicates disequilibrium photochemistry drives sulfur dioxide production in exoplanet atmospheres over a wider range of masses and temperatures than has been reported or expected. The water, carbon dioxide, and sulfur dioxide abundances we measure indicate an atmospheric metallicity of approximately $100\times$ Solar. We see further evidence for disequilibrium chemistry in our inferred methane abundance, which is significantly lower than expected from equilibrium models consistent with our measured water and carbon dioxide abundances., Comment: 25 pages, 9 figures, 6 tables. Accepted in Astrophysical Journal Letters

Spectroscopic phase curves of hot Jupiters measure their emission spectra at multiple orbital phases, thus enabling detailed characterisation of their atmospheres. Precise constraints on the atmospheric composition of these exoplanets offer insights into their formation and evolution. We analyse four phase-resolved emission spectra of the hot Jupiter WASP-43b, generated from a phase curve observed with the MIRI/LRS onboard the JWST, to retrieve its atmospheric properties. Using a parametric 2D temperature model and assuming a chemically homogeneous atmosphere within the observed pressure region, we simultaneously fit the four spectra to constrain the abundances of atmospheric constituents, thereby yielding more precise constraints than previous work that analysed each spectrum independently. Our analysis reveals statistically significant evidence of NH3 (4$\sigma$) in a hot Jupiter's emission spectra for the first time, along with evidence of H2O (6.5$\sigma$), CO (3.1$\sigma$), and a non-detection of CH4. With our abundance constraints, we tentatively estimate the metallicity of WASP-43b at 0.6-6.5$\times$solar and its C/O ratio at 0.6-0.9. Our findings offer vital insights into the atmospheric conditions and formation history of WASP-43b by simultaneously constraining the abundances of carbon, oxygen, and nitrogen-bearing species., Comment: 17 pages, 14 figures, accepted for publication in MNRAS. Comments welcome!

Eclipse mapping uses the shape of the eclipse of an exoplanet to measure its two-dimensional structure. Light curves are mostly composed of longitudinal information, with the latitudinal information only contained in the brief ingress and egress of the eclipse. This imbalance can lead to a spuriously confident map, where the longitudinal structure is constrained by out-of-eclipse data and the latitudinal structure is wrongly determined by the priors on the map. We present a new method to address this issue. The method tests for the presence of an eclipse mapping signal by using k-fold cross-validation to compare the performance of a simple mapping model to the null hypothesis of a uniform disk. If a signal is found, the method fits a map with more degrees of freedom, optimising its information content. The information content is varied by penalising the model likelihood by a factor proportional to the spatial entropy of the map, optimised by cross-validation. We demonstrate this method for simulated datasets then apply it to three observational datasets. The method identifies an eclipse mapping signal for JWST MIRI/LRS observations of WASP-43b but does not identify a signal for JWST NIRISS/SOSS observations of WASP-18b or Spitzer Space Telescope observations of HD 189733b. It is possible to fit eclipse maps to these datasets, but we suggest that these maps are overfitting the eclipse shape. We fit a new map with more spatial freedom to the WASP-43b dataset and show a flatter east-west structure than previously derived., Comment: Accepted at MNRAS

Interactions between exoplanetary atmospheres and internal properties have long been hypothesized to be drivers of the inflation mechanisms of gaseous planets and apparent atmospheric chemical disequilibrium conditions. However, transmission spectra of exoplanets has been limited in its ability to observational confirm these theories due to the limited wavelength coverage of HST and inferences of single molecules, mostly H$_2$O. In this work, we present the panchromatic transmission spectrum of the approximately 750 K, low-density, Neptune-sized exoplanet WASP-107b using a combination of HST WFC3, JWST NIRCam and MIRI. From this spectrum, we detect spectroscopic features due to H$_2$O (21$\sigma$), CH$_4$ (5$\sigma$), CO (7$\sigma$), CO$_2$ (29$\sigma$), SO$_2$ (9$\sigma$), and NH$_3$ (6$\sigma$). The presence of these molecules enable constraints on the atmospheric metal enrichment (M/H is 10--18$\times$ Solar), vertical mixing strength (log$_{10}$K$_{zz}$=8.4--9.0 cm$^2$s$^{-1}$), and internal temperature ($>$345 K). The high internal temperature is suggestive of tidally-driven inflation acting upon a Neptune-like internal structure, which can naturally explain the planet's large radius and low density. These findings suggest that eccentricity driven tidal heating is a critical process governing atmospheric chemistry and interior structure inferences for a majority of the cool ($<$1,000K) super-Earth-to-Saturn mass exoplanet population., Comment: This preprint has not undergone any substantive post-submission improvements or corrections. The Version of Record of this article is published in Nature here: https://www.nature.com/articles/s41586-024-07514-w

