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The lead‑zinc smelter at Trail (British Columbia, Canada) has operated continuously for ∼125 years, with long-standing concerns that transboundary metal(loid) and sulphur emissions have contaminated water bodies in both western Canada and Washington (WA), USA. To assess aquatic ecosystems affected by over a century of industrial contamination requires an understanding of pre-smelting conditions. Here, we use a dated sediment core from Williams Lake (WA), downwind of both the Trail and the short-lived LeRoi (Northport, WA) smelters, to track regional contaminant history and other environmental stressors. Specifically, we examine a selection of chemical elements, cladoceran assemblages, visible range spectroscopy-inferred chlorophyll a (VRS-Chl a) and visible near-infrared spectroscopy-inferred lake-water total organic carbon (VNIRS-TOC). Sedimentary proxies recorded the onset of smelting in 1896 CE, peak periods of aerial emissions in the early to mid-20th century, and the history of emission controls. With a few exceptions, sedimentary metal(loid)s exceeded Canadian Interim Sediment Quality Guidelines during the height of the smelting era and have declined substantially since ca. 2000 CE. The loss of metal-sensitive Cladocera and declines in primary production (VRS-Chl a) at the onset of the regional smelting era indicate a strong biological response to airborne industrial contamination. The largest cladoceran change in the sediment record was concurrent with accelerated mitigation efforts at the Trail facilities following the 1960s; however, this compositional shift was between ecologically similar daphniid taxa. Steep declines in VNIRS-TOC concentrations during the period of peak emissions at Trail suggested an increase in sulphur deposition on the landscape that reduced terrestrial carbon supply. However, the persistence of calcium-sensitive daphniids throughout the record indicates that alkaline Williams Lake had not acidified. Current cladoceran assemblages remain substantially distinct from pre-industrial communities, demonstrating how paleoecotoxicological approaches can be used to track the effects of multiple stressors in a temporally appropriate context., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)

We assessed the concentrations of metals and other trace elements in two of the most common seabird species breeding on Svalbard, the black-legged kittiwake (Rissa tridactyla) and the Brünnich's guillemot (Uria lomvia). Both of these species feed mostly on fish and crustaceans but have different foraging strategies, kittiwakes being surface feeders while guillemots are divers. We investigated the concentrations of arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), lead (Pb), selenium (Se) and zinc (Zn) in the plasma and body feathers of black-legged kittiwakes (n = 17), as well as in the body feathers of Brünnich's guillemots (n = 13). Samples were collected from adult birds at two time points, one week apart during July 2017 in Kongsfjorden, Svalbard. Of the non-essential trace elements, As was found at the highest median concentration at both the first (56.23 ng/g ww) and second (39.99 ng/g ww) sampling timepoints in the kittiwake plasma. When separating for the sexes, as well as sampling time, males sampled at the first sampling time point had significantly higher concentrations of As (median at 0.087 ng/g versus 0.039 ng/g) and Se (median 0.26 ng/g versus 0.16 ng/g) compared to males sampled at the second time point. There was no significant difference in plasma concentrations between females at first and second sampling time points. Kittiwake feathers contained significantly higher concentrations of As, Cd and Hg than guillemot feathers, while guillemot feathers had significantly higher concentrations of Cu, Pb and Zn. However, of the non-essential elements in both kittiwake and guillemot feathers Hg was found with the highest median concentrations at 5160 and 1080 ng/g, respectively, thus in kittiwakes exceeding the level of 5000 ng/g associated with adverse effect (e.g., impaired reproduction). Levels of Hg and Se found in the kittiwake feathers were higher than previous studies on seabirds in the Arctic., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)

Haizhou Bay, a semi-enclosed key aquaculture area in East China, has had relatively limited research focused on trace metals and perfluoroalkyl acids (PFAAs) in its biota. This study characterized the distribution, biomagnification and health risks of selected trace metals and PFAAs in various marine organisms from Haizhou Bay. Among the species examined, zinc (Zn) was the most prevalent metal, followed by copper (Cu) and chromium (Cr), whereas cadmium (Cd), total mercury (THg), and methylmercury (MeHg) contents were relatively low. Perfluorooctane sulfonate (PFOS) was the most abundant PFAA, followed by perfluorooctanoic acid (PFOA). The calculated trophic magnification factors (TMFs) were above one for Cr, THg, MeHg, and all PFAAs except perfluorobutanoic acid (PFBA) and perfluorotetradecanoic acid (PFTeDA). Across animal groups, gastropods exhibited relatively low levels of THg, MeHg, and perfluorosulfonic acids (∑PFSAs). By comparison, fish generally had lower levels of Cd and Cu compared to other animal groups, and demersal fish had significantly higher MeHg compared to gastropods. Certain organisms, such as cephalopods and shrimps, were found to pose potential health risks due to elevated levels of Cd, while levels of other studied metals, PFOS and PFOA generally appeared to be within safe limits for human consumption. Further research is needed to assess the sources and impacts of these and other contaminants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

Background: Mechanistic studies of the effects of environmental risk factors have been exploring the potential role of microRNA(miRNAs) as a possible pathway to clinical disease. In this study we examine whether levels of toenail metals are associated with changes in extracellular miRNA(ex-miRNA) expression., Methods: We used data derived from the Normative Aging Study from 1996 to 2014 to conduct our analyses. We looked at associations between measured toenail metals: arsenic, cadmium, lead, manganese, and mercury and 282 ex-miRNAs in this population using canonical correlation analyses (CCAs) and longitudinal median regression. We adjusted for covariates such as age, education, body mass index, drinking and smoking behaviors, diabetes, and where available, seafood consumption. The p-values obtained from regression analyses were corrected for multiple comparisons. Ex-miRNAs identified to be associated with toenail metal levels were further examined using pathway analyses., Results: Our dataset included 937 observations from 589 men with an average age of 72.9 years at baseline. Both our correlation and regression analyses identified lead and cadmium as exposures most strongly associated with ex-miRNA expression. Numerous ex-miRNAs were identified as being associated with toenail metal levels. miR-27b-3p, in particular, was found to have high correlation with the first canonical dimension in the CCA and was significantly associated with cadmium in the regression analysis. Pathway analyses revealed messenger RNA (mRNA) targets for the ex-miRNAs that were associated with a number of clinical disorders including cancer, cardiovascular disease, and neurological disorders, etc. CONCLUSION: Toenail metals were associated with changes in ex-miRNA levels in both correlational and regression analyses. The ex-miRNAs identified can be linked to a variety of clinical disorders. Further studies are required to validate these findings., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:Joel Schwartz and Andrea Baccarelli reports financial support was provided by National Institute of Environmental Health Sciences. Feiby Nassan reports a relationship with Novo Nordisk Inc that includes: employment. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

