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The lithium metal-solid-state electrolyte interface plays a critical role in the performance of solid-state batteries. However, operando characterization of the buried interface morphology in solid-state cells is particularly difficult because of the lack of direct optical access. Destructive techniques that require isolating the interface inadvertently modify the interface and cannot be used for operando monitoring. In this work, we introduce the concept of thermal wave sensing using modified 3ω sensors that are attached to the outside of the lithium metal-solid-state cells to noninvasively probe the morphology of the lithium metal-electrolyte interface. We show that the thermal interface resistance measured by the 3ω sensors relates directly to the physical morphology of the interface and demonstrates that 3ω thermal wave sensing can be used for noninvasive operando monitoring the morphology evolution of the lithium metal-solid-state electrolyte interface.

Metal-supported solid oxide electrolysis cells (MS-SOECs) are being developed for steam-to-hydrogen electrolysis, especially for utilization of dynamic or intermittent electrical power from renewable sources. Various aspects of the electrocatalyst processing and composition, and metal support structure were explored. Catalyst materials, infiltration temperature and infiltration cycles were optimized for high performance and durability. Numerous catalyst materials were screened for both oxygen and steam electrodes. The oxygen catalyst had moderate impact on both initial cell performance and durability. Reducing Ni content in the steam electrode had little effect on durability, but reduced initial performance. Ex-situ XRD analysis and cell assessment of catalyst infiltration temperature revealed that the optimal range is 750–850 °C. The best cell performance and durability was achieved with LSCF-SDC oxygen electrocatalyst and SDC-Ni (60:40 vol%) steam electrocatalyst infiltrated 11 times at 800 °C and operated at 700 °C. At low steam content, a significant mass transport limitation on the steam side results in limiting current behavior. Thinner and more porous metal supports were implemented, and found to improve steam mass transport at low steam content, relevant for SOECs operating under high H2 recycle rate or high steam utilization.

Green hydrogen is essential to achieving carbon neutrality, and solid oxide electrolysis cells can produce hydrogen using renewable power and waste heat. Insufficient long-term durability of solid oxide electrolysis cells has impeded their commercialization. Here, coatings in the porous stainless steel support of metal-supported solid oxide electrolysis cells (MS-SOECs) are used to dramatically improve their performance and durability. The long-term degradation rate of uncoated MS-SOECs is highly dependent on the current density, with the fastest degradation occurring at the highest current density tested, 0.5 A cm-2. At this current density, coatings are quite effective. Three protective coatings, Co3O4deposited by atomic layer deposition (ALD), Co3O4deposited by electroplating deposition (ED), and CuMn1.8O4(CMO) deposited by electrophoretic deposition (EPD), are explored to enhance the performance of MS-SOECs with La0.6Sr0.4Co0.2Fe0.8O3-Sm0.2Ce0.8O3(LSCF-SDC) as the oxygen catalyst and SDC-Ni as the fuel catalyst. The initial average current density at 1.4 V is increased with coatings. It is 0.83 mA cm-2for the ALD cells, 1.05 mA cm-2for the ED cells, and 1.13 mA cm-2for the EPD cells, compared to 0.65 mA cm-2for the bare cells at 700 °C with 50% H2-50% H2O. The degradation rate over 1000 h of continuous operation is reduced from 36% to 26%, 27%, and 19% kh-1with the three coatings, respectively. These improvements are ascribed to reduced Cr poisoning on the oxygen catalyst, which is one of the primary degradation modes for this type of MS-SOEC.

Revealing the local structure of solid electrolytes (SEs) with electron microscopy is critical for the fundamental understanding of the performance of solid-state batteries (SSBs). However, the intrinsic structural information in the SSB can be misleading if the sample’s interactions with the electron beams are not fully understood. In this work, we systematically investigate the effect of electron beams on Al-doped lithium lanthanum zirconium oxide (LLZO) under different imaging conditions. Li metal is observed to grow directly on the clean surface of LLZO. The Li metal growth kinetics and the morphology obtained are found to be heavily influenced by the temperature, accelerating voltage, and electron beam intensity. We prove that the lithium growth is due to the LLZO delithiation activated by a positive charging effect under electron beam emission. Our results deepen the understanding of the electron beam impact on SEs and provide guidance for battery material characterization using electron microscopy.