High-resolution cross-correlation spectroscopy (HRCCS) combined with adaptive optics has been enormously successful in advancing our knowledge of exoplanet atmospheres, from chemistry to rotation and atmospheric dynamics. This powerful technique now drives major science cases for ELT instrumentation including METIS/ELT, GMTNIRS/GMT and MICHI/TMT, targeting biosignatures on rocky planets at 3-5 $\mu$m, but remains untested beyond 3.5 $\mu$m where the sky thermal background begins to provide the dominant contribution to the noise. We present 3.51-5.21 $\mu$m M-band CRIRES+/VLT observations of the archetypal young directly imaged gas giant $\beta$ Pictoris b, detecting CO absorption at S/N = 6.6 at 4.73 $\mu$m and H$_2$O at S/N = 5.7, and thus extending the use of HRCCS into the thermal background noise dominated infrared. Using this novel spectral range to search for more diverse chemistry we report marginal evidence of SiO at S/N = 4.3, potentially indicative that previously proposed magnesium-silicate clouds in the atmosphere are either patchy, transparent at M-band wavelengths, or possibly absent on the planetary hemisphere observed. The molecular detections are rotationally broadened by the spin of $\beta$ Pic b, and we infer a planetary rotation velocity of $v$sin(i) = 22$\pm$2 km s$^{-1}$ from the cross-correlation with the H$_2$O model template, consistent with previous K-band studies. We discuss the observational challenges posed by the thermal background and telluric contamination in the M-band, the custom analysis procedures required to mitigate these issues, and the opportunities to exploit this new infrared window for HRCCS using existing and next-generation instrumentation., Comment: 17 pages, 20 figures. Accepted for publication in MNRAS

We present eclipse maps of the two-dimensional thermal emission from the dayside of the hot Jupiter WASP-43b, derived from an observation of a phase curve with the JWST MIRI/LRS instrument. The observed eclipse shapes deviate significantly from those expected for a planet emitting uniformly over its surface. We fit a map to this deviation, constructed from spherical harmonics up to order $\ell_{\rm max}=2$, alongside the planetary, orbital, stellar, and systematic parameters. This yields a map with a meridionally-averaged eastward hot-spot shift of $(7.75 \pm 0.36)^{\circ}$, with no significant degeneracy between the map and the additional parameters. We show the latitudinal and longitudinal contributions of the day-side emission structure to the eclipse shape, finding a latitudinal signal of $\sim$200 ppm and a longitudinal signal of $\sim$250 ppm. To investigate the sensitivity of the map to the method, we fix the non-mapping parameters and derive an "eigenmap" fitted with an optimised number of orthogonal phase curves, which yields a similar map to the $\ell_{\rm max}=2$ map. We also fit a map up to $\ell_{\rm max}=3$, which shows a smaller hot-spot shift, with a larger uncertainty. These maps are similar to those produced by atmospheric simulations. We conclude that there is a significant mapping signal which constrains the spherical harmonic components of our model up to $\ell_{\rm max}=2$. Alternative mapping models may derive different structures with smaller-scale features; we suggest that further observations of WASP-43b and other planets will drive the development of more robust methods and more accurate maps., Comment: Accepted for publication in The Astronomical Journal

