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1. A single diiron enzyme catalyses the oxidative rearrangement of tryptophan to indole nitrile.

2. Structural Basis for Methine Excision by a Heme Oxygenase-like Enzyme.

3. The Fe and Zn cofactor dilemma.

4. Oxidative rearrangement of tryptophan to indole nitrile by a single diiron enzyme.

5. Vibrio cholerae V-cGAP3 Is an HD-GYP Phosphodiesterase with a Metal Tunable Substrate Selectivity.

6. Domain Fusion of Two Oxygenases Affords Organophosphonate Degradation in Pathogenic Fungi.

7. The HBx protein from hepatitis B virus coordinates a redox-active Fe-S cluster.

8. Metal Dependence and Functional Diversity of Type I Cas3 Nucleases.

9. Characterization of Fe-S Clusters in Proteins by Mӧssbauer Spectroscopy.

10. The HD-Domain Metalloprotein Superfamily: An Apparent Common Protein Scaffold with Diverse Chemistries.

11. HD-[HD-GYP] Phosphodiesterases: Activities and Evolutionary Diversification within the HD-GYP Family.

12. Hepatitis B Virus Oncoprotein HBx Is Not an ATPase.

13. Structures of Class Id Ribonucleotide Reductase Catalytic Subunits Reveal a Minimal Architecture for Deoxynucleotide Biosynthesis.

14. A New Microbial Pathway for Organophosphonate Degradation Catalyzed by Two Previously Misannotated Non-Heme-Iron Oxygenases.

15. Spectroscopic and Electrochemical Characterization of the Mycofactocin Biosynthetic Protein, MftC, Provides Insight into Its Redox Flipping Mechanism.

16. Redox-dependent rearrangements of the NiFeS cluster of carbon monoxide dehydrogenase.

17. Discovery and characterization of a prevalent human gut bacterial enzyme sufficient for the inactivation of a family of plant toxins.

18. Structural Basis for Superoxide Activation of Flavobacterium johnsoniae Class I Ribonucleotide Reductase and for Radical Initiation by Its Dimanganese Cofactor.

19. The biosynthesis of methanobactin.

20. NADH reduction of nitroaromatics as a probe for residual ferric form high-spin in a cytochrome P450.

21. Organometallic Complex Formed by an Unconventional Radical S-Adenosylmethionine Enzyme.

22. Structure and Function of a Bacterial Microcompartment Shell Protein Engineered to Bind a [4Fe-4S] Cluster.

23. Characterization of Lipoyl Synthase from Mycobacterium tuberculosis.

24. The Carbon Monoxide Dehydrogenase from Desulfovibrio vulgaris.

25. Rapid Reduction of the Diferric-Peroxyhemiacetal Intermediate in Aldehyde-Deformylating Oxygenase by a Cyanobacterial Ferredoxin: Evidence for a Free-Radical Mechanism.

26. Cofactor composition and function of a H 2 -sensing regulatory hydrogenase as revealed by Mössbauer and EPR spectroscopy.

27. Understanding the Effect of Monomeric Iridium(III/IV) Aquo Complexes on the Photoelectrochemistry of IrO(x)·nH2O-Catalyzed Water-Splitting Systems.

28. Mössbauer spectroscopy of Fe/S proteins.

29. Efficient delivery of long-chain fatty aldehydes from the Nostoc punctiforme acyl-acyl carrier protein reductase to its cognate aldehyde-deformylating oxygenase.

30. Pulse Double-Resonance EPR Techniques for the Study of Metallobiomolecules.

31. Evidence for a catalytically and kinetically competent enzyme-substrate cross-linked intermediate in catalysis by lipoyl synthase.

32. ChlR protein of Synechococcus sp. PCC 7002 is a transcription activator that uses an oxygen-sensitive [4Fe-4S] cluster to control genes involved in pigment biosynthesis.

33. Human anamorsin binds [2Fe-2S] clusters with unique electronic properties.

34. Evidence that the fosfomycin-producing epoxidase, HppE, is a non-heme-iron peroxidase.

35. Organophosphonate-degrading PhnZ reveals an emerging family of HD domain mixed-valent diiron oxygenases.

36. Substrate-triggered addition of dioxygen to the diferrous cofactor of aldehyde-deformylating oxygenase to form a diferric-peroxide intermediate.

38. A metal-metal bond in the light-induced state of [NiFe] hydrogenases with relevance to hydrogen evolution.

39. Electronic structure of the unique [4Fe-3S] cluster in O2-tolerant hydrogenases characterized by 57Fe Mossbauer and EPR spectroscopy.

40. Radical-translocation intermediates and hurdling of pathway defects in "super-oxidized" (Mn(IV)/Fe(IV)) Chlamydia trachomatis ribonucleotide reductase.

41. Evolution and diversification of Group 1 [NiFe] hydrogenases. Is there a phylogenetic marker for O(2)-tolerance?

42. Pulse Q-band EPR and ENDOR spectroscopies of the photochemically generated monoprotonated benzosemiquinone radical in frozen alcoholic solution.

43. Spectroscopic characterization of the key catalytic intermediate Ni-C in the O2-tolerant [NiFe] hydrogenase I from Aquifex aeolicus: evidence of a weakly bound hydride.

44. [Fe₄S₄]- and [Fe₃S₄]-cluster formation in synthetic peptides.

45. Characterization of a unique [FeS] cluster in the electron transfer chain of the oxygen tolerant [NiFe] hydrogenase from Aquifex aeolicus.

47. The oxygen-tolerant hydrogenase I from Aquifex aeolicus weakly interacts with carbon monoxide: an electrochemical and time-resolved FTIR study.

48. Membrane-bound hydrogenase I from the hyperthermophilic bacterium Aquifex aeolicus: enzyme activation, redox intermediates and oxygen tolerance.

49. Intermediates in the catalytic cycle of [NiFe] hydrogenase: functional spectroscopy of the active site.

50. Comparison of the membrane-bound [NiFe] hydrogenases from R. eutropha H16 and D. vulgaris Miyazaki F in the oxidized ready state by pulsed EPR.

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