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Protecting sensitive information on data streams is a critical challenge for modern systems. Current approaches to privacy in data streams follow two strategies. The first transforms the stream into a private sequence, enabling the use of non-private analyses but incurring high memory costs. The second uses compact data structures to create private summaries but restricts flexibility to predefined queries. To address these limitations, we propose $\textsf{PrivHP}$, a lightweight synthetic data generator that ensures differential privacy while being resource-efficient. $\textsf{PrivHP}$ generates private synthetic data that preserves the input stream's distribution, allowing flexible downstream analyses without additional privacy costs. It leverages a hierarchical decomposition of the domain, pruning low-frequency subdomains while preserving high-frequency ones in a privacy-preserving manner. To achieve memory efficiency in streaming contexts, $\textsf{PrivHP}$ uses private sketches to estimate subdomain frequencies without accessing the full dataset. $\textsf{PrivHP}$ is parameterized by a privacy budget $\varepsilon$, a pruning parameter $k$ and the sketch width $w$. It can process a dataset of size $n$ in $\mathcal{O}((w+k)\log (\varepsilon n))$ space, $\mathcal{O}(\log (\varepsilon n))$ update time, and outputs a private synthetic data generator in $\mathcal{O}(k\log k\log (\varepsilon n))$ time. Prior methods require $\Omega(n)$ space and construction time. Our evaluation uses the expected 1-Wasserstein distance between the sampler and the empirical distribution. Compared to state-of-the-art methods, we demonstrate that the additional cost in utility is inversely proportional to $k$ and $w$. This represents the first meaningful trade-off between performance and utility for private synthetic data generation., Comment: 28 Pages, 1 Table, 3 Figures, 4 Algorithms

The solar corona is highly structured by bunches of magnetic field lines forming either loops, or twisted flux ropes representing prominences/filaments, or very dynamic structures such as jets. The aim of this paper is to understand the interaction between filament channels and jets. We use high-resolution H$\alpha$ spectra obtained by the ground-based Telescope Heliographique pour lEtude du Magnetisme et des Instabilites Solaires (THEMIS) in Canary Islands, and data from Helioseismic Magnetic Imager (HMI) and Atmospheric Imaging Assembly (AIA) aboard the Solar Dynamics Observatory (SDO). In this paper we present a multi-wavelength study of the interaction of filaments and jets. They both consist of cool plasma embedded in magnetic structures. A jet is particularly well studied in all the AIA channels with a flow reaching 100-180 km s$^{-1}$. Its origin is linked to cancelling flux at the edge of the active region. Large Dopplershifts in H$\alpha$ are derived in a typical area for a short time (order of min). They correspond to flows around 140 km s$^{-1}$. In conclusion we conjecture that these flows correspond to some interchange of magnetic field lines between the filament channel and the jets leading to cool plasmoid ejections or reconnection jets perpendicularly to the jet trajectory., Comment: 13 Figures, 14 pages

Recent gain in popularity of AI conversational agents has led to their increased use for improving productivity and supporting well-being. While previous research has aimed to understand the risks associated with interactions with AI conversational agents, these studies often fall short in capturing the lived experiences. Additionally, psychological risks have often been presented as a sub-category within broader AI-related risks in past taxonomy works, leading to under-representation of the impact of psychological risks of AI use. To address these challenges, our work presents a novel risk taxonomy focusing on psychological risks of using AI gathered through lived experience of individuals. We employed a mixed-method approach, involving a comprehensive survey with 283 individuals with lived mental health experience and workshops involving lived experience experts to develop a psychological risk taxonomy. Our taxonomy features 19 AI behaviors, 21 negative psychological impacts, and 15 contexts related to individuals. Additionally, we propose a novel multi-path vignette based framework for understanding the complex interplay between AI behaviors, psychological impacts, and individual user contexts. Finally, based on the feedback obtained from the workshop sessions, we present design recommendations for developing safer and more robust AI agents. Our work offers an in-depth understanding of the psychological risks associated with AI conversational agents and provides actionable recommendations for policymakers, researchers, and developers., Comment: 25 pages, 2 figures, 4 tables; Corrected typos

While the subclass of interacting supernovae with narrow hydrogen emission lines (SNe IIn) consists of some of the longest-lasting and brightest SNe ever discovered, their progenitors are still not well understood. Investigating SNe IIn as they emit across the electromagnetic spectrum is the most robust way to understand the progenitor evolution before the explosion. This work presents X-Ray, optical, infrared, and radio observations of the strongly interacting Type IIn SN 2020ywx covering a period $>1200$ days after discovery. Through multiwavelength modeling, we find that the progenitor of 2020ywx was losing mass at $\sim10^{-2}$--$10^{-3} \mathrm{\,M_{\odot}\,yr^{-1}}$ for at least 100 yr pre-explosion using the circumstellar medium (CSM) speed of $120$ km/s measured from our optical and NIR spectra. Despite the similar magnitude of mass-loss measured in different wavelength ranges, we find discrepancies between the X-ray and optical/radio-derived mass-loss evolution, which suggest asymmetries in the CSM. Furthermore, we find evidence for dust formation due to the combination of a growing blueshift in optical emission lines and near-infrared continuum emission which we fit with blackbodies at $\sim$ 1000 K. Based on the observed elevated mass loss over more than 100 years and the configuration of the CSM inferred from the multiwavelength observations, we invoke binary interaction as the most plausible mechanism to explain the overall mass-loss evolution. SN 2020ywx is thus a case that may support the growing observational consensus that SNe IIn mass loss is explained by binary interaction., Comment: Submitted to ApJ, 31 pages, 19 figures

