Search

Spaceborne impact ionization mass spectrometers, such as the Cosmic Dust Analyzer on board the past Cassini spacecraft or the SUrface Dust Analyzer being built for NASA's upcoming Europa Clipper mission, are of crucial importance for the exploration of icy moons in the Solar System, such as Saturn's moon Enceladus or Jupiter's moon Europa. For the interpretation of data produced by these instruments, analogue experiments on Earth are essential. To date, thousands of laboratory mass spectra have been recorded with an analogue experiment for impact ionization mass spectrometers. Simulation of mass spectra of ice grains in space is achieved by a Laser Induced Liquid Beam Ion Desorption (LILBID) approach. The desorbed cations or anions are analyzed in a time‐of‐flight mass spectrometer. The amount of unstructured raw data is increasingly challenging to sort, process, interpret and compare with data from space. Thus far this has been achieved manually for individual mass spectra because no database containing the recorded reference spectra was available. Here we describe the development of a comprehensive, extendable database containing cation and anion mass spectra from the laboratory LILBID facility. The database is based on a Relational Database Management System with a web server interface and enables filtering of the laboratory data using a wide range of parameters. The mass spectra can be compared not only with data from past and future space missions but also mass spectral data generated by other, terrestrial, techniques. The validated and approved subset of the database is available for general public (https://lilbid-db.planet.fu-berlin.de)., Plain Language Summary: Thousands of laboratory mass spectra, each with an individual set of experimental parameters, have been recorded so far using a facility situated at Freie Universität Berlin, Germany. The mass spectra help analyze and interpret data returned from spacecraft in the vicinity of icy moons in the Solar System. The unstructured laboratory data is increasingly challenging to sort and compare to the data from space. We developed an extendable database containing the laboratory data. The database is available for general public and allows filtering the stored data for a wide range of experimental parameters and, in turn, significantly improves analysis of data not only from past space missions but also future missions in particular., Key Points: We describe the development of a comprehensive spectral database containing laboratory analogue data for spaceborne mass spectrometers. The database is based on a Relational Database Management System with a web interface and accessible for community use. Filtering the laboratory data using a wide range of experimental parameters allows a straightforward analysis of returned flight data., EC, Horizon 2020 Framework Programme (H2020) http://dx.doi.org/10.13039/100010661, Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659, https://doi.org/10.5281/zenodo.6863855, https://sbnarchive.psi.edu/pds3/cassini/cda/COCDA_0007.tar.gz

International audience; Ammonia is an interesting molecule suspected to be formed in Titan ionosphere and leading to further complex chemistry. Here we experimentally study one of the two ways of formation of ammonia in the ionosphere: the catalysis on surfaces in a N2-H2 plasma. We vary plasma conditions in a CCP RF discharge and follow the ammonia formation thanks to IR and mass spectrometries. We show the strong effect of pressure, H2 percentage, plasma power and metallic surfaces.