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We analyze the possibilities of orbital photopolarimetric measurements to study properties of aerosols in the Earth's atmosphere. As an example, we consider the case when such measurements are performed within a narrow spectral channel centered at 1.378 µm that allows to retrieve microphysical characteristics of stratospheric aerosols separately from those of tropospheric aerosols. We consider the case of stratospheric aerosols caused by volcanic eruption, and adopt the model of the stratosphere in the form of a homogeneous plane-parallel layer composed of polydisperse spherical particles. We use numerically exact solutions of the vector radiative transfer equation to theoretically simulate measurements carried out at various numbers of scattering angles, including: (i) radiance measurements alone; (ii) polarization measurements alone; and (iii) radiance and polarization measurements together. The results of computations show that the simultaneous use of radiance and polarization measurements at a sufficiently large number of scattering angles enables one to retrieve the optical thickness, effective radius, and refractive index of aerosols with adequate accuracy. We demonstrate how the accuracy of the derived values of the optical parameters of aerosols depends on the accuracy of measurements of the intensity and polarization of the reflected light, optical thickness of aerosol layer itself, effective radius of aerosols, width of the particle size distribution, and number of viewing angles.

A new method for modeling the radiative transfer in inhomogeneous three-dimensional media illuminated by a Gaussian beam is described. This approach, called the Spectral Spherical Harmonics Discrete Ordinate Method (SSHDOM), uses the Fourier expansion method to transform the three-dimensional radiative transfer into an one-dimensional equation in the spectral domain, and the Spherical Harmonics Discrete Ordinate Method (SHDOM) for its solution. Specifically, (i) the source function is represented in the spectral domain through a spherical harmonic expansion, (ii) the spectral one-dimensional radiative transfer equation is integrated along discrete ordinates through a spatial grid, and (iii) the solution method is based on the Picard iteration. Both SSHDOM and SHDOM algorithms are implemented in a common computer code.

In this paper, we present numerical methods for solving the phenomenological scalar radiative transfer equation for a discrete random medium illuminated by a Gaussian beam. These rely on the Fourier transform method for the horizontal variables and the discrete ordinate method with matrix exponential for solving the underlying one-dimensional radiative transfer equation in the wavenumber domain. The problem of a Gaussian beam at oblique and normal incidence, as well as, the searchlight problem are treated. A complete description of the methods and the numerical algorithms is provided.

In this paper we present the vector radiative transfer theory for a discrete random medium illuminated by a Gaussian beam. The analysis is based on a plane wave spectrum representation for a Gaussian beam and uses an approach developed previously for a discrete random medium illuminated by a plane electromagnetic wave. Specifically, we establish an integral representation for the coherent field, define an approximate coherent field that satisfies the differential equation fulfilled by the coherent field corresponding to a plane electromagnetic wave and matches the Gaussian beam at the interface of the particulate medium, and finally, derive the vector radiative transfer equation. For weakly focused Gaussian beams, the resulting equation is the traditional radiative transfer equation

The properties of a pencil of light as defined approximately in the geometric optics ray tracing method are investigated. The vector Kirchhoff integral is utilized to accurately compute the electromagnetic near field in and around the pencil of light with various beam base sizes, shapes, propagation directions and medium refractive indices. If a pencil of light has geometric mean cross section size of the order p times the wavelength, it can propagate independently to a distance p2 times the wavelength, where most of the beam energy diffuses out of the beam region. This is consistent with a statement that van de Hulst made in a classical text on light scattering. The electromagnetic near fields in the pencil of light are not uniform, have complicated patterns within short distances from the beam base, and the fields tend to converge to Fraunhofer diffraction fields far away from the base.

Since its inception in the mid-1960s, the T-matrix method has been one of the most versatile and efficient numerically exact computer solvers of the time-harmonic macroscopic Maxwell equations. It has been widely used for the computation of electromagnetic scattering by single and composite particles, discrete random media, periodic structures (including metamaterials), and particles in the vicinity of plane or rough interfaces separating media with different refractive indices. This compilation is the ninth update to the comprehensive thematic database of peer-reviewed T-matrix publications initiated in 2004 and lists relevant publications that have appeared since 2017. It also includes a few earlier publications that have so far been overlooked.

