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Species sensitivity distributions (SSDs) are cumulative distributions of measures of species sensitivity to a stressor or toxicant, and are used to estimate concentrations that will protect p% of a community (PCp). There is conflict between the desire to use high-quality sensitivity data in SSDs, and to construct them with a large number of species forming a representative sample. Trade-offs between data quality and quantity were investigated using the effects of increasing salinity on the macroinvertebrate community from the Hunter River catchment, in eastern Australia. Five SSDs were constructed, representing five points along a continuum of data quality versus data quantity and representativeness. This continuum was achieved by the various inclusion/exclusion of censored data, nonmodeled data, and extrapolation from related species. Protective concentrations were estimated using the Burr type III distribution, Kaplan-Meier survival function, and two Bayesian statistical models. The dominant taxonomic group was the prime determinant of protective concentrations, with an increase in PC95 values resulting from a decrease in the proportion of Ephemeropteran species included in the SSD. In addition, decreases in data quantity in a SSD decreased community representativeness. The authors suggest, at least for salinity, that the inclusion of right censored data provides a more representative sample of species that reflects the natural biotic assemblage of an area to be protected, and will therefore improve risk assessment. © 2013 SETAC.

The majority of ecotoxicological data are generated from standard laboratory-based experiments with organisms exposed in nonflowing systems using highly purified water, which contains very low amounts of dissolved organic matter and suspended particulates. However, such experimental conditions are not ecologically relevant. Thus, there is a need to develop more realistic approaches to determining toxicity, including both lethal and sublethal effects. This research provides information on the effect of natural water constituents, such as suspended particulates and dissolved organic matter, in river water (RW) on the chronic toxicity (7-day reproductive impairment) of the pesticides atrazine, chlorothalonil, and permethrin to the freshwater cladoceran Ceriodaphnia cf. dubia. Standard bioassays were conducted under standard laboratory and more environmentally realistic conditions (using RW). The 7-day IC25 (reproduction impairment) values of atrazine, chlorothalonil, and permethrin to C. cf. dubia ranged from 862.4 to >1000, 51.3 to 66.4, and 0.19 to 0.23 μg/L, respectively. Using the Globally Harmonized System of Classification and Labelling of Chemicals, atrazine is classified as moderately to highly toxic, whereas permethrin and chlorothalonil were both highly toxic. The presence of dissolved organic matter and suspended particles in natural RW did not significantly (p > 0.05) change the toxicity of any of the pesticides to C. cf. dubia compared with that tested in laboratory water (LW). For the tested pesticides, toxicity testing in LW provided an adequate estimate of the hazard posed. © 2012 Springer Science+Business Media New York.

Pesticides predominantly occur in aquatic ecosystems as mixtures of varying complexity, yet relatively few studies have examined the toxicity of pesticide mixtures. Atrazine, chlorothalonil and permethrin are widely used pesticides that have different modes of action. This study examined the chronic toxicities (7-d reproductive impairment) of these pesticides in binary and ternary mixtures to the freshwater cladoceran Ceriodaphnia cf. dubia. The toxicity of the mixtures was compared to that predicted by the independent action (IA) model for mixtures, as this is the most appropriate model for chemicals with different modes of action. Following this they were compared to the toxicity predicted by the concentration addition (CA) model for mixtures. According to the IA model, the toxicity of the chlorothalonil plus atrazine mixture conformed to antagonism, while that of chlorothalonil and permethrin conformed to synergism. The toxicity of the atrazine and permethrin mixture as well as the ternary mixture conformed to IA implying there was either no interaction between the components of these mixtures and/or in the case of the ternary mixture the interactions cancelled each other out to result in IA. The synergistic and antagonistic mixtures deviated from IA by factors greater than 3 and less than 2.5, respectively. When the toxicity of the mixtures was compared to the predictions of the CA model, the binary mixture of chlorothalonil plus atrazine, permethrin plus atrazine and the ternary mixture all conformed to antagonism, while the binary mixture of chlorothalonil plus permethrin conformed to CA. Using the CA model provided estimates of mixture toxicity that did not markedly underestimate the measured toxicity, unlike the IA model, and therefore the CA model is the most suitable to use in ecological risk assessments of these pesticides. © 2011 Elsevier Ltd.

Sponge not only can reduce membrane fouling by means of mechanical cleaning and maintain a balance of suspended-attached microorganisms in submerged membrane bioreactor (SMBR), but also can enhance dissolved organic matter and nutrient removal. This study investigated the performance of three different sizes of sponge (S28-30/45R, S28-30/60R and S28-30/90R) associated with continuous aerated SMBR. A laboratory-scale single stage sponge-SMBR (SSMBR) showed high performance for removing dissolved organic matter (>96%) and PO4-P (>98.8), while coarse sponges such as S28-30/45R, S28-30/60R could achieve more than 99% removal of NH4-N. When three-size sponges (S28-30/45R, S28-30/60R and S28-30/90R) were mixed at a ratio of 1:1:1 and in conjunction with two kinds of membranes (0.1 μm hollow fiber and 2 μm nonwoven), the SSMBR system has proved its generic merits of superior treated effluent quality and less membrane fouling. The NH4-N and PO4-P removal were found excellent, which were more than 99.8% and over 99% respectively. Molecular weight distribution also indicated that major fractions of organic matter could be successfully removed by SSMBR. © 2009 Elsevier B.V. All rights reserved.

