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3 results on '"Molecular‐Lattice Structure"'

1. INCREASE OF EFFICIENCY OF Li+-INTERCALATED CURRENT GENERATION IN SUPRAMOLECULAR ENSEMBLES WITH HIERARCHICAL ARCHITECTURE MCM-41 〈HYDROQUINONE〉.

Author

MATULKA, D. V., GRYGORCHAK, I. I., and LUKIYANETS, B. A.

Subjects
*LITHIUM, *INTERCALATION reactions, *SUPRAMOLECULAR chemistry, *ARCHITECTURE, *MULTICHIP modules (Microelectronics), *HYDROQUINONE, *CATHODES
Abstract

Double-matrix hierarchical structure of the 〈molecular-lattice matrix MCM-41〈hydroquinone〉〉 is synthesized. Its use in the cathode process in the Li+-intercalation current generation showed a significant improvement in the structure of the discharge curve and the practical constancy of diffusion coefficient throughout the discharge process. Theoretical model describing the peculiarities of observed characteristics in the structure is presented. [ABSTRACT FROM AUTHOR]

Published
2013
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2. Current Generation in Double-Matrix Structure: A Theoretical Simulation

Author

Bogdan Lukiyanets, Dariya Matulka, and Ivan Grygorchak

Subjects
Molecular‐Lattice Structure, Intercalation, Kinetic Characteristics, Quantum Size Effect, Materials of engineering and construction. Mechanics of materials, TA401-492, Technology
Abstract

Peculiarities of kinetic characteristics in a supramolecular system, in particular, in a double‐matrix structure observed at change of the guest content in a matrix‐host are investigated. Results obtained within the framework of a time‐independent one‐dimensional Schrödinger equation with three barrier potential qualitatively explain experimental data. They indicate the importance of size quantization of a system, correlation between energy and geometric characteristics of both guest and host in this case.

Published
2013
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3. Current generation in double-matrix structure: A theoretical simulation

Author

D. V. Matulka, I. I. Grygorchak, and B. A. Lukiyanets

Subjects
Materials science, Current generation, Supramolecular chemistry, molecular-lattice structure, intercalation, kinetic characteristics, quantum size effect, Molecular‐Lattice Structure, Kinetic energy, Quantum size effect, Electronic, Optical and Magnetic Materials, Schrödinger equation, symbols.namesake, Quantization (physics), Quantum Size Effect, Kinetic Characteristics, lcsh:Technology (General), Ceramics and Composites, symbols, Intercalation, Physical chemistry, lcsh:T1-995, Statistical physics, Electrical and Electronic Engineering, Biotechnology
Abstract

Peculiarities of kinetic characteristics in a supramolecular system, in particular, in a double-matrix structure observed at change of the guest content in a matrix-host are investigated. Results obtained within the framework of a time-independent one-dimensional Schrödinger equation with three barrier potential qualitatively explain experimental data. They indicate the importance of size quantization of a system, correlation between energy and geometric characteristics of both guest and host in this case.

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