Lake Naivasha, Kenya's second-largest freshwater body is a wetland of international ecological importance and currently subjected to unprecedented anthropogenic influence. The study aims to chronologically reconstruct the main human activities and background weathering reactions that govern metal mobilizations into the lake and their potentially adverse effects on its ecological status. We combine extensive geochemical analyses (major, trace elements, Zn-Pb isotope ratios) in a dated lake sediment record and catchment rocks with remote sensing techniques. Downcore geochemical variations reflect natural ecosystem destabilizations occurring as early as the first half of the 20th century. These coincide with changes towards less radiogenic Pb-isotope values which persist towards the top of the core ( 206 Pb/ 207 Pb = 1.243 at core base ∼1843, to 206 Pb/ 207 Pb = 1.225 at ∼1978). We interpret the land-clearance for agricultural purposes on the Aberdare Range and documented early aviation activities as possible vectors of this early Pb-isotope excursion. The overlapping Pb-isotope signatures between sediment sources and anthropogenic contributions challenges a straightforward deconvolution of the two. Our conservative model calculations suggest, nevertheless, that an addition of up to ∼1.8 % Pb-gasoline influx to the total Pb flux, peaking in the 1980s is able to explain the Pb distribution trend. Homogeneous Zn-isotope compositions in sediments deposited until ∼1970s (δ 66/64 Zn = 0.216-0.225 ‰) do not follow major hydro-climatic events or anthropogenic forcing but likely reflect lake-specific natural cycling. Subsequent higher variations to both heavier (up to δ 66/64 Zn = 0.242 ± 0.005 ‰) and lighter (down to δ 66/64 Zn = 0.184 ± 0.003 ‰) Zn-isotope values are contemporaneous with intensification of large-scale horticultural industry in the catchment. Together with supporting indicators, the lighter Zn-isotope compositions in youngest analysed sediments (21st century) are attributable to increased biological productivity (algal blooms) and ongoing lake eutrophication. Our study demonstrates the applicability of the heavy metal isotope tool to reconstruct human influences on lake environments with complex geological settings such as the East African Rift System., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The presence of various contaminants in airborne dusts from metal mining sites poses obvious risks to human health and the environment. Yet, few studies have thoroughly investigated the properties of airborne particles in terms of their morphology, size distribution and chemical composition, that are associated with health effects around mining activities. This review presents the most recent knowledge on the sources, physicochemical characteristics, and health and environmental risks associated with airborne dusts from various mining and smelting operations. The literature reviewed found only one research on atmospheric dust associated with hydrometallurgical plants compared to a larger number of pyrometallurgical processes/smelters studies. In addition, there are relatively few works comparing the distribution of metals between the fine and coarse size fractions around mining sites. Our analysis suggests that (i) exposure pathways of metal(loid)s to the human body are defined by linking concentration data in human biosamples and contaminated samples such as soils, drinking water and food, and (ii) chitosan and its derivatives may serve as an environmentally friendly and cost-effective method for soil remediation, with removal rates for metal(loid)s around 70-95 % at pH 6-8, and as dust suppressants for unpaved roads around mining sites. The specific limit values for PM and metal(loid)s at mining sites are not well documented. Despite the health risks associated with fine particles around mining areas, regulations have tended to focus on coarse particles. While some air quality agencies have issued regulations for occupational health and safety, there is no global alignment or common regulatory framework for enforcement. Future research priorities should focus on investigating PM and secondary inorganic aerosols associated with hydrometallurgical processes and dust monitoring, using online metal(loid)s analysers to identify the driving parameters in the deposition and resuspension process., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Arthur Kaniki, Jean-Marie Kanda reports a relationship with Kamoa Copper that includes: consulting or advisory. Arthur Kaniki, Jean-Marie Kanda reports a relationship with MMG Kinsevere that includes: consulting or advisory. Arthur Kaniki, Jean-Marie Kanda reports a relationship with Kamoto Copper Company (KCC) that includes: consulting or advisory. Arthur Kaniki, Jean-Marie Kanda reports a relationship with Société de Traitement du Terril de Lubumbashi (STL) that includes: consulting or advisory. Arthur Kaniki, Jean-Marie Kanda reports a relationship with Ruashi Mining that includes: consulting or advisory. Arthur Kaniki, Jean-Marie Kanda reports a relationship with Kipushi Corporation that includes: consulting or advisory. Arthur Kaniki, Jean-Marie Kanda reports a relationship with SOMIKA that includes: consulting or advisory. Arthur Kaniki, Jean-Marie Kanda reports a relationship with Boss Mining that includes: consulting or advisory., (Copyright © 2024 The Author(s). Published by Elsevier B.V. All rights reserved.)

Background: Diminished ovarian reserve (DOR), a triggering factor for female infertility, affects 10% ∼ 35% of women of reproductive age. It is still unclear whether exposure to toxic metals (including metalloid) is associated with DOR risk, especially with respect to their relationships with the clinical phenotypes of DOR., Methods: A case-control study including 439 patients was conducted, and Ba, Ni, As, Tl, Cd, Pb, Hg, Al and Cr levels in BL and FF were measured. Subsequent analyses were focused on Ba, Ni, As and Tl, which had the highest weights in the associations of the nine toxic metals (including metalloid) with DOR risk, by integrating weighted quantile sum (WQS) regression and bayesian kernel machine regression (BKMR) models. Conditional logistic regression models and BKMR models were used to assess the individual and combined effects of Ba, Ni, As and Tl exposures on DOR risk. Multiple linear regression models were used to investigate the relationships between toxic metal (including metalloid) levels in BL and FF and the clinical characteristics of DOR., Results: The levels of Ba [second vs. lowest tertile: adjusted odds ratio (aOR) and 95 % confidence interval (CI) = 1.97 (1.13, 3.44); highest vs. lowest tertile: aOR (95 % CI) = 2.38 (1.32, 4.26)], Ni [highest vs. lowest tertile: aOR (95 % CI) = 2.59 (1.45, 4.65)] and As [highest vs. lowest tertile: aOR (95 % CI) = 1.96 (1.18, 3.25)] in BL, and Ba [highest vs. lowest tertile: aOR (95 % CI) = 4.60 (1.68, 12.61)] in FF were significantly associated with a higher risk of DOR, respectively. The significantly positive combined effect of the four toxic metals (including metalloid) on DOR risk was exhibited when their BL levels exceeded the 25th percentile compared with their median levels. Among these, As (0.9822) and Ba (0.9704) were the primary contributors to this relationship. Similarly, this finding was confirmed by the statistical results from FF samples, with a linear positive correlation between combined exposure and DOR risk, where Ba (0.9440) was the primary contributor. Finally, elevated levels of Ba, Ni, and As in BL and Ba in FF were significantly linked to the higher follicle-stimulating hormone (FSH) levels. The levels of Ba in BL and FF, as well as As in BL, were significantly associated with the lower luteinizing hormone (LH)/FSH ratio values., Conclusion: Overall, the results of this study indicate that elevated levels of Ba, Ni, As and Tl are associated with a higher risk of DOR, whether individually or in combination, and that Ba levels in BL and FF are stable contributors. In addition, exposure to Ba, Ni, As and Tl is linked to various clinical phenotype parameters of DOR. Further research is needed to confirm these associations and to identify potential mechanisms involved., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Inc. All rights reserved.)

Given the research situation of toxic metals (TMs) pollution in farmland soil, it is very critical to study the clay influence on TMs environmental behavior to meet the aim of lowering TMs pollution. This research explores the association among clay minerals and TMs and the health risks in TMs combined polluted farmland of northern China. In this study, agricultural soil, wheat grain, and atmospheric sediments from nonferrous metal smelting (NMS) areas were collected and investigated to determine the effect of clay minerals on TMs. The results show that the content ranges of Cd (0.199 mg/kg ∼1.98 × 10 2  mg/kg), Pb (0.228 × 10 2  mg/kg ∼ 4.87 × 10 3  mg/kg), Cu (0.187 × 10 2  mg/kg ∼ 4.57 × 10 3  mg/kg), and Zn (0.559 × 10 2  mg/kg ∼ 3.04 × 10 3  mg/kg) in the agricultural soil. In particular, Cd has reached heavy pollution by the high pollution index (6.74). The findings indicate that Cd and Pb in wheat grain were influenced by their exchangeable fractions in soil, according to a significant relationship between Cd and Pb in soil and wheat grain. XRD-SEM suggests that TMs come from atmospheric sediments associated with NMS emissions by microsphere signatures with surface burn marks. Meanwhile, Geographical detector indicated that clay was the primary contributor to spatial distribution of Cd and Pb. In addition, XRD results showed that I/S (a mixed layer of illite and smectite), illite, chlorite, and kaolinite co-existed. Whereas the clay minerals with this ratio did not demonstrate better adsorption capacities for Cd and Pb due to the Cd percentage of the residual fraction being less than 9%. The result of negative correlation between exchangeable Cd and clay minerals implies that illite, chlorite, and kaolinite may preferentially adsorb Cd and Pb. It is similar to the relationship between Cd and Pb in wheat grain and illite, chlorite, and kaolinite. In addition, the health assessment result show that the negative correlation between clay minerals and the noncarcinogenic hazard quotient (HQ) and indicate that clay minerals could reduce the noncarcinogenic risk of Pb and Cd for children. Our findings provide a potential mechanism and application of clay minerals for the remediation of soil contaminated with TMs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

