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We analyzed spectral cubes of Callisto's leading and trailing hemispheres, collected with the NIRSpec Integrated Field Unit (G395H) on the James Webb Space Telescope. These spatially resolved data show strong 4.25-micron absorption bands resulting from solid-state 12CO2, with the strongest spectral features at low latitudes near the center of its trailing hemisphere, consistent with radiolytic production spurred by magnetospheric plasma interacting with native H2O mixed with carbonaceous compounds. We detected CO2 rovibrational emission lines between 4.2 and 4.3 microns over both hemispheres, confirming the global presence of CO2 gas in Callisto's tenuous atmosphere. These results represent the first detection of CO2 gas over Callisto's trailing side. The distribution of CO2 gas is offset from the subsolar region on either hemisphere, suggesting that sputtering, radiolysis, and geologic processes help sustain Callisto's atmosphere. We detected a 4.38-micron absorption band that likely results from solid-state 13CO2. A prominent 4.57-micron absorption band that might result from CN-bearing organics is present and significantly stronger on Callisto's leading hemisphere, unlike 12CO2, suggesting these two spectral features are spatially anti-associated. The distribution of the 4.57-micron band is more consistent with a native origin and/or accumulation of dust from Jupiter's irregular satellites. Other, more subtle absorption features could result from CH-bearing organics, CO, carbonyl sulfide (OCS), and Na-bearing minerals. These results highlight the need for preparatory laboratory work and improved surface-atmosphere interaction models to better understand carbon chemistry on the icy Galilean moons before the arrival of NASA's Europa Clipper and ESA's JUICE spacecraft., Comment: Accepted in AAS Planetary Science Journal, January 2024

Pre-trained language models (PLM) based on transformer neural networks developed in the field of natural language processing (NLP) offer great opportunities to improve automatic content analysis in communication science, especially for the coding of complex semantic categories in large datasets via supervised machine learning. However, three characteristics so far impeded the widespread adoption of the methods in the applying disciplines: the dominance of English language models in NLP research, the necessary computing resources, and the effort required to produce training data to fine-tune PLMs. In this study, we address these challenges by using a multilingual transformer model in combination with the adapter extension to transformers, and few-shot learning methods. We test our approach on a realistic use case from communication science to automatically detect claims and arguments together with their stance in the German news debate on arms deliveries to Ukraine. In three experiments, we evaluate (1) data preprocessing strategies and model variants for this task, (2) the performance of different few-shot learning methods, and (3) how well the best setup performs on varying training set sizes in terms of validity, reliability, replicability and reproducibility of the results. We find that our proposed combination of transformer adapters with pattern exploiting training provides a parameter-efficient and easily shareable alternative to fully fine-tuning PLMs. It performs on par in terms of validity, while overall, provides better properties for application in communication studies. The results also show that pre-fine-tuning for a task on a near-domain dataset leads to substantial improvement, in particular in the few-shot setting. Further, the results indicate that it is useful to bias the dataset away from the viewpoints of specific prominent individuals., Comment: Accepted for Studies in Communication and Media

We present a feasibility study for passive sounding of Uranian icy moons using Uranian Kilometric Radio (UKR) emissions in the 100 - 900 kHz band. We provide a summary description of the observation geometry, the UKR characteristics, and estimate the sensitivity for an instrument analogous to the Cassini Radio Plasma Wave Science (RPWS) but with a modified receiver digitizer and signal processing chain. We show that the concept has the potential to directly and unambiguously detect cold oceans within Uranian satellites and provide strong constraints on the interior structure in the presence of warm or no oceans. As part of a geophysical payload, the concept could therefore have a key role in the detection of oceans within the Uranian satellites. The main limitation of the concept is coherence losses attributed to the extended source size of the UKR and dependence on the illumination geometry. These factors represent constraints on the tour design of a future Uranus mission in terms of flyby altitudes and encounter timing.

