22 results on '"Nicolas Delbosc"'
Search Results
2. Validated Thermal Air Management Simulations of Data Centers Using Remote Graphics Processing Units.
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Johannes Sjölund, Mattias Vesterlund, Nicolas Delbosc, Amirul Khan, and Jon Summers
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- 2018
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- View/download PDF
3. Optimized implementation of the Lattice Boltzmann Method on a graphics processing unit towards real-time fluid simulation.
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Nicolas Delbosc, Jon L. Summers, Amirul Khan, Nikil Kapur, and Catherine J. Noakes
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- 2014
- Full Text
- View/download PDF
4. Bioactive Aliphatic Polycarbonates Carrying Guanidinium Functions: An Innovative Approach for Myotonic Dystrophy Type 1 Therapy
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Jean Jacques Vanden Eynde, Radu Oprean, Mathilde Wells, Ioan-Ovidiu Neaga, Alexandra Belayew, Bertrand Blankert, Nicolas Delbosc, Laetitia Verdy, Eugénie Ansseau, Ede Bodoki, Alexandra Baroni, and Stéphanie Hambye
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musculoskeletal diseases ,congenital, hereditary, and neonatal diseases and abnormalities ,Messenger RNA ,business.industry ,General Chemical Engineering ,General Chemistry ,Biology ,medicine.disease ,Myotonic dystrophy ,Molecular biology ,Article ,Chemistry ,chemistry.chemical_compound ,Text mining ,chemistry ,RNA splicing ,medicine ,business ,QD1-999 ,DNA - Abstract
Dystrophia myotonica type 1 (DM1) results from nuclear sequestration of splicing factors by a messenger RNA (mRNA) harboring a large (CUG)n repeat array transcribed from the causal (CTG)n DNA amplification. Several compounds were previously shown to bind the (CUG)n RNA and release the splicing factors. We now investigated for the first time the interaction of an aliphatic polycarbonate carrying guanidinium functions to DM1 DNA/RNA model probes by affinity capillary electrophoresis. The apparent association constants (Ka) were in the range described for reference compounds such as pentamidine. Further macromolecular engineering could improve association specificity. The polymer presented no toxicity in cell culture at concentrations of 1.6–100.0 μg/mL as evaluated both by MTT and real-time monitoring xCELLigence method. These promising results may lay the foundation for a new branch of potential therapeutic agents for DM1.
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- 2019
5. Three computational methods for analysing thermal airflow distributions in the cooling of data centres
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Daniel Burdett, Jonathan Summers, Morgan Tatchell-Evans, Gregory Nicholas de Boer, Adam Johns, Nicolas Delbosc, and Remi Baudot
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Finite volume method ,Computer simulation ,business.industry ,Computer science ,020209 energy ,Applied Mathematics ,Mechanical Engineering ,Multiphysics ,Airflow ,Lattice Boltzmann methods ,Mechanical engineering ,02 engineering and technology ,Computational fluid dynamics ,01 natural sciences ,Plenum space ,Finite element method ,010305 fluids & plasmas ,Computer Science Applications ,Mechanics of Materials ,0103 physical sciences ,0202 electrical engineering, electronic engineering, information engineering ,business - Abstract
Purpose This aim of this work is to investigate different modelling approaches for air-cooled data centres. The study employs three computational methods, which are based on finite element, finite volume and lattice Boltzmann methods and which are respectively implemented via commercial Multiphysics software, open-source computational fluid dynamics code and graphical processing unit-based code developed by the authors. The results focus on comparison of the three methods, all of which include models for turbulence, when applied to two rows of datacom racks with cool air supplied via an underfloor plenum. Design/methodology/approach This paper studies thermal airflows in a data centre by applying different numerical simulation techniques that are able to analyse the thermal airflow distribution for a simplified layout of datacom racks in the presence of a computer room air conditioner. Findings Good quantitative agreement between the three methods is seen in terms of the inlet temperatures to the datacom equipment. The computational methods are contrasted in terms of application to thermal management of data centres. Originality/value The work demonstrates how the different simulation techniques applied to thermal management of airflow in a data centre can provide valuable design and operational understanding. Basing the analysis on three very different computational approaches is new and would offer an informed understanding of their potential for a class of problems.
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- 2018
6. Macrocyclic P3HT Obtained by Intramolecular McMurry Coupling of Linear Bis-Aldehyde Polymer: A Direct Comparison with Linear Homologue
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Julien De Winter, Olivier Coulembier, Nicolas Delbosc, André Persoons, Sébastien Moins, and Philippe Dubois
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chemistry.chemical_classification ,Hydrodynamic radius ,Polymers and Plastics ,Absorption spectroscopy ,Organic Chemistry ,02 engineering and technology ,Polymer ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Aldehyde ,0104 chemical sciences ,Inorganic Chemistry ,Folding (chemistry) ,Crystallography ,chemistry ,Chain (algebraic topology) ,Intramolecular force ,Polymer chemistry ,Materials Chemistry ,McMurry reaction ,0210 nano-technology - Abstract
Different P3HT chain lengths have been synthesized, functionalized at both chain ends with aldehyde moieties and finally cyclized following the McMurry reaction in a pseudo high dilution process. The confirmation of the high yielded intramolecular coupling came from the decrease of the hydrodynamic radius observed by SEC, correlated to the conservation of the mass distribution by MALDI-ToF and by the very low content of residual linear precursor estimated by NMR. Different aggregation behaviors between linear and cyclic and between short and long systems have been pointed out by DSC and UV–vis absorption spectroscopy. We estimate that long cyclic structures present similar aggregation behavior than long linear ones mainly due to the folding of those chains.