This paper proposes a novel loss function, called 'Tube Loss', for simultaneous estimation of bounds of a Prediction Interval (PI) in the regression setup, and also for generating probabilistic forecasts from time series data solving a single optimization problem. The PIs obtained by minimizing the empirical risk based on the Tube Loss are shown to be of better quality than the PIs obtained by the existing methods in the following sense. First, it yields intervals that attain the prespecified confidence level $t \in(0,1)$ asymptotically. A theoretical proof of this fact is given. Secondly, the user is allowed to move the interval up or down by controlling the value of a parameter. This helps the user to choose a PI capturing denser regions of the probability distribution of the response variable inside the interval, and thus, sharpening its width. This is shown to be especially useful when the conditional distribution of the response variable is skewed. Further, the Tube Loss based PI estimation method can trade-off between the coverage and the average width by solving a single optimization problem. It enables further reduction of the average width of PI through re-calibration. Also, unlike a few existing PI estimation methods the gradient descent (GD) method can be used for minimization of empirical risk. Finally, through extensive experimentation, we have shown the efficacy of the Tube Loss based PI estimation in kernel machines, neural networks and deep networks and also for probabilistic forecasting tasks. The codes of the experiments are available at https://github.com/ltpritamanand/Tube_loss

Sulfide-based photocatalysts (PC) are promising materials for efficiently producing hydrogen (H2). This chapter aims to provide a detailed survey of the recent advancements in sulfide-based photocatalysts and emphasize their enhanced performance and pathways to efficient H2 production. A detailed summary has been given, including several metal sulfides, such as cadmium sulfide (CdS), zinc sulfide (ZnS), molybdenum disulfide (MoS2), tungsten disulfide (WS2), lead sulfide (PbS), nickel sulfides (NiS/NiS2), iron disulfide (FeS2), copper sulfides (CuS/Cu2S), cobalt sulfides (CoS/CoS2), tin disulfide (SnS2), indium sulfide (In2S3), bismuth sulfide (Bi2S3), zinc cadmium sulfide (ZnxCd1-xS), manganese cadmium sulfide (MnxCd1-xS), zinc indium sulfide (ZnIn2S4), and cadmium indium sulfide (CdIn2S4). This chapter will focus on the latest advancements in metal-sulfide-based materials for photocatalytic hydrogen evolution reactions (HER), taking its accelerated growth and excellent research into account. After briefly outlining the basic properties, the chapter will showcase the cutting-edge strategies and recent research progress, including the construction of heterojunctions, defect engineering, co-catalyst loading, elemental doping, and single-atom engineering, which improve the electronic structure and charge separation capabilities of metal sulfides for photocatalytic hydrogen production. A future perspective and outlook have been proposed, focusing on some key points and a standard protocol. With this knowledge, we hope sulfide-based photocatalysts can be modified and engineered to improve their efficiency and stability in future research.

Although hydrogen generation by water electrolysis is the cheapest of all other available sources, water splitting still occurs with sluggish kinetics. It is a challenging barrier for H2 production on a large scale. Moreover, research is still underway to understand the oxygen evolution reaction (OER) and design the catalysts with improved OER performance. Herein, we report the synthesis, characterization, and OER performance of iron-doped copper oxide (CuO) as low-cost catalysts for water oxidation. The OER occurs at about 1.49 V versus the RHE with a Tafel slope of 69 mV/dec in a 1 M KOH solution. The overpotential of 338 mV at 10 mA/cm2 is among the lowest compared with other copper-based materials. The catalyst can deliver a stable current density of >10 mA/cm2 for more than 10 hours. Additionally, wastewater treatment, particularly synthetic dye wastewater, is vital for preventing water scarcity and adverse effects on human health and ecotoxicology. The as-synthesized catalysts are also utilized for Fenton-like photo-degradation under low-power visible household LED lights toward the most commonly industrially used simulated Methylene blue dye wastewater. Almost complete degradation of the MB dye has been achieved within 50 minutes of visible light irradiation with a first-order rate constant of 0.0973/min. This dual functionality feature can open new pathways as a non-noble, highly efficient, and robust catalyst for OER and wastewater treatments.

Cryogenic fluids have extensive applications as fuel for launch vehicles in space applications and research. The physics of cryogenic flows are highly complex due to the sensitive nature of phase transformation from liquid to bubbly liquid and vapor, eventually resulting in cavitating flows at the ambient temperature owing to the very low boiling point of cryogenic fluids, which asserts us to classify such flows under multi-phase flow physics regime. This work elucidates the modeling of bubbly flow for cryogenic fluids such as liquid nitrogen in a converging-diverging venturi-like flow device known as cavitating venturi, a passive flow control metering device. The numerical works in literature are usually limited to modeling iso-thermal bubbly flows such as water devoid of involving energy equations because there is no occurrence of interface heat transfer as latent heat of vaporization of water is higher, unlike cryogenic fluids which are sensitive to phase change at ambient conditions. So, to realize an appropriate model for modeling cryogenic bubbly flows such as liquid nitrogen flow, the effect of heat transfer at the interface and convective heat transfer from the surrounding liquid to the traversing bubble needs to be included. Numerical modeling using an in-house code involving a finite-difference method The numerical results showed the importance of including the heat transport equation due to convection and at the interface of bubble-fluid as a significant source term for the bubble dynamics. The work is supported by computational simulation using a commercial CFD package for 2-dimensional simulations to predict a characterizing parameter, namely cavitation length. A limited flow visualization experiment using a high-speed camera is performed to study the cavitating zone length.

