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Osteoporosis is the leading cause of deformity and bones fracture all over the world and has some relationship with the blood concentrations of calcium and lead. Therefore, in the current study, the blood samples of 58 control and 56 clinically diagnosed osteoporotic and osteopenic patients were taken from different hospitals in Pakistan and analyzed for calcium and lead concentrations using atomic absorption spectrometry. In female control samples, the mean calcium value was found to be 98.53 ± 4.81 μg/mL, and in male control samples, the mean blood calcium level was found to be 121.33 ± 7.27 μg/mL. In female control samples, the mean lead value was found to be 0.133 ± 0.005 μg/mL, and in male control samples, the mean lead level was found to be 0.183 ± 0.008 μg/mL. All the male and female control samples showed a mean value of calcium of 115.63 ± 5.2 μg/mL and a mean value of lead of 0.153 ± 0.007 μg/mL. In osteoporotic female patients, the decline in the mean calcium value was found to be 34.93 ± 1.9 μg/mL, and in male patients, the decrease in the mean calcium level was found to be 47.73 ± 2.5 μg/mL. The increase in the mean value of lead in osteoporotic females was 4.13 ± 0.22 μg/mL, whereas in male patients, the increase in the mean lead value was 0.95 ± 0.07 μg/mL. All the male and female patients showed a decrease in the mean value of calcium of 41.43 ± 2.2 μg/mL and an increase in the mean value of Pb of 3.63 ± 0.16 μg/mL.

The reuse of treated domestic wastewater is an imperative source of water for numerous purposes. The treatment of municipal wastewater can be process by utilizing the technique for electrocoagulation. Electrocoagulation (EC) is an eco-friendly technique that combines the functions and advantages of conventional coagulation, flotation, and electrochemistry in water and wastewater treatment. The aim of present study was to assess the potential of electrocoagulation process in removing COD, BOD, TSS, turbidity, sulphate, nitrate, chloride and TDS from municipal wastewater. This experimental study was carried out at a batch system by using copper and aluminium electrodes aiming to treat the municipal wastewater at (0, 7, 14, and 21 volts, 50mamp for 60minutes) from Sample Baloch Colony (SBC), Sample Rind Goth (SRG), Sample Cattle Colony (SCC), Sample Pakistan Machine Tool Factory (SPMTF) and Sample Mehran Highway (SMH). The results revealed that the maximum removal efficiency of COD 96% for SPMTF, BOD 38.5% for SPMTF, TSS 98.14% for SMH, Turbidity 95.7% for SPMTF, Sulphate 95.9% for SRG, Nitrate 95.23% for SMH, Chloride 97.92% for SMH and TDS 96.9% for SRG at 21 volt. The present study suggested that the treated wastewater could be safely reuse for lawns, parks, tree plantation and recreation purpose.

The utilization of biomass for cooking and heating is old, occurring from the early stages of human evolution because of its wide and easy availability. In Asia, a majority of the population is dependent on solid biomass for cooking and heating applications. Biomass cookstove produces emissions like carbon monoxide (CO), and particulate matter with aerodynamic diameter ≤2.5 μm (PM2.5) which are dependent on the classifications and characteristics of fuel used in stoves. These emissions trigger many health risks because of the utilization of traditional cookstoves (TCS) which have less thermal efficiency. The literature contains a considerable amount of information on biomass cookstoves; however, it is dispersed particularly in Asian countries. In this principle, this paper gives an overview of available literature on biomass cookstoves for cooking and heating in Asian countries which are involving Bangladesh, China, India, Mongolia, Nepal, Pakistan, Sri Lanka, and Laos. This paper covers a detailed discussion on various aspects of biomass cookstoves: history, classification, fuel characteristics, health risks, design criteria, the scenario in selected Asian countries, thermal efficiency and emission comparison, and barriers to dissemination of improved biomass cookstoves (ICS). Learning from the review and comparison made conclude that the ICS has better thermal efficiency, and lesser emissions, as well as health risks but, have some potential barriers to dissemination.

Chitin is the most versatile and promising biomaterial after cellulose which can primarily be isolated from crustacean exoskeleton. It has great economic values because of their excellent chemical and biological properties, and their biomedical and industrial applications. This research work aims to report the yield and quality of chitin which has been isolated from crustacean’s waste of shellfish industry of Pakistan using chemical method alternating sodium hydroxide, hydrochloric acid, and hydrogen peroxide. The physicochemical properties of chitin extracted from shrimps were compared with commercial standard chitin (C9213) procured from Sigma-Aldrich. The yield obtained of isolated chitin was 23.78% with ash and moisture contents of 0.05% and 6.3% respectively. A low percentage of moisture and ash contents in isolated chitin indicate the efficiency of the extraction protocol employed. This shrimp's chitin compares with standard chitin using FTIR spectroscopy, proton solid-state NMR (1HSSNMR), X-Ray diffraction (XRD), Scanning electron microscopy (SEM). The thermal behavior of chitin (both standard and samples) was checked with thermo-gravimetric analysis (TGA) and differential scanning calorimetry (DSC). Both standard and extracted samples of chitins exhibited similar physicochemical and structural properties. The biological behavior of samples was also checked with different biological activities, which showed much dependence on the structure and concentration of samples.

This current study aims to study of the thermal behavior of the polyurethane elastomers (PUEs) by varying blends of 1, 4-butanediol and chitosan (CS) into the backbone of polyurethane (PU). The polycaprolactone diol (PCL) was used as a macrodiol while a mixture of CS and 1, 4-butanediol was reacted to extend the polymer. For the preparation of NCO-endcapped polyurethane prepolymer; one equivalent of PCL was reacted with three equivalents of toluene diisocyanate (TDI). The obtained pre-polymer was further extended with CS and 1, 4-butanediol (2 mol) individually and with different blends. The characterization of the structure was determined using FTIR and NMR spectroscopy. The glass transition temperature of prepared polyurethanes was measured by differential scanning calorimetry (DSC). The results obtained showed that, the thermal behavior of PUs was enhanced as the CS contents were increased in the PU backbone. The crystalline behavior of CS increased the hydrophobicity of the prepared PUs. Moreover; the water absorption, contact angle, swelling behavior, work of water adhesion and surface free energy of the synthesized PUs were affected with the addition of chitosan. Finally, it has been concluded resultant chitosan based PU has a potential for biomedical implant i.e., non-absorbable suture.