1. Dynamic optical information encryption strategy based on rare earth ions doped BaSi2O5 phosphors with adjustable trap distribution.
- Author
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He, Cong, Li, Bing, Ye, Chunwen, Wu, Meng, and Zhang, Yanjie
- Subjects
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RARE earth ions , *PHOSPHORS , *INFORMATION technology security , *RARE earth oxides , *MORSE code , *RIETVELD refinement , *ELECTRON traps - Abstract
Multi-modal strategies for optical information storage have received a lot of attention to meet the increasing security requirements. In this case, long persistent luminescence (LPL) phosphors with different dopant ions were obtained by introducing Dy3+ and Ho3+ ions into the BaSi 2 O 5 :Eu2+ phosphor to adjust the distribution and depth of the trap centers. The generation of the pure phase BaSi 2 O 5 was confirmed by X-ray diffraction (XRD) and XRD Rietveld refinement. The peak emission of BaSi 2 O 5 : Eu2+ phosphor is about 500 nm with 313 nm excitation. Both BaSi 2 O 5 : Eu2+, Dy3+, and BaSi 2 O 5 : Eu2+, Ho3+ phosphors exhibit emission characteristics of Eu2+ ions. The trap depths of the three phosphors are different by Gaussian fitting of thermoluminescence (TL) curves, and the depth of BaSi 2 O 5 : Eu2+, Dy3+ phosphor can reach 1.070 eV. Typically, the flexible luminescent film based on BaSi 2 O 5 : Eu2+ phosphor can be written optical pattern using 365 nm ultraviolet (UV) light, such as "DL" and "fireworks" patterns, and subsequently read out by thermal or infrared light stimulus. Further, a strategy for encryption and decryption of dynamic optical information in Morse code has been developed using BaSi 2 O 5 : Eu2+, BaSi 2 O 5 : Eu2+, Dy3+, and BaSi 2 O 5 : Eu2+, Ho3+ phosphors, indicating the prospective use in optical information security. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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