In this semi-tutorial paper, we revisit the interference phenomena caused by pairs of copropagating or counter-propagating transverse electromagnetic waves by letting the host medium be absorbing. We first consider plane waves in an unbounded medium, summarize the standingwave solution of the Maxwell equations, and discuss specific effects caused by nonvanishing absorption. We then consider the superposition of plane and spherical waves in the context of fartfield electromagnetic scattering by a particle. To this end we modify the classical Jones lemma by allowing nonzero absorption in the host medium and consider its most obvious consequences such as forward- and backscattering interference. The physical similarity of the two scenarios (superpositions of plane waves and superpositions of plane and spherical waves) is discussed.

A vector radiative transfer equation with an additional source term typical of dense media is obtained. The analysis includes (i) the derivation of an integral equation for the correlation matrix of the exciting field coefficients accounting for the correlation between the particles, (ii) the derivation of an integral representation for the specific coherency dyadicin terms of this matrix, and (iii) the simplification of the integral equation for the correlation matrix and of the integral representation for the specific coherency dyadic by employing a series of approximations which are characteristic of sparse media.

The problem of backscattering of light by a discrete random medium illuminated by an obliquely incident plane electromagnetic wave is considered.The analysis is performed in a linear-polarization basis and includes a complete derivation of the cross reflection matrix for a layer with densely and sparsely distributed particles, the design of an approximate method for computing the ladder and cross reflection matrices in the case of a semi-infinite medium with a sparse distribution of particles, the derivation of the relations between the elements of the ladder and cross reflection matrices in the exact backscattering direction for dense and sparse media, and the development of practical algorithms for solving the underlying integral equations by the method of Picard iterations and the discrete ordinate method. Simulation results for particles with large size parameters are also presented.

The computation of the coherent field in the case of a plane electromagnetic wave obliquely incident on a discrete random layer with non-scattering boundaries is addressed. For dense media, the analysis is based on a special-form solution for the conditional configuration-averaged exciting field coefficients, and is restricted to the computation of the so-called zeroth-order fields without a special treatment of the boundary regions. In this setting, we calculate the coherent fields reflected and transmitted by the layer, and the coherent field inside the layer. We found that these fields are analytically equivalent to plane electromagnetic waves, and investigated the fulfillment of the boundary conditions for the electric fields at the layer interfaces. The results are then particularized to the cases of normal incidence and a semi-infinite discrete random medium. For sparsely distributed particles, we present a self-consistent derivation of the coherent field and discuss the Twersky and Foldy approximations.

We consider the scattering of a plane electromagnetic wave obliquely incident on a plane-parallel layer of discrete random medium with non-scattering boundaries. We solve the Lax integral equation for the conditional configuration-averaged exciting field coefficients by assuming a special-form solution, that is, by representing the conditional configuration-averaged exciting field coefficients as a linear combination of the coefficients corresponding to an up-going and a down-going wave. This solution representation is supposed to be valid within the whole domain occupied by the particles, even in the close proximity of the boundaries. By balancing the waves with different propagation directions and wavenumbers we derive two homogeneous systems of equations corresponding to the generalized Lorenz–Lorentz law and two inhomogeneous systems of equations corresponding to the generalized Ewald–Oseen extinction theorem. It is shown that (i) the two homogeneous systems of equations of the generalized Lorenz–Lorentz law reduce to a single homogeneous system of equations corresponding to a semi-infinite discrete random medium at normal incidence; (ii) the dispersion equation is direction and polarization independent; and (iii) the two inhomogeneous systems of equations of the generalized Ewald–Oseen extinction theorem can be reduced to two scalar equations by means of the addition theorem for vector spherical harmonics. It is also shown that the same dispersion equation can be obtained without assuming a special-form solution representation in the proximity of the boundaries.