Large language models (LLMs) are notoriously memory-intensive during training, particularly with the popular AdamW optimizer. This memory burden necessitates using more or higher-end GPUs or reducing batch sizes, limiting training scalability and throughput. To address this, various memory-efficient optimizers have been proposed to reduce optimizer memory usage. However, they face critical challenges: (i) reliance on costly SVD operations; (ii) significant performance trade-offs compared to AdamW; and (iii) still substantial optimizer memory overhead to maintain competitive performance. In this work, we identify that AdamW's learning rate adaptation rule can be effectively coarsened as a structured learning rate update. Based on this insight, we propose Approximated Gradient Scaling for Memory-Efficient LLM Optimization (APOLLO), which approximates learning rate scaling using an auxiliary low-rank optimizer state based on pure random projection. This structured learning rate update rule makes APOLLO highly tolerant to further memory reductions while delivering comparable pre-training performance. Even its rank-1 variant, APOLLO-Mini, achieves superior pre-training performance compared to AdamW with SGD-level memory costs. Extensive experiments demonstrate that the APOLLO series performs on-par with or better than AdamW, while achieving greater memory savings by nearly eliminating the optimization states of AdamW. These savings provide significant system-level benefits: (1) Enhanced Throughput: 3x throughput on an 8xA100-80GB setup compared to AdamW by supporting 4x larger batch sizes. (2) Improved Model Scalability: Pre-training LLaMA-13B with naive DDP on A100-80GB GPUs without system-level optimizations. (3) Low-End GPU Friendly Pre-training: Pre-training LLaMA-7B on a single GPU using less than 12 GB of memory with weight quantization., Comment: Preprint

Robots in densely populated real-world environments frequently encounter constrained and cluttered situations such as passing through narrow doorways, hallways, and corridor intersections, where conflicts over limited space result in collisions or deadlocks among the robots. Current decentralized state-of-the-art optimization- and neural network-based approaches (i) are predominantly designed for general open spaces, and (ii) are overly conservative, either guaranteeing safety, or liveness, but not both. While some solutions rely on centralized conflict resolution, their highly invasive trajectories make them impractical for real-world deployment. This paper introduces LiveNet, a fully decentralized and robust neural network controller that enables human-like yielding and passing, resulting in agile, non-conservative, deadlock-free, and safe, navigation in congested, conflict-prone spaces. LiveNet is minimally invasive, without requiring inter-agent communication or cooperative behavior. The key insight behind LiveNet is a unified CBF formulation for simultaneous safety and liveness, which we integrate within a neural network for robustness. We evaluated LiveNet in simulation and found that general multi-robot optimization- and learning-based navigation methods fail to even reach the goal, and while methods designed specially for such environments do succeed, they are 10-20 times slower, 4-5 times more invasive, and much less robust to variations in the scenario configuration such as changes in the start states and goal states, among others. We open-source the LiveNet code at https://github.com/srikarg89/LiveNet{https://github.com/srikarg89/LiveNet.

The ability to differentiate between different models of inflation through the imprint of primordial non-Gaussianity (PNG) requires a tight constraint on the local PNG parameter $f_{\text{NL}}^{\text{loc}}$. Future large scale structure surveys like \textit{Euclid}, Vera C. Rubin Observatory, and the Spectro-Photometer for the History of the Universe, Epoch of Reionization, and Ices Explorer (SPHEREx) will play a crucial role in advancing our understanding of the inflationary epoch. In this light, we present forecasts on PNG with tomographic angular power spectrum from simulations of SPHEREx. We put forward the effects of redshift bin mismatch of galaxies as a source of systematic error when estimating $f_{\text{NL}}^{\text{loc}}$ and galaxy linear halo bias. We %use \texttt{GLASS} to simulate $500$ SPHEREx-like galaxy density fields, and divide the galaxies into $13$ redshift bins assuming Gaussian photometric redshift errors. We show that the misclassification of galaxies in redshift bins can result in strong apparent tensions on $f_{\text{NL}}^{\text{loc}}$ up to $\sim 3\sigma$ and up to $\sim 9\sigma$ on galaxy bias. We propose a scattering matrix formalism to mitigate bin mismatch of galaxies and to obtain unbiased estimates of cosmological parameters from tomographic angular clustering measurements., Comment: Submitted to PASA. 11 Pages, 10 figures, 1 table

We report integral field spectroscopy observations with the Near-Infrared Spectrograph on board JWST targeting the 60 kpc environment surrounding the most luminous quasar known at $z=4.6$. We detect ionized gas filaments on 40 kpc scales connecting a network of merging galaxies likely to form a cluster. We find regions of low ionization consistent with large-scale shock excitation surrounding the central dust-obscured quasar, out to distances nearly eight times the effective stellar radius of the quasar host galaxy. In the nuclear region, we find an ionized outflow driven by the quasar with velocities reaching 13,000 km s$^{-1}$, one of the fastest discovered to date with an outflow rate of 2000 M$_\odot$ yr$^{-1}$ and a kinetic luminosity of 6$\times10^{46}$ erg s$^{-1}$ resulting in coupling efficiency between the bolometric luminosity of the quasar and the outflow of 5%. The kinetic luminosity of the outflow is sufficient to power the turbulent motion of the gas on galactic and circumgalactic scales and is likely the primary driver of the radiative shocks on interstellar medium and circumgalactic medium scales. This provides compelling evidence supporting long-standing theoretical predictions that powerful quasar outflows are a main driver in regulating the heating and accretion rate of gas onto massive central cluster galaxies., Comment: 16 pages, 9 figures, 1 table, submitted to ApJ

