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Understanding the flow of carbon through hyperalkaline lakes is a key means of understanding their biogeochemistry, sedimentology, and their paleoenvironmental and paleoclimatic records. Furthermore, understanding how mineral precipitation is regulated in these lakes can provide insights into how their sequestration of carbon can be managed. We report geophysical surveys of Mono Lake, California, USA, which show unanticipated geomorphological control on the recent/contemporary formation of lacustrine carbonate formations (“tufa”). Acquired shallow-penetration seismic data show a fault zone below the lake floor, but despite the regional evidence for geothermal waters rising up these fractures, we find no evidence for tufa precipitation at the surface exposure of this structure, either in the seismic data or in the swath bathymetry. However, we do find sub-lacustrine tufa columns in these data elsewhere, which is the first time these have been reported directly. We find and report on a strong link between column location and meteoric Ca supply to the lake, with the latter sourced either through surface runoff or groundwater. For example, a region close to a creek inlet has more frequent and larger tufa bodies, which grow at a wider depth range than another region far from an inlet but close to the fault. This demonstrates the importance of meteoric water ingress in regulating carbonate mineral formation in these basins, and raises the possibility that management of water within the catchment could be a means to enhance carbon capture in natural and artificial hyperalkaline lakes.

This study aims to compare the fabrics of anthropogenic carbonates downstream of lime and steel disposal sites with models of carbonate precipitation from natural systems to elucidate potential drivers, precipitation mechanisms, morphological similarities, predictability in 3D facies distributions and depositional models of these systems. For this purpose, a combination of sedimentological, mineralogical and geochemical approaches is conducted including the analysis of microfacies (petrographic microscope and electron microscopy), X‐ray diffraction and hydrochemistry. The data show that both anthropogenic and natural systems exhibit clear proximal, middle and distal zones of carbonate precipitation. The main macroscopic differences are the dominance of swamp environments in the proximal zone and the prevalence of tufa‐like barrage‐and‐pool sequences in the middle and distal zones. Microfabrics in anthropogenic sites are comparable to travertines but lack the sub‐surface facies and at extreme pH exhibit sparry crusts without clear equivalents in travertines. This sedimentology of anthropogenic carbonates shows that calcite mineral formation is complex and not homogeneous or purely driven by thermodynamic processes. Considering the sedimentology of these human‐induced systems will help us understand precipitation mechanisms which will aid both efforts to utilise anthropogenic alkaline wastes for carbon capture and manage their environmental impacts.

Lacustrine non‐skeletal carbonates exhibit a diversity of petrographies due to interactions between physico‐chemical and biologically influenced mechanisms. Despite the suggestion that evaporative concentration was involved in the formation of spherulite and shrubby‐bearing carbonate successions in the Pre‐Salt Cretaceous alkaline lakes of the South Atlantic, no consensus exists about the water chemistries promoting these exotic mineral textures. In this work, an experimental approach was developed to evaluate how changes in salinity (NaCl) and biopolymer concentrations (alginic acid) impact calcite growth dynamics from saline and alkaline synthetic solutions. Hydrochemical and petrographical data from selected modern saline/alkaline environments were compared with experimental datasets to further estimate how the underlying (bio)chemical conditions and lake locations probably converge to allow the formation of calcite spherulite grains in evaporitic settings. Spherulitic calcite from Recent saline lakes and experiments arise from waters with moderate to high [Calcium]/[Alkalinity] ratios ([Ca]/[Alk]) rather than in calcium‐depleted and alkaline‐rich environments which tend to produce single‐crystal calcites during abiotic water mixing or lake evaporation. This observation is consistent with the assembly of polycrystalline textures being a kinetically controlled feature, forced by remarkably high rates of nucleation. Also, the data analysed do not support a causative relationship between evaporite‐driven salinity fluctuations and the preferential formation of spherulites, shrubs or their intermediate textures. Ubiquitous in saline lakes, organic substances can lower the kinetic thresholds for spherulitic calcite aggregation while microbial photosynthesis can also raise pH, altogether enhancing calcite supersaturation and promoting spherulite formation in waters with moderate‐high [Ca]/[Alk] ratios and high salinities. Localised observations of abiotic spherulites in Recent soda lakes can occur in restricted mixing zones where [Ca]/[Alk] ratios are enhanced. This work highlights the roles of concentration regimes associated with biopolymers and microbial metabolism against the background salinity fluctuations in determining the morphological and textural transitions in lacustrine carbonate minerals.