In this paper, the vector radiative transfer equation is derived by means of the vector integral Foldy equations describing the electromagnetic scattering by a group of particles. By assuming that in a discrete random medium the positions of the particles are statistically independent and by applying the Twersky approximation to the order-of-scattering expansion of the total field, we derive the Dyson equation for the coherent field and the ladder approximated Bethe–Salpeter equation for the dyadic correlation function. Then, under the far-field assumption for sparsely distributed particles, the Dyson equation is reduced to the Foldy integral equation for the coherent field, while the iterated solution of the Bethe–Salpeter equation ultimately yields the vector radiative transfer equation.

Our recent tutorial referred to in the title has summarized a general theoretical formalism of electromagnetic scattering by an arbitrary finite object in the presence of arbitrarily distributed impressed currents. This addendum builds on the tutorial to provide a streamlined discussion of specific far-field limits and the corresponding reciprocity relations by introducing appropriate far-field operators and linear maps and deriving the reciprocity relations through the pseudo adjoint of these maps. We thereby extend the compact operator calculus used previously to consider the fields and sources near or inside the scattering object.

For a macroscopically plane-parallel discrete random medium, the boundary conditions for the specific coherency dyadic at a rough interface are derived. The derivation is based on a modification of the Twersky approximation for a scattering system consisting of a group of particles and the rough surface, and reduces to the solution of the scattering problem for a rough surface illuminated by a plane electromagnetic wave propagating in a discrete random medium with non-scattering boundaries. In a matrix-form setting, the boundary conditions for the specific coherency dyadic imply the boundary conditions for specific intensity column vectors which in turn, yield the expressions for the reflection and transmission matrices. The derived expressions are shown to be identical to those obtained by applying a phenomenological approach based on a facet model to the solution of the scattering problem for a rough surface illuminated by a plane electromagnetic wave.

A recently developed FORTRAN program computing far-field optical observables for spherical particles in an absorbing medium has exhibited numerical instability arising when the product of the particle vacuum size parameter and the imaginary part of the refractive index of the host becomes sufficiently large. We offer a simple analytical explanation of this instability and propose a compact numerical algorithm for the stable computation of Lorenz–Mie coefficients based on an upward recursion formula for spherical Hankel functions of a complex argument. Extensive tests confirm an excellent accuracy of this algorithm approaching machine precision. The improved public-domain FORTRAN program is available at https://www.giss.nasa.gov/staff/mmishchenko/Lorenz-Mie.html.

Although free space cannot generate electromagnetic waves, the majority of existing accounts of frequency-domain electromagnetic scattering by particles and particle groups are based on the postulate of existence of an impressed incident field, usually in the form of a plane wave. In this tutorial we discuss how to account for the actual existence of impressed source currents rather than impressed incident fields. Specifically, we outline a self-consistent theoretical formalism describing electromagnetic scattering by an arbitrary finite object in the presence of arbitrarily distributed impressed currents, some of which can be far removed from the object and some can reside in its vicinity, including inside the object. To make the resulting formalism applicable to a wide range of scattering-object morphologies, we use the framework of the volume integral equation formulation of electromagnetic scattering, couple it with the notion of the transition operator, and exploit the fundamental symmetry property of this operator. Among novel results, this tutorial includes a streamlined proof of fundamental symmetry (reciprocity) relations, a simplified derivation of the Foldy equations, and an explicit analytical expression for the transition operator of a multi-component scattering object.

Many applications of electromagnetic scattering involve particles immersed in an absorbing rather than lossless medium, thereby making the conventional scattering theory potentially inapplicable. To analyze this issue quantitatively, we employ the FORTRAN program developed recently on the basis of the first-principles electromagnetic theory to study far-field scattering by spherical particles embedded in an absorbing infinite host medium. We further examine the phenomenon of negative extinction identified recently for monodisperse spheres and uncover additional evidence in favor of its interference origin. We identify the main effects of increasing the width of the size distribution on the ensemble-averaged extinction efficiency factor and show that negative extinction can be eradicated by averaging over a very narrow size distribution. We also analyze, for the first time, the effects of absorption inside the host medium and ensemble averaging on the phase function and other elements of the Stokes scattering matrix. It is shown in particular that increasing absorption significantly suppresses the interference structure and can result in a dramatic expansion of the areas of positive polarization. Furthermore, the phase functions computed for larger effective size parameters can develop a very deep minimum at side-scattering angles bracketed by a strong diffraction peak in the forward direction and a pronounced backscattering maximum.