The present study aims to measure the values of metal pollutants in the dust of schools in Mashhad metropolis, determine the source of metal pollution, evaluate the degree of pollution, assess the health risk (carcinogenicity/non-carcinogenicity) and evaluate the potential ecological risk. For this purpose, after measuring the concentration of metals using an inductively coupled plasma-mass spectrometer, from various indices including Geoaccumulation Index (I geo ), Pollution Load Index (PLI), Contamination Factors (CF), Potential Ecological Risk Index (PERI), Enrichment Factor (EF), and Health Risk Indices such as Hazard Quotient (HQ), Hazard Index (HI), Carcinogenic Risk (CR) were used. The average concentrations of iron, arsenic, cadmium, chromium, copper, nickel, lead, vanadium and zinc (Fe, As, Cd, Cr, Cu, Ni, Pb, V and Zn) were 6361.50, 5.96, 0.59, 61.89, 37.13, 61.31, 28.93, 25.64 and 142.00 µg g -1 , respectively. Based on CF, PLI and I geo indices, most of the findings for the studied elements were at the low pollution level. The results also showed that the most likely origin of the studied metals was anthropogenic sources. The results of PERI indices showed that potential ecological risk at only one of the collection sites. In contrast, a high ecological risk was obtained for Cd. Hazard Index values were below safe levels for all studied elements. CR levels for elements were also classified as negligible and acceptable or tolerable risk, although the highest CR value for Cr indicated possible harm to humans. The findings showed the need for more attention and continuous monitoring of the concentration of metals, especially chromium, to announce a possible warning and prevent their harmful effects. It should be noted that the present study is the first research with mentioned objectives in Mashhad city and also in Khorasan Razavi province., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Owing to increasing levels of potentially toxic metals in road dust, air pollutants suspended in the air, pose significant health risks due to rapid, unplanned urbanization and industrialization. This study investigated the pollution status and health risks of trace metals (i.e., Cr, Cd, Ni, Cu, and Pb) in road dust collected from 16 locations across six land-use categories in Eskişehir, Türkiye, including residential, roadside, traffic, tram stations, and car industrial areas. The analysis of trace metals revealed distinct types of urban pollution based on these functional areas. In areas with heavy traffic, high concentrations of the elements, especially Zn, Cr, and Ni, would indicate significant toxic metal pollution. The overall contamination was evaluated using three indices: enrichment factor (EF 0.45-65.75), geo-accumulation index (I geo  - 2.50-4.18), and pollution index (PI 0.27-27.22). Human health risks of potentially toxic trace metals in urban road dust were evaluated for children and adult groups based on hazardous index (HI) and total cancer risk (TCR). The health risk assessments revealed that children (mean HI children 8.62E - 01; TCR children 6.99E + 04) are more vulnerable to toxic metal exposure than adults (mean HI adults 1.01E - 01; TCR adults 3.01E + 04), with ingestion being the primary exposure route over dermal contact and inhalation. In conclusion, we have captured the interaction between road dust and health risks, especially for children., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Metal contamination in coastal and marine ecosystems has become a significant global concern due to its hazardous characteristics, environmental persistence, and ability to bioaccumulate in aquatic ecosystems. This poses a serious threat to the environment and the health of humans worldwide. To address these concerns, this study estimated the concentrations of metals in various trophic levels, including phytoplankton, zooplankton, bivalve, and fish. Monthly sampling was carried out in Pondicherry Fishing Harbor (PFH) and Pondicherry Open Sea (POS) between January 2017 and December 2018. The value of Cd, Pb, Cr, Co, Ni, Cu, Zn, and Mn in sediment at the PFH was considerably higher compared to the POS, indicating the impact of human activity there. The contamination factor (CF) for other metals was <0.5, suggesting minor contamination in the Pondicherry coastal sediment, the CF value for Cd was higher at PFH. Comparably, the risk index (RI) at the PFH was likewise greater because of Cd, leading to an overall risk grade of "considerable" at the PFH whereas it was "low" at the POS. The marine pollution index (MPI) showed minimal values in fish regardless of the collection sites, which was calculated based on the values of all metals. The estimated daily intake, target hazard quotient, and hazard index assessed for potential human health risk suggest that the values were within acceptable thresholds for adults and children for fish consumption from POS. However, the direct consumption of bivalve for the long term poses significant non-carcinogenic health risks in both age groups, particularly in children, who are 1.31 times more susceptible than adults. These findings highlight the need to evaluate the presence of metals in the food chain to determine their transfer to the different trophic levels, which can help mitigate the associated risks for sustainable coastal ecosystem management., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Diet is a primary source of pollutant exposure. Given children's vulnerability to their effects, this study assessed dietary intake of metals/metalloids and different persistent organic pollutants in children in Tarragona (Spain), compared it with the health-based guideline values (HBGV), and identified the main dietary sources. The analysis included 533 preschoolers and 443 primary school children from the EPINED and ECLIPSES studies. Dietary intake of cadmium (Cd), methylmercury (MeHg), lead (Pb), inorganic arsenic (inAs), polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), dioxin-like polychlorinated biphenyls (DL-PCBs), and non-dioxin-like polychlorinated biphenyls (NDL-PCBs) was estimated using validated food frequency questionnaires and a database from the Catalan Agency for Food Safety. Preschoolers and primary school children exceeded the relevant reference value for InAs and DL-PCBs. Only preschoolers exceeded the limit for MeHg and PCDD/Fs. Cd, Pb, and NDL-PCBs intakes did not exceed the limits in either age group. Salted cereals/potatoes were the main source of InAs; fish for MeHg and DL-PCBs; and milk/yogurt for PCDD/Fs, followed by white fish in preschoolers and fatty fish in primary school children. The findings highlight that dietary exposure to some pollutants poses a significant risk to these children, emphasizing the need for public health policies to reduce pollutants in their diets., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Human activities and climate change have negatively affected the world's oceans, leading to a decline of 30 to 60 % in coastal ecosystems' biodiversity and habitats. The projected increase in the human population to 9.7 billion by 2050 raises concerns about the sustainability of marine ecosystem conservation and exploitation. Marine turtles, as sentinel species, accumulate contaminants, including trace elements, due to their extensive migration and long-life span. However, there is a lack of data on the degree of contamination and their effects on marine turtles' health. This study focuses on assessing in-situ inorganic contamination in juvenile green sea turtles from La Réunion Island and its short-term impact on individual health, using conventional biomarkers and proteomics. The goals include examining contamination patterns in different tissues and identifying potential new biomarkers for long-term monitoring and conservation efforts. The study identified differential metal contamination between blood and scute samples, which could help illuminate temporal exposure to trace elements in turtle individuals. We also found that some conventional biomarkers were related to trace element exposure, while the proteome responded differently to various contaminant mixtures. Immune processes, cellular organization, and metabolism were impacted, indicating that contaminant mixtures in the wild would have an effect on turtle's health. Fifteen biomarker candidates associated with strong molecular responses of sea turtle to trace element contamination are proposed for future long-term monitoring. The findings emphasize the importance of using proteomic approaches to detect subtle physiological responses to contaminants in the wild and support the need for non-targeted analysis of trace elements in the biomonitoring of sea turtle health., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Bivalves possess important ecological and economic values. They have been extensively used as bioindicators for both emerging and classical pollutants in the aquatic environment. This study investigates the levels of trace metals, polycyclic aromatic hydrocarbons (PAHs), and organochlorine pesticides (OCPs), alongside microplastic (MPs), in Tridacna maxima, Paphia textile, and Paratapes undulatus, collected from the Gulf of Suez. This work represents the first investigation of MPs in marine bivalves from the Gulf of Suez. MPs were detected in 72% of the specimens examined and four types of MPs were identified. The metal pollution index indicated that bivalves may have long-term toxic effects on human consumers. The results showed minimal hydrocarbon pollution. Diagnostic ratios indicated a combination of pyrolytic and petrogenic sources, with a notable influence from pyrolytic origins. The risk assessment reflected that the levels of certain trace metals, PAHs, and OCP contaminants could present a low risk to human health., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

