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This research aimed to develop lead-free polymer composites based on poly-methyl methacrylate (PMMA) and embedded with tungsten carbide (WC) micro and nanoparticles for use in radiation protection applications. PMMA was filled with 20 %, 40 %, and 60 % by weight of WC micro- and nanoparticles. The shielding features of the proposed polymer mixtures were evaluated at different radioactive sources of different energies using the HPGe detector. The results revealed that the investigated composites containing micro and nano-structured WC particles showed superior radiation shielding at 81 keV due to the K-edge of the W element occurring at 69.5 keV. The findings also demonstrated that composites loaded with WC nanoparticles were more effective in shielding gamma radiation than those loaded with WC microparticles, even at the same filler wt.%. Furthermore, the sample containing 60 % by weight of nano-WC, coded as P-60nWC, had superior shielding performance than other polymer-based composites reported in the literature. Thus, the proposed nano-WC/PMMA composites can be effectively employed in radiation facilities as alternative environmentally and lead-free radiation shielding materials to protect people and the environment from the harmful risks of gamma radiation.

In this work, the effect of adding Pb nano/microparticles in polyurethane foams to improve thermo-physical and mechanical properties were investigated. Moreover, an attempt has been made to modify the micron-sized lead metal powder into nanostructured Pb powder using a high-energy ball mill. Two types of fillers were used, the first is Pb in micro scale and the second is Pb in nano scale. A lead/polyurethane nanocomposite is made using the in-situ polymerization process. The different characterization techniques describe the state of the dispersion of fillers in foam. The effects of these additions in the foam were evaluated, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD) have all been used to analyze the morphology and dispersion of lead in polyurethane. The findings demonstrate that lead is uniformly distributed throughout the polyurethane matrix. The compression test demonstrates that the inclusion of lead weakens the compression strength of the nanocomposites in comparison to that of pure polyurethane. The TGA study shows that the enhanced thermal stability is a result of the inclusion of fillers, especially nanofillers. The shielding efficiency has been studied, MAC, LAC, HVL, MFP and Zeff were determined either experimentally or by Monte Carlo calculations. The nuclear radiation shielding properties were simulated by the FLUKA code for the photon energy range of 0.0001–100 MeV.

Due to the present industrial world, the risk of radioactivity is notably increasing. Thus, an appropriate shielding material needs to be designed to protect humans and the environment against radiation. In view of this, the present study aims to design new composites of the main matrix of bentonite–gypsum with a low-cost, abundant, and natural matrix. This main matrix was intercalated in various amounts with micro- and nanosized particles of bismuth oxide (Bi2O3) as the filler. Energy dispersive X-ray analysis (EDX) recognized the chemical composition of the prepared specimen. The morphology of the bentonite–gypsum specimen was tested using scanning electron microscopy (SEM). The SEM images showed the uniformity and porosity of a cross-section of samples. The NaI (Tl) scintillation detector was used with four radioactive sources (241Am, 137Cs, 133Ba, and 60Co) of various photon energies. Genie 2000 software was used to determine the area under the peak of the energy spectrum observed in the presence and absence of each specimen. Then, the linear and mass attenuation coefficients were obtained. After comparing the experimental results of the mass attenuation coefficient with the theoretical values from XCOM software, it was found that the experimental results were valid. The radiation shielding parameters were computed, including the mass attenuation coefficients (MAC), half-value layer (HVL), tenth-value layer (TVL), and mean free path (MFP), which are dependent on the linear attenuation coefficient. In addition, the effective atomic number and buildup factors were calculated. The results of all of these parameters provided the same conclusion, which confirms the improvement of the properties of γ-ray shielding materials using a mixture of bentonite and gypsum as the main matrix, which is much better than using bentonite alone. Moreover, bentonite mixed with gypsum is a more economical means of production. Therefore, the investigated bentonite–gypsum materials have potential uses in applications such as gamma-ray shielding materials.