We summarize unique aperture data on the degree of linear polarization observed for distant comets C/2010 S1, C/2010 R1, C/2011 KP36, C/2012 J1, C/2013 V4, and C/2014 A4 with heliocentric distances exceeding 3 AU. Observations have been carried out at the 6-m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences (Nizhnij Arkhyz, Russia) during the period from 2011 to 2016. The measured negative polarization proves to be significantly larger in absolute value than what is typically observed for comets close to the Sun. We compare the new observational data with the results of numerical modeling performed with the T-matrix and superposition T-matrix methods. In our computer simulations, we assume the cometary coma to be an optically thin cloud containing particles in the form of spheroids, fractal aggregates composed of spherical monomers, and mixtures of spheroids and aggregate particles. We obtain a good semi-quantitative agreement between all polarimetric data for the observed distant comets and the results of numerical modeling for the following models of the cometary dust: (i) a mixture of submicrometer water-ice oblate spheroids with aggregates composed of submicrometer silicate monomers; and (ii) a mixture of submicrometer water-ice oblate spheroids and aggregates consisting of both silicate and organic monomers. The microphysical parameters of these models are presented and discussed.

We use the superposition T-matrix method to compare the far-field scattering matrices generated by spheroidal and spherical volumes of discrete random medium having the same volume and populated by identical spherical particles. Our results fully confirm the robustness of the previously identified coherent and diffuse scattering regimes and associated optical phenomena exhibited by spherical particulate volumes and support their explanation in terms of the interference phenomenon coupled with the order-of-scattering expansion of the far-field Foldy equations. We also show that increasing non-sphericity of particulate volumes causes discernible (albeit less pronounced) optical effects in forward and backscattering directions and explain them in terms of the same interference/multiple-scattering phenomenon.

The majority of previous studies of the interaction of individual particles and multi-particle groups with electromagnetic field have focused on either elastic scattering in the presence of an external field or self-emission of electromagnetic radiation. In this paper we apply semi-classical fluctuational electrodynamics to address the ubiquitous scenario wherein a fixed particle or a fixed multi-particle group is exposed to an external quasi-polychromatic electromagnetic field as well as thermally emits its own electromagnetic radiation. We summarize the main relevant axioms of fluctuational electrodynamics, formulate in maximally rigorous mathematical terms the general scattering emission problem for a fixed object, and derive such fundamental corollaries as the scattering emission volume integral equation, the Lippmann Schwinger equation for the dyadic transition operator, the multi-particle scattering emission equations, and the far-field limit. We show that in the framework of fluctuational electrodynamics, the computation of the self-emitted component of the total field is completely separated from that of the elastically scattered field. The same is true of the computation of the emitted and elastically scattered components of quadratic linear forms in the total electromagnetic field. These results pave the way to the practical computation of relevant optical observables.