With priority given to various-sized samples of market-available Hilsa (Tenualosa ilisha), human health consequences of trace metals along with total essential acids, including the fatty acid (FA) and amino acid (AA) profile were measured and compared to different size groups (G I, G II, and G III) using chemometric approaches. Essential amino acids were lower than nonessential amino acids. The G III contained the highest (97.55%) saturated and unsaturated fatty acids. The highest concentrated metal was found in G1 among the groups and the order of metal (mg/kg) was Zn (205.01) > Mn (37.37) > Fe (69.39) > Cu (1.47) > Cr (1.31) > Ni (0.42) > Pb (0.017) > Cd (0.005). Even though the adult group showed no health hazards for Hilsa consumption, non-carcinogenic risks have been identified for G1 fish consumption by children. Continued monitoring is recommended to overcome the health consequences caused by fish consumption., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Metal contamination in soil poses environmental and health risks requiring effective remediation strategies. This study introduces an innovative approach of synergistically employing biochar and bacterial inoculum of Serratia marcescens to address toxic metal (TM) contamination. Physicochemical, enzymatic, and microbial analyses were conducted, employing integrated biomarker response (IBR) and machine-learning approaches for toxicity estimation. The combined application significantly reduced the Cd, Cr, and Pb concentrations by 71.6, 31.2, and 57.1%, respectively, while the Cu concentration increased by 85% in the individual Serratia marcescens treatment. Biochar enhanced microbial biomass by 33-44% after 25 days. Noteworthy physicochemical improvements included a 44.7% increase in organic content and a decrease in pH and electrical conductivity. The K⁺ and Ca 2 ⁺ concentrations increased by 196.9 and 21.6%, respectively, while the Mg 2 ⁺ content decreased by 86.4%. Network analysis revealed intricate relationships, displaying direct and indirect negative correlations between metals and soil physicochemical parameters. The IBR index values indicated effective mitigation of TM toxicity in Serratia marcescens and biochar with individual and combined treatments. Binary classification demonstrated high sensitivity (80.1%) and specificity (80.5%) in identifying TM-contaminated soil. These findings indicate significant biochar- and Serratia marcescens-induced impacts on toxic metal availability, physicochemical properties, and enzymatic activities in metal-contaminated soil, suggesting that blending soil with biochar and microorganisms is an effective remediation strategy., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:Mazhar Iqbal, Tayyab Ashfaq Butt, Ahmed Abdullah Alawi Al-Naghi, Enamur Rahim Latifee, Omar Ali Saad Algassem reports financial support was provided by University of Ha'il. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Seagrasses increase sediment complexity by trapping particulates and influencing biogeochemical cycles via root oxygen loss and organic matter exudation. However, their impact on trace metal sequestration is poorly studied. We found significantly higher trace metal concentrations in seagrass sediments compared to adjacent bare sediments, correlating with total organic carbon, iron, and fine sediments. Sequential extractions showed that most trace metals were dominated by recalcitrant fractions (oxidizable and residual fractions), representing phases such as organic matter, iron sulfides, and crystalline iron oxides. Depth-dependent trends in trace metal partitioning were evident. For example, arsenic in the oxidizable fraction only weakly correlated with Fe in surface sediments (r sp  = 0.55) but correlated strongly in deeper sediments (r sp  = 0.87), consistent with iron sulfides being a dominant host-phase. Overall, these results suggest that the unique geochemical conditions facilitated by seagrasses play an important role in sequestering trace metals in urban estuarine sediments., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Changes in the ocean temperature, seawater acidity, and oxygen level are parts of global change that may indirectly impact the biogeochemical cycles of trace metals in the marine system, particularly for the particulate phase. The different factors influencing the level of particulate trace metals are interesting topics for investigation. Following up on marine research in the estuary and coastal areas, we specifically review the distribution of particulate trace metals. This review aims to provide an overview of the progress of studies on particulate metals in the marine environment and to understand the factors that influence the level of particulate metals. Spatially, the distribution of particulate trace metals decreases towards the sea due to the influence of salinity, while the temporal distribution portrays the unique feature of each location that differences in metal sources and phytoplankton bloom periods might cause., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Jarosite waste is a by-product generated from iron removal process in the jarosite process, which typically contains valuable metals including zinc, nickel, cobalt, silver, indium, and lead. Due to the large amount of jarosite and the less efficient and costly methods of recovering residual metals, it is mainly disposed by landfills. However, leachate generated from the landfills can release high concentrations of heavy metals, which contaminate nearby water resources and pose environmental and health risks. In this review, the environmental and resource properties of jarosite waste were briefly summarized. Then those pyrometallurgical, hydrometallurgical and biological methods were discussed. In this review, considering the polymetallic properties and the low content of valuable metal elements of the jarosite waste, it is indicated that these processes had their own benefits and drawbacks such as overall yield, economic and technical constraints, and the necessity for combined processes to recycle multiple metal ions from jarosite wastes. Finally, this paper provided a critical and systematic review of studies on the novel green recycling technology for metals and material preparation based on the jarosite waste. This review can lay a guidance for the near-zero-waste processing of jarosite waste, with a particular focus on the combination of chemical and biological processes and waste-to-materials., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Landfill leachate-containing per- and polyfluoroalkyl substances (PFAS) is both an important 'sink' and a 'source' of secondary pollution, posing serious threaten to surrounding environments. To date, the pollution characteristics of PFAS in landfill leachate, and the coexistence and interaction between PFAS and other leachate contaminants, such as dissolved organic matter (DOM) and toxic metals remains unclear. Herein, our results showed that 17 target PFAS, with concentrations ranged from 1804 to 43309 ng/L, were detected in landfill leachates. The main PFAS were short-chain and even-chain substances represented by perfluorobutanoic acid (PFBA) and perfluorobutane sulfonic acid (PFBS). Leachate derived DOM is mainly composed of protein-like and humic-like substance, among which the total contribution of protein-like substance is as high as 73.7%. Correlation analysis results showed that the distribution of PFAS was strongly correlated with the substituted functional groups (e.g., carboxyl and hydroxyl) on the aromatic ring of humic-like substance (C2 and E 253 /E 203 ) and autochthonous metabolism by microbial activities (FI). Furthermore, Mn element showed a significantly strong correlation with PFAS. Both organic and inorganic substances positively correlated with toxic metals. Our findings are helpful to understand the environmental fate of PFAS, and contribute to decision-making regarding DOM, toxic metals, and PFAS management in landfill., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

