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In the current climate and energy context, it is important to develop technologies that permit increase the use of renewable sources such as geothermal energy. Enhancing the use of this renewable source is particularly important in some places, due to its availability and the enormous dependence on fossil fuels, as is the case of the Canary Islands. This work proposes the use of thermoelectric generators with heat exchangers working by phase change to transform the heat from the shallow high temperature geothermal anomalies on the island of Lanzarote directly into electricity, since the use of conventional geothermal power plants would not be possible because they would damage the protected environment. To bring this proposal to reality, this work has succeeded in developing and field-installing a geothermal thermoelectric generator that operates without moving parts thanks to its phase-change heat exchangers. This robust generator do not require maintenance nor auxiliary consumption, and produces a minimal environmental impact, it is noiseless, and the use of water as working fluid makes it completely harmless. The developed device consists of a thermosyphon as hot side heat exchanger, thermoelectric modules and cold side heat exchangers also based in phase change. Tests were carried out in the laboratory at various heat source temperatures and varying the number of thermoelectric modules. It was determined that installing more modules decreases the efficiency per module (from 4.83% with 4 modules to 4.59% with 8 modules at a temperature difference between sources of 235 °C), but for the number of modules tested the total power increases, so the field installation was carried out with 8 modules. After the good results in the laboratory, it was satisfactorily installed at Timanfaya National Park (Lanzarote, Spain) in a borehole with gases at 465 °C. This generator presents a maximum output power of 36 W (4.5 W per module), and is generating 286.94 kWh per year, demonstrating the great potential of the developed thermoelectric generators to build a larger-scale renewable installation. Spanish State Research Agency and FEDER-UE funds under the grants TED2021-129359B-I00 and PID2021-124014OB-I00. Open access funding provided by Universidad Pública de Navarra.

Heat exchangers are essential to optimize the efficiency of Thermoelectric Generators (TEGs), and heat pipes without fans have proven to be an advantageous design as it maintains the characteristic robustness of thermoelectricity, low maintenance and lack of moving parts. However, the efficiency of these heat exchangers decreases under natural convection conditions, reducing their heat transfer capacity and thus thermoelectric power production. This work reports on a novel heat exchanger that combines for the first time, phase change and radiative cooling in a thermoelectric generator to improve its efficiency and increase the production of electrical energy, specially under natural convection. For this, two thermoelectric generators with heat-pipes on their cold sides have been tested: one with the radiative coating and the other without it. Their thermal resistances have been determined and the electric power output was compared under different working conditions, namely, natural convection and forced convection indoors and outdoors. The experimental tests show a clear reduction of the heat exchanger thermal resistance thanks to the radiative coating and consequently, an increase of electric production 8.3 % with outdoor wind velocities of 1 m/s, and up to 54.8 % under free convection conditions. The application of the radiative surface treatment is shown to result in a more stable electrical energy production, suppressing the drastic decrease in the generated electric power that occurs in thermoelectric generators when they work under free convection. The authors acknowledge the support of the Spanish Ministry of Science, Innovation and Universities, and the European Regional Development Fund , under grants PID2021-124014OB-I00 (VIVOTEG), TED2021-129359B-I00 (GEOTEG), PGC2018-101743-B-I00 (SIP) and RTI2018-093921-A-C44 (SMOOTH). Open access funding provided by Universidad Pública de Navarra.