A discrete random medium is an object in the form of a finite volume of a vacuum or a homogeneous material medium filled with quasi-randomly and quasi-uniformly distributed discrete macroscopic impurities called small particles. Such objects are ubiquitous in natural and artificial environments. They are often characterized by analyzing theoretically the results of laboratory, in situ, or remote-sensing measurements of the scattering of light and other electromagnetic radiation. Electromagnetic scattering and absorption by particles can also affect the energy budget of a discrete random medium and hence various ambient physical and chemical processes. In either case electromagnetic scattering must be modeled in terms of appropriate optical observables, i.e., quadratic or bilinear forms in the field that quantify the reading of a relevant optical instrument or the electromagnetic energy budget. It is generally believed that time-harmonic Maxwell's equations can accurately describe elastic electromagnetic scattering by macroscopic particulate media that change in time much more slowly than the incident electromagnetic field. However, direct solutions of these equations for discrete random media had been impracticable until quite recently. This has led to a widespread use of various phenomenological approaches in situations when their very applicability can be questioned. Recently, however, a new branch of physical optics has emerged wherein electromagnetic scattering by discrete and discretely heterogeneous random media is modeled directly by using analytical or numerically exact computer solutions of the Maxwell equations. Therefore, the main objective of this Report is to formulate the general theoretical framework of electromagnetic scattering by discrete random media rooted in the Maxwell- Lorentz electromagnetics and discuss its immediate analytical and numerical consequences. Starting from the microscopic Maxwell-Lorentz equations, we trace the development of the first principles formalism enabling accurate calculations of monochromatic and quasi-monochromatic scattering by static and randomly varying multiparticle groups. We illustrate how this general framework can be coupled with state-of-the-art computer solvers of the Maxwell equations and applied to direct modeling of electromagnetic scattering by representative random multi-particle groups with arbitrary packing densities. This first-principles modeling yields general physical insights unavailable with phenomenological approaches. We discuss how the first-order-scattering approximation, the radiative transfer theory, and the theory of weak localization of electromagnetic waves can be derived as immediate corollaries of the Maxwell equations for very specific and well-defined kinds of particulate medium. These recent developments confirm the mesoscopic origin of the radiative transfer, weak localization, and effective-medium regimes and help evaluate the numerical accuracy of widely used approximate modeling methodologies.

The effective-medium approximation (EMA) is based on the assumption that a heterogeneous particle can have a homogeneous counterpart possessing similar scattering and absorption properties. We analyze the numerical accuracy of the EMA by comparing superposition T-matrix computations for spherical aerosol particles filled with numerous randomly distributed small inclusions and Lorenz-Mie computations based on the Maxwell-Garnett mixing rule. We verify numerically that the EMA can indeed be realized for inclusion size parameters smaller than a threshold value. The threshold size parameter depends on the refractive-index contrast between the host and inclusion materials and quite often does not exceed several tenths, especially in calculations of the scattering matrix and the absorption cross section. As the inclusion size parameter approaches the threshold value, the scattering-matrix errors of the EMA start to grow with increasing the host size parameter and or the number of inclusions. We confirm, in particular, the existence of the effective-medium regime in the important case of dust aerosols with hematite or air-bubble inclusions, but then the large refractive-index contrast necessitates inclusion size parameters of the order of a few tenths. Irrespective of the highly restricted conditions of applicability of the EMA, our results provide further evidence that the effective-medium regime must be a direct corollary of the macroscopic Maxwell equations under specific assumptions.

We use the recently generalized version of the multi-sphere superposition T-matrix method (STMM) to compute the scattering and absorption properties of microscopic water droplets contaminated by black carbon. The soot material is assumed to be randomly distributed throughout the droplet interior in the form of numerous small spherical inclusions. Our numerically-exact STMM results are compared with approximate ones obtained using the Maxwell-Garnett effective-medium approximation (MGA) and the Monte Carlo ray-tracing approximation (MCRTA). We show that the popular MGA can be used to calculate the droplet optical cross sections, single-scattering albedo, and asymmetry parameter provided that the soot inclusions are quasi-uniformly distributed throughout the droplet interior, but can fail in computations of the elements of the scattering matrix depending on the volume fraction of soot inclusions. The integral radiative characteristics computed with the MCRTA can deviate more significantly from their exact STMM counterparts, while accurate MCRTA computations of the phase function require droplet size parameters substantially exceeding 60.