Currently, the environmental problems associated with plastic production and waste, such as the consequences of worldwide pollution of natural waters with microplastics, have led to the seeking of alternative materials that can at least partially replace conventional petroleum-based plastics. Substitute materials include bioplastics and similar plant-based materials or their composites. However, their fate when disposed of in unintended environments (e.g., water bodies) remains largely unknown, while such information is highly desirable prior to massive expansion of exploiting such materials. This study aims to contribute filling this knowledge gap. Specifically, 19 different types of bioplastic and similar plant-based material debris (corresponding to the size of microplastics) were kept in long-term contact with water to mimic their behaviour as water pollutants, and the leachates were continuously analysed. Eighteen of the 19 investigated materials released significant amounts of dissolved organic carbon-up to 34.0 mg per g of debris after 12 weeks of leaching. Each leachate also contained one or more of the following elements: Al, B, Ba, Ca, Fe, K, Mg, Mn, N, Na, P, Si, Ti, and Zn. Non-targeted analysis aimed at providing more specific insight into the leachate composition tentatively revealed 91 individual chemicals, mostly fatty acids and other carboxylic acids, phthalates, terephthalates, adipates, phenols, amides, alcohols, or organophosphates. Based on the compound characteristics, they might be additives, non-intentionally added substances, as well as their degradation products. In general, the current results imply that bioplastics and similar plant-based materials should be considered complex materials that undergo industrial processing and comprise additives rather than harmless natural matter. Additionally, various compounds can release from the bioplastic and similar plant-based material debris when deposited in water. It might have consequences on the fluxes of carbon, metals and specific organic contaminants, and it resembles some properties of conventional petroleum-based microplastics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Polycyclic aromatic hydrocarbons (PAHs) and metal elements are commonly considered hazardous air pollutants due to their toxic, mutagenic, and carcinogenic properties. However, few studies have simultaneously examined their potential sources and health effects. This study aimed to quantify the PAHs and metal elements in atmospheric PM 2.5 , investigating their characteristics and potential sources to assess associated health risks in the northern metropolitan area of Taiwan. The measurements indicated that the mean concentrations of total PAHs and metal elements in PM 2.5 were 0.97 ± 0.52 ng m -3 and 590 ± 200 ng m -3 , respectively. Utilizing the positive matrix factorization profiles, the PAH pollution was classified into two sources: industrial emissions, traffic emissions, and coal combustion (69%) were the predominant sources of PAHs, with petroleum volatilization and biomass burning (31%) making a lesser contribution. Similarly, we traced metal elements to three potential sources: natural sources (48%), a combined source of industrial emissions, coal combustion, and traffic exhaust (32%), and a blend of non-exhaust emissions from traffic and waste incineration sources (20%). Results from the potential source contribution function model suggested that the emissions of PAHs and metals could be influenced by the eastern regions of China, although local sources, including waste incinerators, traffic, shipping, and harbor activities, were identified as the primary contributors. Source-attributed excess cancer risk revealed that industry, traffic, and coal combustion had the highest cancer risk posed by PAHs in the cold period (1.0 × 10 -5 ), while the greatest cancer risk among metal elements was linked to non-exhaust emissions from traffic and waste incineration emissions (2.0 × 10 -5 ). This research underscores the importance of considering source contributions to health risk and emission reduction when addressing PM 2.5 pollution. These findings have direct implications for policymakers, providing them with valuable insights to develop strategies that protect public health from the detrimental effects of PAH and metal element exposure., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This study was conducted to assess sediment trace metals (Cd, Cr, Cu, Pb, Ni and Zn) contamination using a systematic approach by collecting sediment samples from 8 transects along the Dubai coastline, each 10 km long, and each transect included its nearshore sediment sampling station. Additionally, 10 sediment samples were collected from the Dubai creek and other potential sources of metal pollution. The sediment samples were collected in December and again in August. However, no significant difference in sediment metal concentration was found between the two sampling campaigns. The sediment trace metal concentrations (0.92-1.31 mg Cd/kg, 2.82-176.6 mg Cr/kg, 2.27-621.67 mg Cu/kg, 0.88-23.6 mg Pb/kg, 1.92-192.2 mg Ni/kg and 9.1-391.05 mg Zn/kg) showed considerable variability, except for Cd (1.08 ± 0.06 mg/kg, 5.55% variability). Despite this, no significant differences in sediment metal concentrations were found between the sampled transects. However, significant variations in Cr, Cu, Pb and Zn were evident between distances from the shoreline to offshore stations along the Dubai coast, and the nearshore locations presented clear evidence of elevated/maximum sediment metal concentrations. Most of the sediment trace metal concentrations, however, were found well within the sediment quality guidelines (SQGs) for nearshore sediments. Trace metal contamination hotspots, nonetheless, were identified at some nearshore stations as determined by metal level exceedance over the SQGs, background levels and the pollution load index, with limited potential ecological risk. Overall, the findings suggest that sediments in the Dubai coastal environment are mainly influenced by anthropogenic activities in stations located in the proximity of ship maintenance, ports, and industrial areas such as Dry Dock, Jaddaf, Jebel Ali Port, Wharfage, Hamriya and DUBAL., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Background: The developing kidney is vulnerable to prenatal environmental factors such as metal exposure, potentially altering the risk of later-life kidney dysfunction. This study examines the relationship between prenatal metal exposures, individually and as mixtures, and adolescent kidney function in Project Viva, a prospective longitudinal birth cohort in Massachusetts, USA., Methods: We used data on metals measured in blood during pregnancy including 15 in the first trimester and four in the second trimester. We calculated estimated glomerular filtration rate (eGFR) in adolescents (mean: 17.7 years) using cystatin C- (eGFRcys) and creatinine-based (eGFRcreat) equations for children. We used linear regression for single metal analyses, and Bayesian kernel machine regression and quantile-based g-computation for mixture analyses, adjusting for relevant covariates. To account for multiple comparisons in the single metal analyses, we applied the Holm-Bonferroni procedure to control the false discovery rate., Results: This study included 371 participants with first trimester metals and adolescent eGFR, and 256 with second trimester metals. Each doubling in first trimester cadmium concentration was associated with lower adolescent eGFRcys (β:-1.51; 95% CI:-2.83, -0.18). Each doubling in first trimester chromium (β:-1.45; 95% CI:-2.71, -0.19), nickel (β:-1.91; 95% CI:-3.65, -0.16), and vanadium (β:-1.69; 95% CI:-3.21, -0.17) was associated with lower adolescent eGFRcreat. After adjusting for multiple comparisons, p-values for associations between adolescent eGFR and chromium, nickel, vanadium and cadmium did not meet the criteria for significance. Metal mixture analyses did not identify statistically significant associations with adolescent eGFR., Conclusions: These findings have important implications for future studies investigating the potential mechanisms through which prenatal metal exposures affect long-term kidney health in children., (© 2024. The Author(s).)

The paper presents a novel technique for quantifying trace metals in aerosol samples in real time. Airborne metals were continuously collected for one week near the Baltic Sea in Finland using a particle-into-liquid sampler (PILS). The collected liquid samples were analyzed for metals using micro-discharge optical emission spectroscopy (µDOES). The micro-discharge analyzer is designed to perform real-time, on-site measurements of metal concentrations in aqueous solutions. Currently, µDOES can provide online measurements of 30 metals, with typical detection limits from 0.01 µg/m 3 to 0.06 µg/m 3 with a long-term repeatability less than 5%. The novelty of this analyzer lies in its compact design, rapid detection capabilities, and ease of operation and maintenance. Several metals, including potassium (K), calcium (Ca), sodium (Na), aluminum (Al), magnesium (Mg), and copper (Cu), were measured in the aerosol samples collected using PILS. The results indicate that this approach has significant potential for future automated online monitoring of airborne metal concentrations, facilitating investigations into their sources and daily variations. The development of real-time technologies for rapid, online, and accurate atmospheric aerosol measurements is essential for advancing climate change research. Such advancements allowing for continuous real-time data enhance our understanding of aerosol dynamics, improve source identification, and inform public health and environmental policies, ultimately contributing to more effective climate change monitoring and mitigation., (© 2024. The Author(s).)

Chemical fingerprinting to characterize the occurrence state and abundance of organic and inorganic constituents within fine particulate matter (PM2.5) is useful in evaluating the associated health risks and tracing pollution sources. Herein, an analytical strategy for the rapid analysis of metal and organic constituents in PM2.5 was developed employing a combination of sequential chemical extraction coupled with mass spectrometry detection. H 2 O, CH 3 OH, EDTA-2Na, electrochemical oxidation, and electrochemical reduction were sequentially utilized to extract the chemical constituents in PM2.5 samples on a homemade device employing simultaneous online detection using two linear trap quadrupole mass spectrometers (LTQ-MS) with electrospray ionization (ESI) in positive and negative modes. After a single analytical procedure, dozens of metals (e.g., Pb, Cr, and Cu), organic compounds (e.g., amines, polycyclic aromatic hydrocarbons, and aliphatic acids), and negative ions (e.g., NO 3 - , NO 2 - , and Cl - ) were comprehensively detected in the water-soluble, liposoluble, insoluble, oxidizable, and reducible fractions of PM2.5 samples, and their physical and chemical relationships were established.

Aging petrochemical landfills serve as reservoirs of inorganic and organic contaminants, posing potential risks of contamination to the surrounding environment. Identifying the pollution characteristics and elucidating the translocation/ transformation processes of typical contaminants in aging petrochemical landfills are crucial yet challenging endeavors. In this study, we employed a combination of chemical analysis and microbial metagenomic technologies to investigate the pollution characteristics of benzene, toluene, ethylbenzene, and xylene (BTEX) as well as metal(loid)s in a representative aging landfill, surrounding soils, and underlying groundwater. Furthermore, we aimed to explore their transformations driven by microbial activity. Our findings revealed widespread distribution of metal(loid)s, including Cd, Ni, Cu, As, Mn, Pb, and Zn, in these environmental media, surpassing soil background values and posing potential ecological risks. Additionally, microbial processes were observed to contribute significantly to the degradation of BTEX compounds and the transformation of metal(loid)s in landfills and surrounding soils, with identified microbial communities and functions playing key roles. Notably, co-occurrence network analysis unveiled the coexistence of functional genes associated with BTEX degradation and metal(loid) transformation, driven primarily by As, Ni, and Cd. These results shed light on the co-selection of resistance traits against BTEX and metal(loid) contaminants in soil microbial consortia under co-contamination scenarios, supporting microbial adaptive evolution in aging petrochemical landfills. The insights gained from this study enhance our understanding of characteristic pollutants and microbial transformation processes in aging landfills, thereby facilitating improved landfill management and contamination remediation strategies., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Inc. All rights reserved.)