Although in the last years thermoelectric generators have arisen as a solution to boost geothermal power generation, tests on field are still scarce. The vast majority of the available studies focus on computational simulations or laboratory experiments, mainly with active heat exchangers that require pumps or fans, and, consequently, present moving parts and auxiliary consumption. The present paper demonstrates for the first time the suitability of a geothermal thermoelectric generator (GTEG) with passive phase change heat exchangers, and therefore, without moving parts nor auxiliary consumption, on the shallow Hot Dry Rock (HDR) field of Timanfaya National Park (Canary Islands, Spain), where 173 °C air anomalies can be found. The device has been in operation without maintenance for 2 years now, producing more than 520 kWh of energy. In terms of power generation, since the installed device is in turn composed of two prototypes with 10 and 6 thermoelectric modules, it has been confirmed that installing more modules leads to a lower generation per module, although total generation can be higher. In fact, the prototype with 10 thermoelectric modules generated a maximum of 20.9 W (2.09 W per module) with a temperature difference between sources of 158 °C, while the prototype with 6 thermoelectric modules obtained 16.67 W (2.78 W per module) under the same conditions. These results open the door for a large-scale exploitation thanks to the intrinsic advantages of modularity, reliability, robustness, and minimal environmental impact of the developed device. The authors would like to acknowledge the support of the Spanish State Research Agency and FEDER-UE under the grants PID2021-124014OB-I00 and TED2021-129359B-I00. Open access funding provided by Universidad Pública de Navarra

The nowadays European educational framework boosts applying the learned theoretical concepts to real situations. Hence, practice sessions are key resources to present students direct applications of the theoretical concepts shown in class. Thus, developing new educational equipment and practice sessions oriented to bringing theoretical knowledge closer to practice should be one of the objectives of teachers. The present work describes a solution proposed by lectures of two Spanish universities looking to increase the knowledge of their engineering students. Along the years, these docents have noticed the lack of connection between the theoretical and practical knowledge among their students, drastically harming their learning procedure. Thus, in order to deepen into practical learning, a teaching methodology involving low-cost prototypes of vapor compression systems and a gamification method to help the students understand the concepts is proposed. The proposed methodology is expected to make a big positive impact on the results obtained by the students, taking into account the preliminary results reached. The authors are indebted to the Spanish Ministry of Science, Innovation and Universities, and European Regional Development Fund for the economic support to this work, included in the RTI2018-093501-B-C21 and RTI2018-093501-B-C22 research projects and to the Public University of Navarre for the economic support to this work included in the PJUPNA2003 research project.

To improve the performance of vapour compression refrigeration cycles, the inclusion of a thermoelectric subcooler for low-medium power units has been the focus of recent studies due to its robustness, compactness and simplicity of operation. In thermoelectric systems, it has been demonstrated that the heat exchangers used in the hot and cold side of the thermoelectric modules have a critical impact in the performance of the system. This influence has not yet been studied for thermoelectric subcooling systems in vapour compression cycles. This work, for the first time, evaluates the impact that the heat exchangers of a thermoelectric subcooler, included in a transcritical carbon dioxide refrigeration cycle, have, in the performance of the refrigeration cycle. The influence is quantified in terms of: optimum working conditions, coefficient of performance and cooling capacity. The results show that, through an optimization of the heat exchangers of the thermoelectric subcooler, the performance improvements on the coefficient of performance using this technology are boosted from 11.96 to 14.75 % and the upgrade in the cooling capacity of the system rises from 21.4 to 26.3 %. Moreover, the optimum gas-cooler working pressure of the system is reduced and the optimum voltage supplied to the thermoelectric modules increases. The authors would like to acknowledge the support of the Spanish Ministry of Science, Innovation and Universities, and European Regional Development Fund, for the funding under the RTI2018-093501-B-C21 and RTI2018-093501-B-C22 research projects. We would also like to acknowledge the support from the Education Department of the Government of Navarra with the Predoctoral Grants for Phd programmes of Interest to Navarra and the Official School of Industrial Engineers of Navarre with the scholarship Fuentes Dutor. Open access funding provided by Universidad Pública de Navarra.