Continental carbonates constitute an interesting topic of study since they are important archives recording climate and paleoenvironmental changes. In Tunisia, calcretes are formed during the Pliocene-early Pleistocene (Villafranchian). They mainly occur in the center and on the coastal plain of Djeffara (Southern East) while their presence is more sporadic in the North of the country. Continental carbonates may form in the soil, groundwater, and palustrine and lacustrine environments. Four criteria are used to differentiate these different environments: host rock, components and micromorphological texture, subaerial exposure (seasonality), and flora and fauna.The purpose of this study is to investigate the palaeoenvironmental significance of Tunisian calcretes for the Plio-Pleistocene. For this aim, well-developed carbonate beds were studied along a north-south transect that crosses the climatic boundaries between the latitudes 33 ° and 37 ° N: North (N36º.43.713 E10º.06.681’) Center (N35º.07.077 'E10º. 14.545 ') and South (N33º.28.898' E10º.20.597 ').Based on the macroscopic, petrographic, and cathodoluminescence observations in association with scanning electron microscopy results, we classified thin sections extracted from the massive horizons in all sites into 8 facies types:The Northern site is characterized by 1) pisolithic calcretes and 2) laminar calcretes showing several beta microfabrics such as rhizolith, peloids, intraclasts, coated grains, bioclast debris, cracks, alveolar septal, spherulite, and organic matter. Moreover, 3) pseudo microkarst carbonates were detected in Northern Tunisia by the presence of vertical layers, peloids, intraclasts, circum crack grain, pedotubules, and rhizoconcretions, and bioclasts.At the central site, 4) laminar calcretes are characterized by planar layers. Both 5) massive brecciated calcretes and 6) mottled nodular brecciated calcretes are distinguished by the abundance of cracks. All these facies types’ shows similar pedogenic components such as peloids, coated grains, gastropod shell, alveolar septal, ooids, and bioclasts.The southern site is characterized on the one hand by 7) laminar calcretes composed of peloids, nodules, coated grains, cracks, and on the other hand by 8) groundwater nodules showing a massive aspect with alpha microfabrics. In all sites, the nodular horizons are pedogenic.Thus, our Plio-early Pleistocene calcretes formed in three main depositional environments: pedogenic, groundwater, and palustrine. The groundwater calcretes are formed under phreatic conditions while the Tunisian pedogenic calcretes and palustrine carbonates exhibit subaerial exposure characteristics (cracks). Except for southern groundwater calcretes, all other types of carbonates show biogenic traces. The palustrine carbonates developed above lacustrine mud. Whereas, pedogenic and groundwater calcretes, develop on different types of host rocks (siliceous and clayey). The difference between fabrics indicates that during the Pliocene-early Pleistocene calcrete form in the north in palustrine settings while it forms in groundwater context in the south. Furthermore, the transition between the different environments is controlled mainly by variation in the water table suggesting a variable but generally more humid climate during the Plio-Pleistocene in North Africa.

Although notoriously difficult to delineate from the wider family of carbonate rocks and sediments, non-marine carbonates represent an important subset, forming in a large variety of depositional settings such as lakes, rivers, hydrothermal vents, caves, soils and sites affected by alkaline pollution (Pentecost, 2005; Alonso Zarza & Tanner 2010; Capezzuoli et al., 2014; Della Porta, 2015) (Figure 1). Due to the erosive and dissolution effect of meteoric waters in terrestrial environments, such carbonates are generally characterised by low preservation potential and their geological record is likely discontinuous and highly altered. Nevertheless, non-marine carbonates represent a significant component of terrestrial sedimentary basins, providing useful proxies of palaeoenvironmental conditions and can offer a means of passive remediation of sites harmed by human industry, including sequestration and storage of carbon dioxide. Understanding the physico-chemical and microbially mediated processes involved in their precipitation helps to constrain biogeochemical cycles, investigate the geological past and plan for the future approaches to global changes.

The influence of extracellular polymeric substances on carbonate mineral growth in natural settings remains one of the most poorly understood contributors to the growth of non‐marine carbonate sediments. The influences of these materials are complicated by their association with living cells creating local microenvironments via metabolism and enzyme production, and by our uncertainty about the extracellular polymeric substances materials themselves. Different mixtures of extracellular polymeric substance molecules may behave in different ways, and differences in the local physical environment may alter how the mixtures influence mineral formation, and even result in different patterns of polymerization. Here, the influence of extracellular polymeric substances on calcite precipitation rate and Mg/Cacalcite in the absence of cells is investigated using extracts of extracellular polymeric substances from temperate fluvial tufa biofilm. The influence is complex, with the concentration of extracellular polymeric substances in solution altering deposition rate and trace element incorporation. Moreover, the results show interaction of the presence/absence of extracellular polymeric substances and both temperature and salinity. However, despite extracting extracellular polymeric substances from the same parent sample, a uniform influence was not found in these experiments, implying that the mixture is sufficiently variable within a sample for microenvironments within the biofilm to either promote or inhibit mineralization. As sedimentologists, we can no longer take the view that extracellular polymeric substances are a bystander material, or that they have a single set of coherent and predictable or intuitive influences. Rather, the emphasis must be on investigating the specific mixtures present in nature, and their complex and dynamic interaction with both mineral surfaces and hydrochemical conditions.

Purpose There is growing interest in and evidence for the benefits of connecting with nature for people living with dementia, sometimes known as “green care”, including reduced stress, improved sleeping and even enhanced cognition. However, many people living with dementia are denied such opportunities, often because of practitioner perceptions of risk and poor design of outdoor spaces. This paper reports on the evaluation of a project that worked with national providers to give people living with dementia opportunities and support to access the natural environment. Design/methodology/approach The evaluation adopted a mixed-methods approach, using a combination of bespoke and commonly used tools and in-depth case study work to identify the facilitators and challenges to delivering the project and explore the experiences of activity participants. Findings Qualitative measures indicated a significant improvement in mental well-being for participants with dementia and family carers following attendance at activity sessions. Research interviews indicated that participants enjoyed activities based on connecting with nature. Being outdoors was a major factor in the experience, along with taking part in activities that were meaningful and opportunities for social interaction. Originality/value This paper provides evidence for the benefits of connecting with nature for people living with dementia. This paper concludes that access to the outdoors is not a luxury, it is a basic human right and one which has become increasingly important in light of restrictions that have emerged as a result of the COVID19 pandemic.