The aim of this study was to investigate the performance of sponge as an active mobile carrier for attachedgrowth biomass in three typical types of aerobic bioreactors to treat a high strength synthetic wastewater. The results show that sponge thickness deteriorated the organic and nutrient removal and 1 cm is the optimumthickness for fixed-bed sponge biofilter (SBF). The sponge volume had significant impact on phosphorus removal rather than organic or nitrogen removal, and 20% volume of sponge could achieve 100% T-P removal within 3 h in a sponge batch reactor (SBR). When sponge coupled with submerged membrane bioreactor (SMBR), the single system show outstanding ammonium (100% at filtration flux of 10 and 15 L/m2 h) and phosphorus (>91% at all fluxes range) removal with optimum pH range of 6-7. © 2009 Elsevier Ltd.

This chapter illustrates the most basis assessment methodologies as decision support system and assessment framework for water reuse scheme and technology evaluation. It includes the analyses of life cycle, material flow, ecological footprint, health risk, energy consumption and economic and social impact in order to form rational concepts and approaches towards a comprehensive assessment method for water reuse.

Salinization of freshwater resources is an increasing global problem, yet there is a paucity of chronic salinity tolerance data linked to very few chronic toxicity test protocols. This research aimed to generate a chronic toxicity test protocol and protective salinity tolerance data for the indigenous South African freshwater shrimp Caridina nilotica. In addition, the theory that LC5s (concentration causing 5% lethality) are indicative of No Observed Effect Concentrations (NOECs) was tested. NaCl and Na2SO4 were used as toxicants as they are indicative of natural and industrial salinization, respectively. NOEC values of 1.9 g l–1 were calculated for both salts. Within the chronic toxicity tests, LC5s that were calculated using regression methods approximated the calculated NOEC values for both salts. Chronic NOECs calculated here are lower, by a factor of 3, than the acute LC50s calculated for the same species and salts. Although evidence exists to suggest that C. nilotica is generally sensitive to toxicants, it was found to be not particularly sensitive to salinity. However, the species was found to be a good chronic toxicity test organism for partial life-cycle toxicity tests where growth was measured as the test endpoint, and may yield valuable chronic toxicity data for other toxicants. Keywords: freshwater shrimp, toxicity tests, chronic response, growth rate, mortality, reproductionAfrican Journal of Aquatic Science 2008, 33(1): 37–44

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n the South African National Water Act (NWA, No 36 of 1998), the ecological Reserve is defined as the quality and quantity of water required to ensure appropriate protection of water resources, so as to secure ecologically sustainable development and use. Aquatic ecosystems are recognised as the core location of water resources, and although considerable progress has been made in developing methods for quantifying environmental flow requirements, this paper describes and discusses the first agreed method for quantifying environmental water quality requirements in an ecological Reserve assessment. Integration of flow and water quality is emphasised, and is based on the philosophy that environmental flows should be motivated to provide ecologically important flow-related habitat, or geomorphological function, but should not be motivated to solve water quality problems by dilution. Water quality is multivariate, and not all variables can be considered in an ecological Reserve assessment, but core water quality variables include: system variables (salts, dissolved oxygen, turbidity, temperature), nutrients (phosphate, nitrite, nitrate) and toxic substances (those listed in the South African Water Quality Guidelines for Aquatic Ecosystems, including toxic metal ions, toxic organic substances, and/or substances from a chemical inventory of an effluent or discharge). In addition, biological indicator data (e.g. SASS data), chlorophyll-a (e.g. phytoplankton and periphyton data) and toxicity test data may be used. For each variable, a concentration range or response is linked to a class within a water resource classification system, where classes range from minimally to severely modified. There are five main stages in the environmental water quality method: Initiate study and determine scope of assessment. Delineate water quality sub-units. Select sites and collect data and information.

There is a growing international trend towards the protection of freshwater resources from pollution by imposing instream guidelines and specified waste-discharge conditions. Current methods for devising freshwater quality guidelines are based on species sensitivity distributions (SSDs) that are used to identify pollutant concentrations, ensuring the protection of a modelled percentage of species (95% protection is a common goal). SSDs are derived from the toxicity test results of as many taxa as possible for each polluting substance. Waste-discharge licences can be for single substances, specified in terms of chemical concentrations, and derived in conjunction with instream guidelines; or for complex mixtures, specified in terms of toxic units. In both cases toxicity test results are the core data used. The emphasis on SSDs calls into question the species constituting the test populations. It is likely that SSDs based in part on the responses of local organisms will achieve superior site-specific ecological protection. Until the early 1990s, there were very few data on the tolerances of South African freshwater organisms. In the intervening decade, the Unilever Centre for Environmental Water Quality at Rhodes University has developed a toxicity database that, to date, records the responses of 21 South African freshwater taxa to 26 single-substance pollutants or mixtures. This is the most comprehensive database of South African toxicity responses available and has been used in the drawing up of methods and guidelines to protect water resources. This paper aims to make these data available and to describe applications of the data using selected case studies.