Restrictive environmental regulations are driving the use of CO 2 as working fluid in commercial vapour compression plants due to its ultra-low global warming potential (GWP 100 = 1) and its natural condition. However, at high ambient temperatures transcritical operating conditions are commonly achieved causing low energy efficiencies in refrigeration facilities. To solve this issue, several improvements have been implemented, especially in large centralized plants where ejectors, parallel compressors or subcooler systems, among others, are frequently used. Despite their good results, these measures are not suitable for small-capacity systems due mainly to the cost and the complexity of the system. Accordingly, this work presents a new subcooling system equipped with thermoelectric modules (TESC), which thanks to its simplicity, low cost and easy control, results very suitable for medium and small capacity plants. The developed methodology finds the gas-cooler pressure and the electric voltage supplied to the TESC system that maximizes the overall COP of the plant taking into account the ambient temperature, the number of thermoelectric modules used and the thermal resistance of the heat exchangers included in the TESC. The obtained results reveal that, with 20 thermoelectric modules, an improvement of 20% in terms of COP and of 25.6% regarding the cooling capacity can be obtained compared to the base cycle of CO 2 of a small cooling plant refrigerated by air. Compared to a cycle that uses an internal heat exchanger IHX, the improvements reach 12.2% and 19.5% respectively. The authors would like to acknowledge the support of the Spanish Ministry of Science, Innovation and Universities for the funding under the FPU Program (FPU16/05203).

Nowadays, geothermal energy in shallow hot dry rock fields is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. However, the efficiency of a thermoelectric generator depends highly on the heat exchangers. In this work, a novel geothermal thermoelectric generator is experimentally developed, characterizing different configurations of biphasic heat exchangers to obtain low thermal resistances that allow the maximum efficiency in the thermoelectric modules. As a result, robust and passive heat exchangers were obtained with thermal resistances of 0.07 K/W and 0.4 K/W in the hot and cold sides, respectively. The geothermal thermoelectric generator was built with the most effective heat exchangers and was experimented under different temperature and convection conditions, generating 36 W (17 W by a prototype with 10 modules and 19 W by a prototype with 6 modules) for a temperature difference of 160 °C between the heat source and the environment. Furthermore, the experimental development showed that it is possible to increase electricity generation with a more compact generator, since a decrease in the number of modules from 10 to 6 increases the efficiency from 3.72% to 4.06%. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.

The use of thermoelectric heat pumps for heat, ventilation, and air conditioning in nearly-zero-energy buildings is one of the most promising applications of thermoelectrics. However, simulation works in the literature are predominately based on the simple model, which was proven to exhibit significant deviations from experimental results. Nine modelling techniques have been compared in this work, according to statistical methods based on uncertainty analysis, in terms of predicted coefficient of performance and cooling power. These techniques come from the combination of three simulation models for thermoelectric modules (simple model, improved model, electric analogy) and five methods for implementing the thermoelectric properties. The main conclusion is that there is no statistical difference in the mean values of coefficient of performance and cooling power provided by these modelling techniques under all the scenarios, at 95% level of confidence. However, differences appear in the precision of these results in terms of uncertainty of the confidence intervals. Minimum values of uncertainty are obtained when the thermal resistance ratio approaches 0.1, being ±8% when using temperature-dependent expressions for the thermoelectric properties, ±18% when using Lineykin’s method, and ± 25% when using Chen’s method. The best combination is that composed of the simple model and temperature-dependent expressions for the thermoelectric properties. Additionally, if low values of resistance ratio are anticipated, empirical expressions from the literature can be used for the thermal resistance of the heat exchangers; for high values, though, experimental tests should be deployed, especially for the heat exchanger on the hot side.

Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In order to leverage shallow hot dry rock (HDR) fields, the present paper proposes an alternative to enhanced geothermal systems (EGS): thermoelectric generators. Based on the conditions of Timanfaya National Park, a prototype has been built to experimentally analyze the feasibility of the proposed solution. The prototype is composed by a two phase closed thermosyphon (TPCT) as hot side heat exchanger, two thermoelectric modules, and it considers different cold side heat exchangers: fin dissipators assisted by a fan and loop thermosyphons, both with various geometries. Experiments have demonstrated that loop thermosyphons represent the best alternative due to their low thermal resistance and, especially, due to their lack of auxiliary consumption, leading to a maximum net power generation of 3.29 W per module with a temperature difference of 180 °C (200 °C in the hot side and 20 °C as ambient temperature), 54% more than with fin dissipators. Hence, there exists a new opportunity for electricity generation in shallow hot dry rock fields: thermoelectric generators with biphasic thermosyphons as heat exchangers, a patented and robust solution. The authors would like to acknowledge the support of the Spanish State Research Agency and FEDER-UE under the grants DPI2014-53158-R and RTC-2017-6628-3 ; as well as the FPU Program of the Spanish Ministry of Science, Innovation and Universities (FPU16/05203 ).