The performance, long-term durability, and thermal cycling tolerance of metal supported solid oxide fuel cells (MS-SOFCs) operating with natural gas reformate fuels is assessed. Symmetric MS-SOFCs with composite SDC-Ni anode catalysts and PrOx cathode catalysts are operated with simulated natural gas steam-reformate and partial-oxidation-reformate fuels with 1 ppm and 5 ppm of sulfur. Cells are operated for 1000 h with initial degradation rates similar to humidified H2, and initial performance differences attributed to the lower H2 concentration in reformate fuels. Additionally, cells tolerate many aggressive thermal cycles with sulfur present, with minimal impact on performance. Post mortem analysis suggests that Ni particle coarsening and Cr deposition are sources of degradation, while carbon and sulfur deposition are not observed. Overall, MS-SOFCs operate successfully with reformed natural gas.

Performance of symmetric-architecture metal-supported solid oxide fuel cells was improved significantly by optimizing the catalyst infiltration process and metal support structure. Optimization of component structure and processing parameters was performed during tape-casting and fabrication of button cells. Mass transport of oxygen in the metal support was identified as a major limitation. To overcome this limitation, pore former loading and thickness of the metal support (130–250 μm) were optimized. The catalyst infiltration process was also improved by studying the impact of firing temperature (400 °C–900 °C) and infiltration cycle numbers (1–15). The maximum power density of the optimized cell was 0.9 W cm−2 at 700 °C using hydrogen as a fuel, a three-fold increase over the baseline cell performance. The degradation rate of optimized cells at 550 °C, 600 °C, and 700 °C was 2%, 4.5%, and 5.5% per 100 h, respectively. The phenomena of mass transport, catalyst coarsening, and chromium poisoning on the catalyst were analyzed by electrochemical impedance spectroscopy and scanning electron microscopy.

All-solid-state batteries (ASSBs) are attractive due to their safety, use of the Li metal anode, high energy density, and innovative processing routes. However, high interfacial resistance, especially on the cathode side, is one of the major challenges for commercialization of ASSBs. Catholyte, either a liquid or solid, is added to lower the cathode/electrolyte interfacial resistance. In this study, we find that residual N-methylpyrrolidone solvent remaining in a PVDF/LiTFSI solid polymer catholyte after incomplete drying can dramatically lower the interfacial resistance between the Li6.25Al0.25La3Zr2O12 electrolyte and LiNi1/3Mn1/3Co1/3O2 cathode-active material. Cells with varying amounts of residual solvent are compared to optimize the residual solvent loading. With moderate residual solvent, the discharge capacity reaches 142 mA h g−1 when cycled at 25 °C and 0.5 C and the capacity retention is 60.5% after 125 cycles. Discharge capacity retention is improved at −10 °C. The conductivity of the free-standing PVDF/LiTFSI film, mimicking the PVDF/LiTFSI catholyte, verifies the role of residual NMP in the cathode. This study demonstrates the possibility of widely differing results for ASSBs when the cathode is not completely dried. Also, it provides a hint for a potential method to lower the cathode/electrolyte interfacial resistance.

Metal-supported solid oxide cells with P434L stainless steel support and BZCYYb-4411 electrode backbone and electrolyte layers are fabricated. Sintering aids for the ceramic layer are optimized. LiF is found to lower the ceramic sintering temperature too much. Manganese oxide enhances sintering and densification without dramatically reducing the sintering onset temperature. The impact of metal particle size on sintering is assessed. A symmetric structure helps to prevent warping or cracking arising from residual mis-match between the metal and ceramic sintering shrinkage. Intact cell structures are successfully prepared with

