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2. Laser photolysis studies of the reaction of chromium(III) octaethylporphyrin complex with triphenylphosphine and triphenylphosphine oxide

Author

Inamo, Masahiko, Matsubara, Nao, Iwayama, Tsutomu S., Okimi, Hiroshi, and Hoshino, Mikio

Subjects
Chromium compounds -- Electric properties, Photolysis -- Research, Chemistry
Abstract

The photoreactions of the chromium(III) octaethylpoprhyrin complex, [Cr(OEP)(Cl)(L)] (L = H2O, Py, OPPh3), in dichloromethane are studied using laser flash photolysis technique. A limited dissociative mechanism, including [Cr(OEP)(Cl)] as an intermediate, is ascribed to the photoinduced axial ligand substitution reactions of [Cr(OEP)(Cl)(L)] in solution based on the rate law and kinetic parameters of the reaction.

Published
2005

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