1. Effect of organic acid additives on sulfite oxidation in a calcium-based slurry.
- Author
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Jeong, Ji Eun, Hwang, Ji Hyeon, and Lee, Chang-Yong
- Subjects
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FLUE gas desulfurization , *LACTIC acid , *ACETIC acid , *FORMIC acid , *SLURRY , *GYPSUM - Abstract
The forced oxidation of sulfite ions was conducted to obtain high-quality gypsum in the flue gas desulfurization system. The effects of formic, lactic, acrylic, acetic, propionic, and hexanoic acids added to calcium-based slurry on sulfite oxidation were investigated in this study. Sulfite oxidation was inhibited when the pKa value of organic acids was small or the carbon chain was long. In the identical slurry pH 6, the SO42- fractions of slurries with formic and lactic acids, which have the smallest pKa values, were lower than half that of the additive-free slurry. The addition of hexanoic acid with the longest carbon chain showed a similar SO42- fraction to that of additive-free slurry. These results indicate that the inhibitory effect on sulfite oxidation is more expressed by the acidity of organic acids. The SO42- fraction in the slurry affects the growth and quality of gypsum crystals. The slurry with acetic acid presented the highest SO42- fraction and resulted in the formation of high-quality gypsum crystals. The findings of this study can contribute to the selection of organic acid additives with high desulfurization efficiency and the production of high-quality gypsum. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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