We present the third discovery from the COol Companions ON Ultrawide orbiTS (COCONUTS) program, the COCONUTS-3 system, composed of a young M5 primary star UCAC4 374-046899 and a very red L6 dwarf WISEA J081322.19$-$152203.2. These two objects have a projected separation of 61$''$ (1891 au) and are physically associated given their common proper motions and estimated distances. The primary star, COCONUTS-3A, has a mass of $0.123\pm0.006$ M$_{\odot}$ and we estimate its age as 100 Myr to 1 Gyr based on its kinematics and spectrophotometric properties. We derive its metallicity as $0.21 \pm 0.07$ dex using empirical calibrations established by older higher-gravity M dwarfs and find this [Fe/H] could be slightly underestimated according to PHOENIX models given COCONUTS-3A's younger age. The companion, COCONUTS-3B, has a near-infrared spectral type of L6$\pm$1 INT-G, and we infer physical properties of $T_{\rm eff} = 1362^{+48}_{-73}$ K, $\log{(g)}= 4.96^{+0.15}_{-0.34}$ dex, $R = 1.03^{+0.12}_{-0.06}$ R$_{\rm Jup}$, and $M = 39^{+11}_{-18}$ M$_{\rm Jup}$, using its bolometric luminosity, its host star's age, and hot-start evolution models. We construct cloudy atmospheric model spectra at the evolution-based physical parameters and compare them to COCONUTS-3B's spectrophotometry. We find this companion possesses ample condensate clouds in its photosphere with the data-model discrepancies likely due to the models using an older version of the opacity database. Compared to field-age L6 dwarfs, COCONUTS-3B has fainter absolute magnitudes and a 120 K cooler $T_{\rm eff}$. Also, the J-K color of this companion is among the reddest for ultracool benchmarks with ages older than a few 100 Myr. COCONUTS-3 likely formed in the same fashion as stellar binaries given the companion-to-host mass ratio of 0.3 and represents a valuable benchmark to quantify the systematics of substellar model atmospheres., Accepted by ApJ. 34 pages including 14 figures and 5 tables

Mixed transition-metal oxide coatings are commonly applied to stainless steel interconnects for solid oxide cell stacks. Such coatings reduce oxidation and Cr evaporation rates, leading to improved degradation rate and stack lifetime. Here, the ChromLok™ MCO-based composition (Mn,Co)3O4 is applied to Crofer 22 APU stainless steel and evaluated specifically for application in solid oxide electrolyzer stacks operating around 800 °C and utilizing oxygen-ion-conducting solid oxide cells. The MCO coating is found to decrease the stainless steel oxidation rate by about one order of magnitude, and decrease the Cr evaporation rate by fourfold. The coating also dramatically lowers the rate of area-specific resistance increase for stainless steel coupons oxidized for 500 h with constant current applied, from 33 mΩ∗cm2 kh−1 for an uncoated coupon to less than 4 mΩ∗cm2 kh−1 for coated coupons. The coating is demonstrated on full-scale interconnects for single-cells, where the coating dramatically reduces degradation rate, and for a stack, which displays stable operation for 700 h.

[Image: see text] Herein we describe our efforts using a late stage functionalization together with more traditional synthetic approaches to generate fluorinated analogues of the clinical candidate AZD9833. The effects of the addition of fluorine on the lipophilicity, permeability, and metabolism are discussed. Many of these changes were tolerated in terms of pharmacology and resulted in high quality molecules which reached advanced stages of profiling in the testing cascade.

We present the discovery of ASASSN-18jd (AT 2018bcb), a luminous optical/UV/X-ray transient located in the nucleus of the galaxy 2MASX J22434289--1659083 at $z=0.1192$. Over the year after discovery, Swift UVOT photometry shows the UV SED of the transient to be well modeled by a slowly shrinking blackbody with temperature $T \sim 2.5 \times 10^{4} \rm ~K$, a maximum observed luminosity of $L_\text{max} = 4.5^{+0.6}_{-0.3} \times 10^{44} \rm ~erg ~s^{-1}$, and a radiated energy of $E = 9.6^{+1.1}_{-0.6} \times 10^{51} \rm ~erg$. X-ray data from Swift XRT and XMM-Newton show a transient, variable X-ray flux with blackbody and power-law components that fade by nearly an order of magnitude over the following year. Optical spectra show strong, roughly constant broad Balmer emission as well as transient features attributable to He II, N III-V, O III, and coronal Fe. While ASASSN-18jd shares similarities with Tidal Disruption Events (TDEs), it is also similar to the newly-discovered nuclear transients seen in quiescent galaxies and faint Active Galactic Nuclei (AGNs)., 24 pages, 16 figures, 2 machine-readable tables (included as ancillary txt files)