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- 2017
7. How cyclic chain topology can reduce the crystallization rate of Poly(3- hexylthiophene) and promote the formation of liquid crystalline phases in comparison with linear analogue chains
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Olivier Coulembier, Jon Maiz, Dujin Wang, Fernando Ruipérez, Nicolas Delbosc, Alejandro J. Müller, Guoming Liu, and European Commission
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Materials science ,Transition temperature ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Topology ,01 natural sciences ,0104 chemical sciences ,law.invention ,Condensed Matter::Soft Condensed Matter ,Differential scanning calorimetry ,Optical microscope ,law ,Liquid crystal ,Materials Chemistry ,Melting point ,Molecule ,Density functional theory ,Crystallization ,0210 nano-technology - Abstract
We have studied how cyclic topology affects the crystallization and morphology of π-conjugated poly(3- hexylthiophene) (P3HT) molecules by comparing linear and cyclic analogues for the first time, with three different chain lengths. We employ a range of experimental techniques including wide-angle X-ray scattering (WAXS), polarized light optical microscopy (PLOM), differential scanning calorimetry (DSC) and a combination of Polarized Light Optical Microscopy (PLOM) and Spectroscopy (S). The crystallization and melting points, melting/crystallization enthalpies, and overall crystallization kinetics of cyclic P3HTs are found to be substantially lower than their linear counterparts. The results are explained by the higher rigidity of cyclic molecules, as predicted by density functional theory (DFT) calculations, in the low molecular weight range explored here, in comparison with linear P3HT chains. Additionally, we have found that cyclic P3HT can form liquid crystalline phases above their crystalline melting points and a new crystal form at lower temperatures. PLOM, WAXS, DSC and PLOM/S results indicate that cyclic P3HTs display bipolar and concentric nematic textures that disappear at a well-defined nematic-isotropic transition temperature. Such liquid crystalline textures are completely absent in the linear P3HTs analogues studied here. We conclude that the cyclic topology induces the formation of liquid crystalline phases as the rigid P3HT oligomers can self-assemble above their crystalline melting temperatures. J.M. acknowledges support from the Provincial Council of Gipuzkoa under the program Fellow Gipuzkoa and “Fomento San Sebastián” in the framework program “Retorno del Talento Local” Donostia up! 2016. We acknowledge the help of Dr. Jaime Martín and Ms. Sara Marina with the combined Microscopy/Spectroscopy measurements. J.M. and A.J.M. acknowledge funding by Mineco MAT2017- 83014-C2-1-P project. N.D. and O.C. are grateful to the Science Policy Office of the Belgian Federal Government (PAI 7/5) and to the Belgian FRFC-FNRS (n°2.4508.12). O.C. is Research Associates of the F.R.S.-FNRS. G.L. is grateful to the Youth Innovation Promotion Association of the Chinese Academy of Sciences (2015026). D.W. and A.J.M acknowledge the support from the National Natural Science Foundation of China (51820105005). All authors gratefully acknowledge the support of the EU through the H2020-MSCA-RISE-2017-778092 BIODEST project. Technical and human support provided by IZO-SGI, SGIker (UPV/EHU, MICINN, GV/EJ, ERDF and ESF) is gratefully acknowledged for assistance and generous allocation of computational resources.
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- 2019
8. TAD Click Chemistry on Aliphatic Polycarbonates: A First Step Toward Tailor-Made Materials
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Alexandra Baroni, Bertrand Blankert, Nicolas Delbosc, Laetitia Vlaminck, Filip Du Prez, and Laetitia Mespouille
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Materials science ,Polymers and Plastics ,Biocompatible Materials ,02 engineering and technology ,Materials design ,010402 general chemistry ,01 natural sciences ,Ring-opening polymerization ,Materials Testing ,Materials Chemistry ,Copolymer ,Conjugated diene ,Polycarboxylate Cement ,Calorimetry, Differential Scanning ,Molecular Structure ,Organic Chemistry ,Triazoles ,021001 nanoscience & nanotechnology ,Biocompatible material ,Combinatorial chemistry ,0104 chemical sciences ,Polymerization ,Click chemistry ,Surface modification ,Click Chemistry ,0210 nano-technology - Abstract
For the first time, the effectiveness of triazolinedione (TAD) click chemistry onto aliphatic polycarbonates (APC) is demonstrated. Statistic copolymers carrying click-reactive conjugated diene (in a ratio of 10%) are synthesized via organocatalyzed ring-opening polymerization. The highly efficient click reaction of TADs carrying simple butyl and phenyl functions are confirmed by 1 H-NMR and DSC. Network formation using a bivalent TAD is also performed and simply characterized by DSC. This post-polymerization functionalization of biocompatible and biodegradable APC pave the way to easy and versatile "on-demand" materials design.
