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Solar photovoltaic power output is modulated by atmospheric aerosols and clouds and thus contains valuable information on the optical properties of the atmosphere. As a ground-based data source with high spatiotemporal resolution it has great potential to complement other ground-based solar irradiance measurements as well as those of weather models and satellites, thus leading to an improved characterisation of global horizontal irradiance. In this work several algorithms are presented that can retrieve global tilted and horizontal irradiance and atmospheric optical properties from solar photovoltaic data and/or pyranometer measurements. Specifically, the aerosol (cloud) optical depth is inferred during clear sky (completely overcast) conditions. The method is tested on data from two measurement campaigns that took place in Allgäu, Germany in autumn 2018 and summer 2019, and the results are compared with local pyranometer measurements as well as satellite and weather model data. Using power data measured at 1 Hz and averaged to 1 minute resolution, the hourly global horizontal irradiance is extracted with a mean bias error compared to concurrent pyranometer measurements of 11.45 W m−2, averaged over the two campaigns, whereas for the retrieval using coarser 15 minute power data the mean bias error is 16.39 W m−2. During completely overcast periods the cloud optical depth is extracted from photovoltaic power using a lookup table method based on a one-dimensional radiative transfer simulation, and the results are compared to both satellite retrievals as well as data from the COSMO weather model. Potential applications of this approach for extracting cloud optical properties are discussed, as well as certain limitations, such as the representation of 3D radiative effects that occur under broken cloud conditions. In principle this method could provide an unprecedented amount of ground-based data on both irradiance and optical properties of the atmosphere, as long as the required photovoltaic power data are available and are properly pre-screened to remove unwanted artefacts in the signal. Possible solutions to this problem are discussed in the context of future work.

Proposal of a poster for the EMS2022Intention:Within the research project EnerSHelF (Energy-Self-Sufficiency for Health Facilities in Ghana), i. a. energy-meteorological and load-related measurement data are collected, for which an overview of the availability is to be presented on a poster.Context:In Ghana, the total electricity consumed has almost doubled between 2008 and 2018 according to the Energy Commission of Ghana. This goes along with an unstable power grid, resulting in power outages whenever electricity consumption peaks. The blackouts called "dumsor" in Ghana, pose a severe burden to the healthcare sector. Innovative solutions are needed to reduce greenhouse gas emissions and improve energy and health access.The aim of the project is therefore to develop PV-based energy solutions for healthcare facilities and to improve the reliability and integrability of such systems in the local electricity grid.The work is based on a measurement campaign that has been running since 2020 at three hospitals spread across the country. The variables measured include:Global tilted irradiance (GTI)Soiling ratio and temperature of the PV panelsAll-sky camera recordingsLoad measurement aggregate (grid node)Load measurement sub-distribution (departments and devices)In addition, weather stations are operated at the sites to improve weather forecasts.These datasets can be used to follow different approaches to managing the harsh conditions caused by dry and rainy seasons, and to design and control PV hybrid systems appropriately.According to the World Bank (2017) only 3% of the population in West Africa and the Sahel can currently access PV power through off-grid systems. As an important catalyst for sustainable development, access to a reliable source of clean energy is vital for inclusive economic development, improved human health, wellbeing and security. As such, EnerSHelF can contribute to Sustainable Development Goals (SDG) of health (SDG 3), energy (SDG 7) and partnerships (SDG 17).

The electrochemical behaviour of direct methanol fuel cells (DMFCs) is sensitive to methanol concentration; thus, to avoid external sensors, it is a promising candidate to monitor the concentration of methanol in the fuel circulation loop, which is central to the efficient operation of direct methanol fuel cell systems. We address this issue and report on an extremely robust electrochemical methanol sensing technique that is not sensitive to temperature, cell degradation and membrane electrode assembly (MEA) type. We develop a temperature independent empirical correlation of the dynamic response of cell voltage to step changes in current with methanol concentration. This equation is successfully validated under various operating scenarios at both the single cell and stack levels. Our sensing method achieves an impressive accuracy of ±0.1 M and this is expected to increase the reliability of methanol sensing and simplify the control logic of DMFC systems.