The discovery of the kagome metal CsV$_3$Sb$_5$ sparked broad interest, due to the coexistence of a charge density wave (CDW) phase and possible unconventional superconductivity in the material. In this study, we use low-energy electron diffraction (LEED) with a $\mu$m-sized electron beam to explore the periodic lattice distortion at the antimony-terminated surface in the CDW phase. We recorded high-quality backscattering diffraction patterns in ultrahigh vacuum from multiple cleaved samples. Unexpectedly, we did not find superstructure reflexes at intensity levels predicted from dynamical LEED calculations for the reported $2 \times 2 \times 2$ bulk structure. Our results suggest that in CsV$_3$Sb$_5$ the periodic lattice distortion accompanying the CDW is less pronounced at Sb-terminated surfaces than in the bulk., Comment: 9 pages, 6 figures

Synthetic data generation with Large Language Models is a promising paradigm for augmenting natural data over a nearly infinite range of tasks. Given this variety, direct comparisons among synthetic data generation algorithms are scarce, making it difficult to understand where improvement comes from and what bottlenecks exist. We propose to evaluate algorithms via the makeup of synthetic data generated by each algorithm in terms of data quality, diversity, and complexity. We choose these three characteristics for their significance in open-ended processes and the impact each has on the capabilities of downstream models. We find quality to be essential for in-distribution model generalization, diversity to be essential for out-of-distribution generalization, and complexity to be beneficial for both. Further, we emphasize the existence of Quality-Diversity trade-offs in training data and the downstream effects on model performance. We then examine the effect of various components in the synthetic data pipeline on each data characteristic. This examination allows us to taxonomize and compare synthetic data generation algorithms through the components they utilize and the resulting effects on data QDC composition. This analysis extends into a discussion on the importance of balancing QDC in synthetic data for efficient reinforcement learning and self-improvement algorithms. Analogous to the QD trade-offs in training data, often there exist trade-offs between model output quality and output diversity which impact the composition of synthetic data. We observe that many models are currently evaluated and optimized only for output quality, thereby limiting output diversity and the potential for self-improvement. We argue that balancing these trade-offs is essential to the development of future self-improvement algorithms and highlight a number of works making progress in this direction.

The recent advances in quantum information processing, sensing and communications are surveyed with the objective of identifying the associated knowledge gaps and formulating a roadmap for their future evolution. Since the operation of quantum systems is prone to the deleterious effects of decoherence, which manifests itself in terms of bit-flips, phase-flips or both, the pivotal subject of quantum error mitigation is reviewed both in the presence and absence of quantum coding. The state-of-the-art, knowledge gaps and future evolution of quantum machine learning are also discussed, followed by a discourse on quantum radar systems and briefly hypothesizing about the feasibility of integrated sensing and communications in the quantum domain. Finally, we conclude with a set of promising future research ideas in the field of ultimately secure quantum communications with the objective of harnessing ideas from the classical communications field.

Achieving quantum advantage in energy storage and power extraction is a primary objective in the design of quantum-based batteries. We explore how long-range (LR) interactions in conjunction with Floquet driving can improve the performance of quantum batteries, particularly when the battery is initialized in a fully polarized state. In particular, we exhibit that by optimizing the driving frequency, the maximum average power scales super extensively with system-size which is not achievable through next-nearest neighbor interactions or traditional unitary charging, thereby gaining genuine quantum advantage. We illustrate that the inclusion of either two-body or many-body interaction terms in the LR charging Hamiltonian leads to a scaling benefit. Furthermore, we discover that a super-linear scaling in power results from increasing the strength of interaction compared to the transverse magnetic field and the range of interaction with low fall-off rate, highlighting the advantageous role of long-range interactions in optimizing quantum battery charging., Comment: 10 pages, 8 figures

We consider the problem of identifying the defectives from a population of items via a non-adaptive group testing framework with a random pooling-matrix design. We analyze the sufficient number of tests needed for approximate set identification, i.e., for identifying almost all the defective and non-defective items with high confidence. To this end, we view the group testing problem as a function learning problem and develop our analysis using the probably approximately correct (PAC) framework. Using this formulation, we derive sufficiency bounds on the number of tests for three popular binary group testing algorithms: column matching, combinatorial basis pursuit, and definite defectives. We compare the derived bounds with the existing ones in the literature for exact recovery theoretically and using simulations. Finally, we contrast the three group testing algorithms under consideration in terms of the sufficient testing rate surface and the sufficient number of tests contours across the range of the approximation and confidence levels.

Segment Anything Model 2 (SAM 2) has emerged as a powerful tool for video object segmentation and tracking anything. Key components of SAM 2 that drive the impressive video object segmentation performance include a large multistage image encoder for frame feature extraction and a memory mechanism that stores memory contexts from past frames to help current frame segmentation. The high computation complexity of multistage image encoder and memory module has limited its applications in real-world tasks, e.g., video object segmentation on mobile devices. To address this limitation, we propose EfficientTAMs, lightweight track anything models that produce high-quality results with low latency and model size. Our idea is based on revisiting the plain, nonhierarchical Vision Transformer (ViT) as an image encoder for video object segmentation, and introducing an efficient memory module, which reduces the complexity for both frame feature extraction and memory computation for current frame segmentation. We take vanilla lightweight ViTs and efficient memory module to build EfficientTAMs, and train the models on SA-1B and SA-V datasets for video object segmentation and track anything tasks. We evaluate on multiple video segmentation benchmarks including semi-supervised VOS and promptable video segmentation, and find that our proposed EfficientTAM with vanilla ViT perform comparably to SAM 2 model (HieraB+SAM 2) with ~2x speedup on A100 and ~2.4x parameter reduction. On segment anything image tasks, our EfficientTAMs also perform favorably over original SAM with ~20x speedup on A100 and ~20x parameter reduction. On mobile devices such as iPhone 15 Pro Max, our EfficientTAMs can run at ~10 FPS for performing video object segmentation with reasonable quality, highlighting the capability of small models for on-device video object segmentation applications.