We present an atmospheric retrieval analysis of HST/WFC3/G141 spectroscopic phase curve observations of two brown dwarfs, WD-0137B and EPIC-2122B, in ultra-short period orbits around white dwarf hosts. These systems are analogous to hot and ultra-hot Jupiter systems, enabling a unique and high-precision comparison to exoplanet systems. We use the PETRA retrieval suite to test various analysis setups, including joint-phase retrievals, multiple temperature structures, and non-uniform abundances. We find that WD-0137B has a dayside that closely resembles that of other ultra-hot Jupiters with inverted temperature structures and H$^-$ opacity, but quickly transitions to a mostly non-inverted temperature structure on the nightside. Meanwhile, EPIC-2122B's atmosphere remains inverted at all constrained longitudes, with dominant H$^-$ opacity. Retrievals with multiple temperature profiles and non-uniform vertical abundances were generally not statistically justified for this dataset, but retrievals with dayside-dilution factors were found to be justified. Retrieving all phases simultaneously with a linear combination of a dayside and nightside atmosphere was found to be an adequate representation of the entire phase-curve once a longitudinal temperature gradient free parameter was included in the retrieval. Comparing to global circulation models, we attribute behavior in the 1D retrievals to the inclined viewing geometry of the systems, which results in always-visible irradiated and inverted portions of the atmosphere "contaminating" spectra measured from the nightside hemisphere. This study sheds light on the similarities between these irradiated brown dwarf systems and hot and ultra-hot Jupiters, but also their unique differences, including the influence of the inclined viewing geometry., Comment: 19 pages, 15 figures, 3 tables. Accepted for publication in ApJ

The population of hot Jupiters is extremely diverse, with large variations in their irradiation, period, gravity and chemical composition. To understand the intrinsic planet diversity through the observed population level trends, we explore the a-priori scatter in the population created by the different responses of atmospheric circulation to planetary parameters. We use the SPARC/MITgcm 3D global circulation model to simulate 345 planets spanning a wide range of instellation, metallicity, gravity and rotation periods typical for hot Jupiters, while differentiating between models with and without TiO/VO in their atmosphere. We show that the combined effect of the planetary parameters leads to a large diversity in the ability of atmospheres to transport heat from day-side to night-side at a given equilibrium temperature. We further show that the hot-spot offset is a non-monotonic function of planetary rotation period and explain our findings by a competition between the rotational and divergent parts of the circulation. As a consequence, hot-spot offset and phase curve amplitude are not necessarily correlated. Finally, we compare the observables from our grid to the population of Spitzer and Hubble observations of hot Jupiters. We find that the sudden jump in brightness temperature observed in the Spitzer secondary eclipse measurements can be naturally explained by the cold-trapping of TiO/VO at approximately 1800K. The grid of modelled spectra, phase curves and thermal structures are made available to the community, together with a python code for visualization of the grid properties, at https://doi.org/10.5281/zenodo.10785321 and http://sim3d.oca.eu/., Comment: 28 pages, 25 figures, accepted in MNRAS

Brown dwarfs in ultra-short period orbits around white dwarfs offer a unique opportunity to study the properties of tidally-locked, fast rotating (1-3 hr), and highly-irradiated atmospheres. Here, we present phase-resolved spectrophotometry of the white dwarf-brown dwarf (WD-BD) binary SDSS 1557, which is the fifth WD-BD binary in our six-object sample. Using the Hubble Space Telescope Wide Field Camera 3 Near-infrared G141 instrument, the 1.1 to 1.7 $\mu$m phase curves show rotational modulations with semi-amplitudes of 10.5$\pm$0.1%. We observe a wavelength dependent amplitude, with longer wavelengths producing larger amplitudes, while no wavelength dependent phase shifts were identified. The phase-resolved extracted BD spectra exhibit steep slopes and are nearly featureless. A simple radiative energy redistribution atmospheric model recreates the hemisphere integrated brightness temperatures at three distinct phases and finds evidence for weak redistribution efficiency. Our model also predicts a higher inclination than previously published. We find that SDSS 1557B, the second most irradiated BD in our sample, is likely dominated by clouds on the night side, whereas the featureless day side spectrum is likely dominated by H$^-$ opacity and a temperature inversion, much like the other highly-irradiated BD EPIC2122B., Comment: 19 pages and 11 figures. Accepted to Astrophysical Journal