Jupiter's magnetosphere is considered to be the most powerful particle accelerator in the Solar System, accelerating electrons from eV to 70 MeV and ions to GeV energies. How electromagnetic processes drive energy and particle flows, producing and removing energetic particles, is at the heart of Heliophysics. Particularly, the 2013 Decadal Strategy for Solar and Space Physics was to "Discover and characterize fundamental processes that occur both within the heliosphere and throughout the universe". The Jovian system offers an ideal natural laboratory to investigate all of the universal processes highlighted in the previous Decadal. The X-ray waveband has been widely used to remotely study plasma across astrophysical systems. The majority of astrophysical emissions can be grouped into 5 X-ray processes: fluorescence, thermal/coronal, scattering, charge exchange and particle acceleration. The Jovian system offers perhaps the only system that presents a rich catalog of all of these X-ray emission processes and can also be visited in-situ, affording the special possibility to directly link fundamental plasma processes with their resulting X-ray signatures. This offers invaluable ground-truths for astrophysical objects beyond the reach of in-situ exploration (e.g. brown dwarfs, magnetars or galaxy clusters that map the cosmos). Here, we show how coupling in-situ measurements with in-orbit X-ray observations of Jupiter's radiation belts, Galilean satellites, Io Torus, and atmosphere addresses fundamental heliophysics questions with wide-reaching impact across helio- and astrophysics. New developments like miniaturized X-ray optics and radiation-tolerant detectors, provide compact, lightweight, wide-field X-ray instruments perfectly suited to the Jupiter system, enabling this exciting new possibility., Comment: A White Paper for the 2024-2033 Solar and Space Physics (Heliophysics) Decadal Survey

The Cassini spacecraft observed that Saturn's moon Enceladus possesses a series of jets erupting from its South Polar Terrain. Previous studies of in situ data collected by Cassini's Ion and Neutral Mass Spectrometer (INMS) have identified H$_2$O, CO$_2$, CH$_4$, NH$_3$, and H$_2$ within the plume of ejected material. Identification of minor species in the plume remains an ongoing challenge, owing to the large number of possible combinations that can be used to fit the INMS data. Here, we present the detection of several new compounds of strong importance to the habitability of Enceladus, including HCN, C$_2$H$_2$, C$_3$H$_6$, and C$_2$H$_6$. Our analyses of the low velocity INMS data, coupled with our detailed statistical framework, enable discrimination between previously ambiguous species in the plume by alleviating the effects of high dimensional model fitting. Together with plausible mineralogical catalysts and redox gradients derived from surface radiolysis, these compounds could potentially support extant microbial communities or drive complex organic synthesis leading to the origin of life., Comment: revised manuscript

At least two active plumes were observed on Neptune's moon Triton during the Voyager 2 flyby in 1989. Models for Triton's plumes have previously been grouped into five hypotheses, two of which are primarily atmospheric phenomena and are generally considered unlikely, and three of which include eruptive processes and are plausible. These hypotheses are compared, including new arguments, such as comparisons based on current understanding of Mars, Enceladus, and Pluto. An eruption model based on a solar-powered, solid-state greenhouse effect was previously considered the leading hypothesis for Triton's plumes, in part due to the proximity of the plumes to the subsolar latitude during the Voyager 2 flyby and the distribution of Triton's fans that are putatively deposits from former plumes. The other two eruption hypotheses are powered by internal heat, not solar insolation. Based on new analyses of the ostensible relation between the latitude of the subsolar point on Triton and the geographic locations of the plumes and fans, we argue that neither the locations of the plumes nor fans are strong evidence in favor of the solar-powered hypothesis. We conclude that all three eruption hypotheses should be considered further. Five tests are presented that could be implemented with remote sensing observations from future spacecraft to confidently distinguish among the eruption hypotheses for Triton's plumes. The five tests are based on the: (1) composition and thickness of Triton's southern hemisphere terrains, (2) composition of fan deposits, (3) distribution of active plumes, (4) distribution of fans, and (5) surface temperature at the locations of plumes and/or fans. The tests are independent, but complementary, and implementable with a single flyby mission such as the Trident mission concept. We note that, in the case of the solar-driven hypothesis, the 2030s and 2040s may be the last ..., Comment: Accepted for publication in Icarus