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- 2018
9. Synthesis of Polyphthalaldehyde-Based Block Copolymers: Utilization of a Thermo-Sacrificial Segment for an Easy Access to Fine-Tuned Poly(3-hexylthiophene) Nanostructured Films
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Roberto Lazzaroni, Noémie Hergué, Olivier Coulembier, Laurence Pessoni, Mathieu Surin, Philippe Dubois, Pascal Gerbaux, Julien De Winter, and Nicolas Delbosc
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chemistry.chemical_classification ,Materials science ,Polymers and Plastics ,Nanoporous ,Organic Chemistry ,02 engineering and technology ,Polymer ,Thermal treatment ,Conjugated system ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Inorganic Chemistry ,chemistry.chemical_compound ,chemistry ,Polymerization ,Polymer chemistry ,Materials Chemistry ,Copolymer ,Moiety ,Azide ,0210 nano-technology - Abstract
This work deals with the synthesis and characterization of new diblock copolymers based on π-conjugated and depolymerizable units. These diblock copolymers are based on a regioregular poly(3-hexylthiophene) sequence associated with a sacrificial block, namely polyphthalaldehyde. The conjugated polymer was obtained by Grignard metathesis polymerization and end-capped by an alkynyl group while the depolymerizable segment was synthesized by an anionic cyclopolymerization from an azide moiety. Diblock copolymers with different molecular weights were then successfully synthesized via an alkyne–azide coupling reaction. Under specific conditions, these copolymers self-assemble into fibrillar nanostructures in thin films. The elimination of polyphthalaldehyde was carried out by thermal treatment, generating nanoporous poly(3-hexylthiophene) films. The use of a dry treatment to remove the polyphthalaldehyde block strongly reduces the morphological damages that would occur with a “wet” processing route. These nanop...
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- 2016
10. Recodable surfaces based on switchable hydrogen bonds
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Marie-Alice Virolleaud, Alexander Welle, Andreas Walther, Nils Wedler-Jasinski, Nicolas Delbosc, Leonie Barner, Julien Bernard, Damien Montarnal, Christopher Barner-Kowollik, Karlsruhe Institute of Technology (KIT), Ingénierie des Matériaux Polymères (IMP), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Jean Monnet [Saint-Étienne] (UJM)-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Institut National des Sciences Appliquées (INSA)-Université de Lyon-Institut National des Sciences Appliquées (INSA)-Université de Lyon-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon, and Montarnal, Damien
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[CHIM.POLY] Chemical Sciences/Polymers ,Materials science ,Hydrogen bond ,Spatially resolved ,Metals and Alloys ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Photochemistry ,01 natural sciences ,Catalysis ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,[CHIM.POLY]Chemical Sciences/Polymers ,chemistry ,Polymer chemistry ,Materials Chemistry ,Ceramics and Composites ,Methyl methacrylate ,0210 nano-technology - Abstract
International audience; We introduce recodable surfaces solely based on reversible artificial hydrogen bonding interactions. We show that a symmetrical oligoamide (SOA) attached to poly(methyl methacrylate) (PMMA) can be repeatedly immobilized and cleaved off spatially defined surface domains photochemically functionalized with asymmetric oligoamides (AOAs). The spatially resolved recodability is imaged and quantified via ToF-SIMS.
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- 2016
11. Validated thermal air management simulations ofdata centers using remote graphics processing units
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Jon Summers, Nicolas Delbosc, Mattias Vesterlund, Amirul Khan, and Johannes Sjolund
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Fluid Mechanics and Acoustics ,Computer science ,020209 energy ,Workload ,Strömningsmekanik och akustik ,02 engineering and technology ,Atmospheric model ,Data modeling ,GPU ,lattice Boltzmann methods ,Datorsystem ,Computer Systems ,0202 electrical engineering, electronic engineering, information engineering ,Code (cryptography) ,Boundary value problem ,Graphics ,data centers ,thermal management ,CFD ,Simulation ,Test data - Abstract
Simulation tools for thermal management of data centers help to improve layout of new builds or analyse thermal problems in existing data centers. The development of LBM on remote GPUs as an approach for such simulations is discussed making use of VirtualGL and prioritised multi-threaded implementations of an existing LBM code. The simulation is configured to model an existing and highly monitored test data center. Steady-state root mean square averages of measured and simulated temperatures are compared showing good agreement. The full capability of this simulation approach is demonstrated when comparing rack temperatures against a time varying workload, which employs time-dependent boundary conditions.