The aim of the present study was to examine whether full leg-length compression tights modify physiological and kinematic measures during treadmill running at a competitive race pace in moderately trained runners. Thirteen males and five females completed two 15-minute running tests at a speed corresponding to a recent race time wearing compression tights or loose-fitting running shorts. Running economy (RE) was determined by oxygen consumption and carbon dioxide expiration during the final 3 minutes of treadmill running. Muscle oxygenation, skin temperature, heart rate (HR), vertical oscillation, step frequency and ground contact time (GCT) were measured continuously. GCT was shorter with compression compared with control trials ( p = 0.03), however, no differences in RE, muscle oxygenation, vertical oscillation, step frequency, HR or skin temperature were revealed. Despite a shorter GCT with compression tights, the findings suggest that moderately trained runners do not benefit nor limit physiological responses at a competitive race pace.

© 2019 The Authors Constructed wetlands can treat highly alkaline leachate resulting from the weathering of steel slag before reuse (e.g. as aggregate)or during disposal in repositories and legacy sites. This study aimed to assess how metal(loid)s soluble at high pH, such as arsenic (As), chromium (Cr), and vanadium (V)are removed in constructed wetlands and how they accumulate in the sediments and the plants (Phragmites australis, common reed). The results show that reedbeds were very effective at removing calcium (98%), aluminium (81%), barium (98%), chromium (90%), gallium (80%), nickel (98%), and zinc (98%), and lowering pH and alkalinity. No statistical difference was found for As and V between leachate influent and wetland samples, showing that these metal(loid)s were not efficiently removed. As, Cr, and V were significantly higher in the reedbed sediments than in a reference site. However, sediment concentrations are not at levels that would pose a concern regarding reuse for agricultural purposes (average values of 39 ± 26 mg kg −1 for As, 108 ± 15 mg kg −1 for Cr, and 231 ± 34 mg kg −1 for V). Also, there is no significant uptake of metals by the aboveground portions of the reeds compared to reference conditions. Results show statistically significant enrichment in metal(loid)s in rhizomes and also a seasonal effect on the Cr concentrations. The data suggest minimal risk of oxyanion-forming element uptake and cycling in wetlands receiving alkaline steel slag.

Conservation organizations are increasingly aware of the need to motivate pro‐environmental behavior by connecting people with nature. However, to maximize the effectiveness of the limited resources available, there needs to be a better understanding of the variability in people's connection to nature shown at different ages. We examined connection to nature among people aged 5–75 years, using two popular measures, in a cross‐sectional UK sample, based on the hypothesis that there would be clear, age‐related patterns in people's connection to nature, with specific “breakpoints” associated with differences in feelings of connection. Data were collected across a variety of locations. Analysis of generalized additive models revealed similar age‐related patterns for both measures, with connection declining from childhood to an overall low in the mid‐teens, followed by a rise to the early 20s and reaching a plateau that lasts to the end of the lifetime. Both measures also showed that females generally had higher connection scores than males. These findings have implications for conservation action.

This chapter discusses a number of nature-health and green exercise conceptual models that evidence pathways between nature exposure and health outcomes. Models vary in their complexity, from providing simple linear causal pathways whereby nature impacts individual health, to more complex models focusing on multidimensional interactions between human behaviors and health outcomes. The more complex models recognize the importance of mutual interaction and reciprocal feedback loops between components, alongside human agency, which acknowledges individual motivations and behavioral decisions. This chapter also discusses green exercise models, such as the ecological dynamics model and intertwining pathways. These models seek to understand both acute and longer-term green exercise behaviors and the factors that determine the outcomes. By integrating knowledge and models from different fields of research, we can begin to fully understand the physical and social characteristics of environments and experiences that can maximize the health and wellbeing outcomes of green exercise behaviors and ensure the necessary behavioral affordances can occur. The chapter concludes that models need to be based on rigorous evidence, be testable and reliable, so that they can provide a blueprint for researchers and health care professionals to inform public health research, policy, and practice.

The Mediterranean-Atlantic water mass exchange provides the ideal setting for deciphering the role of gateway evolution in ocean circulation. However, the dynamics of Mediterranean Outflow Water (MOW) during the closure of the Late Miocene Mediterranean-Atlantic gateways are poorly understood. Here, we define the sedimentary evolution of Neogene basins from the Gulf of Cádiz to the West Iberian margin to investigate MOW circulation during the latest Miocene. Seismic interpretation highlights a middle to upper Messinian seismic unit of transparent facies, whose base predates the onset of the Messinian salinity crisis (MSC). Its facies and distribution imply a predominantly hemipelagic environment along the Atlantic margins, suggesting an absence or intermittence of MOW preceding evaporite precipitation in the Mediterranean, simultaneous to progressive gateway restriction. The removal of MOW from the Mediterranean-Atlantic water mass exchange reorganized the Atlantic water masses and is correlated to a severe weakening of the Atlantic Meridional Overturning Circulation (AMOC) and a period of further cooling in the North Atlantic during the latest Miocene.

The tufa deposits in the Kurkur–Dungul area, southern Egypt, date from marine isotope stage (MIS) 11 to MIS 1. Springs across the region were active during glacial periods (with sea-level below –50 m), reflecting changed atmospheric circulation over the Indian Ocean, as well as peak interglacial periods. During times of low sea-level, reduced Indonesian throughflow promoted formation of an Indian Ocean Warm Pool, and anomalous rainfall on its western margin. We suggest that Egypt lies at the intersection of westerly (‘maghrebian’) and easterly (‘mashriqian’) rainfall provinces, which show different timing with relation to orbital forcing and different source water regions. Tufa-growth periods are therefore not mechanistically linked to ‘humid periods’ or ‘sapropel events’ identified elsewhere. Stable isotope and T(Δ47) data are also inconsistent with these spring systems being part of a larger system spanning northern Africa, and lack a clear interaction between northern hemisphere heating and mid-latitude rainfall. We also follow previous researchers in concluding that formation of springline deposit formation was probably delayed compared with rainfall, owing to aquifer flow distances. This delay is unlikely to be sufficient to explain why rainfall is out of phase with movements of the monsoon belts, but may complicate interpretation of these records.\ud \ud Supplementary material: A lithofacies description and supplementary figures and tables are available at https://doi.org/10.6084/m9.figshare.c.5246661