CO2 ice is present on the trailing hemisphere of Ariel but is mostly absent from its leading hemisphere. The leading/trailing hemispherical asymmetry in the distribution of CO2 ice is consistent with radiolytic production of CO2, formed by charged particle bombardment of H2O ice and carbonaceous material in Ariel's regolith. This longitudinal distribution of CO2 on Ariel was previously characterized using 13 near-infrared reflectance spectra collected at 'low' sub-observer latitudes between 30S to 30N. Here, we investigated the distribution of CO2 ice on Ariel using 18 new spectra: two collected over low sub-observer latitudes, five collected at 'mid' sub-observer latitudes (31 - 44N), and eleven collected over 'high' sub-observer latitudes (45 - 51N). Analysis of these data indicates that CO2 ice is primarily concentrated on Ariel's trailing hemisphere. However, CO2 ice band strengths are diminished in the spectra collected over mid and high sub-observer latitudes. This sub-observer latitudinal trend may result from radiolytic production of CO2 molecules at high latitudes and subsequent migration of this constituent to low latitude cold traps. We detected a subtle feature near 2.13 microns in two spectra collected over high sub-observer latitudes, which might result from a 'forbidden' transition mode of CO2 ice that is substantially stronger in well mixed substrates composed of CO2 and H2O ice, consistent with regolith-mixed CO2 ice grains formed by radiolysis. Additionally, we detected a 2.35-micron feature in some low sub-observer latitude spectra, which might result from CO formed as part of a CO2 radiolytic production cycle., Comment: Accepted in Planetary Science Journal

The Galileo mission to Jupiter discovered magnetic signatures associated with hidden sub-surface oceans at the moons Europa and Callisto using the phenomenon of magnetic induction. These induced magnetic fields originate from electrically conductive layers within the moons and are driven by Jupiter's strong time-varying magnetic field. The ice giants and their moons are also ideal laboratories for magnetic induction studies. Both Uranus and Neptune have a strongly tilted magnetic axis with respect to their spin axis, creating a dynamic and strongly variable magnetic field environment at the orbits of their major moons. Although Voyager 2 visited the ice giants in the 1980s, it did not pass close enough to any of the moons to detect magnetic induction signatures. However, Voyager 2 revealed that some of these moons exhibit surface features that hint at recent geologically activity, possibly associated with sub-surface oceans. Future missions to the ice giants may therefore be capable of discovering sub-surface oceans, thereby adding to the family of known ocean worlds in our solar system. Here, we assess magnetic induction as a technique for investigating sub-surface oceans within the major moons of Uranus. Furthermore, we establish the ability to distinguish induction responses created by different interior characteristics that tie into the induction response: ocean thickness, conductivity, and depth, and ionospheric conductance. The results reported here demonstrate the possibility of single-pass ocean detection and constrained characterization within the moons of Miranda, Ariel, and Umbriel, and provide guidance for magnetometer selection and trajectory design for future missions to Uranus.

The 27 satellites of Uranus are enigmatic, with dark surfaces coated by material that could be rich in organics. Voyager 2 imaged the southern hemispheres of Uranus' five largest 'classical' moons Miranda, Ariel, Umbriel, Titania, and Oberon, as well as the largest ring moon Puck, but their northern hemispheres were largely unobservable at the time of the flyby and were not imaged. Additionally, no spatially resolved datasets exist for the other 21 known moons, and their surface properties are essentially unknown. Because Voyager 2 was not equipped with a near-infrared mapping spectrometer, our knowledge of the Uranian moons' surface compositions, and the processes that modify them, is limited to disk-integrated datasets collected by ground- and space-based telescopes. Nevertheless, images collected by the Imaging Science System on Voyager 2 and reflectance spectra collected by telescope facilities indicate that the five classical moons are candidate ocean worlds that might currently have, or had, liquid subsurface layers beneath their icy surfaces. To determine whether these moons are ocean worlds, and investigate Uranus' ring moons and irregular satellites, close-up observations and measurements made by instruments onboard a Uranus orbiter are needed., Comment: Accepted in AAS Planetary Science Journal. arXiv admin note: text overlap with arXiv:2007.07284

We investigated whether sulfur-bearing species are present on the icy Galilean moon Callisto by analyzing eight near-infrared reflectance spectra collected over a wide range of sub-observer longitudes. We measured the band areas and depths of a 4-micron feature in these spectra, which has been attributed to sulfur dioxide (SO2), as well as carbonates, in previously collected datasets of this moon. All eight spectra we collected display the 4-micron band. The four spectra collected over Callisto's leading hemisphere display significantly stronger 4-micron bands compared to the four trailing hemisphere spectra (> 3-sigma difference). We compared the central wavelength position and shape of Callisto's 4-micron band to laboratory spectra of various sulfur-bearing species and carbonates. Our comparison demonstrates that Callisto's 4-micron band has a spectral signature similar to thermally-altered sulfur, as well as a 4.025 micron feature attributed to disulfanide (HS2). Our analysis therefore supports the presence of S-bearing species on Callisto but is not consistent with the presence of SO2. The significantly stronger 4-micron band detected on Callisto's leading hemisphere could result from collisions with H2S-rich dust grains that originate on Jupiter's retrograde irregular satellites or implantation of magnetospheric S ions that originate from volcanic activity on Io. Alternatively, S-bearing species could be native to Callisto and are exposed by dust collisions and larger impacts that drive regolith overturn, primarily on its leading side.