We present the discovery that ATLAS18mlw was a tidal disruption event (TDE) in the galaxy WISEA J073544.83+663717.3, at a distance of 334 Mpc. Initially discovered by the Asteroid Terrestrial Impact Last Alert System (ATLAS) on 2018 March 17.3, the TDE nature of the transient was uncovered only recently with the re-reduction of a SuperNova Integral Field Spectrograph (SNIFS) spectrum. This spectrum, taken by the Spectral Classification of Astronomical Transients (SCAT) survey, shows a strong blue continuum and a broad H$\alpha$ emission line. Here we present roughly six years of optical survey photometry beginning before the TDE to constrain AGN activity, optical spectroscopy of the transient, and a detailed study of the host galaxy properties through analysis of archival photometry and a host spectrum. ATLAS18mlw was detected in ground-based light curves for roughly two months. From a blackbody fit to the transient spectrum and bolometric correction of the optical light curve, we conclude that ATLAS18mlw is likely a low-luminosity TDE with a peak luminosity of log(L [erg s$^{-1}$]) = $43.5 \pm 0.2$. The TDE classification is further supported by the quiescent Balmer strong nature of the host galaxy. We also calculated the TDE decline rate from the bolometric light curve and find $\Delta L_{40} = -0.7 \pm 0.2$ dex, making ATLAS18mlw a member of the growing class of "faint and fast" TDEs with low peak luminosities and fast decline rates., Comment: 14 pages, 6 figures, 1 table. Will be submitted to AAS journals. Comments welcome

Author(s): Shen, F; Jonson, RA; Parkinson, DY; Tucker, MC | Abstract: Solid-state lithium batteries are promising for safety and energy density compared with traditional lithium-ion batteries. However, the large interfacial resistance between the electrode and electrolyte is a bottleneck to achieving high-performance solid-state batteries. Engineered electrode structures with a porous scaffold of the solid electrolyte material are promising to lower the interfacial resistance and provide a mechanical support for a thin solid electrolyte layer. In this work, two ceramic processing techniques are used to fabricate porous/dense bilayer architectures based on a Li6.25Al0.25La3Zr2O12 (LLZO) Li-garnet material. Finger-like vertically aligned pores are created by the phase inversion (PI) process. A water bath presaturated with Li salt prevents Li loss during the PI solvent exchange step. Pore size and porosity can be optimized by adjusting the bath temperature. The high shear compaction process was used to prepare LLZO tapes with 40, 60, and 80nvol% poreformer. The porosity of the tapes after sintering is 39.5%, 58.4%, and 75.4%, respectively. Microtomography exhibits the porosity, pore shape, and pore distribution of the tapes. A typical cathode material LiNi0.33Mn0.33Co0.33O2n(NMC) is filled into the pores via vacuum infiltration, and a dense cathode layer is formed within the garnet scaffold.

We place statistical constraints on Type Ia supernova (SN Ia) progenitors using 227 nebular phase spectra of 111 SNe Ia. We find no evidence of stripped companion emission in any of the nebular phase spectra. Upper limits are placed on the amount of mass that could go undetected in each spectrum using recent hydrodynamic simulations. With these null detections, we place an observational $3\sigma$ upper limit on the fraction of SNe Ia that are produced through the classical H-rich non-degenerate companion scenario of < 5.5%. Additionally, we set a tentative $3\sigma$ upper limit on He star progenitor scenarios of < 6.4%, although further theoretical modelling is required. These limits refer to our most representative sample including normal, 91bg-like, 91T-like, and "Super Chandrasekhar" \sne but excluding SNe Iax and SNe Ia-CSM. As part of our analysis, we also derive a Nebular Phase Phillips Relation, which approximates the brightness of a SN Ia from $150-500$~days after maximum using the peak magnitude and decline rate parameter $\Delta m_{15} (B)$., Comment: 18 pages, 8 figures, and 3 tables in main text, plus 3 pages of appendices with 1 figure and 7 tables. Accepted by MNRAS