The 15th Electromagnetic and Light Scattering Conference (ELS-XV) was held in Leipzig, Germany from 21 to 26 of June 2015. This conference built on the great success of the previous meetings held in Amsterdam (1995), Helsinki(1997) [2], New York City(1998) [3], Vigo (1999),Halifax (2000), Gainesville (2002), Bremen (2003), Salobreña (2005), St. Petersburg (2006), Bodrum (2007), Hatfield (2008), Helsinki (2010), Taormina (2011), and Lille as well as the workshops held in Bremen (1996,1998) and Moscow (1997). As usual, the main objective of this conference was to bring together scientists, engineers, and PhD students studying various aspects of electromagnetic scattering and to provide a relaxed atmosphere for in-depth discussion of theory, measurements, and applications. Furthermore, ELS-XV supported the United Nations "Year of Light" and celebrated the150th anniversary of Maxwell's electromagnetics. Maxwell's paper on "A Dynamical Theory of the Electromagnetic Field" was published in1865 and has widely been acknowledged as one of the supreme achievements in the history of science. The conference was attended by136 scientists from 22 countries. The scientific program included two plenary lectures, 16 invited reviews, 88 contributed oral talks, and 70 poster presentations. The program and the abstracts of conference presentations are available at the conference website http://www.els-xv-2015.net/home.html. Following the well-established ELS practice and with Elsevier's encouragement, we solicited full-size papers for a topical issue of the Journal of Quantitative Spectroscopy and Radiative Transfer (JQSRT). The result of this collective effort is now in the reader's hands. As always, every invited review and regular paper included in this topical issue has undergone the same rigorous peer review process as any other manuscript published in the JQSRT.

The T-matrix method is one of the most versatile and efficient direct computer solvers of the macroscopic Maxwell equations and is widely used for the computation of electromagnetic scattering by single and composite particles, discrete random media, and particles in the vicinity of an interface separating two half-spaces with different refractive indices. This paper is the seventh update to the comprehensive thematic database of peer-reviewed T-matrix publications initiated by us in 2004 and includes relevant publications that have appeared since 2013. It also lists a number of earlier publications overlooked previously.

We describe a simple yet efficient numerical algorithm for computing polarized bidirectional reflectance of an optically thick (semi-infinite), macroscopically flat layer composed of statistically isotropic and mirror symmetric random particles. The spatial distribution of the particles is assumed to be sparse, random, and statistically uniform. The 44 Stokes reflection matrix is calculated by iterating the Ambartsumian's vector nonlinear integral equation. The result is a numerically exact solution of the vector radiative transfer equation and as such fully satisfies the energy conservation law and the fundamental reciprocity relation. Since this technique bypasses the computation of the internal radiation field, it is very fast and highly accurate. The FORTRAN implementation of the technique is publicly available on the World Wide Web at http://www.giss.nasa.gov/staff/ mmishchenko/brf. It can be combined with several existing computer programs providing the requisite single-scattering properties of spherical or morphologically complex particles and applied to a wide range of optical characterization problems. Benchmark results obtained with this program can be used for testing alternative solvers of the vector radiative transfer equation.

Increasing our understanding of the Earth-atmosphere system has been a scientific and political priority for the last few decades. This system not only touches on environmental science, but it has applicability to our broader understanding of planetary atmospheres in general. While this issue focuses primarily on electromagnetics, other fundamental fields of science, including fluid and thermodynamics play major roles. In recent years, significant research efforts have led to advances in the fields of radiative transfer and electromagnetic scattering from irregularly shaped particles. Recently, several workshops and small conferences have taken place to promote the fusion of these efforts. Late in 2013, for instance, two such meetings took place. The Optical Characterization of Atmospheric Aerosols (OCAA) meeting took place in Smolenice, Slovakia to promote a better understanding of microphysical properties of aerosol particles, and the characterization of such atmospheric particles using optical techniques. A complementary conference was organized in Nagoya, Japan, the 3rd International Symposium on Atmospheric Light Scattering and Remote Sensing (ISALSaRS), whose goal is to fuse the advances achieved in particle characterization with remote-sensing techniques. While the focus of these meetings is slightly different, they represent the same aspects of this rapidly growing field. This Topical Issue is the first of two parts. Within this issue we analyze different aspects of the problem of atmospheric characterization and present a broad overview of the topical area. Research includes theory and experiment, ranging from fundamental microphysical properties of individual aerosol particles to broad characterizations of atmospheric properties. Since this is an active field, we also have encouraged the submission of ideas for new methodologies that may represent the future of the field.