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12. The Asymmetric Kharasch Addition “On Water” Catalyzed by “RhCl[(–)-DIOP]” Species

13. The ruthenium-catalyzed reduction and reductive N-alkylation of secondary amides with hydrosilanes: practical synthesis of secondary and tertiary amines by judicious choice of hydrosilanes

20. A triruthenium carbonyl cluster bearing a bridging acenaphthylene ligand: an efficient catalyst for reduction of esters, carboxylic acids, and amides by trialkylsilanes

22. Synthetic studies of cis-3a-aryloctahydroindole derivatives by copper-catalyzed cyclization of N-allyltrichloroacetamides: facile construction of benzylic quaternary carbons by carbon-carbon bond-forming reactions

31. Separation and identification of higher molecular weight fullerenes by high-performance liquid chromatography with monomeric and polymeric octadecylsilica bonded phases

32. Transition metal-catalyzed radical cyclizations: a low-temperature process for the cyclization of N-protected N-allyltrichloroacetamides to trichlorinated gamma-lactams and application to the stereoselective preparation of beta,gamma-disubstituted gamma-lactams

33. Transition metal catalyzed radical cyclization: new preparative route to gamma-lactams from allylic alcohols via the (3.3)-sigmatropic rearrangement of allylic trichloroacetimidates and the subsequent ruthenium-catalyzed cyclization of N-allyltrichloroacetamides

41. Inside Front Cover

47. Persistent four-coordinate iron-centered radical stabilized by π-donation† †Electronic supplementary information (ESI) available: Experimental, crystallographic, computational details, and crystal data for 2, 4, 5 and 8. CCDC 1057111–1057113 and 1425703. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02601f Click here for additional data file. Click here for additional data file

50. Rotation of Ethylene Molecule on the Organometallic Species: A Possibility to Control the Rotation Rate

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