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- 2018
12. Real-time flow simulation of indoor environments using lattice Boltzmann method
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Nicolas Delbosc, Catherine J. Noakes, Jonathan Summers, and M. Amirul Islam Khan
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Computer science ,business.industry ,Flow (psychology) ,Turbulent airflow ,Lattice Boltzmann methods ,Time evolution ,Graphics processing unit ,Building and Construction ,Mechanics ,Computational fluid dynamics ,Computer Science::Performance ,Physics::Fluid Dynamics ,Computer Science::Computational Engineering, Finance, and Science ,Test chamber ,business ,Simulation ,ComputingMethodologies_COMPUTERGRAPHICS ,Energy (miscellaneous) - Abstract
A novel lattice Boltzmann method (LBM) based 3D computational fluid dynamics (CFD) technique has been implemented on the graphics processing unit (GPU) for the purpose of simulating the indoor environment in real-time. We study the time evolution of the turbulent airflow and temperature inside a test chamber and in a simple model of a four-bed hospital room. The predicted results from LBM are compared with traditional CFD based large eddy simulations (LES). Reasonable agreement between LBM results and LES method is observed with significantly faster computational times.
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- 2015
13. Potential of polymethacrylate pseudo crown ethers as solid state polymer electrolytes
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Jean-François Gohy, José C. Martins, Sébastien Moins, Olivier Coulembier, Philippe Dubois, André Decroly, Vincent Lemaur, Arnaud Krumpmann, Jérôme Cornil, Nicolas Delbosc, and Roberto Lazzaroni
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Materials science ,Diffusion ,Inorganic chemistry ,Solid-state ,Supramolecular chemistry ,02 engineering and technology ,Electrolyte ,Conductivity ,010402 general chemistry ,01 natural sciences ,Catalysis ,Metal ,Materials Chemistry ,chemistry.chemical_classification ,Molar mass ,Metals and Alloys ,General Chemistry ,Polymer ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Chemical engineering ,chemistry ,visual_art ,Ceramics and Composites ,visual_art.visual_art_medium ,lipids (amino acids, peptides, and proteins) ,0210 nano-technology - Abstract
The association of kinetic studies, DFT calculations and 1H–7Li NMR analyses allowed the control of the cyclo-ATRP of PEG9DMA and the production of polymethacrylate pseudo crown-ethers of various molar masses. Their potential to act as a solid-state polymer electrolyte in Li-ion batteries has been highlighted and may come from the supramolecular organization of the cyclo-PEG forming a Li+ diffusion channel.
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- 2017
14. Optimized implementation of the Lattice Boltzmann Method on a graphics processing unit towards real-time fluid simulation
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Jonathan Summers, Nikil Kapur, Nicolas Delbosc, Amirul Khan, and Catherine J. Noakes
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Computer science ,Graphics processing unit ,Lattice Boltzmann methods ,Parallel computing ,Solver ,Computational science ,Power (physics) ,Computer graphics ,Computational Mathematics ,CUDA ,Computational Theory and Mathematics ,Modeling and Simulation ,Fluid dynamics ,Focus (optics) - Abstract
Real-time fluid simulation is an active field of research in computer graphics, but they usually focus on visual impact rather than physical accuracy. However, by combining a lattice Boltzmann model with the parallel computing power of a graphics processing unit, both real-time compute capability and satisfactory physical accuracy are now achievable. The implementation of an optimized 3D real-time thermal and turbulent fluid flow solver with a performance of half a billion lattice node updates per second is described in detail. The effects of the hardware error checking code and the competition between appropriate boundary conditions and performance capabilities are discussed.
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- 2014
15. Fluorenone-Based Molecules for Bulk-Heterojunction Solar Cells: Synthesis, Characterization, and Photovoltaic Properties
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Rémi de Bettignies, Martial Billon, Renaud Demadrille, Nicolas Delbosc, Séverine Bailly, Adam Pron, Frédéric Lincker, Institut de biologie moléculaire des plantes (IBMP), Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), Institut National de L'Energie Solaire (INES), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), Propriétés Optiques des Matériaux et Applications (POMA), Centre National de la Recherche Scientifique (CNRS)-Université d'Angers (UA), Structures et propriétés d'architectures moléculaire (SPRAM - UMR 5819), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Institut Nanosciences et Cryogénie (INAC), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Faculty of Chemistry Technology (Warsaw, Poland), Warsaw University of Technology [Warsaw], SYstèmes Moléculaires et nanoMatériaux pour l’Energie et la Santé (SYMMES), Institut de Chimie du CNRS (INC)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS), Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université d'Angers (UA)-Centre National de la Recherche Scientifique (CNRS), Institut Nanosciences et Cryogénie (INAC), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)
