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This study deals with possibility of the applications of inorganic substances specifically natural bentonite in function of reinforced nanofillers in polymeric materials. X-ray diffraction, FTIR spectroscopy and thermal analysis (TG, DSC and DTA) were used to characterize natural bentonite in more detail. At the prepared model, rubber compounds with various amounts of added filler were determinated vulcanization characteristics and physical–mechanical properties. The measured values were compared with the values of commercially used polymeric materials with the original composition. [ABSTRACT FROM AUTHOR]

The application of DCSBD (Diffuse Coplanar Surface Barrier Discharge) plasma is referred to as the surface modification/activation of materials. The exposure of material surfaces to DCSBD plasma is initiated by changes in their chemical composition, surface wettability and roughness. The given study presents the mentioned plasma application in the context of the modification of the material viscoelastic properties, namely the PVC polymer film. The measurement of viscoelastic properties changes of PVC was primarily examined by a sensitive thermal method of dynamic-mechanical analysis. This analysis allows identifying changes in the glass transition temperature of PVC, before and after DCSBD plasma application, Tangens Delta, supported by glass transition temperatures of Elastic and Loss modulus. The results of the present study prove that DCSBD plasma applied on both sides to PVC surfaces causes changes in its viscoelastic properties. In addition, these changes are presented depending on the variability of the material position, with respect to the winding of the electrodes in the ceramic dielectric generating the DCSBD plasma during modification. The variability of the PVC position holds an important role, as it determines the proportion of filamentous and diffuse components of the plasma that will interact with the material surface during modification. The application of DCSBD plasma must, therefore, be considered a complex modification of the material, and as a result, non-surface changes must also be considered.

The curing bladder is the main element when producing a car tire. The tire curing bladder is a cylindrical bag concaved with a heat transfer medium, hot water, steam or gas during the vulcanization process. It is highly stressed due to the extremely high temperatures and pressures inside the pressing mold and it ensures the optimal process of vulcanization. Therefore, it is necessary to verify the quality of the tire curing bladder made of a suitable elastomer (rubber) blend. Analysis of rubber is an important technological operation in research and development in the automotive industry. The purpose of rubber blend analysis may be to confirm that the manufacturer or supplier owns or supplies a material according to the composition pattern, to clarify the cause of difficulties and failures during processing or to verify that the individual components of the rubber blend are correctly batched during technological operation "mixing". Five analytical methods were used to determine the quality, presence and quantity of applied curing resin, specifically a combination of pyrolysis, gas chromatography and mass spectrometry and a combination of infrared spectroscopy and thermogravimetry. The concentration and percentage of the curing resin were determined from individual measurements and by comparing with reference samples (standards) from an industrial factory., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)