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Measurements of Pb isotope ratios in ice containing sub-pg g(-1) concentrations are easily compromised by contamination, particularly where limited sample is available. Improved techniques are essential if Antarctic ice cores are to be analysed with sufficient spatial resolution to reveal seasonal variations due to climate. This was achieved here by using stainless steel chisels and saws and strict protocols in an ultra-clean cold room to decontaminate and section ice cores. Artificial ice cores, prepared from high purity water were used to develop and refine the procedures and quantify blanks. Ba and In, two other important elements present at pg g-1 and fg g(-1) concentrations in Polar ice, were also measured. The final blank amounted to 0.2 +/- 0.2 pg of Pb with Pb-206/Pb-207 and Pb-208/Pb-207 ratios of 1.16 +/- 0.12 and 2.35 +/- 0.16, respectively, 1.5 +/- 0.4 pg of Ba and 0.6 +/- 2.0 fg of In, most of which probably originates from abrasion of the steel saws by the ice. The procedure was demonstrated on a Holocene Antarctic ice core section and was shown to contribute blanks of only similar to 5%, similar to 14% and similar to 0.8% to monthly resolved samples with respective Pb, Ba and In concentrations of 0.12 pg g(-1), 0.3 pg g(-1) and 2.3 fg g(-1). Uncertainties in the Pb isotopic ratio measurements were degraded by only similar to 0.2%. (C) 2009 Elsevier B.V. All rights reserved.

The aim of deep ice drilling on Law Dome, Antarctica, has been to exploit the special characteristics of Law Dome summit, i.e. low temperature and high accumulation near an ice divide, to obtain a high-resolution ice core for climatic/environmental studies of the Holocene and the Last Glacial Maximum (LGM). Drilling was completed in February 1993, when basal ice containing small fragments of rock was reached at a depth of 1196 m. Accurate ice dating, obtained by counting annual layers revealed by fine-detail δ18О, peroxide and electrical-conductivity measurements, is continuous down to 399 m, corresponding to a date of AD 1304. Sulphate concentration measurements, made around depths where conductivity tracing indicates volcanic fallout, allow confirmation of the dating (for Agung in 1963 and Tambora in 1815) or estimates of the eruption date from the ice dating (for the Kuwae, Vanuatu, eruption ~1457). The lower part of the core is dated by extrapolating the layer-counting using a simple model of the ice flow. At the LGM, ice-fabric measurements show a large decrease (250 to 14 mm2) in crystal size and a narrow maximum in c-axis vertically. The main zone of strong single-pole fabrics however, is located higher up in a broad zone around 900 m. Oxygen-isotope (δ18O) measurements show Holocene ice down to 1113 m, the LGM at 1133 m and warm (δ18O) about the same as Holocene) ice near the base of the ice sheet. The LGM/Holocene δ18O shift of 7.0‰, only ~1‰ larger than for Vostok, indicates that Law Dome remained an independent ice cap and was not overridden by the inland ice sheet in the Glacial.

Antarctic snowfall exhibits substantial variability over a range of time scales, with consequent impacts on global sea level and the mass balance of the ice sheets. To assess how snowfall has affected the thickness of the ice sheets in Antarctica and to provide an extended perspective, we derived a 50-year time series of snowfall accumulation over the continent by combining model simulations and observations primarily from ice cores. There has been no statistically significant change in snowfall since the 1950s, indicating that Antarctic precipitation is not mitigating global sea level rise as expected, despite recent winter warming of the overlying atmosphere.