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Materials science ,02 engineering and technology ,Conjugated system ,010402 general chemistry ,01 natural sciences ,7. Clean energy ,Polymer solar cell ,law.invention ,Biomaterials ,chemistry.chemical_compound ,law ,Solar cell ,Electrochemistry ,Thiophene ,[CHIM]Chemical Sciences ,Molecule ,Organic chemistry ,HOMO/LUMO ,ComputingMilieux_MISCELLANEOUS ,chemistry.chemical_classification ,[CHIM.ORGA]Chemical Sciences/Organic chemistry ,[SPI.NRJ]Engineering Sciences [physics]/Electric power ,[CHIM.MATE]Chemical Sciences/Material chemistry ,Electron acceptor ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,chemistry ,Fluorenone ,Physical chemistry ,0210 nano-technology - Abstract
A series of four conjugated molecules consisting of a fluorenone central unit symmetrically coupled to different oligothiophene segments are conceptually designed and synthesized to provide new electroactive materials for application in photovoltaic devices. The combination of electron-donating oligothiophene building blocks with an electron-accepting fluorenone unit results in the emergence of a new band assigned to an intramolecular charge transfer transition that gives rise to the extension of the absorption spectral range of the resulting molecules. Detailed spectroscopic and voltammetric investigations show that all studied molecules have highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) level positions, which make them good candidates for the application as electron-donors in bulk-heterojunction photovoltaic cells, with (6,6)-phenyl-C61-butyric acid methyl ester (PCBM)-C60 as electron acceptor component. Moderate device performances, with power conversion efficiencies (PCEs) comprised between 0.3 and 0.6%, were obtained with rigid molecules, containing either the bridging units between the thiophene rings, i.e., (2,7-bis(4,4 0 -dioctyl-cyclopenta[2,1-b:3,4-b 0 ]dithiophen-2yl)-fluoren-9-one (SCPTF) and 2,7-bis(4-(dioctylmethylene)-cyclopenta[2,1-b:3,4-b 0 ]dithiophen-5-yl)-fluoren-9-one (MCPTF) or a vinylene unit 2,7-bis(5-[(E)-1,2-bis(3-octylthien-2-yl)ethylene])-fluoren-9-one (TVF), whereas with (2,7-bis-(3,3 000 -dioctyl[2,2 0 ;5 0 ,2 00 ;5 00 ,2 000 ]quaterthiophen-5-yl)-fluoren-9-one (QTF) PCE up to 1.2% (under AM 1.5 illumination, 100mW cm � 2 , active area 0.28cm 2 ) was obtained. The strong p-stacking interactions in the solid state for this oligomer leading to improved morphology could explain the good performances of QTF-based devices, which rank among the highest recorded for nonpolymeric materials. Consequently, fluorenone-based non-polymeric molecules constitute highly attractive materials for solution-processable solar cell applications.
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- 2008
16. Highly Ordered Nanoporous Films from Supramolecular Diblock Copolymers with Hydrogen-Bonding Junctions
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Craig J. Hawker, Damien Montarnal, Marie-Alice Virolleaud, Julien Bernard, Nicolas Delbosc, Cécile Chamignon, Yingdong Luo, Eric Drockenmuller, Ingénierie des Matériaux Polymères (IMP), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Jean Monnet [Saint-Étienne] (UJM)-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Université de Lyon-Institut National des Sciences Appliquées (INSA)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon, ANR-12-JS08-0011,NAMASTE,Elaboration de matériaux nanoporeux à partir de copolymères à blocs supramoléculaires(2012), Laboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265 (C2P2), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École supérieure de Chimie Physique Electronique de Lyon (CPE)-Centre National de la Recherche Scientifique (CNRS), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2), Université de Lyon-Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Université Jean Monnet [Saint-Étienne] (UJM)-Centre National de la Recherche Scientifique (CNRS), Materials Research Laboratory (MRL), University of California [Santa Barbara] (UCSB), and University of California-University of California
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Materials science ,Supramolecular chemistry ,macromolecular substances ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Catalysis ,supramolecular diblock copolymers ,Polymer chemistry ,Copolymer ,Reversible addition−fragmentation chain-transfer polymerization ,ComputingMilieux_MISCELLANEOUS ,chemistry.chemical_classification ,Nanoporous ,Hydrogen bond ,technology, industry, and agriculture ,nanoporous membranes ,General Chemistry ,Polymer ,General Medicine ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,hydrogen bonding ,0104 chemical sciences ,Supramolecular polymers ,[CHIM.POLY]Chemical Sciences/Polymers ,chemistry ,Covalent bond ,RAFT agents ,0210 nano-technology - Abstract
International audience; We designed efficient precursors that combine complementary associative groups with exceptional binding affinities and thiocarbonylthio moieties enabling precise RAFT polymerization. Well defined PS and PMMA supramolecular polymers with molecular weights up to 30 kgmol(-1) are synthesized and shown to form highly stable supramolecular diblock copolymers (BCPs) when mixed, in non-polar solvents or in the bulk. Hierarchical self-assembly of such supramolecular BCPs by thermal annealing affords morphologies with excellent lateral order, comparable to features expected from covalent diblock copolymer analogues. Simple washing of the resulting materials with protic solvents disrupts the supramolecular association and selectively dissolves one polymer, affording a straightforward process for preparing well-ordered nanoporous materials without resorting to crosslinking or invasive chemical degradations.
