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7. Related papers

Author

National Institute for Materials Science and National Institute for Materials Science

Published
2023

8. FGMnews (No.11-41)

Author

National Institute for Materials Science and National Institute for Materials Science

Published
2023

11. FGM 2002

Author

National Institute for Materials Science and National Institute for Materials Science

Published
2023

16. FGMnews (No.1-10)

Author

National Institute for Materials Science and National Institute for Materials Science

Published
2023

40. Development of genetic and electrochemical diagnosis and inhibition technologies for invisible corrosion caused by microorganisms (Contract Research); FY2021 Nuclear Energy Science & Technology and Human Resource Development Project

Author

Collaborative Laboratories for Advanced Decommissioning Science and National Institute for Materials Science

Abstract

日本原子力研究開発機構(JAEA)廃炉環境国際共同研究センター(CLADS)では、令和3年度英知を結集した原子力科学技術・人材育成推進事業(以下、「本事業」という)を実施している。本事業は、東京電力ホールディングス株式会社福島第一原子力発電所(1F)の廃炉等を始めとした原子力分野の課題解決に貢献するため、国内外の英知を結集し、様々な分野の知見や経験を、従前の機関や分野の壁を越えて緊密に融合・連携させた基礎的・基盤的研究及び人材育成を推進することを目的としている。平成30年度の新規採択課題から実施主体を文部科学省からJAEAに移行することで、JAEAとアカデミアとの連携を強化し、廃炉に資する中長期的な研究開発・人材育成をより安定的かつ継続的に実施する体制を構築した。本研究は、研究課題のうち、令和2年度に採択された「健全性崩壊をもたらす微生物による視認不可腐食の分子生物・電気化学的診断及び抑制技術の開発」の令和3年度の研究成果について取りまとめたものである。本研究は、微生物が関与して誘起・加速する金属材料の腐食(微生物鉄腐食)に関して、加速検査試験片、オンサイト遺伝子検査などの革新的な診断技術を開発、1Fで想定される微生物腐食の発生・進行条件の洗い出しを行い、水質や環境コントロールによって微生物腐食を防ぐ方法を提案することを目的とした。さらに、材料・微生物・電気化学を基盤とした研究拠点を発展的に形成し、現場技術者が使用可能な技術の開発、さらには高い学際性を持つリーダー人材の育成を目指す。本年度の実験から特に1Fと関連する環境サンプルから淡水では初となる電気微生物鉄腐食を行うメタン生成細菌が単離され、高い鉄腐食能が確認された。その他にも、局所的に激しい腐食を行う細菌の単離や、腐食細菌を集積する材料・技術開発が進んだ。, The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science \& Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2021. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station (1F), Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2020, this report summarizes the research results of the "Development of genetic and electrochemical diagnosis and inhibition technologies for invisible corrosion caused by microorganisms" conducted in FY2021. The present study aims to develop innovative diagnostic techniques such as accelerated test specimens and on-site genetic testing for microbially induced and accelerated corrosion of metallic materials (microbially influenced corrosion, MIC), and to identify the conditions that promote MIC at 1F for proposing methods to prevent MIC through water quality and environmental control. We also aim to develop a research base based on materials, microorganisms, and electrochemistry, to develop technologies that can be used by engineers in the field, and to cultivate

Published
2023

41. Development of genetic and electrochemical diagnosis and inhibition technologies for invisible corrosion caused by microorganisms (Contract research); FY2020 Nuclear Energy Science & Technology and Human Resource Development Project

Author

Collaborative Laboratories for Advanced Decommissioning Science and National Institute for Materials Science