Measuring the abundances of C- and O-bearing species in exoplanet atmospheres enables us to constrain the C/O ratio, that contains indications about the planet formation history. With a wavelength coverage going from 0.95 to 2.5 microns, the high-resolution (R$\sim$70 000) spectropolarimeter SPIRou can detect spectral lines of major bearers of C and O in exoplanets. Here we present our study of SPIRou transmission spectra of WASP-76 b acquired for the ATMOSPHERIX program. We applied the publicly available data analysis pipeline developed within the ATMOSPHERIX consortium, analysing the data using 1-D models created with the petitRADTRANS code, with and without a grey cloud deck. We report the detection of H$_2$O and CO at a Doppler shift of around -6 km.s$^{-1}$, consistent with previous observations of the planet. Finding a deep cloud deck to be favoured, we measured in mass mixing ratio (MMR) log(H$_2$O)$_{MMR}$ = -4.52 $\pm$ 0.77 and log(CO)$_{MMR}$ = -3.09 $\pm$ 1.05 consistent with a sub-solar metallicity to more than 1$\sigma$. We report 3$\sigma$ upper limits for the abundances of C$_2$H$_2$, HCN and OH. We estimated a C/O ratio of 0.94 $\pm$ 0.39 ($\sim$ 1.7 $\pm$ 0.7 x solar, with errors indicated corresponding to the 2$\sigma$ values) for the limbs of WASP-76 b at the pressures probed by SPIRou. We used 1-D ATMO forward models to verify the validity of our estimation. Comparing them to our abundance estimations of H$_2$O and CO, as well as our upper limits for C$_2$H$_2$, HCN and OH, we found that our results were consistent with a C/O ratio between 1 and 2 x solar, and hence with our C/O estimation. Finally, we found indications of asymmetry for both H$_2$O and CO when investigating the dynamics of their signatures, pointing to a complex scenario involving possibly both a temperature difference between limbs and clouds being behind the asymmetry this planet is best known for., Comment: 20 pages, 19 figures, accepted for publication in A&A

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $\mu$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$\sigma$ upper limit of 1-6 parts per million, depending on model assumptions)., Comment: 61 pages, 13 figures, 4 tables. This preprint has been submitted to and accepted in principle for publication in Nature Astronomy without significant changes

Ultra-hot Jupiters (UHJs) are natural laboratories to study extreme physics in planetary atmospheres and their rich observational data sets are yet to be confronted with models with varying complexities at a population level. In this work, we update the general circulation model of Tan & Komacek (2019) to include a non-grey radiative transfer scheme and apply it to simulate the realistic thermal structures, phase-dependent spectra, and wavelength-dependent phase curves of UHJs. We performed grids of models over a large range of equilibrium temperatures and rotation periods for varying assumptions, showing that the fractional day-night brightness temperature differences remain almost constant or slightly increase with increasing equilibrium temperature from the visible to mid-infrared wavelengths. This differs from previous work primarily due to the increasing planetary rotation rate with increasing equilibrium temperature for fixed host star type. Radiative effects of varying atmospheric compositions become more significant in dayside brightness temperature in longer wavelengths. Data-model comparisons of dayside brightness temperatures and phase curve amplitudes as a function of equilibrium temperature are in broad agreement. Observations show a large scatter compared to models even with a range of different assumptions, indicating significantly varying intrinsic properties in the hot Jupiter population. Our cloud-free models generally struggle to match all observations for individual targets with a single set of parameter choices, indicating the need for extra processes for understanding the heat transport of UHJs., Comment: Accepted to MNRAS; data underlying this article is available in Zenodo https://doi.org/10.5281/zenodo.10121933