Ancient and recent terrestrial carbonate-precipitating systems are characterised by a heterogeneous array of deposits volumetrically dominated by calcite. In these environments, calcite precipitates display an extraordinary morphological diversity, from single crystal rhombohedral prisms, to blocky crystalline encrustations, or spherulitic to dendritic aggregates. Despite many decades of thorough descriptive and interpretative work on these fabrics, relating calcite micro-morphology with sedimentary hydrogeochemical conditions remains a challenge. Environmental interpretations have been hampered by the fact that calcite morphogenesis results from the complex interaction between different physico-chemical parameters which often act simultaneously (e.g., carbonate mineral supersaturation, Mg/Ca ratio of the parental fluid, organic and inorganic additives). To try to experimentally address the sedimentological causes of calcite morphogenesis, an experimental approach yielding a first attempt at a calcite growth-form phase diagram is presented here. The initial aim was to account for the carbonate products experimentally nucleated in alkaline, saline lake settings. These are the result of at least two competing calcite precipitation ‘driving forces’ that affect morphogenesis: the calcite supersaturation level of the parental fluid, and the concentration of microbial-derived organic molecules (alginic acid). A key finding of this study is that common naturally-occurring calcite products such as calcite floating rafts, rhombohedral prismatic forms, di-pyramid calcite crystals, spherulitic calcite grains, or vertically stacked spheroidal calcite aggregates, can be related to specific hydrogeochemical contexts, and their physical transitions pinpointed in a phase diagram. By exploring binary or ternary responses to forcing in morphological phase-space, links between calcite growth forms and (palaeo)environmental conditions can be determined. This provides a truly process-oriented means of navigating questions around carbonate precipitate morphogenesis for the future.

Highlights: • NW Pacific ice-rafted debris found further south than previously thought. • Largest iceberg events were comparable in magnitude to N Atlantic Heinrich Events. • Iceberg flux to ODP Site 1207 was episodic throughout the late Quaternary. • Kamchatka-Koryak bergs frequently reached south of the N Pacific Subarctic Front. • Ice-rafting and climate contrast sharply between the last two glacial periods. Abstract: The ice-rafted-debris (IRD) record of the open Northwest Pacific points towards the existence of substantial glacial ice on the Northeast Siberian coast during the late Quaternary. However, the scale and timing of glaciation and de-glaciation remains controversial due to the dearth of both onshore and offshore records. Existing IRD data suggests at least one event of dynamic and abrupt change during mid-late Marine Isotope Stage (MIS 3) which mimics the massive collapse of the Laurentide ice sheet during Heinrich Events. It is uncertain whether other events of this magnitude occurred during the late Quaternary. Here we present a ∼160,000 yr IRD series, planktic foraminiferal counts and an age model, derived from a benthic O curve, radiocarbon dates and tephrochronology, from core ODP 1207A (37.79°N, 162.75°E), revealing the presence of low but episodic flux of IRD. We conclude that glacial Northwest Pacific icebergs spread further south than previously thought, with icebergs emanating from Northeast Siberia being transported to the transition region between the subpolar and subtropical waters, south of the subarctic front during at least the Quaternary's last two glacial periods. The episodic nature of the 1207A IRD record during the last glacial, combined with coupled climate-iceberg modelling, suggests occasional times of much enhanced ice flux from the Kamchatka-Koryak coast, with other potential sources on the Sea of Okhotsk coast. These findings support the hypothesis of a variable but extensive ice mass during the last glacial over Northeast Siberia, particularly early in the last glacial period, behaving independently of North American and Eurasian ice masses. In strong contrast, IRD was absent during much of the penultimate glacial Marine Isotope Stage (MIS) 6 suggesting the possibility of very different Northeast Siberian ice coverage between the last two glacial periods.

This study's purpose was to (i) assess the impact of a 7-week pulmonary rehabilitation (PR) programme upon patient outcomes; incremental shuttle walk test (ISWT), COPD assessment tool (CAT), Clinical COPD Questionnaire (CCQ) and the Hospital Anxiety and Depression Scale (HADS); (ii) assess the impact of COPD severity on ISWT, psychological functioning and quality of life measures following PR; (iii) assess the feasibility of incorporating individually prescribed one repetition maximum (1RM) training loads into the existing strength training programme. Patients were people with COPD enrolled onto one of three versions (locations A, B and C) of a 7-week PR programme, which consisted of group exercise sessions and a social plus education element. Two locations incorporated individually prescribed training loads. Minimal clinically important changes (MCICs) are reported for the ISWT across all locations. Statistically significant changes in both CAT and the CCQ were found, with MCIC's evident for CAT score overall and individually at location B. MCIC's were not found for the CCQ. No statistically significant or MCICs were evident for the HADS. MCIC's were present only in patients with mild to moderate severity for the ISWT. For the CAT, moderate, severe and very severe patients with COPD experienced MCIC's. MCIC's and statistically significant increases in 1RM strength were seen at both locations. These findings evidence an effective PR service. Basic strength exercise programming and assessment are feasible and should be implemented in PR services to maximise patient outcomes.