Abstract

日本原子力研究開発機構(JAEA)廃炉環境国際共同研究センター(CLADS)では、令和2年度英知を結集した原子力科学技術・人材育成推進事業(以下、「本事業」という)を実施している。本事業は、東京電力ホールディングス株式会社福島第一原子力発電所(以下、「1F」という)の廃炉等をはじめとした原子力分野の課題解決に貢献するため、国内外の英知を結集し、様々な分野の知見や経験を、従前の機関や分野の壁を越えて緊密に融合・連携させた基礎的・基盤的研究及び人材育成を推進することを目的としている。平成30年度の新規採択課題から実施主体を文部科学省からJAEAに移行することで、JAEAとアカデミアとの連携を強化し、廃炉に資する中長期的な研究開発・人材育成をより安定的かつ継続的に実施する体制を構築した。本研究は、研究課題のうち、令和2年度に採択された「健全性崩壊をもたらす微生物による視認不可腐食の分子生物・電気化学的診断及び抑制技術の開発」の令和2年度の研究成果について取りまとめたものである。本研究は、微生物が関与して誘起・加速する金属材料の腐食(微生物鉄腐食)に関して、加速検査試験片、オンサイト遺伝子検査などの革新的な診断技術を開発、1Fで想定される微生物腐食の発生・進行条件の洗い出しを行い、水質や環境コントロールによって微生物腐食を防ぐ方法を提案することを目的とした。さらに、材料・微生物・電気化学を基盤とした研究拠点を発展的に形成し、現場技術者が使用可能な技術の開発、さらには高い学際性を持つリーダー人材の育成を目指す。本年度の実験から特に1Fと関連する環境サンプルから微生物による腐食反応が確認できており、この腐食反応を抑制する条件の特定が今後進むことが期待できる。その他の計画に関しても、次年度以降の重要な実験を始めるための予備的な知見が得られた。, The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science \& Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2020. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station (1F), Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2020, this report summarizes the research results of the "Development of genetic and electrochemical diagnosis and inhibition technologies for invisible corrosion caused by microorganisms" conducted in FY2020. The present study aims to develop innovative diagnostic techniques such as accelerated test specimens and on-site genetic testing for microbially induced and accelerated corrosion of metallic materials (microbially influenced corrosion, MIC), and to identify the conditions that promote MIC at 1F for proposing methods to prevent MIC through water quality and environmental control. We also aim to develop a research base based on materials, microorganisms, and electrochemistry, to develop technologies that can be used by engineers in the field, and to cultivate leade

Published
2022

42. Change in the electronic structure of the bismuth chalcogenide superconductor CsBi4-xPbxTe6 by dissociation of the bismuth dimers

Author

National Institutes for Quantum and Radiological Science and Technology, Okayama University, National Institute for Materials Science, National Institute for Materials Science, Cardiff University, Okayama University, National Institute for Materials Science, Kyushu Institute of Technology, Okazaki, Hiroyuki, Terashima, Kensei, Billington, David, Iwata, Keiji, Wakita, Takanori, Tanaka, Masashi, Takano, Yoshihiko, Muraoka, Yuji, Yokoya, Takayoshi, National Institutes for Quantum and Radiological Science and Technology, Okayama University, National Institute for Materials Science, National Institute for Materials Science, Cardiff University, Okayama University, National Institute for Materials Science, Kyushu Institute of Technology, Okazaki, Hiroyuki, Terashima, Kensei, Billington, David, Iwata, Keiji, Wakita, Takanori, Tanaka, Masashi, Takano, Yoshihiko, Muraoka, Yuji, and Yokoya, Takayoshi

Abstract

type:Journal Article, CsBi4−x Pb x Te6 is synthesized and the superconductivity associated with the structural transition from Pb substitution is studied. Photoemission spectroscopy measurements are performed in order to elucidate the relationship between the electronic structure and the occurrence of the superconductivity. When Bi is substituted with Pb, an electron doping-like change in the electronic structure is directly observed which is contrary to the naive expectation of hole doping. This observation is consistent with band structure calculations and appears to be a unique characteristic of CsBi4−x Pb x Te6 because of the dissociation of Bi dimers upon Pb substitution. These results indicate that it may be possible to control the electron and hole doping via manipulating the Bi dimers through Pb substitution.

Published
2020

43. Growth and superconducting properties of Cd-doped La(O,F)BiS2 single crystals

Author

University of Yamanashi/ MANA National Institute for Materials Science, Graduate School of Engineering, Kyushu Institute of Technology/ MANA National Institute for Materials Science, University of Yamanashi, MANA National Institute for Materials Science, Nagao, Masanori, Tanaka, Masashi, Watauchi, Satoshi, Takano, Yoshihiko, Tanaka, Isao, University of Yamanashi/ MANA National Institute for Materials Science, Graduate School of Engineering, Kyushu Institute of Technology/ MANA National Institute for Materials Science, University of Yamanashi, MANA National Institute for Materials Science, Nagao, Masanori, Tanaka, Masashi, Watauchi, Satoshi, Takano, Yoshihiko, and Tanaka, Isao

Abstract

type:Journal Article, Cd-doped La(O,F)BiS2 single crystals were grown using a CsCl/KCl flux. The grown crystals have a plate-like shape with ~1–2 mm square size in a well-developed ab-plane. The Cd doping in the crystals was successfully characterized by single crystal X-ray diffraction and electron probe microanalysis techniques. The superconductivity of La(O,F)BiS2 was gradually suppressed with Cd doping. The superconducting transition temperature with zero resistivity of La(O0.54F0.46)(Bi0.92Cd0.08)S2 was 2.3 K. The Cd doping does not change the superconducting anisotropy so much, albeit the considerable suppression of Tc.