We present the first results of our ongoing project conducting simultaneous multiwavelength observations of flares on nearby active M dwarfs. We acquired data of the nearby dM3.5e star EV Lac using 5 different observatories: NASA's Transiting Exoplanet Survey Satellite (TESS), NASA's Neil Gehrels Swift Observatory (\textit{Swift}), NASA's Neutron Interior Composition Explorer (NICER), the University of Hawaii 2.2-m telescope (UH88) and the Las Cumbres Observatory Global Telescope (LCOGT) Network. During the $\sim$25 days of TESS observations, we acquired three simultaneous UV/X-ray observations using \textit{Swift} that total $\sim$18 ks, 21 simultaneous epochs totaling $\sim$98 ks of X-ray data using NICER, one observation ($\sim$ 3 hours) with UH88, and one observation ($\sim$ 3 hours) with LCOGT. We identified 56 flares in the TESS light curve with estimated energies in the range log $E_{\rm T}$ (erg) = (30.5 - 33.2), nine flares in the \textit{Swift} UVM2 light curve with estimated energies in the range log $E_{UV}$ (erg) = (29.3 - 31.1), 14 flares in the NICER light curve with estimated minimum energies in the range log $E_{N}$ (erg) = (30.5 - 32.3), and 1 flare in the LCOGT light curve with log $E_{L}$ (erg) = 31.6. We find that the flare frequency distributions (FFDs) of TESS and NICER flares have comparable slopes, $\beta_{T}$ = -0.67$\pm$0.09 and $\beta_{N}$ = -0.65$\pm$0.19, and the FFD of UVOT flares has a shallower slope ($\beta_{U}$ = -0.38$\pm$0.13). Furthermore, we do not find conclusive evidence for either the first ionization potential (FIP) or the inverse FIP effect during coronal flares on EV Lac., Comment: 28 pages, 16 Figures, Accepted for publication in the Astrophysical Journal

Protonic ceramic fuel or electrolysis cells (PCFC/PCEC) have shown promising performance at intermediate temperatures. However, these technologies have not yet been demonstrated in a stack, hence the oxidation behavior of the metallic interconnect under relevant operating environments is unknown. In this work, ferritic stainless steels 430 SS, 441 SS, and Crofer 22 APU were investigated for their use as interconnect materials in the PCFC/PCEC stack. The bare metal sheets were exposed to a humidified air environment in the temperature range from 450 °C to 650 °C, to simulate their application in a PCFC cathode or PCEC anode. Breakaway oxidation with rapid weight gain and Fe outward diffusion/oxidation was observed on all the selected stainless steel materials. A protective coating is deemed necessary to prevent the metallic interconnect from oxidizing. To mitigate the observed breakaway oxidation, state-of-the-art protective coatings, Y2O3, Ce0.02Mn1.49Co1.49O4, CuMn1.8O4 and Ce/Co, were applied to the stainless steel sheets and their oxidation resistance was investigated. Dual atmosphere testing further validated the effectiveness of the protective coatings in realistic PCFC/PCEC environments, with a hydrogen gradient across the interconnect. Several combinations of metal and coating material were found to be viable for use as the interconnect for PCFC/PCEC stacks.