- Published
- 2015
17. Simulation of the spreading of a gas-propelled micro-droplet upon impact on a dry surface using a lattice-Boltzmann approach
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Alfonso Ortega, Mark C. T. Wilson, Nicolas Delbosc, Jonathan Summers, and Mahsa Ebrahim
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Fluid Flow and Transfer Processes ,Physics ,Mechanical Engineering ,Nozzle ,Flow (psychology) ,Computational Mechanics ,Lattice Boltzmann methods ,Reynolds number ,Thermodynamics ,Mechanics ,Condensed Matter Physics ,01 natural sciences ,010305 fluids & plasmas ,Physics::Fluid Dynamics ,symbols.namesake ,Mechanics of Materials ,Free surface ,Phase (matter) ,0103 physical sciences ,symbols ,Two-phase flow ,010306 general physics ,Order of magnitude - Abstract
Spray cooling is one of the most promising methods of cooling high heat flux electronics. Depending on the type of the nozzle, spray cooling can be categorized as single-phase or two-phase. In the latter, which is known to be more effective, a secondary gas is used to further pressurize the liquid and form smaller droplets at higher velocities. The gas is also assumed to assist the spreading phase by imposing normal and tangential forces on the droplet free surface which adds to the complicated hydrodynamics of the droplet impact. Moreover, the order of magnitude of droplet size in spray cooling is 10−6 m, thereby introducing a low Weber and Reynolds numbers’ impact regime which heretofore has not been well understood. A 3D lattice Boltzmann method was implemented to simulate the impact of a single micro-droplet on a dry surface both in ambient air and under a stagnation gas flow. Two cases were closely compared and correlations were proposed for the instantaneous spreading diameter. Contrary to recent findings at higher impact Weber and Reynolds numbers, it was found that a stagnation flow only significantly affects the spreading phase for Ca* ≥ 0.35 but has little influence on the receding physics.
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- 2017
18. Synthesis, optoelectronic and photovoltaic properties of conjugated alternating copolymers incorporating 2,1,3-benzothiadiazole or fluorenone units: a comparative study
- Author
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Nicolas Delbosc, Wan Zaireen Nisa Yahya, Solenn Berson, Noëlla Lemaitre, Benjamin Grévin, Jean-Pierre Travers, Renaud Demadrille, Franz Fuchs, Jérôme Faure-Vincent, Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Structures et propriétés d'architectures moléculaire (SPRAM - UMR 5819), Institut Nanosciences et Cryogénie (INAC), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'Innovation pour les Technologies des Energies Nouvelles et les nanomatériaux (LITEN), Institut National de L'Energie Solaire (INES), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Synthèse, Structure et Propriétés de Matériaux Fonctionnels (STEP), SYstèmes Moléculaires et nanoMatériaux pour l’Energie et la Santé (SYMMES), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Institut Nanosciences et Cryogénie (INAC), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Institut de Chimie du CNRS (INC)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Materials science ,General Chemical Engineering ,Conjugated system ,Fluorene ,7. Clean energy ,law.invention ,chemistry.chemical_compound ,[SPI]Engineering Sciences [physics] ,Suzuki reaction ,law ,Polymer chemistry ,Solar cell ,[CHIM]Chemical Sciences ,ComputingMilieux_MISCELLANEOUS ,chemistry.chemical_classification ,[CHIM.ORGA]Chemical Sciences/Organic chemistry ,Photovoltaic system ,Energy conversion efficiency ,[SPI.NRJ]Engineering Sciences [physics]/Electric power ,General Chemistry ,Polymer ,[CHIM.MATE]Chemical Sciences/Material chemistry ,[CHIM.POLY]Chemical Sciences/Polymers ,Fluorenone ,chemistry ,Chemical engineering - Abstract
A series of p-type alternating copolymers based on oligothiophene and fluorene electron-donating units, and fluorenone or benzothiadiazole electron-withdrawing units was synthesised via Suzuki coupling reaction. Their optical, electrochemical and photovoltaic properties were investigated in detail allowing rational rules to be drawn on the structure–property relationships. We highlight in this work the crucial role of the side solubilizing groups attached to the polymer backbones that have a significant impact on the morphology of the blends and the solar cell's power conversion efficiency. Devices with an active area of 0.28 cm2, based on fluorenone-copolymers and [70]PCBM blends showed Voc up to 0.95 V and Power Conversion Efficiencies (PCE) up to 1.82% under AM1.5 simulated sunlight (100 mW cm−2) conditions. These values are improved compared to the ones reported to date for this class of materials.