The closure of Late Miocene Mediterranean-Atlantic gateways and the restriction of Mediterranean Outflow Water (MOW) led to the Messinian Salinity Crisis (MSC), the dynamics of which is not well understood. However, restriction of the Mediterranean-Atlantic exchange and the Mediterranean Outflow Water (MOW) is one of the prerequisites to generate hypersaline conditions for evaporitic deposition. During the Late Miocene, MOW circulation was active through a Mediterranean-Atlantic exchange of the Betic, Riffian, and possibly Gibraltar gateways. This connection is thought to have ceased or reduced with the onset of the MSC, before re-establishing through the Gibraltar gateway since the Pliocene to the present. In this study, we define the sedimentary evolution of the Neogene Basins of the Gulf of Cádiz to investigate MOW evolution during the latest Miocene. Seismic interpretation shows an Upper Messinian sedimentary unit of transparent seismic facies. It could also be found in the lower Guadalquivir and Gharb basins, and towards the West Portuguese margin. Biostratigraphic dating indicate an onset of deposition predating the MSC. Distribution of this transparent unit implicates the dominant deposition of hemipelagic/pelagic deposits during a period of quiescence in the Atlantic margins, subsequent to MOW disconnection. This suggests that weakening or cut-off of the intermediate bottom currents of the Mediterranean-Atlantic exchange through the Betic-Gibraltar-Riffian paleo-gateways precedes the onset of MSC evaporites. This work is crucial for the understanding of sedimentary, paleoceanographic and climatic implications of the Latest Miocene Mediterranean isolation in the Atlantic margins.

Over the last decennia, alkaline leachates from the weathering of legacy steel slag disposal sites have affected the surrounding soils and drainage streams. The hyperalkaline and hypersaline conditions around these sites are comparable to extreme paleo environments such as alkaline lakes in rift volcanic settings. Investigating the carbonate deposits forming in these man-made systems provides a unique opportunity to link the ongoing physical and microbial processes to their resultant carbonate morphologies.Here we present data from 3 sites across Dene Burn, a slag drainage stream in Consett, County Durham, UK. After 100 years, iron and steel production ceased in 1980, leaving over 20 million tons of slag in the form of several large mounds. Analysis showed Dene Burn to be typical of slag drainage waters with an elevated pH (>9) and saturated with different secondary phase minerals- particularly calcite. However, the physical distribution of carbonates is more comparable with estimated local kinetic precipitation rate than it is to thermodynamic saturation, indicating that the fundamental control on carbonate formation arises from crystal surface processes. A microbial community comprising predominantly Proteobacteria (Alpha-, Gamma-, Beta- and Deltaproteobacteria), Cyanobacteria, Bacillariophyta (diatoms) and Bacteroidetes (Flavobacterium) was identified at the 3 sites. The microbial communities and an abundance of extracellular polymeric substances (EPS) were shown in close association with the mineral phases detected at the sites. The presence and composition of these biofilms appears to control local carbonate mineralisation rates and carbonate morphologies.Drainage streams from steel slag provide a unique opportunity to study carbonate mineral formation under extreme environmental conditions. Furthermore, maximising carbonate formation at such sites could be utilised as a remediation and carbonate sequestration technique.

This study investigated the efficacy of medium-term Green Exercise (GE, being physically active within a natural environment) interventions for improving wellbeing, by pooling data collected at the start and end of participants&rsquo, engagement with a range of GE interventions. Hypotheses were that (i) interventions would show good efficacy for improving wellbeing in the overall sample, (ii) compared to participants reporting &lsquo, average to high&rsquo, wellbeing at the start of their project, participants with &lsquo, low&rsquo, starting wellbeing would report greater improvements post-intervention, and (iii) improvements would significantly differ between age groups. The pooled dataset was categorized in line with UK norms (n = 318) and analyzed using a standardized meta-analysis approach. Effect size was large: g = 0.812 (95% CI [0.599, 1.025]), and differences in wellbeing changes associated with project duration, age or sex were not statistically significant. Compared to those reporting &lsquo, average-high&rsquo, starting wellbeing, participants reporting &lsquo, starting wellbeing exhibited greater improvements (BCa 95% CI [&minus, 31.8, &minus, 26.5]), with 60.8% moving into the &lsquo, wellbeing category. GE can play an important role in facilitating wellbeing and can provide alternative pathways for health and social care practice. Public health commissioners should consider integrating such interventions for patients experiencing low wellbeing or associated comorbidities.

&lsquo, Green exercise&rsquo, (being physically active within a natural environment) research has examined the influence of environmental setting on health and wellbeing-related exercise outcomes. However, it is not known whether social exercise settings influence green exercise-associated changes in mood, self-esteem, and connection to nature. This study directly compared outcomes of participating in green exercise alone compared to in a group. Using repeated measures, counterbalanced and randomized-crossover design, participants (n = 40) completed two 3 km runs around sports fields. These fields had a relatively flat grass terrain, predominant view of trees, and open grassland. On one occasion participants ran alone and on the other they ran in a group of 4&ndash, 5 participants. Questionnaire measures of mood, self-esteem, and connection to nature were completed immediately pre- and post-run. Across all of the measures, two-way mixed ANOVAs found that there were statistically significant effects for time but not for time-by-condition interactions. The simplest interpretation of this finding is that social setting does not influence individuals&rsquo, attainment of the psychological outcomes of green exercise participation. However, we discuss the possibility that more complex processes might underpin this finding.