The LBNL metal-supported solid oxide cell architecture contains zirconia electrolyte and porous backbones co-sintered between porous stainless steel supports. Advantages of this design include low-cost structural materials, mechanical ruggedness, excellent tolerance to redox cycling, and extremely fast start-up capability. With infiltrated catalysts, high performance is also achieved: 1.5 W/cm2 with hydrogen fuel and 1.3 W/cm2 with internal reforming of ethanol fuel at 700 °C; 2.6 A/cm2 electrolysis current density at 1.3V and 50% steam/50% hydrogen at 700°C. Recent approaches to mitigating catalyst coarsening and Cr deposition within the cathode stabilize the microstructure during operation. The degradation rate is improved to 2.3% kh-1 at 700°C in fuel cell mode. Electrolysis operation, however, results in higher degradation rate. Preliminary effort to fabricate metal-supported cells with proton conducting electrolyte is successful for La0.99Ca0.01NbO4 electrolyte, and specific challenges for BaZr0.7Ce0.2Y0.1O3-δ electrolyte are determined.

Author(s): Schuler, T; Chowdhury, A; Freiberg, AT; Sneed, B; Spingler, FB; Tucker, MC; More, KL; Radke, CJ; Weber, AZ | Abstract: Significant mass-transport resistances in polymer-electrolyte-fuel-cell catalyst layers (CLs) impose a lower limit on Pt-loading levels, hindering wide-spread fuel-cell commercialization. The origin of this resistance remains unclear. Minimization of CL mass-transport resistance is imperative to achieve better CL design and performance. In this paper, an operando method based on H2 limiting current is used to characterize and quantify CL resistance in traditional porous Pt/carbon-based electrodes. CL sub-resistances are isolated using continuum multiscale modeling and experiments, investigating the effects of reactant molecular weight, pressure, and ionomer to carbon weight ratio. The results expose CL resistance including both interfacial and transport components, although the majority of the CL resistance is ascribed to a local resistance close to the Pt reaction sites, which includes interfacial resistance and local transport resistance. Variations in temperature, humidity, and primary particle loading (Pt:C ratio) highlight the impact of operating conditions and CL design parameters on CL sub-resistances. The observed trends guide optimization of CL design to achieve novel low-loaded fuel-cell electrodes.

High power density is required to commercialize solid oxide fuel cells for vehicular applications. In this work, high performance of metal supported solid oxide fuel cells (MS-SOFCs) is achieved via catalyst composition, electrode structure, and processing optimization. The full cell configuration consists of a dense ceramic electrolyte and porous ceramic backbones (electrodes) sandwiched between porous stainless steel metal supports. The conventional YSZ electrolyte and backbones are replaced with more conductive and thinner 10Sc1CeSZ ceramics. MS-SOFCs are co-sintered in a single step and subsequently infiltrated with nanocatalysts. Five categories of cathode catalysts are screened in full cells, including: perovskites, nickelates, praseodymium oxide, binary layered composites, and ternary layered composites. Various anode compositions are also tested. The conventional LSM cathode catalyst is replaced with more active Pr6O11 and the Ni content of the SDC-Ni anode is increased. The resulting cells achieve a peak power of 1.56, 2.0, and 2.85 W cm−2 at 700, 750, and 800 °C, respectively, with 3%H2O/H2 as fuel and cathode exposed to air. Multiple cells show reproducible performance (Pmax = 1.50 ± 0.06 W cm−2) and OCV (1.10 ± 0.02 V). The performance is further increased with cathode exposed to pure oxygen (2.0 W cm−2 at 700 °C).

The aim of this article is to gather 9 thought leaders and their team members to present their ideas about the future of in vitro fertilization and the andrology laboratory. Although we have seen much progress and innovation in the laboratory over the years, there is still much to come, and this article looks at what these leaders think will be important in the future development of technology and processes in the laboratory.

ASASSN-14ko is a recently discovered periodically flaring transient at the center of the AGN ESO 253-G003 with a slowly decreasing period. Here we show that the flares originate from the northern, brighter nucleus in this dual-AGN, post-merger system. The light curves for the two flares that occurred in May 2020 and September 2020 are nearly identical over all wavelengths. For both events, Swift observations showed that the UV and optical wavelengths brightened in unison. The effective temperature of the UV/optical emission rises and falls with the increase and subsequent decline in the luminosity. The X-ray flux, in contrast, first rapidly drops over $\sim$2.6 days, rises for $\sim$5.8 days, drops again over $\sim$4.3 days and then recovers. The X-ray spectral evolution of the two flares differ, however. During the May 2020 peak the spectrum softened with increases in the X-ray luminosity, while we observed the reverse for the September 2020 peak., 12 pages, 6 figures, and 1 table. Submitted to ApJ, comments welcome