- Published
- 2014
19. Control of the Aggregation of a Phenylenevinylenediimide Chromophore by Use of Supramolecular Chemistry: Enhanced Electroluminescence in Supramolecular Organic Devices
- Author
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Joël J. E. Moreau, Guillaume Wantz, Olivier Dautel, Mathias Reynes, Jean-Pierre Lère-Porte, Nicolas Delbosc, Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), Laboratoire de l'intégration, du matériau au système (IMS), Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Université Sciences et Technologies - Bordeaux 1, ANR-07-JCJC-0022 grant / NANOTECTUM, and ANR-07-JCJC-0022,NANO-TECTUM,Elaboration de réseaux organiques semi-conducteurs poreux par la tectonique moléculaire(2007)
- Subjects
Materials science ,General Chemical Engineering ,Supramolecular chemistry ,02 engineering and technology ,Electroluminescence ,010402 general chemistry ,Photochemistry ,01 natural sciences ,Supramolecular assembly ,chemistry.chemical_compound ,Materials Chemistry ,Imide ,chemistry.chemical_classification ,hydrogen bond ,Hydrogen bond ,[CHIM.ORGA]Chemical Sciences/Organic chemistry ,General Chemistry ,[CHIM.MATE]Chemical Sciences/Material chemistry ,Chromophore ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Supramolecular polymers ,chemistry ,Absorption (chemistry) ,0210 nano-technology ,optoelectronic ,supramolecular - Abstract
International audience; A new approach toward the tuning of the supramolecular organization of π-conjugated substructures containing imide functional groups has been investigated using the concept of supramolecular chemistry. This approach, which allows enhanced emission properties of the active material, was evaluated in the fabrication of optoelectronic devices. A linear ditopic chromophore H-ImPV was synthesized. This N−H imide constitutes a recognizing unit with an acceptor−donor−acceptor (ADA) hydrogen bond motif. End-capping of this new chromophore with a monotopic structuring unit allowed control of the supramolecular aggregation of the π-conjugated chromophore. The studies of the absorption and emission properties of the H-ImPV, in solution or in the solid state (thin films, powders), clearly revealed different aggregation behaviors, depending on the presence of the monotopic structuring unit: hindered unit (Cy-DAT) led to the formation of J-aggregates. In all cases, evidence for the heteromolecular association H-ImPV···Cy-DAT was obtained from an infrared absorption band located at 2715 cm−1, which was typical of the hydrogen bonding present in the ADA···DAD triplet. This has been illustrated by the fabrication of light-emitting devices based on films of H-ImPV and [H-ImPV.(Cy-DAT)2]. H-ImPV presents a poor ability to emit light, because of its aggregation, which induces quenching of luminescence. The high efficiencies exhibited by the devices based on a single layer of [H-ImPV.(Cy-DAT)2] are the result of the J-aggregation of chromophores, because of the bulky cyclohexyl fragments of the Cy-DAT. Tuning of the supramolecular organization of the H-ImPV by the addition of two equivalents of Cy-DAT in the active layer allowed recovery of the performances exhibited by the organic light-emitting devices (OLEDs) of the isolated chromophore. Therefore, the use of Cy-DAT is an interesting alternative to avoid aggregation and to significantly increase luminance. As a consequence, the luminous efficiencies of the devices are much better for the coassembled active layer.
- Published
- 2010
20. Conjugated alternating copolymer of dialkylquaterthiophene and fluorenone: synthesis, characterisation and photovoltaic properties
- Author
-
Nicolas Delbosc, Rémi de Bettignies, Renaud Demadrille, Muriel Firon, Martial Billon, Adam Pron, Yann Kervella, Patrice Rannou, SYstèmes Moléculaires et nanoMatériaux pour l’Energie et la Santé (SYMMES), Institut de Chimie du CNRS (INC)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Spectrométrie Physique (LSP), Université Joseph Fourier - Grenoble 1 (UJF)-Centre National de la Recherche Scientifique (CNRS), Laboratoire Composants Solaires (LCS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Propriétés Optiques des Matériaux et Applications (POMA), Centre National de la Recherche Scientifique (CNRS)-Université d'Angers (UA), Structures et propriétés d'architectures moléculaire (SPRAM - UMR 5819), Institut Nanosciences et Cryogénie (INAC), Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Synthèse, Structure et Propriétés de Matériaux Fonctionnels (STEP), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Faculty of Chemistry Technology (Warsaw, Poland), Warsaw University of Technology [Warsaw], Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université d'Angers (UA)-Centre National de la Recherche Scientifique (CNRS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG)
- Subjects
Organic solar cell ,Absorption spectroscopy ,Stereochemistry ,02 engineering and technology ,Photovoltaic effect ,Conjugated system ,010402 general chemistry ,Photochemistry ,01 natural sciences ,7. Clean energy ,chemistry.chemical_compound ,[SPI]Engineering Sciences [physics] ,[CHIM.ANAL]Chemical Sciences/Analytical chemistry ,Materials Chemistry ,[CHIM]Chemical Sciences ,HOMO/LUMO ,ComputingMilieux_MISCELLANEOUS ,chemistry.chemical_classification ,[SPI.NRJ]Engineering Sciences [physics]/Electric power ,General Chemistry ,Electron acceptor ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,[CHIM.POLY]Chemical Sciences/Polymers ,chemistry ,Fluorenone ,Cyclic voltammetry ,0210 nano-technology - Abstract
New π-conjugated alternating copolymers containing thienylene and fluorenone units, namely poly[(5,5‴-dioctyl-[2,2′;5′,2″;5″,2‴]quaterthiophene)-alt-(2,7-fluoren-9-one)] (PQTF8), as well as its analogue without fluorenone groups (PQT8), have been synthesized. Absorption studies carried out both in solution and in thin films indicate that the presence of fluorenone chromophores in PQTF8 leads to a significant extension of the absorption spectrum in the visible range as compared to PQT8. The redox properties of both polymers, in particular their LUMO and HOMO levels, have been characterized by cyclic voltammetry and have been found suitable for potential use of these systems in organic solar cells. Finally, these materials have been tested as donor components in bulk-heterojunction-type photovoltaic cells using PCBM as an electron acceptor. We demonstrate a strong effect of the polymer's molecular weight on crucial cell parameters, such as the short-circuit current density Jsc, and therefore on the overall cell efficiency. This effect is particularly pronounced for PQTF8-based cells leading to power conversion efficiencies up to 1.5% for the highest molecular weights.
