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6. Deoxygenative Geminal Silylboration of Amides Using Silylboronates: Synthesis and Use of α‐Boryl‐α‐Silylalkylamines.

7. Use of Aliphatic Carboxylic Acid Derivatives for NHC/Photoredox-Catalyzed meta -Selective Acylation of Electron-Rich Arenes.

11. N‑Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis

12. Radical C‐Glycosylation Using Photoexcitable Unprotected Glycosyl Borate.

20. Radical Caging Strategy for Cholinergic Optopharmacology

22. Synthesis of tertiary alkylphosphonate oligonucleotides through light-driven radical-polar crossover reactions

45. Photoredox-Catalyzed Site-Selective Intermolecular C(sp3)–H Alkylation of Tetrahydrofurfuryl Alcohol Derivatives

46. Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of alpha-ketoesters with terminal alkynes: OH center dot center dot center dot O/sp(3)-CH center dot center dot center dot O two-point hydrogen bonding

48. Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of α-ketoesters with terminal alkynes: OH···O/sp3-CH···O two-point hydrogen bonding combined with dispersive attractions† †Electronic supplementary information (ESI) available: Representative experimental procedures, spectroscopic data, and computational details. See DOI: 10.1039/c8sc00527c

49. Cobalt-catalyzed trimethylsilylmethylmagnesium-promoted radical alkenylation of alkyl halides: A complement to the heck reaction

50. Cobalt(diamine)-catalyzed cross-coupling reaction of alkyl halides with arylmagnesium reagents: Stereoselective constructions of arylated asymmetric carbons and application to total synthesis of AH13205

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