Author(s): Dogdibegovic, E; Fukuyama, Y; Tucker, MC | Abstract: The authors regret that a technical mistake has been discovered, which impacts the current density and power density reported in this article. Briefly, the mistake was caused by catalyst solution leaking out of the intended 1 cm2 catalyzed area and depositing catalyst over the whole cell. As a result, the calculated current and power densities (total divided by the catalyzed area) were higher than reality because the measured current and power were dividing by the intended 1 cm2 instead of the actual area including the leakage, which was approximately 5 cm2. This issue is presented, analysed, and discussed in further detail in the supporting information of Reference 1. The authors would like to apologise for any inconvenience caused.

Metal-supported solid oxide fuel cells with symmetric architecture, having metal supports on both sides of the cell, are scaled up from button cell size to large 50 cm2 active area cell size. The cells remain flat after sintering assisted by the symmetric structure. Equivalent performance is achieved for button cells and large cells, and thermal cycling and redox cycling tolerance are demonstrated for the large cells. The catalyst infiltration process is improved to enable high-throughput manufacturing. The cumbersome lab-scale molten nitrate infiltration process is replaced with a room-temperature process in which a shelf-stable aqueous solution of nitrate salts is applied to the cell by spraying, painting, or other scalable techniques. A fast-ramp thermal conversion of the nitrate salts to the final oxide catalyst composition is implemented, allowing many infiltration cycles to be accomplished in a single work shift. Increasing the number of infiltration cycles from 5 to 10 led to an increase in peak power density from approximately 0.3 to 0.52 W cm−2.

We present observations of the extremely luminous but ambiguous nuclear transient (ANT) ASASSN-17jz, spanning roughly 1200 days of the object's evolution. ASASSN-17jz was discovered by the All-Sky Automated Survey for Supernovae (ASAS-SN) in the galaxy SDSS J171955.84+414049.4 on UT 2017 July 27 at a redshift of $z=0.1641$. The transient peaked at an absolute $B$-band magnitude of $M_{B,{\rm peak}}=-22.81$, corresponding to a bolometric luminosity of $L_{\rm bol,peak}=8.3\times10^{44}$~erg~s$^{-1}$, and exhibited late-time ultraviolet emission that was still ongoing in our latest observations. Integrating the full light curve gives a total emitted energy of $E_{\rm tot}=(1.36\pm0.08)\times10^{52}$~erg, with $(0.80\pm0.02)\times10^{52}$~erg of this emitted within 200 days of peak light. This late-time ultraviolet emission is accompanied by increasing X-ray emission that becomes softer as it brightens. ASASSN-17jz exhibited a large number of spectral emission lines most commonly seen in active galactic nuclei (AGNs) with little evidence of evolution. It also showed transient Balmer features which became fainter and broader over time, and are still being detected $>1000$ days after peak brightness. We consider various physical scenarios for the origin of the transient, including supernovae (SNe), tidal disruption events (TDEs), AGN outbursts, and ANTs. We find that the most likely explanation is that ASASSN-17jz was an SN~IIn occurring in or near the disk of an existing AGN, and that the late-time emission is caused by the AGN transitioning to a more active state., 35 pages, 20 figures, 10 tables. Submitted to ApJ. A machine-readable table containing the host-subtracted photometry presented in this manuscript is included as an ancillary file. Updated with edits in response to reviewer's comments and to include additional authors