Biodosimetry can define risks in inhabitants of areas with potential contaminants, ensuring environmental protection and living conditions due to toxic and radioactive effects. This study aimed to evaluate metals and radionuclides in dental structures and alveolar bones in residents of a uranium area in Paraíba and Pernambuco, Brazil. Eighty-nine specimens were pulverized, fractionated, and chemically prepared for analysis by EDXRF, FAAS, and ICP-MS. Levels of Ca, Cu, Fe, Si, Mn, Ni, Pb, Sr, Ti, V, Zn, K, Mn, Th, and U were investigated. Higher concentrations were measured for Ca, with an average of 272,986.4 mg kg -1 . Ni presented in lower concentrations, with an average of 30.4 mg kg -1 . For U, concentrations ranged from 1.5 to 145.0 mg kg -1 , with more than 27% of the samples above the reference value of 8.1 μg kg -1 . For Th, almost 38% of the results were above the limit of 3.5 μg kg -1 . In the bone spicules, the contents of U and Th ranged from 45.1 to 1451.2 μg kg -1 and from 7.5 to 78.4 μg kg -1 , in this order. The levels of radionuclides were more expressive for the teeth collected in São José do Sabugi, suggesting contamination through food and water consumption. In the bone spicules, the levels of U were up to 179 times higher than the safety limit. The results indicate a possible risk of contamination with probable induced radiobiological effects., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

New industries are proliferating in the recovery of agri-food wastes, such as those involved in the revaluation of alperujo, generated in the production of olive oil. Despite the potential environmental benefits, their activity is not exempt from new forms of emissions, aggravated by the massification of waste treatments. This work reports a six-month field campaign carried out in an alperujo desiccation plant which can serve as a proxy for these emerging industries in the Mediterranean countries. The study focused on air quality parameters, covering criteria pollutants, metals and microbiological load of particulate matter and the characterization of volatile organic compounds (VOCs). The results show a slight contribution of the factory to the NOx levels in the surroundings (3.0-12.5 μg/m 3 ). Statistically significant effects were not observed for ozone, CO, SO 2 , or PM 10 . Concerning the levels of metals, concentrations were low and calculated health risk indexes indicated safe conditions in the area. The most abundant elements were Na (6.5 × 10 2  ng/m 3 ), K (4.0 × 10 2  ng/m 3 ), Al (2.7 × 10 2  ng/m 3 ), Zn (2.1 × 10 2  ng/m 3 ), Ca (2.16 × 10 2  ng/m 3 ), Fe (3.6 × 10 1  ng/m 3 ) and Mg (3.2 × 10 1  ng/m 3 ). Bacterial counts, with a mean value of 15.9 CFU/m 3 , showed a seasonal shift, mainly explained by weather (air moisture and temperature) and PM 2.5 concentration. The genomic analysis showed Cutibacterium as the dominant genus during the cold months while Bacillus predominated in the warm season. The VOCs with higher average concentrations were acetic acid (130 μg/m 3 ), nonanoic acid (124 μg/m 3 ), benzoic acid (29.7 μg/m 3 ), octanoic acid (19.9 μg/m 3 ) and nonanal (4.70 μg/m 3 ), with the rest of compounds in concentrations below 4 μg/m 3 . Odorant pollutants with the greatest contribution to olfactory nuisance were aldehydes (from pentanaldehyde to decanaldehyde), acetic acid and phenol. Although the observable effects of the waste treatments were low, several parameters showed an influence on the environment which should be assessed to foresee and prevent long-term consequences., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

This research examines the contamination levels in the Pashur River in Bangladesh stemming from trace metal discharge originating from the Mongla seaport and various industrial outlets. It delves into both ecological risks and potential health hazards for humans consuming fish carrying accumulated trace metals. The research employed atomic absorption spectrometry to measure the concentrations of chromium (Cr), arsenic (As), manganese (Mn), copper (Cu), zinc (Zn), nickel (Ni), lead (Pb), and cadmium (Cd) in surface water, sediment, and fish samples. Target hazard quotient (THQ) and carcinogenic risks were calculated to determine the human health risk caused by the consumption of these targeted fish species. An R I value of 42.89 indicates that the collective presence of trace metals in sediment poses significant ecological risks to the study area. Although the majority of trace metals present in sediment are categorized under class 1 (ranging from unpolluted to moderately polluted) based on the I geo values, Cd is classified under class 2, signifying a moderate level of pollution. Significantly, THQ values surpass the threshold of 1 for Cr and As, indicating potential health risks associated with the consumption of specific fish species. Among the trace metals analyzed, Ni demonstrates the highest cancer risk (CR) value, at 5.78 × 10 3 , indicating a notable cancer risk associated with the consumption of targeted fish. Recommendations include the strict enforcement of waste disposal policies to mitigate anthropogenic discharge and safeguard the river from further pollution., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Exposure to metal(loid)s can cause adverse health effects. This study evaluated the concentrations of aluminum, arsenic, cadmium, chromium, mercury, nickel, and lead in particulate matter <10 μm (PM 10 ) and in the urine of 100 participants from urban residential areas in Iran. A total of 100 residential buildings (one adult from each household) in six cities across Iran were recruited for this study. The levels of metal(loid)s in PM 10 and the urine of participants were measured using acid digestion followed by inductively coupled plasma mass spectrometry (ICP-MS). The average (±SE) PM 10 concentration in the buildings was 51.7 ± 3.46 μg/m 3 . Aluminum and cadmium had the highest and lowest concentrations among the metal(loid)s, averaging 3.74 ± 1.26 μg/m 3 and 0.01 ± 0.001 μg/m 3 , respectively. In 85 % of the samples, the concentration of metal(loid)s in indoor air exceeded WHO air quality standards. Cadmium and lead had the highest and lowest numbers of indoor air samples exceeding the recommended standards, respectively. A significant correlation was found between the concentration of metal(loid)s in urine samples and indoor PM 10 levels, as well as the wealth index of participants. There was also a significant direct relationship between the concentrations of nickel, arsenic, lead, and mercury in urine and the age of participants. Factors such as building location, type of cooling systems, use of printers at home, and natural ventilation influenced the concentration and types of metal(loid)s in the indoor air., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier B.V.)