To investigate past changes in the Mediterranean Overflow Water (MOW) to the Atlantic, we analyzed the strength of the MOW and benthic δC along the last 250 kyr at Integrated Ocean Drilling Program (IODP) Site U1389 in the Gulf of Cadiz, near the Strait of Gibraltar. Both the strength of the MOW and the benthic δC were mainly driven by precession-controlled fluctuations in the Mediterranean hydrologic budget. Reduced/enhanced Nile discharge and lower/higher Mediterranean annual rainfall at precession maxima/minima resulted in higher/lower MOW strengths at Gibraltar and stronger/weaker Mediterranean overturning circulation. At millennial scale, the higher heat and freshwater loss to the atmosphere during Greenland stadials increased buoyancy loss in the eastern Mediterranean. This enhanced the density gradient with Atlantic water, resulting in a higher MOW velocity in the Gulf of Cadiz. Unlike non-Heinrich stadials, a lower-amplitude increase in velocity was seen during Heinrich stadials (HSs), and a significant drop in velocity was recorded in the middle phase. This weak MOW was especially recognized in Termination I and II during HS1 and HS11. These lower velocities at the depth of Site U1389 were triggered by MOW deepening due to the lower densities of Atlantic intermediate water caused by freshwater released from the Laurentide and Eurasian ice sheets. The intrusion of salt and heat at deeper depths in the Atlantic during HSs and its shoaling at the end could have contributed to drive the changes in the Atlantic Meridional Overturning Circulation during Terminations., This work was funded by the Ministry of Economy of Spain Project RTI2018‐099489‐B‐I00, CGL2015‐68459‐P, and Junta de Castilla y León (UIC 102). We appreciate the work of Jose Ignacio Martin Cruz in sample processing and the picking of planktic and benthic foraminifers. We are very grateful to IODP for inviting some of us to participate in Expedition 339 Mediterranean Outflow and providing the samples used in this study. Part of this work has been done in colaboration with “The Drifters” Research Group at Royal Holloway University of London (RHUL), and it is related to the projects CTM 2012‐39599‐C03, CGL2016‐80445‐R, and CTM2016‐75129‐C3‐1‐R. Also, we thank María Druet (IGME, Spain) for their help in the base map for Figure 1c. Suggestions and comments from Dr. Antje Voelker and Samuel Toucanne were very helpful and substantially improved the last version of this manuscript.

Lacustrine carbonate chimneys are striking, metre-scale constructions. If these were bioinfluenced constructions, they could be priority targets in the search for early and extraterrestrial microbial life. However, there are questions over whether such chimneys are built on a geobiological framework or are solely abiotic geomorphological features produced by mixing of lake and spring waters. Here, we use correlative microscopy to show that microbes were living around Pleistocene Mono Lake carbonate chimneys during their growth. A plausible interpretation, in line with some recent works by others on other lacustrine carbonates, is that benthic cyanobacteria and their associated extracellular organic material (EOM) formed tubular biofilms around rising sublacustrine spring vent waters, binding calcium ions and trapping and binding detrital silicate sediment. Decay of these biofilms would locally have increased calcium and carbonate ion activity, inducing calcite precipitation on and around the biofilms. Early manganese carbonate mineralisation was directly associated with cell walls, potentially related to microbial activity though the precise mechanism remains to be elucidated. Much of the calcite crystal growth was likely abiotic, and no strong evidence for either authigenic silicate growth or a clay mineral precursor framework was observed. Nevertheless, it seems likely that the biofilms provided initial sites for calcite nucleation and encouraged the primary organised crystal growth. We suggest that the nano-, micro- and macroscale fabrics of these Pleistocene Mono Lake chimneys were affected by the presence of centimetre-thick tubular and vertically stacked calcifying microbial mats. Such carbonate chimneys represent a promising macroscale target in the exploration for ancient or extraterrestrial life.

Lacustrine carbonate deposits with spherulitic facies are poorly understood, but are key to understanding the economically important “Pre-Salt” Mesozoic strata of the South Atlantic. A major barrier to research into these unique and spectacular facies is the lack of good lacustrine spherulite-dominated deposits which are known in outcrop. Stratigraphy and petrography suggest one of the best analogue systems is found in the Carboniferous of Scotland: the East Kirkton Limestone. Here we propose a hydrogeochemical model that explains why the CaCO3, SiO2, Mg-Si-Al mineral suite associated with spherular radial calcite facies forms in alkaline lakes above basaltic bedrock. Demonstrating links between igneous bedrock chemistry, lake and spring water chemistry and mineral precipitation, this model has implications for studies of lacustrine sediments in rift basins of all ages. Using empirical and theoretical approaches, we analyze the relationship between metal mobilization from sub-surface volcaniclastic rocks and the potential for precipitation of carbonate minerals, various Mg-bearing minerals and chalcedony in a lacustrine spherulitic carbonate setting. This suite of minerals is most likely formed by in-gassing of CO2 to a carbon-limited alkaline spring water, consistent with the reaction of alkali igneous rocks in the subsurface with meteoric groundwater. We suggest that an analogous system to that at East Kirkton caused development of the ‘Pre-Salt’ spherulitic carbonate deposits.

Leachable vanadium (V) from steel production residues poses a potential environmental hazard due to its mobility and toxicity under the highly alkaline pH conditions that characterise these leachates. This work aims to test the efficiency of anion exchange resins for vanadium removal and recovery from steel slag leachates at a representative average pH of 11.5. Kinetic studies were performed to understand the vanadium sorption process. The sorption kinetics were consistent with a pseudo-first order kinetic model. The isotherm data cannot differentiate between the Langmuir and Freundlich models. The maximum adsorption capacity (Langmuir value qmax) was 27 mg V g−1 resin. In column anion exchange, breakthrough was only 14% of the influent concentration after passing 90 L of steel slag leachate with 2 mg L−1 V through the column. When eluting the column 57–72% of vanadium was recovered from the resin with 2 M NaOH. Trials on the reuse of the anion exchange resin showed it could be reused 20 times without loss of efficacy, and on average 69% of V was recovered during regeneration. The results document for the first time the use of anion exchange resins to remove vanadium from steel slag leachate. As an environmental contaminant, removal of V from leachates may be an obligation for long-term management requirements of steel slag repositories. Vanadium removal coupled with the recovery can potentially be used to offset long-term legacy treatment costs.

