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The surface of Mercury is dominated by extensive, widespread lava plains that formed early in its history. The emplacement of these lavas was accompanied by the release of magmatic volatiles, the bulk of which were lost to space via thermal escape and/or photodissociation. Here we consider the fate of these erupted volatiles by quantifying the volumes of erupted volcanic plains and estimating the associated masses of erupted volatiles. The concentrations and speciation of volatiles in Mercury's magmas are not known with certainty at this time, so we model a wide range of cases, based on existing experimental data and speciation models, at 3–7 log fO2 units below conditions determined by the iron-wüstite buffer. Cases range from relatively low gas content scenarios (total exsolved gas mass of 9×1015 kg) to high gas content scenarios (total exsolved gas = 5 × 1019 kg). We estimate that the average duration of a transient volcanic atmosphere resulting from a single eruption would be between ∼250 and ∼210,000 years, depending on the volume, degassed volatile content, and eruption rate of an individual eruption, as well as the fO2 conditions of the planet's interior. If a dense transient atmosphere was ever surface-bound long enough for the released volatiles to be transported to and cold-trapped at Mercury's polar regions, those trapped volatiles are predicted to be well-mixed with the regolith, and at least 16 m beneath the surface given regolith gardening rates. These volatiles would have a composition and age distinctly different from those of the H2O-ice deposits observed at the poles of Mercury today. © 2021 Elsevier B.V.

The surface of Mercury is dominated by extensive, widespread lava plains that formed early in its history. The emplacement of these lavas was accompanied by the release of magmatic volatiles, the bulk of which were lost to space via thermal escape and/or photodissociation. Here we consider the fate of these erupted volatiles by quantifying the volumes of erupted volcanic plains and estimating the associated masses of erupted volatiles. The concentrations and speciation of volatiles in Mercury's magmas are not known with certainty at this time, so we model a wide range of cases, based on existing experimental data and speciation models, at 3–7 log fO2 units below conditions determined by the iron-wüstite buffer. Cases range from relatively low gas content scenarios (total exsolved gas mass of 9×1015 kg) to high gas content scenarios (total exsolved gas = 5 × 1019 kg). We estimate that the average duration of a transient volcanic atmosphere resulting from a single eruption would be between ∼250 and ∼210,000 years, depending on the volume, degassed volatile content, and eruption rate of an individual eruption, as well as the fO2 conditions of the planet's interior. If a dense transient atmosphere was ever surface-bound long enough for the released volatiles to be transported to and cold-trapped at Mercury's polar regions, those trapped volatiles are predicted to be well-mixed with the regolith, and at least 16 m beneath the surface given regolith gardening rates. These volatiles would have a composition and age distinctly different from those of the H2O-ice deposits observed at the poles of Mercury today. © 2021 Elsevier B.V.

We present an improved lunar digital elevation model (DEM) covering latitudes within ±60°, at a horizontal resolution of 512 pixels per degree (~60 m at the equator) and a typical vertical accuracy ~3 to 4 m. This DEM is constructed from ~4.5×109geodetically-accurate topographic heights from the Lunar Orbiter Laser Altimeter (LOLA) onboard the Lunar Reconnaissance Orbiter, to which we co-registered 43,200 stereo-derived DEMs (each 1°×1°) from the SELENE Terrain Camera (TC) (~1010pixels total). After co-registration, approximately 90% of the TC DEMs show root-mean-square vertical residuals with the LOLA data of <5 m compared to ~ 50% prior to co-registration. We use the co-registered TC data to estimate and correct orbital and pointing geolocation errors from the LOLA altimetric profiles (typically amounting to <10 m horizontally and <1 m vertically). By combining both co-registered datasets, we obtain a near-global DEM with high geodetic accuracy, and without the need for surface interpolation. We evaluate the resulting LOLA + TC merged DEM (designated as "SLDEM2015") with particular attention to quantifying seams and crossover errors., United States. National Aeronautics and Space Administration. Lunar Reconnaissance Orbiter Project and Planetary Geology and Geophysics Program