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2. A high-spin and durable polyradical: Poly(4-diphenylaminium-1,2-phenylenevinylene)

Author

Murata, Hidenori, Takahashi, Masahiro, Namba, Kazuaki, Takahashi, Naoki, and Nishide, Hiroyuki

Subjects
Radicals (Chemistry) -- Chemical properties, Radicals (Chemistry) -- Atomic properties, Amines -- Chemical properties, Amines -- Atomic properties, Spin coupling -- Analysis, Biological sciences, Chemistry
Abstract

A purely organic, high-spin and durable polyradical molecule is synthesized. It is based on the non-Kekule- and non-disjoint design of a pi-conjugated poly(1,2-phenylenevinylene) backbone pendantly 4-substituted with multiple robust arylaminium radicals.

Published
2004

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