Africa spans the hemispheres from temperate region to temperate region and has a long history of hominin evolution. Although the number of Quaternary palaeoclimatic records from the continent is increasing, much of the history of spatial and temporal climatic variability is still debated. Speleothems, as archives of terrestrial hydroclimate variability, can help reveal this history. Here we review the progress made to date, with a focus on the first version of the Speleothem Isotopes Synthesis and AnaLysis (SISAL) database. The geology of Africa has limited development of large karst regions to four areas: along the northern coast bordering the Mediterranean, eastern Africa and the Horn of Africa, southwestern Africa and southern Africa. Exploitation of the speleothem palaeoclimate archives in these regions is uneven, with long histories of research, e.g., in South Africa, but large areas with no investigations such as West Africa. Consequently, the evidence of past climate change reviewed here is irregularly sampled in both time and space. Nevertheless, we show evidence of migration of the monsoon belt, with enhanced rainfall during interglacials observed in northeast Africa, southern Arabia and the northern part of southern Africa. Evidence from eastern Africa indicates significant decadal and centennial scale rainfall variability. In northwestern and southern Africa, precession and eccentricity influence speleothem growth, largely through changing synoptic storm activity.

Our landscape is a significant health resource that promotes physical, mental and social wellbeing. Salutogenic landscapes afford behaviours that reduce stress, restore mental fatigue and enhance mood, self-esteem and wellbeing. They also foster physical wellbeing via opportunities to be active, and social wellbeing improves due to increased levels of social engagement, integration, participation and social support. This chapter explores how the landscape can offer opportunities for health and wellbeing benefits, and within the current context of escalating public mental ill-health, it analyses the role of nature-based interventions in wellbeing promotion. The evidence will help advance our understanding of the notion of restorative landscapes.

This paper presents a route for the treatment of MSWI fly (FA) and bottom ashes (BA) using microorganisms to critically assess whether bioleaching is within reach of effective industrial application. The leaching of metals from BA and FA was investigated in a controlled laboratory environment using a culture isolated from a natural system where the dominant strains are acidophilic bacteria, mainly Acidothiobacillus thiooxidans and Acidothiobacillus ferrooxidans. The community of microorganisms (mostly acidophilic, S- and Fe-oxidizing bacteria) was collected directly from overflows and ponds at the sediment–water interface of a natural system near a post-mining site. Pre-cultivation was done in 250 mL flasks followed by the adaptation to the different substrates (both FA and BA). The effect of different material pre-treatment and elemental sulphur concentrations were evaluated for both BA and FA, at a starting pH of 4. The bioleaching of BA and FA substrates experienced good yields of metal extraction with an optimum duration of two weeks. The results showed that more than 90% Zn, Cu, and 10% Pb are removed from FA; while 100% Cu, 80% Zn and 20% Pb are removed from BA samples. Batch experiments with regenerating ion-exchange resins did not perform well for metal recovery, but could serve as a valuable decontamination step. The techniques used here with FA and BA can be used for urban mining purposes (e.g. ashes and other meal-rich anthropogenic wastes), but also low-grade ores in the mining industry, contributing to resource recovery or decontamination agendas.

With an estimated annual production of two billion tonnes globally, alkaline industrial wastes can be considered both major global waste streams, and materials that offer significant options for potential resource recovery. Alkaline wastes are usually derived from high temperature production (e.g. steel and alumina) or disposal (e.g. incineration) processes and are increasingly abundant given rising global demand for steel and alumina and the drive for waste incineration in some jurisdictions. Although relatively long-standing afteruses have been adopted for these materials providing opportunities for value recovery (e.g. steel slag use as an aggregate), they are not sufficient to consume all residues generated or completely limit potential environmental impacts. These impacts can include the generation of fugitive dusts, challenges associated with revegetation, and effects on the water environment. These wastes can produce highly alkaline leachates enriched with trace metals (e.g. As, Cr, Mo, V) and persist over decades after site closure. Vanadium, one of the most hazardous ecotoxins in leachates, is also a valuable commodity for renewable energy technologies, unifying the often divergent needs of resource recovery and remediation. Case studies are included to illustrate routes to resource recovery from wastes from two major industrial sectors: steel production and alumina production.