The nZEB standards reduce the energy demand of these buildings to a minimum, obtaining this little energy from renewable resources. Taking these aspect into consideration, a thermoelectric cooler-heat pump is proposed to achieve the comfort temperature along the whole year. The same device can provide heat in winter and it can cool down the buildings in summer just by switching the voltage supply polarity. Heat pipes are studied to work on both sides of the thermoelectric modules in order to optimize the heat transfer as these devices present really good thermal resistances and they can work in any position. However, they present pretty different thermal resistances if they work on the cold or on the hot side of the modules. A methodology to thermally characterize these heat exchangers working in both orientations is proposed and a validated computational model is developed to optimize the thermoelectric cooler-heat pump for a nZEB application. The number of thermoelectric modules, the position of the device, the ambient temperature and the air mass flow determine the operation and consequently they need to be studied in order to optimize the application. The authors are indebted to the Spanish Ministry of Economy and Competitiveness for the economic support to this work, included in the DPI2014-53158-R research project.

Trabajo presentado a la 2nd International Conference on Energy and Power, ICEP2018. 2018, Australia The scarcity of fresh water amongst a growing population is an impending global issue, which must be addressed by utilizing renewable energy sources. A Concentrated Photovoltaic (CPV) and Direct Contact Membrane Distillation (DCMD) hybrid system is a viable solution to address water shortage in arid and rural areas. The objective is to determine the feasibility of the combination of a DCMD and CPV system, demonstrate fresh water production utilizing the DCMD method and increase total CPV system efficiency. An experimental setup has been designed and built, and the results indicate a mass flux of 7.096 L/m2.h is achievable with a Polytetrafluoroethylene Membrane area of 0.0491 m2, salinity concentration of 1±0.1 % and a membrane temperature difference of 18.82 °C.

Thermoelectricity, in the form of thermoelectric generators, holds a great potential in waste heat recovery, this potential has been studied and proved in several laboratory and theoretical works. By the means of a thermoelectric generator, part of the energy that normally is wasted in a manufacturing process, can be transformed into electricity, however, implementing this technology in real industries still remains a challenge and on-site tests need to be performed in order to prove the real capabilities of this technology. In this work, a computational model to simulate the behaviour of a thermoelectric generator that harvest waste heat from hot fumes is developed. Using the computational model an optimal configuration for a thermoelectric generator is obtained, also an experimental study of the performance of different heat pipes working as cold side heat exchangers is carried out in order to optimize the performance of the whole thermoelectric generator, thermal resistances of under 0,25 K/W are obtained. The optimized configuration of the thermoelectric generator has been built, installed and tested under real conditions at a rockwool manufacturing plant and experimental data has been obtained during the 30 days field test period. Results show that 4.6 W of average electrical power are produced during the testing period with an efficiency of 2.38%. Moreover, the computational model is validated using this experimental data. Furthermore, the full harvesting potential of an optimized designed that takes advantage of the whole pipe is calculated using the validated computational model, resulting in 30.8 MWh of energy harvested during a sample year which could meet the demand of 8.34 Spanish average households. The authors are indebted to the Navarra Government for economic support of this work, included in the 0011-1365-2018-000101 Research Project, also to the State Research Agency of Spain for economic support, included in the RTI2018-093501-B-C22 Project from the Research Challenges Program. We would also like to acknowledge the support from the FPU Program of the Spanish Ministry of Science, Innovation and Universities (FPU16/05203).

