1. High level active <italic>n</italic>+ doping of strained germanium through co-implantation and nanosecond pulsed laser melting.
- Author
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Pastor, David, Gandhi, Hemi H., Monmeyran, Corentin P., Akey, Austin J., Milazzo, Ruggero, Cai, Yan, Napolitani, Enrico, Gwilliam, Russell M., Crowe, Iain F., Michel, Jurgen, Kimerling, L. C., Agarwal, Anuradha, Mazur, Eric, and Aziz, Michael J.
- Subjects
ELECTRIC properties of germanium ,PULSED laser deposition ,ION implantation ,SCANNING electron microscopy ,CRYSTALLINITY - Abstract
Obtaining high level active
n + carrier concentrations in germanium (Ge) has been a significant challenge for further development of Ge devices. By ion implanting phosphorus (P) and fluorine (F) into Ge and restoring crystallinity using Nd:YAG nanosecond pulsed laser melting (PLM), we demonstrate 1020 cm−3 n + carrier concentration in tensile-strained epitaxial germanium-on-silicon. Scanning electron microscopy shows that after laser treatment, samples implanted with P have an ablated surface, whereas P + F co-implanted samples have good crystallinity and a smooth surface topography. We characterize P and F concentration depth profiles using secondary ion mass spectrometry and spreading resistance profiling. The peak carrier concentration, 1020 cm−3 at 80 nm below the surface, coincides with the peak F concentration, illustrating the key role of F in increasing donor activation. Cross-sectional transmission electron microscopy of the co-implanted sample shows that the Ge epilayer region damaged during implantation is a single crystal after PLM. High-resolution X-ray diffraction and Raman spectroscopy measurements both indicate that the as-grown epitaxial layer strain is preserved after PLM. These results demonstrate that co-implantation and PLM can achieve the combination ofn + carrier concentration and strain in Ge epilayers necessary for next-generation, high-performance Ge-on-Si devices. [ABSTRACT FROM AUTHOR]- Published
- 2018
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