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Thermoplastic starch (TPS) suffers from its intrinsic low mechanical strength and high brittleness due to its strong hydrogen bonding and low chain mobility. The conventional way to crosslink the TPS film can improve the strength and stiffness of the films, but usually reduces the flexibility of the film, and increases its brittleness. In this study, the incorporation of the hybrid nanofiller [1 wt% nanocellulose (C) and 4 wt% nano bentonite (B)] into the TPS proved to improve greatly the films' strength and flexibility. The hybrid nanofillers with ratio 4B:1C was incorporated into the crosslinked thermoplastic corn starch (CR-TPCS) film to increase the its flexibility and toughness and produced a high mechanical strength fully biodegradable film. Two different aqueous carboxylic acids: citric acid (CA) and tartaric acid (TA) with different pH values (2,4,6) as the green crosslinker were employed. Substantial increase of tensile strength (3.98 to 9.17 MPa), Young's modulus (9.10 to 46.30 MPa) and elongation at break (55.2 to 135.7%) was observed for the CA- 4B1C/pH2 films compared to the CR-TPCS films. The melting temperature (Tm) of the CA-4B1C/pH2 improved compared to the TPCS/4B1C (un-crosslinked) film due to its crosslinking effect. Meanwhile, the CA-4B1C films exhibited the highest degree of substitution and di-esterification with the lowest swelling and water solubility properties due to the formation of a special "bridge" structure between the CA, nanocellulose and plasticizer. The "bridge" structure developed between the TPCS chains serves as the toughener to motivate higher chain stress relaxation and load endurance. The crosslinked "bridge structure" also proved to effectively reduce the retrogradation phenomenal in the TPCS films. This combination method of hybridization and crosslinking is an efficient, low cost, and environmentally friendly technique to overcome the low flexibility and brittleness problem of the TPS based packaging film. [ABSTRACT FROM AUTHOR]

One of the main phenomena that contributes to the non-success of cable insulation made of cross-linked polyethylene (XLPE) is electrical treeing. To improve the XPLE cable insulation, the use of nanofiller has been introduced. Adding the nanofiller in the based composite offers better cable lifetime and resistance to deal with the cable failure. One of the potential nanofillers that can increase the insulation performance of XLPE cable is silica nanofiller. To this extent, the studies on silica nanofiller in XLPE are focusing on the impulse breakdown strength, dielectric loss, permittivity, space charge, alternating current (AC), and partial discharge. The studies reveal that the dielectric properties of the XLPE nanocomposite have significant improvement. Therefore, this work investigates the effect of various concentrations of silica nanofiller in XLPE composite as electrical tree inhibitor. The concentrations of silica nanofiller in XLPE were 0.25 wt%, 0.5 wt%, 0.75 wt%, 1.0 wt%, 1.25 wt%, 1.5 wt%, and 1.75 wt%. The silica nanofillers have 96%-99% purity, 20-30 nm sizes and the shapes are spherical. As a result, the XLPE composite containing 1.5 wt% silica nanofiller demonstrate higher tree inception voltage and detaining the tree propagation speed, which could be considered as an inhibitor medium of electrical tree growth. [ABSTRACT FROM AUTHOR]