Although there is an important lack of commercial thermoelectric applications mainly due to their low efficiency, there exist some cases in which thermoelectric generators are the best option thanks to their well-known advantages, such as reliability, lack of maintenance and scalability. In this sense, the present paper develops a novel thermoelectric application in order to supply power to volcanic monitoring stations, making them completely autonomous. These stations become indispensable in any volcano since they are able to predict eruptions. Nevertheless, they present energy supply difficulties due to the absence of power grid, the remote access, and the climatology. As a solution, this work has designed a new integral system composed of thermoelectric generators with high efficiency heat exchangers, and its associated electronics, developed thanks to Internet of Things (IoT) technologies. Thus, the heat emitted from volcanic fumaroles is transformed directly into electricity with thermoelectric generators with passive heat exchangers based on phase change, leading to a continuous generation without moving parts that powers different sensors, the information of which is emitted via LoRa. The viability of the solution has been demonstrated both at the laboratory and at a real volcano, Teide (Canary Islands, Spain), where a compact prototype has been installed in an 82 &deg, C fumarole. The results obtained during more than eight months of operation prove the robustness and durability of the developed generator, which has been in operation without maintenance and under several kinds of meteorological conditions, leading to an average generation of 0.49 W and a continuous emission over more than 14 km.

Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 ∘ C . Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 ∘ C . The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0 . 33 W per module given a temperature difference between the heat reservoirs encompassed in the 69&ndash, 86 ∘ C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.

One of the options to reduce industrial energy costs and the environmental impact is to recover the waste-heat produce in some processes. This paper proposes the use of thermoelectric generators at a stone wool manufacturing plant to transform waste-heat from a hot gas flow into useful electricity. A combination of two computational models, previously developed and validated, has been used to perform the optimization from a double point of view: power output and economic cost. The proposed thermoelectric generator includes fin dissipaters and biphasic thermosyphons as the hot and cold side heat exchangers respectively. The model takes into account the temperature drop along the duct where the gases flow, the electric consumption of the auxiliary equipment, and the configuration and geometry of the heat exchangers. After the simulations a maximum net power production of 45 838 W is achieved considering an occupancy ratio of 0.40 and a fin spacing of 10 mm. The installation cost is minimized to 10.6 €/W with an occupancy ratio of 0.24. Besides, the Levelised Cost of Electricity, LCOE, is estimated for a thermoelectric generator for the first time. It is necessary to use standar methodologies to compare this technology to others. The LCOE estimated for the proposed design is around 15 c€/kWh within the ranges of current energy sources, proving, in this way, the capabilities of waste-heat recovery from industrial processes at reasonable prices with thermoelectric generators. The authors are indebted to the Government of Navarre funds for economic support of this work, included in the 0011-1365-2018-000101 Research Project; and the Spanish Ministry of Economy and Competitiveness for the economic support thanks to the DPI2014-53158-R project.

Generally, in the optimization of thermoelectric generators, only the heat exchangers or the thermoelectric modules themselves are taken into account. However, the assembly of the generator as a whole is of vital importance since a bad contact or a thermal bridge can waste the performance of an optimal generator. In this sense, the present chapter analyzes experimentally the use of different interface materials to reduce the thermal contact resistance between the modules and the heat exchangers, the influence of the pressure distribution in the assembly as well as the effect of different insulating materials in order to reduce the thermal bridge between the exchangers. Thus, it has been demonstrated that a good assembly requires the implementation of thermal interface materials to ensure the microscopic contact between the heat exchangers and the modules, besides a uniform clamping pressure. Nevertheless, since this is normally achieved with screws, they represent a source of thermal bridges in conjunction with the small distance between the exchangers. In order to reduce heat losses due to thermal bridges, which can represent up to one-third of the incoming heat, an increment of the distance between the exchangers and the use of an insulator is recommended. The authors are indebted to the Ministry of Economy, Industry and CompetitivenessGovernment of Spain and FEDER Funds for economic support of this work, included in the DPI2014-53158-R Research Project, as well as to the FPU Program of the Spanish Ministry of Education, Culture and Sport (FPU16/05203).