The five classical Uranian moons are possible ocean worlds that exhibit bizarre geologic landforms, hinting at recent surface-interior communication. However, Uranus' classical moons, as well as its ring moons and irregular satellites, remain poorly understood. We assert that a Flagship-class orbiter is needed to explore the Uranian satellites.

We investigated whether ammonia-rich constituents are present on the surface of the Uranian moon Ariel by analyzing 32 near-infrared reflectance spectra collected over a wide range of sub-observer longitudes and latitudes. We measured the band areas and depths of a 2.2-{\micron} feature in these spectra, which has been attributed to ammonia-bearing species on other icy bodies. Ten spectra display prominent 2.2-{\micron} features with band areas and depths > 2{\sigma}. We determined the longitudinal distribution of the 2.2-{\micron} band, finding no statistically meaningful differences between Ariel's leading and trailing hemispheres, indicating that this band is distributed across Ariel's surface. We compared the band centers and shapes of the five Ariel spectra displaying the strongest 2.2-{\micron} bands to laboratory spectra of various ammonia-bearing and ammonium-bearing species, finding that the spectral signatures of the Ariel spectra are best matched by ammonia-hydrates and flash frozen ammonia-water solutions. Our analysis also revealed that four Ariel spectra display 2.24-{\micron} bands (> 2{\sigma} band areas and depths), with band centers and shapes that are best matched by ammonia ice. Because ammonia should be efficiently removed over short timescales by ultraviolet photons, cosmic rays, and charged particles trapped in Uranus' magnetosphere, the possible presence of this constituent supports geologic activity in the recent past, such as emplacement of ammonia-rich cryolavas and exposure of ammonia-rich deposits by tectonism, impact events, and mass wasting.

We use data from Cassini's Composite Infrared Spectrometer CIRS to map Mimas' surface temperatures and its thermophysical properties. This provides a dramatic improvement on the work in Howett et al. (2011), where the values were determined at only two regions on Mimas (one inside, and another outside of the anomalous region). We use all spatially-resolved scans made by CIRS' focal plane 3 (FP3, 600 to 1100 cm-1) of Mimas' surface, which are largely daytime observations but do include one nighttime one. The resulting temperature maps confirm the presence and location of Mimas' previously discovered thermally anomalous region. No other thermally anomalous regions were discovered, although we note that the surface coverage is incomplete on Mimas' leading and anti-Saturn hemisphere. The thermal inertia map confirms that the anomalous region has a notably higher thermal inertia than its surroundings: 98 +/- 42 J m-2 K-1 s-1/2 inside of the anomaly, compared to 34 +/- 32 J m-2 K-1 s-1/2 outside. The albedo inside and outside of the anomalous region agrees within their uncertainty: 0.45+/-0.08 inside compared to 0.41 +/- 0.07 outside the anomaly. Interestingly the albedo appears brighter inside the anomaly region, which may not be surprising given this region does appear brighter at some UV wavelengths (0.338 microns, see Schenk et al., 2011). However, this result should be treated with caution because, as previously stated, statistically the albedo of these two regions is the same when their uncertainties are considered. These thermal inertia and albedo values determined here are consistent with those found by Howett et al. (2011), who determined the thermal inertia inside the anomaly to be 66 +/- 23 J m-2 K-1 s-1/2 and less than 16 J m-2 K-1 s-1/2 outside, with albedos that varied from 0.49 to 0.70.

The Atmospheric Radiation Interaction Simulator (AtRIS) was used to model the altitude-dependent Venusian absorbed dose and the Venusian dose equivalent. For the first time, we modeled the dose rates for different shape-, size-, and composition-mimicking detectors (phantoms): a CO$_2$-based phantom, a water-based microbial cell, and a phantom mimicking human tissue. Based on a new model approach, we give a reliable estimate of the altitude-dependent Venusian radiation dose in water-based microorganisms here for the first time. These microorganisms are representative of known terrestrial life. We also present a detailed analysis of the influence of the strongest ground-level enhancements measured at the Earth's surface, and of the impact of two historic extreme solar events on the Venusian radiation dose. Our study shows that because a phantom based on Venusian air was used, and because furthermore, the quality factors of different radiation types were not taken into account, previous model efforts have underestimated the radiation hazard for any putative Venusian cloud-based life by up to a factor of five. However, because we furthermore show that even the strongest events would not have had a hazardous effect on putative microorganisms within the potentially habitable zone (51 km - 62 km), these differences may play only a minor role.

