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In this era of non-fullerene acceptor (NFA) based organic solar cells, reducing voltage losses while maintaining high photocurrents is the holy grail of current research. Recent focus lies in understanding the manifold fundamental mechanisms in organic blends with minimal energy offsets - particularly the relationship between ionization energy offset ({\Delta}IE) and free charge generation. We quantitatively probe this relationship in multiple NFA-based blends by mixing Y5 and Y6 NFAs with PM6 of varying molecular weights, covering a 15% to 1% power conversion efficiency (PCE) range and a progression of {\Delta}IE. Spectroelectrochemistry reveals a critical {\Delta}IE of approximately 0.3 eV, below which the PCE sharply declines. Transient absorption spectroscopy consistently reveals that a smaller {\Delta}IE slows the dissociation of the NFA's local singlet exciton (LE) into free charges, albeit restorable by an electric field. Bias-dependent time delayed collection experiments quantify the free charge generation efficiency, while photoluminescence quantum efficiency measurements assess photocurrent loss from LE decay. Combined with transient photoluminescence experiments, we find that the decay of singlet excitons is the primary competition to free charge generation in low-offset NFA-based organic solar cells, with neither noticeable losses from charge-transfer (CT) decay nor evidence for LE-CT hybridization. Our experimental data align with Marcus theory calculations, supported by density functional theory simulations, for zero-field free charge generation and exciton decay efficiencies. We find that efficient photocurrent generation generally requires that the CT state is located below the LE, but that this restriction is lifted in systems with a small reorganization energy for charge transfer.

A new meteor shower $\lambda$-Sculptorids produced by the comet 46P/Wirtanen was forecast for December 12, 2023. The predicted activity was highly uncertain, but generally considered to be low. Observations in Australia, New Zealand, and Oceania were solicited to help constrain the size distribution of meteoroids in the shower. This work aims to characterize the new meteor shower, by comparing the observed and predicted radiants and orbits, and to provide a calibration for future predictions. Global Meteor Network video cameras were used to observe the meteor shower. Multi-station observations were used to compute trajectories and orbits, while single-station observations were used to measure the flux profile. A total of 23 $\lambda$-Sculptorid orbits have been measured. The shower peaked at a zenithal hourly rate (ZHR) of $0.65^{+0.24}_{-0.20}$ meteors per hour at $\lambda_{\odot} = 259.988^{\circ} \pm 0.042^{\circ}$. Due to the low in-atmosphere speed of 15~km s$^{-1}$, the mean mass of observed meteoroids was 0.5~g ($\sim10$~mm diameter), an order of magnitude higher than predicted. The dynamical simulations of the meteoroid stream can only produce such large meteoroids arriving at Earth in 2023 with correct radiants when a very low meteoroid density of $\sim 100$~kg~m$^{-3}$ is assumed. However, this assumption cannot reproduce the activity profile. It may be reproduced by considering higher density meteoroids in a larger ecliptic plane-crossing time window ($\Delta T$ = 20 days) and trails ejected prior to 1908, but then the observed radiant structure is not reproduced., Comment: Accepted for publication in A&A

The Golden (British Columbia, Canada) meteorite fall occurred on Oct 4, 2021 at 0534 UT with the first recovered fragment (1.3 kg) landing on an occupied bed. The meteorite is an unbrecciated, low-shock (S2) ordinary chondrite of intermediate composition, typed as an L/LL5. From noble gas measurements the cosmic ray exposure age is 25 Ma while gas retention ages are all >2 Ga. Short-lived radionuclides and noble gas measurements of the pre-atmospheric size overlap with estimates from infrasound and lightcurve modelling producing a preferred pre-atmospheric mass of 70-200 kg. The orbit of Golden has a high inclination (23.5 degs) and is consistent with delivery from the inner main belt. The highest probability (60%) of an origin is from the Hungaria group. We propose that Golden may originate among the background S-type asteroids found interspersed in the Hungaria region. The current collection of 18 L and LL chondrite orbits shows a strong preference for origins in the inner main belt, suggesting multiple parent bodies may be required to explain the diversity in CRE ages and shock states., Comment: 92 Pages, 20 Tables, 21 Figures, plus 3 appendices, accepted in Meteoritics and Planetary Science Oct 26 2023