Published
2019

44. Uniaxial strain effects on the superconducting transition in Re-doped Hg-1223 cuprate superconductors

Author

Graduate School of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan, Faculty of Science, Fukuoka University, Fukuoka 814-0180, Japan, National Institute for Materials Science, Tsukuba 305-0047, Japan, National Institute for Materials Science, Tsukuba 305-0047, Japan, School of Science and Technology, Kwansei Gakuin University, Hyogo 669-1337, Japan, Mito, Masaki, Ogata, Kazuma, Goto, Hiroki, Tsuruta, Kazuki, Nakamura, Kazuma, Deguchi, Hiroyuki, Horide, Tomoya, Matsumoto, Kaname, Tajiri, Takayuki, Hara, Hiroshi, Ozaki, Toshinori, Takeya, Hiroyuki, Takano, Yoshihiko, Graduate School of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan, Faculty of Science, Fukuoka University, Fukuoka 814-0180, Japan, National Institute for Materials Science, Tsukuba 305-0047, Japan, National Institute for Materials Science, Tsukuba 305-0047, Japan, School of Science and Technology, Kwansei Gakuin University, Hyogo 669-1337, Japan, Mito, Masaki, Ogata, Kazuma, Goto, Hiroki, Tsuruta, Kazuki, Nakamura, Kazuma, Deguchi, Hiroyuki, Horide, Tomoya, Matsumoto, Kaname, Tajiri, Takayuki, Hara, Hiroshi, Ozaki, Toshinori, Takeya, Hiroyuki, and Takano, Yoshihiko

Abstract

type:Journal Article, The effects of uniaxial strain and hydrostatic pressure on Hg0.83Re0.18Ba2Ca2.4Cu3.6O14 [Hg0.83(Re0.18)-1223] were investigated by ac magnetic measurements under stress corresponding to a pressure of 20 GPa at maximum. According to a previous thermal study based on the Ehrenfest relation, in-plane contraction should increase the superconducting transition temperature Tc, whereas out-of-plane contraction should decrease Tc. This suggests that the increase in Tc under hydrostatic-pressure contraction must be smaller than that under in-plane contraction. However, the present uniaxial-strain experiments revealed enhancement of Tc under both in-plane and out-of-plane contraction, and the largest enhancement was observed under hydrostatic-pressure contraction. According to a band calculation, all contraction styles induce hole doping from the HgO blocks to the CuO2 blocks, and hydrostatic-pressure contraction yields the largest hole doping among three contractions. This behavior explains well a series of changes in Tc in the stress region of below 8 GPa. More specifically, under hydrostatic-pressure contraction, Tc exhibited an increase, a decrease, and another increase with increasing pressure, and this multistep change is similar to that observed in Bi-2223-type cuprate superconductors, suggesting that it is necessary to distinguish the effect of strain on the middle CuO2 plane in the three-CuO2-plane package from that on the outer planes.

Published
2019

45. Superconductivity and its enhancement under high pressure in “F-free” single crystals of CeOBiS2

Author

Graduate School of Engineering, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata, Kitakyushu, 804-8550, Japan, WPI-MANA, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan, University of Yamanashi, 7-32 Miyamae, Kofu, Yamanashi 400-8511, Japan, WPI-MANA, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan, National Institute of Technology, Yonago College, 4448 Hikona, Yonago, Tottori 683-8502, Japan, Tanaka, Masashi, Nagao, Masanori, Matsumoto, Ryo, Kataoka, Noriyuki, Ueta, Ikuo, Tanaka, Hiromi, Watauchi, Satoshi, Tanaka, Isao, Takano, Yoshihiko, Graduate School of Engineering, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata, Kitakyushu, 804-8550, Japan, WPI-MANA, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan, University of Yamanashi, 7-32 Miyamae, Kofu, Yamanashi 400-8511, Japan, WPI-MANA, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan, National Institute of Technology, Yonago College, 4448 Hikona, Yonago, Tottori 683-8502, Japan, Tanaka, Masashi, Nagao, Masanori, Matsumoto, Ryo, Kataoka, Noriyuki, Ueta, Ikuo, Tanaka, Hiromi, Watauchi, Satoshi, Tanaka, Isao, and Takano, Yoshihiko