This study integrates Transit Signal Priority (TSP) into multi-agent reinforcement learning (MARL) based traffic signal control. The first part of the study develops adaptive signal control based on MARL for a pair of coordinated intersections in a microscopic simulation environment. The two agents, one for each intersection, are centrally trained using a value decomposition network (VDN) architecture. The trained agents show slightly better performance compared to coordinated actuated signal control based on overall intersection delay at v/c of 0.95. In the second part of the study the trained signal control agents are used as background signal controllers while developing event-based TSP agents. In one variation, independent TSP agents are formulated and trained under a decentralized training and decentralized execution (DTDE) framework to implement TSP at each intersection. In the second variation, the two TSP agents are centrally trained under a centralized training and decentralized execution (CTDE) framework and VDN architecture to select and implement coordinated TSP strategies across the two intersections. In both cases the agents converge to the same bus delay value, but independent agents show high instability throughout the training process. For the test runs, the two independent agents reduce bus delay across the two intersections by 22% compared to the no TSP case while the coordinated TSP agents achieve 27% delay reduction. In both cases, there is only a slight increase in delay for a majority of the side street movements.

Spin relaxation of electrons in materials involve both reversible dephasing and irreversible decoherence processes. Their interplay leads to a complex dependence of spin relaxation times on the direction and magnitude of magnetic fields, relevant for spintronics and quantum information applications. Here, we use real-time first-principles density matrix dynamics simulations to directly simulate Hahn echo measurements, disentangle dephasing from decoherence, and predict T1, T2 and T2* spin lifetimes. We show that g-factor fluctuations lead to non-trivial magnetic field dependence of each of these lifetimes in inversion-symmetric crystals of CsPbBr3 and silicon, even when only intrinsic spin-phonon scattering is present. Most importantly, fluctuations in the off-diagonal components of the g-tensor lead to a strong magnetic field dependence of even the T1 lifetime in silicon. Our calculations elucidate the detailed role of anisotropic g-factors in determining the spin dynamics even in simple, low spin-orbit coupling materials such as silicon.

Mitigating climate change requires transforming agriculture to minimize environ mental impact and build climate resilience. Regenerative agricultural practices enhance soil organic carbon (SOC) levels, thus improving soil health and sequestering carbon. A challenge to increasing regenerative agriculture practices is cheaply measuring SOC over time and understanding how SOC is affected by regenerative agricultural practices and other environmental factors and farm management practices. To address this challenge, we introduce an AI-driven Soil Organic Carbon Copilot that automates the ingestion of complex multi-resolution, multi-modal data to provide large-scale insights into soil health and regenerative practices. Our data includes extreme weather event data (e.g., drought and wildfire incidents), farm management data (e.g., cropland information and tillage predictions), and SOC predictions. We find that integrating public data and specialized models enables large-scale, localized analysis for sustainable agriculture. In comparisons of agricultural practices across California counties, we find evidence that diverse agricultural activity may mitigate the negative effects of tillage; and that while extreme weather conditions heavily affect SOC, composting may mitigate SOC loss. Finally, implementing role-specific personas empowers agronomists, farm consultants, policymakers, and other stakeholders to implement evidence-based strategies that promote sustainable agriculture and build climate resilience.

Addressing climate change calls for action to control CO$_2$ pollution. Direct air and ocean capture offer a solution to this challenge. Making carbon capture competitive with alternatives, such as forestation and mineralisation, requires fundamentally novel approaches and ideas. One such approach is electrosorption, which is currently limited by the availability of suitable electrosorbents. In this work, we introduce a metal-organic copper-2,3,6,7,10,11-hexahydroxytriphenylene (Cu$_3$(HHTP)$_2$) metal-organic framework (MOF) that can act as electrosorbent for CO$_2$ capture, thereby expanding the palette of materials that can be used for this process. Cu$_3$(HHTP)$_2$ is the first MOF to switch its ability to capture and release CO$_2$ in aqueous electrolytes. By using cyclic voltammetry (CV) and differential electrochemical mass spectrometry (DEMS), we demonstrate reversible CO$_2$ electrosorption. Based on density functional theory (DFT) calculations, we provide atomistic insights into the mechanism of electrosorption and conclude that efficient CO$_2$ capture is facilitated by a combination of redox-active copper and aromatic HHTP ligand within Cu3(HHTP)2. By showcasing the applicability of Cu$_3$(HHTP)$_2$ -- with a CO$_2$ capacity of 2 mmol g$^{-1}$ and an adsorption enthalpy of -20 kJ mol$^{-1}$ - this study encourages further exploration of conductive redox-active MOFs in the search for superior CO$_2$ electrosorbents., Comment: 17 pages, 4 figures, supporting information

Uncertainty quantification is crucial in time series prediction, and quantile regression offers a valuable mechanism for uncertainty quantification which is useful for extreme value forecasting. Although deep learning models have been prominent in multi-step ahead prediction, the development and evaluation of quantile deep learning models have been limited. We present a novel quantile regression deep learning framework for multi-step time series prediction. In this way, we elevate the capabilities of deep learning models by incorporating quantile regression, thus providing a more nuanced understanding of predictive values. We provide an implementation of prominent deep learning models for multi-step ahead time series prediction and evaluate their performance under high volatility and extreme conditions. We include multivariate and univariate modelling, strategies and provide a comparison with conventional deep learning models from the literature. Our models are tested on two cryptocurrencies: Bitcoin and Ethereum, using daily close-price data and selected benchmark time series datasets. The results show that integrating a quantile loss function with deep learning provides additional predictions for selected quantiles without a loss in the prediction accuracy when compared to the literature. Our quantile model has the ability to handle volatility more effectively and provides additional information for decision-making and uncertainty quantification through the use of quantiles when compared to conventional deep learning models.

