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1. Mechanistics insights into the chemistry of Ru(II) complexes containing CI and DMSO ligands

Author

Mola, Joaqium, Romero, Isabel, Rodriguez, Montserrat, Bozoglian, Fernando, Poater, Albert, Sola, Miquel, Parella, Teodor, Benet-Buchholz, Jordi, Fontrodona, Xavier, and Llobet, Antoni

Subjects
Dimethyl sulfoxide -- Structure, Dimethyl sulfoxide -- Spectra, Ruthenium -- Spectra, Ruthenium -- Structure, Nuclear magnetic resonance spectroscopy -- Usage, X-rays -- Diffraction, X-rays -- Usage, Chemistry
Abstract

New isomeric ruthenium complexes containing the bpea ligand (where bpea = N,N-bis-(2-pyridylmethyl)ethylamine) and coordinating in both the meridional and facial fashion are synthesized. Its characteristics and structure are studied using NMR spectroscopy, x-ray diffraction and cyclic voltammetry methods.

Published
2007

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