$^{15}$N($\alpha$,$\gamma$)$^{19}$F is believed to be the primary means of stellar nucleosynthesis of fluorine. Here we present the use of a single-fluid bubble chamber to measure the cross section of the time-inverse photo-dissociation reaction. The method benefits from a luminosity increase of several orders of magnitude due to the use of a thicker liquid target -- when compared to thin films or gas targets -- and from the reciprocity theorem. We discuss the results of an experiment at the Thomas Jefferson National Accelerator Facility, where the cross section of the photodisintegration process $^{19}$F($\gamma$, $\alpha$)$^{15}$N was measured by bombarding a superheated fluid of C$_3$F$_8$ with bremsstrahlung $\gamma$-rays produced by impinging a 4 - 5.5 MeV electron beam on a Cu radiator. From the photodissociation yield the cross section was extracted by performing a convolution with a Monte Carlo-generated $\gamma$-ray beam spectrum. The measurement produced a cross section that was then time inverted using the reciprocity theorem. The cross section for the $^{15}$N($\alpha$,$\gamma$)$^{19}$F reaction was determined down to a value in the range of hundreds of picobarns. With further improvements of the experimental setup the technique could potentially push cross section measurements down to the single picobarn range., Comment: Corrected Typos. Accepted for Publication in Physical Review C

The Hamburg (H4) meteorite fell on January 17, 2018 at 01:08 UT approximately 10km North of Ann Arbor, Michigan. More than two dozen fragments totaling under one kilogram were recovered, primarily from frozen lake surfaces. The fireball initial velocity was 15.83 $\pm$ 0.05 km/s, based on four independent records showing the fireball above 50 km altitude. The radiant had a zenith angle of 66.1 $\pm$ 0.29 degs and an azimuth of 121.56 $\pm$ 1.2 degs. The resulting low inclination ($<$ 1 deg) Apollo-type orbit has a large aphelion distance and Tisserand value relative to Jupiter (Tj) of $\sim$ 3. Two major flares dominant the energy deposition profile, centred at 24.1 and 21.7 km altitude respectively under dynamic pressures of 5-7 MPa. Our preferred total energy for the Hamburg fireball is 2 to 7 T TNT (8.4 to 28 x 10$^9$ J), which corresponds to a likely initial mass in the range of 60 to 225 kg or diameter between 0.3 to 0.5 m. Based on the model of Granvik et al (2018), the meteorite originated in an escape route from the mid-outer asteroid belt. Hamburg is the 14th known H-chondrite with an instrumentally-derived pre-atmospheric orbit, half of which have small ($<$5 deg) inclinations making connection with (6) Hebe problematic. A definitive parent body consistent with all 14 known H-chondrite orbits remains elusive, Comment: 85 pages, 4 tables, 15 figures, 1 appendix. Accepted to Meteoritics and Planetary Science, June 19, 2019

This work presents numerical simulations of meteoroid streams released by comet 21P/Giacobini-Zinner over the period 1850-2030. The initial methodology, based on Vaubaillon et al. (2005), has been updated and modified to account for the evolution of the comet's dust production along its orbit. The peak time, intensity, and duration of the shower were assessed using simulated activity profiles that are calibrated to match observations of historic Draconid outbursts. The characteristics of all the main apparitions of the shower are reproduced, with a peak time accuracy of half an hour and an intensity estimate correct to within a factor of 2 (visual showers) or 3 (radio outbursts). Our model also revealed the existence of a previously unreported strong radio outburst on October 9 1999, that has since been confirmed by archival radar measurements. The first results of the model, presented in Egal et al. (2018), provided one of the best predictions of the recent 2018 outburst. Three future radio outbursts are predicted in the next decade, in 2019, 2025 and 2029. The strongest activity is expected in 2025 when the Earth encounters the young 2012 trail. Because of the dynamical uncertainties associated with comet 21P's orbital evolution between the 1959 and 1965 apparitions, observations of the 2019 radio outburst would be particularly helpful to improve the confidence of subsequent forecasts., Comment: Icarus - Accepted