The atmospheric dynamics of tidally-locked hot Jupiters is characterized by strong equatorial winds. Understanding the interaction between global circulation and chemistry is crucial in atmospheric studies and interpreting observations. Two-dimensional (2D) photochemical transport models shed light on how the atmospheric composition depends on circulation. In this paper, we introduce the 2D photochemical (horizontal and vertical) transport model, VULCAN 2D, which improves on the pseudo-2D approaches by allowing for non-uniform zonal winds. We extensively validate our VULCAN 2D with analytical solutions and benchmark comparisons. Applications to HD 189733 b and HD 209458 b reveal a transition in mixing regimes: horizontal transport predominates below $\sim$0.1 mbar while vertical mixing is more important at higher altitudes above 0.1 mbar. Motivated by the previously inferred carbon-rich atmosphere, we find that HD 209458 b with super-solar carbon-to-oxygen ratio (C/O) exhibits pronounced C$_2$H$_4$ absorption on the morning limb but not on the evening limb, owing to horizontal transport from the nightside. We discuss when a pseudo-2D approach is a valid assumption and its inherent limitations. Finally, we demonstrate the effect of horizontal transport in transmission observations and its impact on the morning-evening limb asymmetry with synthetic spectra, highlighting the need to consider global transport when interpreting exoplanet atmospheres., Comment: 19 pages, 20 figures, published in ApJ

The abundances of major carbon and oxygen bearing gases in the atmospheres of giant exoplanets provide insights into atmospheric chemistry and planet formation processes. Thermochemistry suggests that methane should be the dominant carbon-bearing species below $\sim$1000 K over a range of plausible atmospheric compositions; this is the case for the Solar System planets and has been confirmed in the atmospheres of brown dwarfs and self-luminous directly imaged exoplanets. However, methane has not yet been definitively detected with space-based spectroscopy in the atmosphere of a transiting exoplanet, but a few detections have been made with ground-based, high-resolution transit spectroscopy including a tentative detection for WASP-80b. Here we report transmission and emission spectra spanning 2.4-4.0 micrometers of the 825 K warm Jupiter WASP-80b taken with JWST's NIRCam instrument, both of which show strong evidence for methane at greater than 6-sigma significance. The derived methane abundances from both viewing geometries are consistent with each other and with solar to sub-solar C/O and ~5$\times$ solar metallicity, which is consistent with theoretical predictions., Comment: 23 pages, 10 figures, 3 tables. This preprint has been submitted to and accepted in principle for publication in Nature without significant changes

We present ground and space-based photometric observations of TOI-270 (L231-32), a system of three transiting planets consisting of one super-Earth and two sub-Neptunes discovered by TESS around a bright (K-mag=8.25) M3V dwarf. The planets orbit near low-order mean-motion resonances (5:3 and 2:1), and are thus expected to exhibit large transit timing variations (TTVs). Following an extensive observing campaign using 8 different observatories between 2018 and 2020, we now report a clear detection of TTVs for planets c and d, with amplitudes of $\sim$10 minutes and a super-period of $\sim$3 years, as well as significantly refined estimates of the radii and mean orbital periods of all three planets. Dynamical modeling of the TTVs alone puts strong constraints on the mass ratio of planets c and d and on their eccentricities. When incorporating recently published constraints from radial velocity observations, we obtain masses of $M_{\mathrm{b}}=1.48\pm0.18\,M_\oplus$, $M_{c}=6.20\pm0.31\,M_\oplus$ and $M_{\mathrm{d}}=4.20\pm0.16\,M_\oplus$ for planets b, c and d, respectively. We also detect small, but significant eccentricities for all three planets : $e_\mathrm{b} =0.0167\pm0.0084$, $e_{c} =0.0044\pm0.0006$ and $e_{d} = 0.0066\pm0.0020$. Our findings imply an Earth-like rocky composition for the inner planet, and Earth-like cores with an additional He/H$_2$O atmosphere for the outer two. TOI-270 is now one of the best-constrained systems of small transiting planets, and it remains an excellent target for atmospheric characterization., Comment: 22 pages, 7 figures