Metal pollutants in fine particulate matter (PM 2.5 ) are physiologically toxic, threatening ecosystems through atmospheric deposition. Biotoxicity and bioavailability are mainly determined by the active speciation of metal pollutants in PM 2.5 . As a megacity in China, Beijing has suffered severe particulate pollution over the past two decades, and the health effects of metal pollutants in PM 2.5 have received significant attention. However, there is a limited understanding of the active forms of metals in PM 2.5 and their ecological risks to plants, soil or water in Beijing. It is essential that the ecological risks of metal pollutants in PM 2.5 are accurately evaluated based on their bioavailability, identifying the key pollutants and revealing historic trends to future risks control. A two-year project measured the chemical speciation of pollution elements (As, Cd, Cu, Cr, Ni, Mn, Pb, Sb, Sr, Ti, and Zn) in PM 2.5 in Beijing, in particular their bioavailability, assessing ecological risks and identifying key pollutants. The mass concentrations of total and active species of pollution elements were 199.12 ng/m 3 and 114.97 ng/m 3 , respectively. Active fractions accounted for 57.7 % of the total. Cd had the highest active proportion. Based on the risk assessment code (RAC), most pollution elements except Ti had moderate or high ecological risk, with RAC exceeding 30 %. Cd, with an RAC of 70 %, presented the strongest ecological risk. Comparing our data with previous research shows that concentrations of pollution elements in PM 2.5 in Beijing have decreased over the past decade. However, although the total concentrations of Cd in PM 2.5 have decreased by >50 % over the past decade, based on machine model simulation, its ecological risk has reduced by only 10 %. Our research shows that the ecological risks of pollution elements remain high despite their decreasing concentrations. Controlling the active species of metal pollutants in PM 2.5 in Beijing in the future is vital., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Field determination of the metal adsorption capacity of microplastics (MPs) by using a passive sampler had been done in typical subtropical mariculture area in China. The adsorption of eight metals (Fe, Mn, Cu, Zn, As, Pb, Cr and Cd) by five types of MPs (low-density polyethylene, polypropylene, polystyrene, poly(ethylene terephthalate) and poly(vinyl chloride) (PVC) was compared, including metal types, mariculture types (cage and longline culture), metal residue content in ambient environment, polymer types and particle sizes of MPs. The results showed that Cu, Zn, As, Cd, Pb and Cr in the mariculture environment were contaminated compared with the quality criteria. The concentrations of these six metals adsorbed on five MPs increased linearly with those in seawater. More enriched Cu and As in MPs in marine cage culture than in longline culture, due to the obvious endogenous pollution emissions for the artificial diets, fish medicine and disinfectants. Aged PVC with more cracks and pores showed higher metal adsorption capacity than any other polymers. MPs with a smaller size range of 50-74 μm tended to accumulate higher amounts of metals than those with a larger size range of 74-178 μm, consisting with the surface characteristics of MPs. The significant positive relationship between the concentrations of nutrients in seawater and the adsorption amounts of Cu, Zn and As on MPs implies that the eutrophication would promote their pollution. Based on the ecological risk assessment, the occurrence of MPs could aggravate the potential risk of metals to marine organisms in intensive mariculture areas. This is the first time to reveal the impacts of the adsorption of metals on aged MPs on the potential ecological risks of metals to organisms under the realistic environmental condition., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The Adriatic Sea is an enclosed basin threatened by marine pollution due to its hydrographic features and anthropogenic pressure. Although zooplankton has been worldwide regarded as an immediate warning signal of contamination, limited information is available on the contamination of these organisms at the Adriatic level. Hence, this study provides comprehensive data on the presence and levels of multiple pollutants in zooplankton collected from 46 locations. With regards to legacy contaminants, both PCB and DDT levels have declined since the 1980s. Specifically, most samples were characterized by low DDT contamination (average of 3 ± 2.7 ng g - 1 dry weight) and only few of these accumulated levels of concern for what concerns PCB, pointing out possible hotspots of contamination in the central-eastern Adriatic Sea. As regards metal(loid)s, the Metal Pollution Index identified areas of concern in the north Adriatic Sea (Gulf of Venice) with high levels of Co, Cu, Hg, Cr and Pb; in the Central Adriatic Sea (Tremiti islands) with high levels of Co, Ni, Hg, Cr and Pb; in the Southern Adriatic Sea (Taranto and offshore Corfu), with high levels of most metal(loid)s, especially Cr, Ni and Zn. Certain metal(loid)s (e.g. Cd, Pb and Hg) have declined over time and most of them are lower than well-known contaminated worldwide marine ecosystems. Only Cu appears to be particularly high in the Mediterranean zooplankton. Overall, this work suggests a general improvement of the status of contamination of the Adriatic Sea., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Stored rainwater, the primary source of drinking water in the villages and towns of the Loess Plateau in northwest China, has been found to contain per- and polyfluoroalkyl substances (PFASs) and lacks necessary treatment measures. Coagulation is a common water treatment process, and enhancing its efficacy in removing PFASs can significantly improve treatment efficiency, reduce costs, and minimize the environmental and health risks associated with perfluorinated compounds. This study investigated the removal efficiency of perfluorobutanoic acid (PFBA), perfluorobutanesulfonic acid (PFBS), perfluorooctanoic acid (PFOA), and perfluorooctanesulfonic acid (PFOS) using inorganic salt coagulants alone and in combination with polydimethyldiallylammonium chloride (PDMDAAC). The results indicated that the removal efficiencies of the four PFASs by polyferric chloride (PFCl) and polyaluminum chloride (PACl) increased with alkalinity. PDMDAAC significantly enhanced the coagulation removal efficiency of the four PFASs. The removal efficiency of the four PFASs was highest when the raw water pH was near 7. Within the molecular weight range of 0-500,000 for PDMDAAC, the removal efficiency of the four PFASs increased with increasing molecular weight. Charge neutralization is the primary coagulation mechanism for the removal of anionic PFASs. Therefore, this study provides guidance for selecting coagulants to remove PFASs from stored rainwater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

One of the goals of sustainable agricultural production is to avoid soil contamination by elements defined as trace metals (TMs). The aim of this study was to assess the long-term impact of the use of pig slurry (PS) and NPK mineral fertilizers on the soil content of cadmium (Cd), copper (Cu), lead (Pb) and zinc (Zn). In a 9-year crop rotation, PS was used three times only before root crops. The same four levels of NPK doses (N 0 P 0 K 0 , N 1 P 1 K 1 , N 3 P 2 K 2 , N 4 P 2 K 2 ) were applied to both plots with and without PS. Soil samples were collected in early spring from topsoil (0-0.3 m) and subsoil (0.3-0.6 m). Three forms of TMs were determined in the soil: pseudo-total (Aqua regia); bioavailable (Mehlich 3 method) and readily bioavailable (mobile) forms (1 M NH 4 NO 3 ). The tested factors did not have a significant impact on the Cd, Cu and Pb content, regardless of the form analyzed and the soil depth. PS application significantly increased the content of bioavailable forms of Zn regardless of the year, and the content of pseudo-total Zn only in the sugar beet year, i.e. after manure application. Increasing NPK doses increased the content of mobile Zn in the topsoil, especially in PS plots. A tendency to accumulate mobile forms of Cd and Pb was also observed on NPK-fertilized plots. Thus, long-term application of high NPK doses may increase the risk of contamination of the food chain with these metals. The content of mobile Cd and Zn was positively related to the content of total nitrogen in the soil and negatively related to pH., (© 2024. The Author(s).)