Abstract

type:Journal Article, “F-free” CeOBiS2 single crystals have successfully grown, thoroughly eliminating a concern about F-contamination by using a high-purity CsCl flux. The obtained crystals have a plate-like shape with a size of 1.0–3.0 mm in the well-developed plane. Single crystal X-ray structural analysis clearly revealed that the CeOBiS2 crystallizes with a space group P4/nmm (with lattice parameters of a = 4.0189 (6) Å, c = 13.573 (2) Å). The bond valence sum estimation and X-ray photoelectron spectroscopy analysis showed that the chemical state of Ce was in the mixed valence of Ce3+ and Ce4+. The single crystals show superconductivity with zero resistivity at ∼1.3 K. This is the first conclusive evidence of superconductivity driven by Ce valence fluctuation in surely non-doped CeOBiS2. The superconducting transition temperature was enhanced up to ∼3.8 K by applying hydrostatic pressure.

Published
2019

46. Quenching Dependence on Superconductivity in the Synthesizing Process of Single Crystals of RbxFe2-ySe2

Author

Graduate School of Engineering, Kyushu Institute of Technology/WPI-MANA, National Institute for Materials Science, WPI-MANA, National Institute for Materials Science, Tanaka, Masashi, Takeya, Hiroyuki, Takano, Yoshihiko, Graduate School of Engineering, Kyushu Institute of Technology/WPI-MANA, National Institute for Materials Science, WPI-MANA, National Institute for Materials Science, Tanaka, Masashi, Takeya, Hiroyuki, and Takano, Yoshihiko

Abstract

type:Journal Article, Superconducting single crystals of Rb-intercalated FeSe compounds RbxFe2-ySe2 were prepared by using a starting material of Rb2Se as a Rb source. The superconducting properties and the surface microstructures were systematically controlled by varying the cooling rate in the quenching process. The higher cooling rate in the sample provided a higher superconducting transition temperature with highly connected superconducting mesh-like surface structure. Extremely slow-cooling process led to the complete isolation between the superconducting domains., source:https://doi.org/10.1016/j.ssc.2017.08.002

Published
2019

47. Observation of zero resistance in as-electrodeposited FeSe

Author

WPI-MANA, National Institute for Materials Science, Graduate School of Pure and Applied Sciences, University of Tsukuba, WPI-MANA, National Institute for Materials Science, Graduate School of Engineering, Kyushu Institute of Technology, Institute for Metallic Materials, IFW Dresden, Department of Materials Physics, Nagoya University, Institute for Metallic Materials, IFW Dresden, WPI-MANA, National Institute for Materials Science, Institute for Technical Physics, Karlsruhe Institute of Technology, Yamashita, Aichi, Matsumoto, Ryo, Tanaka, Masashi, Hara, Hiroshi, Iida, Kazumasa, Holzapfel, Bernhard, Takeya, Hiroyuki, Takano, Yoshihiko, WPI-MANA, National Institute for Materials Science, Graduate School of Pure and Applied Sciences, University of Tsukuba, WPI-MANA, National Institute for Materials Science, Graduate School of Engineering, Kyushu Institute of Technology, Institute for Metallic Materials, IFW Dresden, Department of Materials Physics, Nagoya University, Institute for Metallic Materials, IFW Dresden, WPI-MANA, National Institute for Materials Science, Institute for Technical Physics, Karlsruhe Institute of Technology, Yamashita, Aichi, Matsumoto, Ryo, Tanaka, Masashi, Hara, Hiroshi, Iida, Kazumasa, Holzapfel, Bernhard, Takeya, Hiroyuki, and Takano, Yoshihiko

Abstract

type:Journal Article, Superconducting FeSe films were electrochemically deposited on rolling-assisted biaxially textured substrate (RABiTS) tape. We observed zero resistivity in the as-electrodeposited FeSe film prepared on the RABiTS when the appropriate voltage was applied while it was dipped into the solution. When the RABiTS tape was dipped in the solution without applying voltage, a thin Se film was deposited on the substrate. The compositional ratio of the FeSe film got closer to the stoichiometric ratio with decreasing the dipping time before applying voltage., source:https://doi.org/10.1016/j.ssc.2017.11.018