The Magellanic Stream has long been known to contain multiple HI strands and corresponding stellar populations are beginning to be discovered. Combining an H3-selected sample with stars drawn from the Gaia catalog, we trace stars along a sub-dominant strand of the Magellanic Stream, as defined by gas content, across 30$^\circ$ on the sky. We find that the dominant strand is devoid of stars with Galactocentric distance $\lesssim 55$ kpc while the subdominant strand shows a close correspondence to such stars. We conclude that (1) the two Stream strands have different origins, (2) they are likely only close in projection, (3) the subdominant strand is tidal in origin, and (4) the subdominant strand is composed of disk material, likely drawn from the disk of the Small Magellanic Cloud., Comment: 8 pages, 8 figures

This paper presents Llama Guard 3-1B-INT4, a compact and efficient Llama Guard model, which has been open-sourced to the community during Meta Connect 2024. We demonstrate that Llama Guard 3-1B-INT4 can be deployed on resource-constrained devices, achieving a throughput of at least 30 tokens per second and a time-to-first-token of 2.5 seconds or less on a commodity Android mobile CPU. Notably, our experiments show that Llama Guard 3-1B-INT4 attains comparable or superior safety moderation scores to its larger counterpart, Llama Guard 3-1B, despite being approximately 7 times smaller in size (440MB).

The detection and subsequent inference of binary black hole signals rely heavily on the accuracy of the waveform model employed. In the highly non-linear, dynamic, and strong-field regime near merger, these waveforms can only be accurately modeled through numerical relativity simulations. Considering the precision requirements of next-generation gravitational wave observatories, we present in this paper high-resolution simulations of four non-spinning quasi-circular binary black hole systems with mass ratios of 1, 2, 3, and 4, conducted using the GR-Athena++ code. We extract waveforms from these simulations using both finite radius and Cauchy characteristic extraction methods. Additionally, we provide a comprehensive error analysis to evaluate the accuracy and convergence of the waveforms. This dataset encompasses gravitational waves of the precision (self-mismatch) demanded by upcoming gravitational detectors such as LISA, Cosmic Explorer, and Einstein Telescope. The waveforms are publicly available on ScholarSphere, and represent the first set of waveforms of the new GR-Athena++ catalog., Comment: The gravitational wave catalog of this work is publicly available at https://scholarsphere.psu.edu/catalog?q=GRAthena

Transition metal telluride compositions are explored extensively for their unique magnetic behavior. Since chromium telluride (Cr2Te3) exhibits a near-room-temperature phase transition, the material can be effectively used in applications such as magnetic refrigeration. Compared to existing magnetocaloric materials, Heusler alloys, and rare-earth-based alloys, the large-scale synthesis of Cr2Te3 involves less complexity, resulting in a stable composition. Compared to existing tellurides, Cr2Te3 exhibited a large magnetic entropy change of 2.36 J/kg-K at a very small magnetic field of 0.1 T. The refrigeration capacity (RC) of 160 J/kg was determined from entropy change versus temperature curve. The results were comparable with the existing Cr compounds. The telluride system, Cr2Te3 compared to pure gadolinium, reveals an enhanced room temperature magnetocaloric effect (MCE) with a broad working temperature range. The heating cycle of MCE was successfully visualized using a thermal imaging setup. To confirm the observed magnetic properties of Cr2Te3, first-principles calculations were conducted. Through density functional theory (DFT) studies, we were able to determine both Curie temperature (TC) and Neel temperature (TN) which validated our experimental transitions at the same temperatures. Structural transition was also observed using first principles DFT calculation which is responsible for magnetic behavior.

In recent years, with the rapid development of augmented reality (AR) technology, there is an increasing demand for multi-user collaborative experiences. Unlike for single-user experiences, ensuring the spatial localization of every user and maintaining synchronization and consistency of positioning and orientation across multiple users is a significant challenge. In this paper, we propose a multi-user localization system based on ORB-SLAM2 using monocular RGB images as a development platform based on the Unity 3D game engine. This system not only performs user localization but also places a common virtual object on a planar surface (such as table) in the environment so that every user holds a proper perspective view of the object. These generated virtual objects serve as reference points for multi-user position synchronization. The positioning information is passed among every user's AR devices via a central server, based on which the relative position and movement of other users in the space of a specific user are presented via virtual avatars all with respect to these virtual objects. In addition, we use deep learning techniques to estimate the depth map of an image from a single RGB image to solve occlusion problems in AR applications, making virtual objects appear more natural in AR scenes.

Task-oriented dialogue systems rely on predefined conversation schemes (dialogue flows) often represented as directed acyclic graphs. These flows can be manually designed or automatically generated from previously recorded conversations. Due to variations in domain expertise or reliance on different sets of prior conversations, these dialogue flows can manifest in significantly different graph structures. Despite their importance, there is no standard method for evaluating the quality of dialogue flows. We introduce FuDGE (Fuzzy Dialogue-Graph Edit Distance), a novel metric that evaluates dialogue flows by assessing their structural complexity and representational coverage of the conversation data. FuDGE measures how well individual conversations align with a flow and, consequently, how well a set of conversations is represented by the flow overall. Through extensive experiments on manually configured flows and flows generated by automated techniques, we demonstrate the effectiveness of FuDGE and its evaluation framework. By standardizing and optimizing dialogue flows, FuDGE enables conversational designers and automated techniques to achieve higher levels of efficiency and automation.