Close-in lava planets represent an extreme example of terrestrial worlds, but their high temperatures may allow us to probe a diversity of crustal compositions. The brightest and most well-studied of these objects is 55 Cancri e, a nearby super-Earth with a remarkably short 17-hour orbit. However, despite numerous studies, debate remains about the existence and composition of its atmosphere. We present upper limits on the atmospheric pressure of 55 Cnc e derived from high-resolution time-series spectra taken with Gemini-N/MAROON-X. Our results are consistent with current crustal evaporation models for this planet which predict a thin $\sim$ 100 mbar atmosphere. We conclude that, if a mineral atmosphere is present on 55 Cnc e, the atmospheric pressure is below 100 mbar., Comment: Accepted to the AJ. 7 pages, 5 figures

The search for clouds on the dayside of hot Jupiters has been disadvantaged due to hot Jupiters having a limited number of high quality space-based observations. To date, retrieval studies have found no evidence for grey clouds on the dayside, however none of these studies explored the impact of scattering clouds. In this study we reanalyse the dayside emission spectrum of the hot Jupiter WASP-43b considering the different Spitzer data in the literature. We find that, in 2 of the 4 data sets explored, retrieving with a model that contains a scattering cloud is favoured over a cloud free model by a confidence of 3.13 - 3.36 $\sigma$. The other 2 data sets finds no evidence for scattering clouds. We find that the retrieved H$_2$O abundance is consistent regardless of the Spitzer data used and is consistent with literature values. We perform the same analysis for the hot Jupiter HD 209458b and find no evidence for dayside clouds, consistent with previous studies., Comment: 7 pages, 6 figures. Accepted for publication with MNRAS

Ultra-hot Jupiters are perfect targets for transmission spectroscopy. However, their atmospheres feature strong spatial variations in temperature, chemistry, dynamics, cloud coverage, and scale height. This makes transit observations at high spectral resolution challenging to interpret. In this work, we model the cross-correlation signal of five chemical species (Fe, CO, H$_\text{2}$O, OH, and TiO) on WASP-76b, a benchmark ultra-hot Jupiter. We compute phase-dependent high-resolution transmission spectra of 3D SPARC/MITgcm models. The spectra are obtained with gCMCRT, a 3D Monte-Carlo radiative-transfer code. We find that, on top of atmospheric dynamics, the phase-dependent Doppler shift of the absorption lines in the planetary rest frame is shaped by the combined effect of planetary rotation and the unique 3D spatial distribution of chemical species. For species probing the dayside (e.g., refractories or molecules like CO and OH), the two effects act in tandem, leading to increasing blueshifts with orbital phase. For species that are depleted on the dayside (e.g., H$_\text{2}$O and TiO), the two effects act in an opposite manner, and could lead to increasing redshifts during the transit. This behaviour yields species-dependent offsets from a planet's expected $K_\text{p}$ value that can be much larger than planetary wind speeds. The offsets are usually negative for refractory species. We provide an analytical formula to estimate the size of a planet's $K_\text{p}$ offsets, which can serve as a prior for atmospheric retrievals. We conclude that observing the phase-resolved absorption signal of multiple species is key to constraining the 3D thermochemical structure and dynamics of ultra-hot Jupiters., Comment: 21 pages, 14 figures, accepted for publication in MNRAS

The newly operational JWST offers the potential to study the atmospheres of distant worlds with precision that has not been achieved before. One of the first exoplanets observed by JWST in the summer of 2022 was WASP-96 b, a hot-Saturn orbiting a G8 star. As part of the Early Release Observations program, one transit of WASP-96 b was observed with NIRISS/SOSS to capture its transmission spectrum from 0.6-2.85 microns. In this work, we utilise four retrieval frameworks to report precise and robust measurements of WASP-96 b's atmospheric composition. We constrain the logarithmic volume mixing ratios of multiple chemical species in its atmosphere, including: H$_2$O = $-3.59 ^{+ 0.35 }_{- 0.35 }$, CO$_2$ = $-4.38 ^{+ 0.47 }_{- 0.57 }$ and K = $-8.04 ^{+ 1.22 }_{- 1.71 }$. Notably, our results offer a first abundance constraint on potassium in WASP-96 b's atmosphere, and important inferences on carbon-bearing species such as CO$_2$ and CO. Our short wavelength NIRISS/SOSS data are best explained by the presence of an enhanced Rayleigh scattering slope, despite previous inferences of a clear atmosphere - although we find no evidence for a grey cloud deck. Finally, we explore the data resolution required to appropriately interpret observations using NIRISS/SOSS. We find that our inferences are robust against different binning schemes. That is, from low $R = 125$ to the native resolution of the instrument, the bulk atmospheric properties of the planet are consistent. Our systematic analysis of these exquisite observations demonstrates the power of NIRISS/SOSS to detect and constrain multiple molecular and atomic species in the atmospheres of hot giant planets., Comment: 12 pages, 5 Figures. Accepted for publication in MNRAS. Companion paper to Radica et al., 2023

Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by photochemical hazes have the potential to drastically alter temperature structure and atmospheric circulation of these planets but have previously been neglected in general circulation models (GCMs). We present GCM simulations of hot Jupiter HD 189733b that include photochemical hazes as a radiatively active tracer fully coupled to atmospheric dynamics. The influence of haze radiative feedback strongly depends on the assumed haze optical properties. For soot hazes, two distinct thermal inversions form, separated by a local temperature minimum around 10$^{-5}$ bar caused by upwelling on the dayside mixing air with low haze abundance upwards. The equatorial jet broadens and slows down. The horizontal distribution of hazes remains relatively similar to simulations with radiatively passive tracers. For Titan-type hazes, the equatorial jet accelerates and extends to much lower pressures, resulting in a dramatically different 3D distribution of hazes compared to radiatively passive or soot hazes. Further experimental and observational studies to constrain the optical properties of photochemical hazes will therefore be crucial for understanding the role of hazes in exoplanet atmospheres. In the dayside emission spectrum, for both types of hazes the amplitude of near-infrared features is reduced, while the emitted flux at longer wavelengths ($>$4 $\mu$m) increases. Haze radiative feedback leads to increased phase curve amplitudes in many infrared wavelength regions, mostly due to stronger dayside emission., Comment: 31 pages, 18 figures, accepted for publication in ApJ

There are no planets intermediate in size between Earth and Neptune in our Solar System, yet these objects are found around a substantial fraction of other stars. Population statistics show that close-in planets in this size range bifurcate into two classes based on their radii. It is hypothesized that the group with larger radii (referred to as "sub-Neptunes") is distinguished by having hydrogen-dominated atmospheres that are a few percent of the total mass of the planets. GJ 1214b is an archetype sub-Neptune that has been observed extensively using transmission spectroscopy to test this hypothesis. However, the measured spectra are featureless, and thus inconclusive, due to the presence of high-altitude aerosols in the planet's atmosphere. Here we report a spectroscopic thermal phase curve of GJ 1214b obtained with JWST in the mid-infrared. The dayside and nightside spectra (average brightness temperatures of 553 $\pm$ 9 and 437 $\pm$ 19 K, respectively) each show >3$\sigma$ evidence of absorption features, with H$_2$O as the most likely cause in both. The measured global thermal emission implies that GJ 1214b's Bond albedo is 0.51 $\pm$ 0.06. Comparison between the spectroscopic phase curve data and three-dimensional models of GJ 1214b reveal a planet with a high metallicity atmosphere blanketed by a thick and highly reflective layer of clouds or haze., Comment: Published online in Nature on May 10, 2023

The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI LRS observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000 $\times$ solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities $\leq$300 $\times$ solar due to their large corresponding molecular feature amplitudes, preferring values $\geq$1000 $\times$ solar and column haze production rates $\geq$10$^{-10}$ g cm$^{-2}$ s$^{-1}$. The steam atmosphere scenario with similarly high haze production rates also exhibit sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights $\geq$15 g mol$^{-1}$ are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b's atmosphere would likely require multiple transits and eclipses using JWST across the near and mid-infrared, potentially complemented by groundbased high resolution transmission spectroscopy., Comment: 21 pages, 10 figures, 4 tables. Accepted for publication by ApJ