We present Multi-Unit Spectroscopic Explorer (MUSE) integral-field spectroscopy of ESO 253-G003, which hosts a known active galactic nucleus (AGN) and the periodic nuclear transient ASASSN-14ko, observed as part of the All-weather MUse Supernova Integral-field of Nearby Galaxies survey. The MUSE observations reveal that the inner region hosts two AGN separated by 1.4±0.1 kpc (≍1 ′′. 7). The brighter nucleus has asymmetric broad permitted emission-line profiles and is associated with the archival AGN designation. The fainter nucleus does not have a broad emission-line component but exhibits other AGN characteristics, including vFWHM≈700 km~s−1 forbidden line emission, log10([OIII]/Hβ)≈1.1 , and high-excitation potential emission lines, such as [Fe VII] λ6086 and He II λ4686. The host galaxy exhibits a disturbed morphology with large kpc-scale tidal features, potential outflows from both nuclei, and a likely superbubble. A circular relativistic disc model cannot reproduce the asymmetric broad emission-line profiles in the brighter nucleus, but two non-axisymmetric disc models provide good fits to the broad emission-line profiles: an elliptical disc model and a circular disc + spiral arm model. Implications for the periodic nuclear transient ASASSN-14ko are discussed., MAT acknowledges support from the DOE CSGF through grant no. DE-SC0019323. BJS and CSK are supported by NSF grant no. AST-1907570. BJS is also supported by NASA grant no. 80NSSC19K1717 and NSF grants AST-1920392 and AST-1911074. CSK is supported by NSF grant no. AST-181440. KAA is supported by the Danish National Research Foundation (DNRF132). Support for JLP is provided in part by FONDECYT through grant n.1191038 and by the Ministry for the Economy, Development, and Tourism’s Millennium Science Initiative through grant no. IC120009, awarded to The Millennium Institute of Astrophysics, MAS. LG acknowledges financial support from the Spanish Ministry of Science, Innovation and Universities (MICIU) under the 2019 Ramón y Cajal program RYC2019-027683 and from the Spanish MICIU project PID2020-115253GA-I00. Parts of this research were supported by the Australian Research Council Centre of Excellence for All Sky Astrophysics in 3 Dimensions (ASTRO 3D), through project number CE170100013. LG was funded by the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 839090, and partially supported by the Spanish grant no. PGC2018-095317-B-C21 within the European Funds for Regional Development (FEDER). Support for TW-SH was provided by NASA through the NASA Hubble Fellowship grant no. #HST-HF2-51458.001-A awarded by the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., for NASA, under contract NAS5-26555. Based on observations collected at the European Organization for Astronomical Research in the Southern Hemisphere under ESO programme 096.D-0296(A).

We present observations of ASASSN-19dj, a nearby tidal disruption event (TDE) discovered in the post-starburst galaxy KUG 0810+227 by the All-Sky Automated Survey for Supernovae (ASAS-SN) at a distance of d $\simeq98$ Mpc. We observed ASASSN-19dj from $-$21 to 392 d relative to peak ultraviolet (UV)/optical emission using high-cadence, multiwavelength spectroscopy and photometry. From the ASAS-SN $g$-band data, we determine that the TDE began to brighten on 2019 February 6.8 and for the first 16 d the rise was consistent with a flux $\propto t^2$ power-law. ASASSN-19dj peaked in the UV/optical on 2019 March 6.5 (MJD = 58548.5) at a bolometric luminosity of $L = (6.2 \pm 0.2) \times 10^{44} \text{ erg s}^{-1}$. Initially remaining roughly constant in X-rays and slowly fading in the UV/optical, the X-ray flux increased by over an order of magnitude $\sim$225 d after peak, resulting from the expansion of the X-ray emitting region. The late-time X-ray emission is well fitted by a blackbody with an effective radius of $\sim1 \times 10^{12} \text{ cm}$ and a temperature of $\sim6 \times 10^{5} \text{ K}$. The X-ray hardness ratio becomes softer after brightening and then returns to a harder state as the X-rays fade. Analysis of Catalina Real-Time Transient Survey images reveals a nuclear outburst roughly 14.5 yr earlier with a smooth decline and a luminosity of $L_V\geq1.4 \times 10^{43}$ erg s$^{-1}$, although the nature of the flare is unknown. ASASSN-19dj occurred in the most extreme post-starburst galaxy yet to host a TDE, with Lick H$\delta_{A}$ = $7.67\pm0.17$ \AA., Comment: Updated to match accepted MNRAS version