Published
2019

48. Colloidal Synthesis of Air-Stable Alloyed CsSn1–xPbxI3 Perovskite Nanocrystals for Use in Solar Cells

Author

Faculty of Informatics and Engineering, The University of Electro-Communications, Faculty of Life Science and Systems Engineering, Kyushu Institute of Technology, Faculty of Informatics and Engineering, The University of Electro-Communications, CREST, Japan Science and Technology Agency (JST), Faculty of Life Science and Systems Engineering, Kyushu Institute of Technology, CREST, Japan Science and Technology Agency (JST), Department of Electrical and Electronic Engineering, Faculty of Science and Engineering, Ritsumeikan University, CREST, Japan Science and Technology Agency (JST), Department of Electrical and Electronic Engineering, Miyazaki University,CREST, Japan Science and Technology Agency (JST), Beijing Key Laboratory of Novel Thin Film Solar Cells, State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Center for Green Research on Energy and Environmental Materials, National Institute for Materials Science (NIMS), Global Research Center for Environmental and Energy Based on Nanomaterials Science, National Institute for Materials Science (NIMS), Liu, Feng, Ding, Chao, Zhang, Yaohong, Ripolles, Teresa S., Kamisaka, Taichi, Toyoda, Taro, Hayase, Shuzi, Minemoto, Takashi, Yoshino, Kenji, Dai, Songyuan, Yanagida, Masatoshi, Noguchi, Hidenori, Shen, Qing, Faculty of Informatics and Engineering, The University of Electro-Communications, Faculty of Life Science and Systems Engineering, Kyushu Institute of Technology, Faculty of Informatics and Engineering, The University of Electro-Communications, CREST, Japan Science and Technology Agency (JST), Faculty of Life Science and Systems Engineering, Kyushu Institute of Technology, CREST, Japan Science and Technology Agency (JST), Department of Electrical and Electronic Engineering, Faculty of Science and Engineering, Ritsumeikan University, CREST, Japan Science and Technology Agency (JST), Department of Electrical and Electronic Engineering, Miyazaki University,CREST, Japan Science and Technology Agency (JST), Beijing Key Laboratory of Novel Thin Film Solar Cells, State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Center for Green Research on Energy and Environmental Materials, National Institute for Materials Science (NIMS), Global Research Center for Environmental and Energy Based on Nanomaterials Science, National Institute for Materials Science (NIMS), Liu, Feng, Ding, Chao, Zhang, Yaohong, Ripolles, Teresa S., Kamisaka, Taichi, Toyoda, Taro, Hayase, Shuzi, Minemoto, Takashi, Yoshino, Kenji, Dai, Songyuan, Yanagida, Masatoshi, Noguchi, Hidenori, and Shen, Qing

Abstract

type:Journal Article, Organic–inorganic hybrid perovskite solar cells have demonstrated unprecedented high power conversion efficiencies in the past few years. Now, the universal instability of the perovskites has become the main barrier for this kind of solar cells to realize commercialization. This situation can be even worse for those tin-based perovskites, especially for CsSnI3, because upon exposure to ambient atmosphere the desired black orthorhombic phase CsSnI3 would promptly lose single crystallinity and degrade to the inactive yellow phase, followed by irreversible oxidation into metallic Cs2SnI6. By alloying CsSnI3 with CsPbI3, we herein report the synthesis of alloyed perovskite quantum dot (QD), CsSn1–xPbxI3, which not only can be phase-stable for months in purified colloidal solution but also remains intact even directly exposed to ambient air, far superior to both of its parent CsSnI3 and CsPbI3 QDs. Ultrafast transient absorption spectroscopy studies reveal that the photoexcited electrons in the alloyed QDs can be injected into TiO2 nanocrystals at a fast rate of 1.12 × 1011 s–1, which enables a high photocurrent generation in solar cells.

Published
2018

49. High Pressure Polymerization of Metal Doped C60 ~In an Attempt to Prepare Carbon Clathrate Compounds~

Author

Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata, Kitakyushu 804-8550, Japan, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Japan, Tanaka, M., Yamanaka, S., Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata, Kitakyushu 804-8550, Japan, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Japan, Tanaka, M., and Yamanaka, S.

Abstract

type:Conference Paper, 57th European High Pressure Research Group Meeting on High Pressure Science and Technology (EHPRG2019), 1st - 6th September 2019, Prague, Czech Republic, source:https://www.ehprg2019.org

Published
2020

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