The origin of spherical-radial calcite bodies - spherulites - in sublacustrine, hyperalkaline and saline systems is unclear, and therefore their palaeoenvironmental significance as allochems is disputed. Here, we experimentally investigate two hypotheses concerning the origin of spherulites. The first is that spherulites precipitate from solutions super-saturated with respect to magnesium-silicate clays, such as stevensite. The second is that spherulite precipitation happens in the presence of dissolved, organic acid molecules. In both cases, experiments were performed under sterile conditions using large batches of a synthetic and cell-free solution replicating waters found in hyperalkaline, saline lakes (such as Mono Lake, California). Our experimental results show that a highly alkaline and highly saline solution supersaturated with respect to calcite (control solution) will precipitate euhedral to subhedral rhombic and trigonal bladed calcite crystals. The same solution supersaturated with respect to stevensite precipitates sheet-like stevensite crystals rather than a gel, and calcite precipitation is reduced by ~. 50% compared to the control solution, producing a mixture of patchy prismatic subhedral to euhedral, and minor needle-like, calcite crystals. Enhanced magnesium concentration in solution is the likely the cause of decreased volumes of calcite precipitation, as this raised equilibrium ion activity ratio in the solution. On the other hand, when alginic acid was present then the result was widespread development of micron-size calcium carbonate spherulite bodies. With further growth time, but falling supersaturation, these spherules fused into botryoidal-topped crusts made of micron-size fibro-radial calcite crystals. We conclude that the simplest tested mechanism to deposit significant spherical-radial calcite bodies is to begin with a strongly supersaturated solution that contains specific but environmentally-common organic acids. Furthermore, we found that this morphology is not a universal consequence of having organic acids dissolved in the solution, but rather spherulite development requires specific binding behaviour. Finally, we found that the location of calcite precipitation was altered from the air:water interface to the surface of the glassware when organic acids were present, implying that attached calcite precipitates reflect precipitation via metal-organic intermediaries, rather than direct forcing via gas exchange.

There is an urgent global need for accessible and cost-effective pro-mental health infrastructure. Public green spaces were officially designated in the 19th century, informed by a belief that they might provide health benefits. We outline modern research evidence that greenspace can play a pivotal role in population-level mental health.

Vanadium is a toxic metal present in alkaline leachates produced during the weathering of steel slags. Slag leaching can therefore have deleterious effects on local watercourses due to metal toxicity, the effects of the high pH (9–12.5) and rapid carbonation (leading to smothering of benthic communities). We studied the fate and behaviour of V in slag leachate both through field observations of a heavily affected stream (Howden Burn, Consett UK) and in controlled laboratory experiments where slag leachates were neutralised by CO2 ingassing from air. V was found to be removed from leachates downstream from the Howden Burn source contemporaneously with a fall in pH, Ca, Al and Fe concentrations. In the neutralisation experiments pH reduced from 12 → 8, and limited quantities of V were incorporated into precipitated CaCO3. The presence of kaolinite clay (i.e. SiOH and AlOH surfaces) during neutralisation experiments had no measureable effect on V uptake in the alkaline to circumneutral pH range. XANES analysis showed that V was present in precipitates recovered from experiments as adsorbed or incorporated V(V) indicating its likely presence in leachates as the vanadate oxyanion (HVO42−). Nano-scale particles of 2-line ferrihydrite also formed in the neutralised leachates potentially providing an additional sorption surface for V uptake. Indeed, removal of V from leachates was significantly enhanced by the addition of goethite (i.e. FeOOH surfaces) to experiments. EXAFS analysis of recovered goethite samples showed HVO42− was adsorbed by the formation of strong inner-sphere complexes, facilitating V removal from solution at pH

This exploratory study enhances previous research into green exercise and addresses a gap in the research by exploring the contribution of individual and combined senses in the recovery of mood and stress after a psychological stressor, whilst rigorously controlling exercise intensity. The hypotheses were: (i) recovery of mood and stress from a state of psychological stress would be greater following simulated green exercise compared to rest, (ii) green exercise would facilitate better recovery than exercise alone, (iii) these effects would remain 10 min following intervention, and (iv) visual stimuli alone would enhance recovery from a state of psychological stress compared to sound. Fifty participants were randomly assigned to one of five groups: REST, exercise, exercise with nature sounds, exercise with nature visual and exercise with nature sound and visual. An initial visit to obtain predicted peak power output values and to familiarize participants with the equipment being used was followed by a second visit, where participants experienced one test condition. Baseline measures of heart rate, blood pressure, total mood disturbance (TMD), and perceived stress were taken, before participants completed a stressor based on the Trier Social Stress test. Measures of heart rate and blood pressure were recorded in the last 30 s of the stressor to assess efficacy of the stressor. Immediately post stressor, measures of mood and perceived stress were taken followed by the intervention assigned (one of five described above). Measures of mood and perceived stress were taken again immediately post intervention and 10 min post intervention. Results showed that green exercise improved mood and stress scores more than exercise alone or REST. For both TMD and perceived stress, improvements in all simulated nature conditions were significantly improved compared to REST or exercise alone immediately post intervention. There were no significant changes 10 min post intervention in either mood or perceived stress compared to immediately post intervention values in any of the groups. This study suggests that environmental exercise settings including nature sounds, visual or both combined should be considered as important in the use of exercise as a therapeutic activity or recovery from acute psychological stress.

Africa spans the hemispheres from temperate region to temperate region and has a long history of hominin evolution. Although the number of Quaternary palaeoclimatic records from the continent is increasing, much of the history of spatial and temporal climatic variability is still debated. Speleothems, as archives of terrestrial hydroclimate variability, can help reveal this history. Here we review the progress made to date, with a focus on the first version of the Speleothem Isotopes Synthesis and AnaLysis (SISAL) database. The geology of Africa has limited development of large karst regions to four areas: along the northern coast bordering the Mediterranean, eastern Africa and the Horn of Africa, southwestern Africa and southern Africa. Exploitation of the speleothem palaeoclimate archives in these regions is uneven, with long histories of research, e.g., in South Africa, but large areas with no investigations such as West Africa. Consequently, the evidence of past climate change reviewed here is irregularly sampled in both time and space. Nevertheless, we show evidence of migration of the monsoon belt, with enhanced rainfall during interglacials observed in northeast Africa, southern Arabia and the northern part of southern Africa. Evidence from eastern Africa indicates significant decadal and centennial scale rainfall variability. In northwestern and southern Africa, precession and eccentricity influence speleothem growth, largely through changing synoptic storm activity.