Waste heat recovery can apply to a wide range of applications, from transportation, or industries to domestic appliances. Thermoelectric generation technology applied to those cases could produce electrical energy and thus improve their efficiency. A validated computational methodology, which simulates the behavior of any thermoelectric generator and calculates the energy consumption of the auxiliary equipment involved, has been used to determine the potential of waste heat harvesting. The usable energy, the net energy, generated has to be maximized, not only the thermoelectric generation has to be maximized, but also the consumption of the auxiliary equipment has to be minimized, or if possible eliminated. Heat exchangers with a liquid as the heat carrier procure high thermoelectric generations, as their thermal resistances are very low, nevertheless when the consumption of their auxiliary consumption is borne in mind, their use is not that promising. The optimal thermoelectric energy obtained from the flue gases of a real industry using these dissipation systems is 119 MWh/year, while the maximum net energy is 73 MWh/year due to the consumption of the auxiliary equipment. The latest scenario does not only represent a 40% reduction from the optimal thermoelectric generation but also a different optimal working point. The complete elimination of the auxiliary equipment using novel biphasic thermosyphons with free convection at the same application produces a net energy of 128 MWh/year. This novel dissipation technology presents an increase on the thermoelectric generation due to its low thermal resistances, but above all due to the elimination of the auxiliary consumption. The authors are indebted to the Spanish Ministry of Economy and Competitiveness for the economic support to this work, included in the DPI2014-53158-R research project.

An important issue in thermoelectric generators is the thermal design of the heat exchangers since it can improve their performance by increasing the heat absorbed or dissipated by the thermoelectric modules. Due to its several advantages, compared to conventional dissipation systems, a thermosyphon heat exchanger with phase change is proposed to be placed on the cold side of thermoelectric generators. Some of these advantages are: high heat-transfer rates; absence of moving parts and lack of auxiliary con- sumption (because fans or pumps are not required); and the fact that these systems are wickless. A com- putational model is developed to design and predict the behaviour of this heat exchangers. Furthermore, a prototype has been built and tested in order to demonstrate its performance and validate the compu- tational model. The model predicts the thermal resistance of the heat exchanger with a relative error in the interval [?8.09;7.83] in the 95% of the cases. Finally, the use of thermosyphons with phase change in thermoelectric generators has been studied in a waste-heat recovery application, stating that including them on the cold side of the generators improves the net thermoelectric production by 36% compared to that obtained with finned dissipators under forced convection. The authors are indebted to the Ministry of Economy, Industry and Competitiveness-Government of Spain and FEDER Funds for economic support of this work, included in the DPI2014-53158-R Research Project.

Waste heat generation has a widespread presence into daily applications, however, due to the low-temperature grade which presents, its exploitation with the most common technologies is complicated. Thermoelectricity presents the possibility of harvesting any temperature grade heat; besides it also includes many other advantages which make thermoelectric generators perfect for generating electric power from waste heat. A prototype divided into two levels along the chimney which uses the waste heat of a combustion has been built. The experimentation has been used to determine the parameters that influence the generation and to validate a generic computational model able to predict the thermoelectric generation of any application, but specially applications where waste heat is harvested. The temperature and mass flow of the flue gases and the load resistance determine the generation, and consequently, these parameters have been included into the model, among many others. This computational model incorporates all the elements included into the generators (heat exchangers, ceramics, unions) and all the thermoelectric phenomena and moreover, it takes into account the temperature loss of the flue gases while circulating along the thermoelectric generator. The built prototype presents a 65 % reduction in the generation of the two levels of the thermoelectric generator due to the temperature loss of the flue gases. The general computational model predicts the thermoelectric generation with an accuracy of the ±12 %. The authors are indebted to the Spanish Ministry of Economy and Competitiveness for the economic support to this work, included in the DPI2014-53158-R research project.