- Published
- 2007
21. Control of the Aggregation of a Phenylenevinylenediimide Chromophore by Use of Supramolecular Chemistry: Enhanced Electroluminescence in Supramolecular Organic Devices.
- Author
-
Nicolas Delbosc, Mathias Reynes, Olivier J. Dautel, Guillaume Wantz, Jean-Pierre LeÌre-Porte, and JoeÌl J. E. Moreau
- Subjects
- *
CLUSTERING of particles , *IMIDES , *SUPRAMOLECULAR chemistry , *ELECTROLUMINESCENCE , *FUNCTIONAL groups , *OPTOELECTRONIC devices , *ELECTRON donor-acceptor complexes , *SOLUTION (Chemistry) - Abstract
A new approach toward the tuning of the supramolecular organization of Ï-conjugated substructures containing imide functional groups has been investigated using the concept of supramolecular chemistry. This approach, which allows enhanced emission properties of the active material, was evaluated in the fabrication of optoelectronic devices. A linear ditopic chromophore H-ImPVwas synthesized. This NâH imide constitutes a recognizing unit with an acceptorâdonorâacceptor (ADA) hydrogen bond motif. End-capping of this new chromophore with a monotopic structuring unit allowed control of the supramolecular aggregation of the Ï-conjugated chromophore. The studies of the absorption and emission properties of the H-ImPV, in solution or in the solid state (thin films, powders), clearly revealed different aggregation behaviors, depending on the presence of the monotopic structuring unit: hindered unit (Cy-DAT) led to the formation of J-aggregates. In all cases, evidence for the heteromolecular association H-ImPV·â·â·Cy-DATwas obtained from an infrared absorption band located at 2715 cmâ1, which was typical of the hydrogen bonding present in the ADA·â·â·DAD triplet. This has been illustrated by the fabrication of light-emitting devices based on films of H-ImPVand [H-ImPV.(Cy-DAT)2]. H-ImPVpresents a poor ability to emit light, because of its aggregation, which induces quenching of luminescence. The high efficiencies exhibited by the devices based on a single layer of [H-ImPV.(Cy-DAT)2] are the result of the J-aggregation of chromophores, because of the bulky cyclohexyl fragments of the Cy-DAT. Tuning of the supramolecular organization of the H-ImPVby the addition of two equivalents of Cy-DATin the active layer allowed recovery of the performances exhibited by the organic light-emitting devices (OLEDs) of the isolated chromophore. Therefore, the use of Cy-DATis an interesting alternative to avoid aggregation and to significantly increase luminance. As a consequence, the luminous efficiencies of the devices are much better for the coassembled active layer. [ABSTRACT FROM AUTHOR]
- Published
- 2010
- Full Text
- View/download PDF
22. Conjugated alternating copolymer of dialkylquaterthiophene and fluorenone: synthesis, characterisation and photovoltaic properties.
- Author
-
Renaud Demadrille, Nicolas Delbosc, Yann Kervella, Muriel Firon, Rémi De Bettignies, Martial Billon, Patrice Rannou, and Adam Pron
- Abstract
New π-conjugated alternating copolymers containing thienylene and fluorenone units, namely poly[(5,5‴-dioctyl-[2,2′;5′,2″;5″,2‴]quaterthiophene)-alt-(2,7-fluoren-9-one)] (PQTF8), as well as its analogue without fluorenone groups (PQT8), have been synthesized. Absorption studies carried out both in solution and in thin films indicate that the presence of fluorenone chromophores in PQTF8 leads to a significant extension of the absorption spectrum in the visible range as compared to PQT8. The redox properties of both polymers, in particular their LUMO and HOMO levels, have been characterized by cyclic voltammetry and have been found suitable for potential use of these systems in organic solar cells. Finally, these materials have been tested as donor components in bulk-heterojunction-type photovoltaic cells using PCBM as an electron acceptor. We demonstrate a strong effect of the polymer's molecular weight on crucial cell parameters, such as the short-circuit current density Jsc, and therefore on the overall cell efficiency. This effect is particularly pronounced for PQTF8-based cells leading to power conversion efficiencies up to 1.5% for the highest molecular weights. [ABSTRACT FROM AUTHOR]
- Published
- 2007
- Full Text
- View/download PDF
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