Ganymede's surface exhibits great geological diversity, with old dark terrains, expressed through the surface composition, which is known to be dominated by two constituents: H2O-ice and an unidentified darkening agent. In this paper, new investigations of the composition of Ganymede's surface at global scale are presented. The analyses are derived from the linear spectral modeling of a high spectral resolution dataset, acquired with the near-infrared ground-based integral field spectrometer SINFONI of the VLT. We find that the Oren-Nayar (1994) model, generalizing the Lambert's law for rough surfaces, produces excellent photometric corrections. Modeling confirms that Ganymede's surface composition is dominated by H2O-ice, mostly crystalline, as well as a darkening agent, but it also highlights the necessity of secondary species to better fit the measurements: sulfuric acid hydrate and salts. A latitudinal gradient and a hemispherical dichotomy are the strongest spatial patterns observed for the darkening agent, the H2O-ice, and the sulfuric acid: the darkening agent is the major compound at the equator and mid-latitudes, especially on the trailing hemisphere, while the H2O-ice and the sulfuric acid are mostly located at high latitudes and on the leading hemisphere. This anti-correlation is likely a consequence of the bombardment of the constituents in the Jovian magnetosphere which are more intense at higher latitudes. Furthermore, the modeling confirms that polar caps are enriched in small, fresh, H2O-ice grains while equatorial regions are composed of larger grains. Finally, the spatial distribution of the salts is neither related to the Jovian magnetospheric bombardment nor the craters. These species are mostly detected on bright grooved terrains surrounding darker areas. Endogenous processes, such as freezing of upwelling fluids in the ice shell, may explain this distribution.

Jupiter has the most energetic and complex radiation belts in our solar system. Their hazardous environment is the reason why so many spacecraft avoid rather than investigate them, and explains how they have kept many of their secrets so well hidden, despite having been studied for decades. In this White Paper we argue why these secrets are worth unveiling. Jupiter's radiation belts and the vast magnetosphere that encloses them constitute an unprecedented physical laboratory, suitable for both interdisciplinary and novel scientific investigations: from studying fundamental high energy plasma physics processes which operate throughout the universe, such as adiabatic charged particle acceleration and nonlinear wave-particle interactions; to exploiting the astrobiological consequences of energetic particle radiation. The in-situ exploration of the uninviting environment of Jupiter's radiation belts present us with many challenges in mission design, science planning, instrumentation and technology development. We address these challenges by reviewing the different options that exist for direct and indirect observation of this unique system. We stress the need for new instruments, the value of synergistic Earth and Jupiter-based remote sensing and in-situ investigations, and the vital importance of multi-spacecraft, in-situ measurements. While simultaneous, multi-point in-situ observations have long become the standard for exploring electromagnetic interactions in the inner solar system, they have never taken place at Jupiter or any strongly magnetized planet besides Earth. We conclude that a dedicated multi-spacecraft mission to Jupiter's radiation belts is an essential and obvious way forward and deserves to be given a high priority in ESA's Voyage 2050 programme., Comment: 28 pages, 3 Tables, 11 Figures

Lightning was detected by Voyager 2 at Uranus and Neptune, and weaker electrical processes also occur throughout planetary atmospheres from galactic cosmic ray (GCR) ionisation. Lightning is an indicator of convection, whereas electrical processes away from storms modulate cloud formation and chemistry, particularly if there is little insolation to drive other mechanisms. The ice giants appear to be unique in the Solar System in that they are distant enough from the Sun for GCR-related mechanisms to be significant for clouds and climate, yet also convective enough for lightning to occur. This paper reviews observations (both from Voyager 2 and Earth), data analysis and modelling, and considers options for future missions. Radio, energetic particle and magnetic instruments are recommended for future orbiters, and Huygens-like atmospheric electricity sensors for in situ observations. Uranian lightning is also expected to be detectable from terrestrial radio telescopes., Comment: Revised version for Space Science Reviews