The rapid increase in solar photovoltaic (PV) installations worldwide has resulted in the electricity grid becoming increasingly dependent on atmospheric conditions, thus requiring more accurate forecasts of incoming solar irradiance. In this context, measured data from PV systems are a valuable source of information about the optical properties of the atmosphere, in particular the cloud optical depth (COD). This work reports first results from an inversion algorithm developed to infer global, direct and diffuse irradiance as well as atmospheric optical properties from PV power measurements, with the goal of assimilating this information into numerical weather prediction (NWP) models. High resolution measurements from both PV systems and pyranometers were collected as part of the BMWi-funded MetPVNet project, in the Allgäu region during autumn 2018 and summer 2019. These data were then used together with a PV model and both the DISORT and MYSTIC radiative transfer schemes within libRadtran (Emde et al., 2016; Mayer and Kylling, 2005)⁠ to infer cloud optical depth as well as direct, diffuse and global irradiance under highly variable atmospheric conditions. Hourly averages of each of the retrieved quantities were compared with the corresponding predictions of the COSMO weather model as well as data from satellite retrievals, and periods with differing degrees of variability and different cloud types were analysed. The DISORT-based algorithm is able to accurately retrieve COD, direct and diffuse irradiance components as long as the cloud fraction is high enough, whereas under broken cloud conditions the presence of 3D effects can lead to large errors. In that case the global horizontal irradiance is derived from tilted irradiance measurements and/or PV data using a lookup table based on the MYSTIC 3D Monte Carlo radiative transfer solver (Mayer, 2009)⁠. This work will provide the basis for future investigations using a larger number of PV systems to evaluate the improvements to irradiance and power forecasts that could be achieved by the assimilation of inferred irradiance into an NWP model. References Emde, C., Buras-Schnell, R., Kylling, A., Mayer, B., Gasteiger, J., Hamann, U., Kylling, J., Richter, B., Pause, C., Dowling, T. and Bugliaro, L.: The libRadtran software package for radiative transfer calculations (version 2.0.1), Geosci. Model Dev., 9(5), 1647–1672, doi:10.5194/gmd-9-1647-2016, 2016. Mayer, B.: Radiative transfer in the cloudy atmosphere, EPJ Web Conf., 1, 75–99, doi:10.1140/epjconf/e2009-00912-1, 2009. Mayer, B. and Kylling, A.: Technical note: The libRadtran software package for radiative transfer calculations - description and examples of use, Atmos. Chem. Phys., 5(7), 1855–1877, doi:10.5194/acp-5-1855-2005, 2005.

Photovoltaic (PV) power data are a valuable but as yet under-utilised resource that could be used to characterise global irradiance with unprecedented spatio-temporal resolution. The resulting knowledge of atmospheric conditions can then be fed back into weather models and will ultimately serve to improve forecasts of PV power itself. This provides a data-driven alternative to statistical methods that use post-processing to overcome inconsistencies between ground-based irradiance measurements and the corresponding predictions of regional weather models (see for instance Frank et al., 2018). This work reports first results from an algorithm developed to infer global horizontal irradiance as well as atmospheric optical properties such as aerosol or cloud optical depth from PV power measurements.Building on previous work (Buchmann, 2018), an improved forward model of PV power as a function of atmospheric conditions was developed. As part of the BMWi-funded project MetPVNet, PV power data from twenty systems in the Allgäu region were made available, and the corresponding irradiance, temperature and wind speed were measured during two measurement campaigns in autumn 2018 and summer 2019. System calibration was performed using all available clear sky days; the corresponding irradiance was simulated using libRadtran (Emde et al., 2016). Particular attention was paid to describing the dynamic variations in PV module temperature in order to correctly take into account the heat capacity of the solar panels.PV power data from the calibrated systems were then used together with both the DISORT and MYSTIC radiative transfer codes (Emde et al., 2016) to infer aerosol optical depth, cloud optical depth and irradiance under all sky conditions. The results were compared to predictions from the COSMO weather model, and the accuracy of the inverted quantities was compared using both a simple and more complex forward model. The potential of the method to extract irradiance data over a larger area as well as the increase in information from combining neighbouring PV systems will be explored in future work.References Buchmann, T., 2018: Potenzial von Photovoltaikanlagen zur Ableitung raum-zeitlich hoch aufgelöster Globalstrahlungsdaten. Heidelberg University, http://archiv.ub.uni-heidelberg.de/volltextserver/24687/.Emde, C., and Coauthors, 2016: The libRadtran software package for radiative transfer calculations (version 2.0.1). Geosci. Model Dev., 9, 1647–1672, doi:10.5194/gmd-9-1647-2016. https://www.geosci-model-dev.net/9/1647/2016/.Frank, C. W., S. Wahl, J. D. Keller, B. Pospichal, A. Hense, and S. Crewell, 2018: Bias correction of a novel European reanalysis data set for solar energy applications. Sol. Energy, 164, 12–24, doi:10.1016/j.solener.2018.02.012. https://doi.org/10.1016/j.solener.2018.02.012.

The temperature of photovoltaic modules is modelled as a dynamic function of ambient temperature, shortwave and longwave irradiance and wind speed, in order to allow for a more accurate characterisation of their efficiency. A simple dynamic thermal model is developed by extending an existing parametric steady-state model using an exponential smoothing kernel to include the effect of the heat capacity of the system. The four parameters of the model are fitted to measured data from three photovoltaic systems in the Allgäu region in Germany using non-linear optimisation. The dynamic model reduces the root-mean-square error between measured and modelled module temperature to 1.58 K on average, compared to 3.03 K for the steady-state model, whereas the maximum instantaneous error is reduced from 20.02 to 6.58 K.