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$\newcommand{\Max}{\mathrm{Max4PC}}$ The Four point condition (4PC henceforth) is a well known condition characterising distances in trees $T$. Let $w,x,y,z$ be four vertices in $T$ and let $d_{x,y}$ denote the distance between vertices $x,y$ in $T$. The 4PC condition says that among the three terms $d_{w,x} + d_{y,z}$, $d_{w,y} + d_{x,z}$ and $d_{w,z} + d_{x,y}$ the maximum value equals the second maximum value. We define an $\binom{n}{2} \times \binom{n}{2}$ sized matrix $\Max_T$ from a tree $T$ where the rows and columns are indexed by size-2 subsets. The entry of $\Max_T$ corresponding to the row indexed by $\{w,x\}$ and column $\{y,z\}$ is the maximum value among the three terms $d_{w,x} + d_{y,z}$, $d_{w,y} + d_{x,z}$ and $d_{w,z} + d_{x,y}$. In this work, we determine basic properties of this matrix like rank, give an algorithm that outputs a family of bases, and find the determinant of $\Max_T$ when restricted to our basis. We further determine the inertia and the Smith Normal Form (SNF) of $\Max_T$.

Let $T$ be a tree on $n$ vertices and let $L_q^T$ be the $q$-analogue of its Laplacian. For a partition $\lambda \vdash n$, let the normalized immanant of $L_q^T$ indexed by $\lambda$ be denoted as $d_{\lambda}(L_q^T)$. A string of inequalities among $d_{\lambda}(L_q^T)$ is known when $\lambda$ varies over hook partitions of $n$ as the size of the first part of $\lambda$ decreases. In this work, we show a similar sequence of inequalities when $\lambda$ varies over two row partitions of $n$ as the size of the first part of $\lambda$ decreases. Our main lemma is an identity involving binomial coefficients and irreducible character values of $S_n$ indexed by two row partitions. Our proof can be interpreted using the combinatorics of Riordan paths and our main lemma admits a nice probabilisitic interpretation involving peaks at odd heights in generalized Dyck paths or equivalently involving special descents in Standard Young Tableaux with two rows. As a corollary, we also get inequalities between $d_{\lambda_1}(L_q^{T_1})$ and $d_{\lambda_2}(L_q^{T_2})$ when $T_1$ and $T_2$ are comparable trees in the $GTS_n$ poset and when $\lambda_1$ and $\lambda_2$ are both two rowed partitions of $n$, with $\lambda_1$ having a larger first part than $\lambda_2$.

Let $G$ be a bipartite graph on $n$ vertices with the Laplacian matrix $L_G$. When $G$ is a tree, inequalities involving coefficients of immanantal polynomials of $L_G$ are known as we go up $GTS_n$ poset of unlabelled trees with $n$ vertices. We extend $GTS$ operation on a tree to an arbitrary graph, we call it generalized graph shift (hencefourth $GGS$) operation. Using $GGS$ operation, we generalize these known inequalities associated with trees to bipartite graphs. Using vertex orientations of $G$, we give a combinatorial interpretation for each coefficient of the Laplacian immanantal polynomial of $G$ which is used to prove counter parts of Schur theorem and Lieb's conjecture for these coefficients. We define $GGS_n$ poset on $\Omega_{C_k}^v(n)$, the set of unlabelled unicyclic graphs with $n$ vertices where each vertex of the cycle $C_k$ has degree $2$ except one vertex $v$. Using $GGS_n$ poset on $\Omega_{C_{2k}}^v(n)$, we solves an extreme value problem of finding the max-min pair in $\Omega_{C_{2k}}^v(n)$ for each coefficient of the generalized Laplacian polynomials. At the end of this paper, we also discuss the monotonicity of the spectral radius and the Wiener index of an unicyclic graph when we go up along $GGS_n$ poset of $\Omega_{C_k}^v(n)$.

Let $T$ be a tree on $n$ vertices with $q$-Laplacian $L_T^q$ and Laplacian matrix $L_T$. Let $GTS_n$ be the generalized tree shift poset on the set of unlabelled trees on $n$ vertices. Inequalities are known between coefficients of the immanantal polynomial of $L_T$ (and $L_T^q$) as we go up the poset $GTS_n$. Using the Frobenius characteristic, this can be thought as a result involving the schur symmetric function $s_{\lambda}$. In this paper, we use an arbitrary symmetric function to define a {\it generalized matrix function} of an $n \times n$ matrix. When the symmetric function is the monomial and the forgotten symmetric function, we generalize such inequalities among coefficients of the generalized matrix polynomial of $L_T^q$ as we go up the $GTS_n$ poset., Comment: 11 pages

Let $T$ be a tree on $n$ vertices with $q$-Laplacian $L_{T}^{q}$. Let $GTS_n$ be the generalized tree shift poset on the set of unlabelled trees with $n$ vertices. We prove that for all $q \in R$, going up on $GTS_n$ has the following effect: the spectral radius and the second smallest eigenvalue of $L_{T}^{q}$ increase while the smallest eigenvalue of $L_{T}^{q}$ decreases. These generalize known results for eigenvalues of the Laplacian. As a corollary, we obtain consequences about the eigenvalues of $q,t$-Laplacians and exponential distance matrices of trees.

Let $T$ be a tree on $n$ vertices with Laplacian $L_T$ and let $GTS_n$ be the generalized tree shift poset on the set of unlabelled trees on $n$ vertices. Inequalities are known for coefficients of the characteristic polynomial of $L_T$ as we go up the poset $GTS_n$. In this work, we generalize these inequalities to the $q$-Laplacian $L^q_T$ of $T$ and to the coefficients of all immanantal polynomials.