The Polarized Electrons for Polarized Positrons experiment at the injector of the Continuous Electron Beam Accelerator Facility has demonstrated for the first time the efficient transfer of polarization from electrons to positrons produced by the polarized bremsstrahlung radiation induced by a polarized electron beam in a high-$Z$ target. Positron polarization up to 82\% have been measured for an initial electron beam momentum of 8.19~MeV/$c$, limited only by the electron beam polarization. This technique extends polarized positron capabilities from GeV to MeV electron beams, and opens access to polarized positron beam physics to a wide community., Comment: 5 pages, 4 figures

In-plane thermal conduction and phonon transport in both single-crystalline and polycrystalline Si two-dimensional phononic crystal (PnC) nanostructures were investigated at room temperature. The impact of phononic patterning on thermal conductivity was larger in polycrystalline Si PnCs than in single-crystalline Si PnCs. The difference in the impact is attributed to the difference in the thermal phonon mean free path (MFP) distribution induced by grain boundary scattering in the two materials. Grain size analysis and numerical simulation using the Monte Carlo technique indicate that grain boundaries and phononic patterning are efficient phonon scattering mechanisms for different MFP length scales. This multiscale phonon blocking structure covers a large part of the broad distribution of thermal phonon MFPs and thus efficiently reduces thermal conduction., Comment: 5 pages, 6 fgures, Journal paper

F\"orster's theory of resonant energy transfer (FRET) predicts the strength and range of exciton transport between separated molecules. We introduce an exactly soluble model for FRET which reproduces F\"orster's results as well as incorporating quantum coherence effects. As an application the model is used to analyze a system composed of quantum dots and the protein bacteriorhodopsin., Comment: 10 pages, 2 figures

At the beginning of the Space Age, spacecraft designers and mission planners were very concerned about meteoroids. They envisioned vehicles being ripped to pieces by streams of fast-moving space rocks, a notion promoted by the science fiction novels and movies of the time. The reality is, of course, different—the meteoroid streams that produce meteor showers are not dense by laypeople’s standards, having spatial densities of just a handful of particles per cubic kilometer, even during meteor outbursts. The ever-present, diffuse, sporadic background, which produces observed meteor rates of only 5 to 8 meteors per hour, makes up 90% of the meteoroid risk to spacecraft that spend at least a year in low Earth orbit (LEO), whereas the visually spectacular but short-lived meteor showers make up the other 10%. Still, meteoroids do pose a significant risk to spacecraft. At Earth, they can travel 12 to 72 km/s. These high speeds cause even small meteoroids to carry enormous kinetic energy, making them capable of doing serious damage to spacecraft. For example, a 1-mm-diameter meteoroid moving at 25 km/s can inflict the same damage as a bullet fired from a 0.357 Magnum pistol. An exterior wire can be severed by a 0.1-mm (100 mm) particle, a spacesuit can be penetrated by a 0.5-mm meteoroid, and an unshielded pressure wall (like the cabin of the Space Shuttle) can be perforated by centimeter-sized particles. Along with mechanical damage, meteoroids can also cause other types of spacecraft anomalies. Meteoroids can transfer their momentum to the spacecraft, which can destroy or damage equipment such as shunt resistors and charge-coupled device (CCD) detectors with a clear view of space. Meteoroid impacts can also generate plasma. The impact vaporizes material, producing a crater and an expanding plasma, which can in turn provide a conductive path for any charge accumulated on the spacecraft. This effect is thought to be responsible for the demise of a satellite in one case: the OLYMPUS communications satellite was sent tumbling out of control during the 1993 Perseid outburst, and a Perseid meteoroid strike has been posited as a possible cause (McDonnell et al. 1993; Caswell et al. 1995). Other researchers have suggested that very fast meteoroids could produce a small electromagnetic pulse capable of disrupting spacecraft function (Close et al. 2010).