With infrared flux contrasts larger than typically seen in hot Jupiter, tidally-locked white dwarf-brown dwarf binaries offer a superior opportunity to investigate atmospheric processes in irradiated atmospheres. NLTT5306 is such a system, with a M$_{BD}$ = 52 $\pm$ 3 M$_{Jup}$ brown dwarf orbiting a T$_{eff}$ = 7756 $\pm$ 35 K white dwarf with an ultra-short period of $\sim$102 min. We present HST/WFC3 spectroscopic phase curves of NLTT5306, consisting of 47 spectra from 1.1 to 1.7 microns with an average S/N=65 per wavelength. We extracted the phase-resolved spectra of the brown dwarf NLTT5306B, finding a small (<100 K) day/night temperature difference ($\sim$5 percent of the average day-side temperature). Our best-fit model phase curves revealed a complex wavelength-dependence on amplitudes and relative phase offsets, suggesting longitudinal-vertical atmospheric structure. The night-side spectrum was well-fit by a cloudy, non-irradiated atmospheric model while the day-side was best-matched by a cloudy, weakly irradiated model. Additionally, we created a simple radiative energy redistribution model of the atmosphere and found evidence for efficient day-to-night heat redistribution and a moderately high Bond albedo. We also discovered an internal heat flux much higher than expected given the published system age, leading to an age reassessment that resulted in NLTT5306B most likely being much younger. We find that NLTT5306B is the only known significantly irradiated brown dwarf where the global temperature structure is not dominated by external irradiation, but rather its own internal heat. Our study provides an essential insight into the drivers of global circulation and day-to-night heat transport as a function of irradiation, rotation rate, and internal heat., Comment: 31 pages, 25 figures, Accepted to Astrophysical Journal with video abstract. Video abstract available at https://www.rachaelamaro.com/research-1

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $\mu$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$\sigma$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$\sigma$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators., Comment: JWST ERS bright star observations. Uploaded to inform JWST Cycle 2 proposals. Manuscript under review. 50 pages, 14 figures, 2 tables

The Kepler and TESS missions revealed a remarkable abundance of sub-Neptune exoplanets. Despite this abundance, our understanding of the nature and compositional diversity of sub-Neptunes remains limited, to a large part because atmospheric studies via transmission spectroscopy almost exclusively aimed for low-density sub-Neptunes and even those were often affected by high-altitude clouds. The recent TESS discovery of the hot, dense TOI-824b ($2.93\,R_\oplus$ and $18.47\,M_\oplus$) opens a new window into sub-Neptune science by enabling the study of a dense sub-Neptune via secondary eclipses. Here, we present the detection of TOI-824b's hot day side via Spitzer secondary eclipse observations in the $3.6$ and $4.5\,\mathrm{\mu m}$ channels, combined with a reanalysis of its interior composition. The measured eclipse depths (142$^{+57}_{-52}$ and 245$^{+75}_{-77}$ ppm) and brightness temperatures (1463$^{+183}_{-196}$ and 1484$^{+180}_{-202}$ K) indicate a poor heat redistribution ($f>$ 0.49) and a low Bond albedo (A$_{B}<$ 0.26). We conclude that TOI-824b could be an "exposed Neptune mantle": a planet with a Neptune-like water-rich interior that never accreted a hydrogen envelope or that subsequently lost it. The hot day-side temperature is then naturally explained by a high-metallicity envelope re-emitting the bulk of the incoming radiation from the day side. TOI-824b's density is also consistent with a massive rocky core that accreted up to 1% of hydrogen, but the observed eclipse depths favor our high-metallicity GCM simulation to a solar-metallicity GCM simulation with a likelihood ratio of 7:1. The new insights into TOI-824b's nature suggest that the sub-Neptune population may be more diverse than previously thought, with some of the dense hot sub-Neptunes potentially not hosting a hydrogen-rich envelope as generally assumed for sub-Neptunes., Comment: Accepted for publication in The Astrophysical Journal, 14 pages, 5 figures

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 \mu$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator., Comment: 48 pages, 12 figures, 2 tables. Under review at Nature

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $\mu$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $\mu$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$\sigma$) and G395H (4.5$\sigma$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations., Comment: 39 pages, 14 figures, accepted to be published in Nature