We examine the role of LIGO-India in facilitating multi-messenger astronomy in the era of next generation observatories. A network with two L-shaped Cosmic Explorer (CE) detectors and one triangular Einstein Telescope (ET) would detect nearly the entire annual binary neutron star merger population up to a redshift of 0.5, localizing over 10,000 events within $10\ \mathrm{deg}^2$, including $\sim 150$ events within $0.1\ \mathrm{deg}^2$. Luminosity distance would be measured to within 10% for over 9,000 events and within 1% for $\sim 100$ events. Notably, replacing the 20 km CE detector with LIGO-India operating in A$^\sharp$ sensitivity (I$^\sharp$) retains comparable performance, achieving a similar number of detections and localization of over 9,000 events within $10\ \mathrm{deg}^2$ and $\sim 90$ events within $0.1\ \mathrm{deg}^2$. This configuration detects over $\sim 6,000$ events with luminosity distance uncertainties under 10%, including $\sim 50$ events with under 1%. Both networks are capable of detecting $\mathcal{O}(100)$ events up to 10 minutes before merger, with localization areas $\leq 10\ \mathrm{deg}^2$. While I$^\sharp$'s $5\times $ longer baseline with CE, compared to a second CE in the United States, achieves excellent localization and early warning capabilities, its shorter arms and narrower sensitivity band would limit its effectiveness for other science goals, e.g. detecting population III binary black hole mergers at $z \gtrsim 10$, neutron star mergers at $z \sim 2$, or constraining cosmological parameters., Comment: 17 pages (10 pages main text, 5 pages appendices, 2 pages bibliography), 12 figures, 4 tables

We present the observations of a quiescent filament eruption and its deflection from the radial direction. The event occurred in the southern solar hemisphere on 2021 May 9 and was observed by the Atmospheric Imaging Assembly (AIA) on board the Solar Dynamics Observatory (SDO), by the STEREO A Observatory and GONG. Part of the filament erupted in the west direction, while major part of the filament deviated towards east direction. LASCO observed a very weak CME towards the west direction where it faded quickly. Moreover, the eruption was associated with CME observed by STEREO A COR1 and COR2. Our observations provide the evidence that the filament eruption was highly non-radial in nature., Comment: Accepted in the Proceedings of IAUS 388

Miniaturization of electronic components has led to overheating, increasing power consumption and causing early circuit failures. Conventional heat dissipation methods are becoming inadequate due to limited surface area and higher short-circuit risks. This study presents a fast, low-cost, and scalable technique using 2D hexagonal boron nitride (hBN) coatings to enhance heat dissipation in commercial electronics. Inexpensive hBN layers, applied by drop casting or spray coating, boost thermal conductivity at IC surfaces from below 0.3 W/m-K to 260 W/m-K, resulting in over double the heat flux and convective heat transfer. This significantly reduces operating temperatures and power consumption, as demonstrated by a 17.4% reduction in a coated audio amplifier circuit board. Density functional theory indicates enhanced interaction between 2D hBN and packaging materials as a key factor. This approach promises substantial energy and cost savings for large-scale electronics without altering existing manufacturing processes., Comment: 27 Pages, 5 Figures

Intent discovery is crucial for both building new conversational agents and improving existing ones. While several approaches have been proposed for intent discovery, most rely on clustering to group similar utterances together. Traditional evaluation of these utterance clusters requires intent labels for each utterance, limiting scalability. Although some clustering quality metrics exist that do not require labeled data, they focus solely on cluster geometry while ignoring the linguistic nuances present in conversational transcripts. In this paper, we introduce Keyword-based Utterance Level Clustering Quality (KULCQ), an unsupervised metric that leverages keyword analysis to evaluate clustering quality. We demonstrate KULCQ's effectiveness by comparing it with existing unsupervised clustering metrics and validate its performance through comprehensive ablation studies. Our results show that KULCQ better captures semantic relationships in conversational data while maintaining consistency with geometric clustering principles.

We study an architecture for fault-tolerant measurement-based quantum computation (FT-MBQC) over optically-networked trapped-ion modules. The architecture is implemented with a finite number of modules and ions per module, and leverages photonic interactions for generating remote entanglement between modules and local Coulomb interactions for intra-modular entangling gates. We focus on generating the topologically protected Raussendorf-Harrington-Goyal (RHG) lattice cluster state, which is known to be robust against lattice bond failures and qubit noise, with the modules acting as lattice sites. To ensure that the remote entanglement generation rates surpass the bond-failure tolerance threshold of the RHG lattice, we employ spatial and temporal multiplexing. For realistic system timing parameters, we estimate the code cycle time of the RHG lattice and the ion resources required in a bi-layered implementation, where the number of modules matches the number of sites in two lattice layers, and qubits are reinitialized after measurement. For large distances between modules, we incorporate quantum repeaters between sites and analyze the benefits in terms of cumulative resource requirements. Finally, we derive and analyze a qubit noise-tolerance threshold inequality for the RHG lattice generation in the proposed architecture that accounts for noise from various sources. This includes the depolarizing noise arising from the photonically-mediated remote entanglement generation between modules due to finite optical detection efficiency, limited visibility, and the presence of dark clicks, in addition to the noise from imperfect gates and measurements, and memory decoherence with time. Our work thus underscores the hardware and channel threshold requirements to realize distributed FT-MBQC in a leading qubit platform today -- trapped ions., Comment: 20 pages, 19 figures

