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We have used grazing-angle infrared spectroscopy to detect the Berreman effect (BE) in the quasi-two-dimensional electron system (q-2DES) which forms spontaneously at the interface between SrTiO$_{3}$ (STO) and a thin film of LaAlO$_3$ (LAO). From the BE, which allows one to study longitudinal optical excitations in ultrathin films like the q-2DES, we have extracted at different temperatures its thickness, the charge density and mobility of the carriers under crystalline LAO (sample A), and the charge density under amorphous LAO (sample B). This quantity turns out to be higher than in sample A, but a comparison with Hall measurements shows that under amorphous LAO the charges are partly localized at low $T$ with a low activation energy (about 190 K in $k_B$ units), and are thermally activated according to a model for large polarons. The thickness of the q-2DES extracted from our spectra turns out to be 4 $\pm 1$ nm for crystalline LAO, 7 $\pm 2$ nm for amorphous LAO., Comment: 21 pages, 7 figures

YBa2Cu3O72d (YBCO) artificial grain-boundary Josephson junctions have been fabricated, employing a recently implemented biepitaxial technique. The grain boundaries can be obtained by controlling the orientation of the MgO seed layer and are characterized by a misalignment of the c axes ~45° c-axis tilt or 45° c-axis twist!. A detailed characterization of the Josephson properties has been carried out, showing remarkable differences in the transport parameters of tilt and twist junctions. High-resolution electron microscopy showed the presence of perfect basal plane faced boundaries in the cross sections of tilt boundaries; however interfaces meandering along the sample thickness are also sometimes observed. The correlation between transport properties and microstructure is investigated and the possibility to employ these junctions to explore the symmetry of the order parameter is presented. On the basis of the analysis of microstructural data and of a qualitative growth model for ~103! YBCO grains, it is suggested that clean basal plane boundaries exhibiting uniform Josephson properties could be obtained by this technique.

We study the structural, magnetic, and transport properties of LaAlO3/EuTiO3/SrTiO3 heterostructures grown by pulsed laser deposition. The samples are characterized in situ by electron diffraction and scanning probe microscopy and ex situ by transport measurements and x-ray absorption spectroscopy. LaAlO3/EuTiO3/SrTiO3 films show a ferromagnetic transition at T

We have investigated the properties of biepitaxial YBa2Cu3O72d grain boundary Josephson junctions, which appear to be characterized by low barrier transmission probabilities. Extrinsic and intrinsic d-wave effects are discussed within the framework of novel designs for p-circuitry and qubits. The absence of spontaneous magnetization and of the consequent additional noise, in a wide range of experimental conditions, seems to be encouraging for designs of ‘‘quiet’’ devices

Phase-sensitive, spatially resolved optical second-harmonic-generation experiments were performed on LaAlO3/SrTiO3 heterostructures. Lateral inhomogeneities on a length scale of ≈ 30 μm are found when a one-unit-cell-thick epitaxial monolayer of LaAlO3 is grown on TiO2-terminated SrTiO3 single crystals. The inhomogeneity is absent in samples with LaAlO3 layers of more than one unit cell. The results are discussed in the framework of electronic, oxidic, and chemical inhomogeneities.

We present various concepts and experimental procedures to produce biepitaxial YBa2Cu3O72x grainboundary Josephson junctions. The device properties have an interesting phenomenology, related in part to the possible influence of ‘‘p loops.’’ The performance of our junctions and superconducting quantum interference devices indicates significant improvement in the biepitaxial technique. Further, we propose methods for fabricating circuits in which 0 and p loops are controllably located on the same chip.

The polarization induced at the LaAlO3/SrTiO3 interface has been explored by optical second harmonic generation (SHG) spectroscopy. Our data reveal that an orbital reconstruction of the SrTiO3 surface occurs when three epitaxial monolayers of LaAlO3 are deposited on top of it. The reconstruction manifests as a spectral modification of a Ti4+(3d) state at the LaAlO3/SrTiO3 interface which is accompanied by a displacement of the Ti4+ ions in adjacent SrTiO3 monolayers in order to compensate for the polarization discontinuity induced at the interface. According to the SHG experiment, the carriers transferred to the interface are trapped because in spite of the orbital reconstruction, the interface remains insulating. The onset of conductivity with the formation of a two-dimensional electron liquid appears to be a subordinate effect related to a minority of carriers and occurs upon further increase of the LaAlO3 coverage.

In order to analyze the effect of strain on the magnetic properties of narrow-band manganites, temperature-and field-dependent susceptibilities of about 8.5-nm-thick epitaxial Pr(0.7)Ca(0.3)MnO(3) films, respectively, grown on (001) and (110) SrTiO(3) substrates, have been compared. For ultrathin samples grown on (001) SrTiO(3), a bulklike cluster-glass magnetic behavior is found, indicative of the possible coexistence of antiferromagnetic and ferromagnetic phases. On the contrary, ultrathin films grown on (110) substrates show a robust ferromagnetism with a strong spontaneous magnetization of about 3.4 mu(B)/Mn atom along the easy axis. On the base of high-resolution reciprocal space mapping analyses performed by x-ray diffraction, the different behaviors are discussed in terms of the crystallographic constraints imposed by the epitaxy of Pr(0.7)Ca(0.3)MnO(3) on SrTiO(3). We suggest that for growth on (110) SrTiO(3), the tensile strain on the film c axis, lying within the substrate plane, favors the ferromagnetic phase, possibly by allowing a mixed occupancy and hybridization of both in-plane and out-of-plane e(g) orbitals. Our data allow to shed some physics of inhomogeneous states in manganites and on the nature of their ferromagnetic insulating state.

We have measured the angular dependence of the Josephson critical current density (Jc)in c-axis tilt biepitaxial grain boundary YBa2Cu3O7-x junctions. We observe for the first time intrinsic d -wave pairing symmetry effects manifested as an oscillatory dependence of Jc on angle. This intrinsic effect is evident even though spontaneous currents, possibly induced by faceting or barrier impurities, are observed in the grain boundaries.