Each year, the production of synthetic dye wastewater reaches a trillion tons, posing a significant challenge to addressing water scarcity on a global level. Hence, the treatment of wastewater to prevent water scarcity is of prime importance, and failing to do so will increase ecotoxicological risks and human health. Textile wastewater contains harmful dye. Photocatalytic degradation of such dye-contaminated wastewater is crucial to purifying the dye-contaminated water. However, this process takes time, uses high-power lamps, and is expensive. Here, we report the effect of the concentration of precursor on the size and surface morphology of TiO2 nanostructures prepared by facile hydrothermal synthesis and its ability to perform as a photocatalyst to degrade the most common industrial textile dye, methylene blue (MB), under natural sunlight. The impact of particle size on the photocatalytic activity and photocarrier migration rate was thoroughly examined. Also, the effect of pH on adsorption and photocatalytic degradation has been evaluated in detail. With several optimized conditions, almost complete dye degradation was achieved within 40 minutes under the direct illumination of natural sunlight. The enhanced photocatalytic performance can be correlated to the synergetic effect of a higher charge transfer mechanism, good catalytic active surface area availability (386 m2/g), and several optimized parameters that affect the reaction efficacy. Additionally, repeated use of NPs without sacrificing performance five times confirmed its stability and Sustainability as a promising candidate for large-scale industrial textile wastewater remedies.

Supramolecular gels are formed by the self-assembly of low molecular weight organic gelators with their solvent molecules. These are emerging novel materials with good semiconducting and light emitting properties with application potential as hole and electron transport layers in organic solar cells, LEDs, stimulus-responsive smart semiconducting materials, thin film transistors (TFT) etc. In this context charge transport and mobility of charge carriers in these materials assume extreme significance. In the study, Electrochemical impedance spectroscopy, which is a non-destructive technique, is used to analyze frequency dependent electrochemical impedance values, of a novel meallogel, ZnA_CA (Zinc Acetate_Citric Acid), and used to evaluate the charge properties and mobility. A comparative study of mobility values obtained from diode I-V characteristics of the gel and Impedance measurements has also been made., Comment: 8 pages, 3 figures

Owing to their rapid cooling rate and hence loss-limited propagation distance, cosmic-ray electrons and positrons (CRe) at very high energies probe local cosmic-ray accelerators and provide constraints on exotic production mechanisms such as annihilation of dark matter particles. We present a high-statistics measurement of the spectrum of CRe candidate events from 0.3 to 40 TeV with the High Energy Stereoscopic System (H.E.S.S.), covering two orders of magnitude in energy and reaching a proton rejection power of better than $10^{4}$. The measured spectrum is well described by a broken power law, with a break around 1 TeV, where the spectral index increases from $\Gamma_1 = 3.25$ $\pm$ 0.02 (stat) $\pm$ 0.2 (sys) to $\Gamma_2 = 4.49$ $\pm$ 0.04 (stat) $\pm$ 0.2 (sys). Apart from the break, the spectrum is featureless. The absence of distinct signatures at multi-TeV energies imposes constraints on the presence of nearby CRe accelerators and the local CRe propagation mechanisms., Comment: main paper: 8 pages, 4 figures, supplemental material: 12 pages, 14 figures, accepted for publication in Physical Review Letters https://journals.aps.org/prl/

The ability to generate bipartite entanglement in quantum computing technologies is widely regarded as pivotal. However, the role of genuinely multipartite entanglement is much less understood than bipartite entanglement, particularly in the context of solving complicated optimization problems using quantum devices. It is thus crucial from both the algorithmic and hardware standpoints to understand whether multipartite entanglement contributes to achieving a good solution. Here, we tackle this challenge by analyzing genuine multipartite entanglement -- quantified by the generalized geometric measure -- generated in Trotterized quantum annealing and the quantum approximate optimization algorithm. Using numerical benchmarks, we analyze its occurrence in the annealing schedule in detail. We observe a multipartite-entanglement barrier, and we explore how it correlates to the algorithm's success. We also prove how multipartite entanglement provides an upper bound to the overlap of the instantaneous state with an exact solution. Vice versa, the overlaps to the initial and final product states, which can be easily measured experimentally, offer upper bounds for the multipartite entanglement during the entire schedule. Our results help to shed light on how complex quantum correlations come to bear as a resource in quantum optimization., Comment: 8+5 pages, 7+7 figures

In the past few years, the improved sensitivity and cadence of wide-field optical surveys have enabled the discovery of several afterglows without associated detected gamma-ray bursts (GRBs). We present the identification, observations, and multiwavelength modeling of a recent such afterglow (AT2023lcr), and model three literature events (AT2020blt, AT2021any, and AT2021lfa) in a consistent fashion. For each event, we consider the following possibilities as to why a GRB was not observed: 1) the jet was off-axis; 2) the jet had a low initial Lorentz factor; and 3) the afterglow was the result of an on-axis classical GRB (on-axis jet with physical parameters typical of the GRB population), but the emission was undetected by gamma-ray satellites. We estimate all physical parameters using afterglowpy and Markov Chain Monte Carlo methods from emcee. We find that AT2023lcr, AT2020blt, and AT2021any are consistent with on-axis classical GRBs, and AT2021lfa is consistent with both on-axis low Lorentz factor ($\Gamma_0 \approx 5 - 13$) and off-axis ($\theta_\text{obs}=2\theta_\text{jet}$) high Lorentz factor ($\Gamma_0 \approx 100$) jets., Comment: 40 pages, 18 figures, 20 tables

We show how the flow approach of Duch, with elementary differentials as coordinates, can be used to prove local well-posedness for rough stochastic differential equations driven by fractional Brownian motion with Hurst index $H > \frac{1}{4}$. A novelty appearing here is that we use coordinates for the flow that are indexed by trees rather than multi-indices.