Volcanic eruptions can release large amounts of tephra, lava, and gases, drawing attention due to their magnitude, energy, and impact on life and the environment. Among the most documented and sometimes dramatic effects of volcanic ashes are those linked to the input of diverse elements in the environment, which are released as a consequence of ash weathering. Laboratory studies have been conducted to investigate and predict the environmental input of chemical elements from volcanic ashes. This research paper describes the optimization of batch leaching tests used to investigate the release of ions from ashes collected in the Andes Cordillera after the eruption of the Puyehue volcano in 2011. Chemometric multivariate strategies were employed to evaluate the influence of variables affecting the leaching of volcanic ash. The effects of the main variables, namely contact time, the acidity of the leaching agent, the solid/liquid ratio, the particle size, and the stirring speed, were studied in leaching tests. To determine the optimal conditions for selected metal determinations, we employ Darringer's desirability function, which allows for the simultaneous optimization of the selected responses (element concentrations during the leaching process). Multielemental analysis (Na, Mg, Al, Si, P, Cl, K, Ca, V, Cr, Mn, Fe, Ni, Cu, Zn, Sr, Cd, Hg, Tl, and Pb) was quantified by ICP-MS (inductively coupled plasma-mass spectrometry) following adequate dilution of test leaching. These results established the optimal experimental conditions for leaching volcanic ash. The most significant variables were the solid/liquid ratio and the stirring speed, resulting in two groups of elements with an adequate global desirability function (D) value., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This study focused on 120 specimens of the shrimp Palaemon elegans collected in intertidal zones in eight selected areas. This study aimed to assess the suitability of P. elegans as a bioindicator of natural and anthropogenic marine pollution. Metal concentrations of aluminum (Al), cadmium (Cd), copper (Cu), iron (Fe), lead (Pb), and zinc (Zn) were measured in shrimp collected from various sites in the Canary Islands, including areas affected by volcanic activity, industrial activity, and control zones. The determination of metal concentrations was conducted using inductively coupled plasma optical emission spectrophotometry (ICP-OES). The results showed significant differences in metal concentrations across the studied sites, with the highest levels of Al, Cu, Fe, Pb, and Zn observed in areas impacted by the Tajogaite volcanic eruption and harbor activity. Sites near old landfills and sewage pipes also exhibited elevated levels of Cd, Cu, and Pb, indicating strong anthropogenic influence. Al was found in the highest concentration in Harbour, reaching 25.7 ± 6.2 mg/kg, while the lowest concentration was observed in Control Lp at 11.5 ± 0.69 mg/kg. Conversely, lower metal concentrations were detected in control zones and areas with high dinoflagellate presence, suggesting a potential role of bioremediation by marine phytoplankton. The ability of P. elegans to accumulate metals in its tissues, particularly in areas of high pollution, highlights its potential as a bioindicator species. This study underscores the importance of P. elegans in monitoring marine pollution and provides insights into the environmental impact of both natural and human-induced contamination on coastal ecosystems., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This work presents a year-long integral study of air quality parameters in Ciudad Real, a small city in the center of Spain, and its influence on the nearby national park, Las Tablas de Daimiel. The study covers meteorological parameters and criteria pollutants such as O 3 , NO, NO 2 , SO 2 , and PM 10 . Additionally, for each month, a 1-week campaign was performed sampling air in sorbent tubes with 8-h time resolution to analyze anthropogenic volatile organic compounds and the effects of seasons, daytime, and working-weekend days. During these campaigns, 24-h PM 2.5 samples were also collected to measure the load of bacteria and fungi, as well as the trace concentrations of elements.The city and the national park NOx profiles showed that emissions from the town had a non-perceivable effect on the protected area. PM 10 levels in Ciudad Real were influenced by Saharan intrusions, as was the national park; however, Ciudad Real had a higher contribution from anthropogenic sources. Ozone levels were lower in the city during the cold season due to the higher concentration of NOx and have not changed significantly in the last decade.The VOCs with higher average concentrations were toluene, m,p-xylene, benzene, methylene chloride, and o-xylene, with traffic being the main source of these pollutants in the city. For benzene and carbon tetrachloride levels, weak carcinogenic risks were estimated. In PM 2.5 , the most abundant metals were Na, Zn, Mg, Ca, Al, Fe, and K. The carcinogenic and non-carcinogenic risks estimated from the levels of the studied metals were negligible. Bacterial and fungal counts positively correlated with the concentration of PM 2.5 . Microbial community composition showed seasonal variability, with the dominance of human pathogenic bacteria which correlated with certain pollutants such as SO 2 . Bacillus and Cutibacterium were the most abundant genera., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Very little information exists on the particle and chemical contamination of consumer (horticultural) composts. In this study, anthropogenic microcellulosics (AMCs), microplastics (MPs) and other microscopic debris, along with anthropogenically impacted metals (Cu, Zn, Pb), have been determined in 12 composts (seven garden composts and five growbags) purchased at outlets in the UK. AMCs and MPs, determined microscopically, were present in all samples at up to about 1100 kg -1 dw. AMCs were more abundant and were dominated by fibres constructed of rayon and cotton, while petroleum-based MPs exhibited a greater diversity in shape and polymeric construction (including polyolefins, polyethylene terephthalate, polyvinyl chloride, resins, paints and rubbers). Other microdebris, present in much smaller concentrations in the composts, consisted of fragments of glass, metal and machined wood and spherical glass beads. Concentrations of the anthropogenically impacted metals, Cu, Pb and Zn, determined directly by energy-dispersive X-ray fluorescence spectrometry, were heterogeneously distributed and averaged 52.4, 192 and 51.6 mg kg -1 dw, respectively. Although concentrations of anthropogenic particles were not related to cost or type of compost, physico-chemical properties or metal concentrations, a significant relationship between Pb content and particle diversity (number of polymers and debris types) was established. This relationship might result from the general contamination of the environment by both Pb and anthropogenic particulates, or the association of the metal with various types of material (e.g. paints, polyvinyl chloride, glass). Despite the ubiquity and diversity of MPs and microdebris in consumer composts, an understanding of their impacts on plant growth, either directly or indirectly (e.g. by interacting with metals), is unknown., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Many studies have studied biochar immobilizing chromium (Cr) in soil. However, few studies were conducted to reduce the environmental risks due to biochar aging in soil. In this study, we adopt FeCl 3 , MgCl 2 , and AlCl 3 to activate sewage sludge to form modified biochar and produce biochar tubules. Then, the column experiments were carried out to study the effect of fluctuating groundwater table on Cr leaching behavior, total Cr, and fractions distribution with the insertion of biochar tubule. Results showed that the Cr immobilization performance was improved by metal-modification biochar, the biochar tubules can significantly decrease the Cr leaching amounts, retard the Cr downward migration in the soil, and there was a better effect with slightly Cr-contaminated soil. In addition, the immobilization effect is also impacted by the biochar's application mode and the hydrodynamic conditions. Detailedly, the Cr leaching amounts maximally decreased by 33.39%, the residual amounts maximally increased by 10.05% in the soil column, and the exchangeable (EX) and carbonates-bound (CB) fractions were maximally increased by 85.18%, 151.78% at the equal depth of soil column, respectively. BET, SEM-EDS, XRD, and FTIR analyses revealed that biochars' immobilization mechanisms on Cr involved reduction(predominately), physisorption, precipitation, and complexation. Risk assessment demonstrated that the sewage sludge biochar has very low environmental risk. This study indicates that the biochar tubule applied to immobilize Cr in soil has potential and provides new insights into reducing environmental risks due to biochar aging., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

The pandemic (COVID-19) had diverse effects on marine pollution. Throughout the lockdown periods, temporary enhancements in water quality and biodiversity were observed due to reduced human activity and constraints on travel and maritime transportation. The marine snail, Phorcus sauciatus, served as an indicator for marine pollution, and samples were collected in Tenerife, Canary Islands, during various months in 2020. The findings indicated that metal concentrations in Phorcus sauciatus were higher in February but declined in July and December as a result of reduced tourist activity during the pandemic. This underscores the significance of promoting sustainable tourism in the Canary Islands to mitigate high metal concentrations in the marine environment. The COVID-19 pandemic had a positive impact on reducing metal concentrations in marine pollution, underscoring the importance of adopting sustainable tourism practices to protect marine ecosystems., Competing Interests: Declaration of competing interest All authors declare that the use of animals for this research complies with the requirements of European legislation on the use of animals for experimentation. All anemone samples have been taken with fishing permits and permission from the Spanish ministry. Samples were obtained from broodstock captured, so these organisms were not slaughtered by the authors of this manuscript, therefore we faithfully comply with the Code of Practice for Housing and Care of Animals Used in Scientific Procedures., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This study aimed to assess the concentrations of eight trace metals - Cr, As, Pb, Mn, Ni, Zn, Hg, and Co - in the intertidal zone of Cox's Bazar of Bangladesh, the world's longest continuous beach. Most metal concentrations were below sediment quality guidelines and other comparative studies. The mean metal concentrations (mg kg -1 ) were as follows: Mn (471.67) > Zn (256.35) > Cr (89.96) > Pb (39.66) > Ni (36.44) > As (18.79) > Co (11.08) > Hg (0.0036). Statistical analyses revealed that only samples collected from stations 5 and 7 presented any cause for concern. Risk assessment indices, i.e., Geo-accumulation Index (I geo ), Contamination Factor (CF), Pollution Load Index (PLI), Potential Ecological Risk Index (PERI), and Toxic Risk Index (TRI), all indicated a low to moderate risk of pollution for all sites, suggesting that the study area is currently free from any significant negative impacts resulting from human activities. The calculated Hazard Index (HI) was <1, indicating no significant non-carcinogenic impact on adults or children. The Total Carcinogenic Risk was also well below the threshold value., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Birds are good bioindicators of disturbance in the environment. They are present in different habitats and trophic levels. In addition, rapid urbanization has led birds to use cities as shelter and for seeking food resources. Sewage treatment plants (STPs) are suitable locations for free-living birds within cities. However, few studies address the impacts of emerging pollutants from sewage treatment plants on wild birds. In this sense, the aim of this study was to analyze the genotoxic, mutagenic, and immunological impacts from metal and pollutant exposure on free-living birds collected at a STP. For comparison, birds were collected in a preserved environment, the Silvania National Forest (FLONA). To achieve this, we used non-destructive biomarkers sensitive to environmental changes. Birds were collected in both environments using mist nets. After collection, birds were weighed, measured, species-identified, and released. Blood was collected for comet assay, micronucleus test, and leukocyte profile, while feathers were collected for metal concentration analysis. Water physicochemical parameters were measured at both sites, and water samples were collected for metal analysis. Our results demonstrated that birds collected at the STP exhibit a higher frequency of genotoxic damage and erythrocyte abnormalities, and increased immune response compared to FLONA birds. Traces of potentially toxic metals, such as Hg and As, were found in the birds feathers from both environments, raising concerns about metal contamination in both environments. Trophic guilds appear to respond similarly to exposure. The parameters and metals found in the water reflect environmental characteristics and may be influencing pollutant availability. Finally, despite the advancement of our findings, studies linking these damages to detrimental effects on behavior and reproduction are encouraged., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:Renata Maria Pereira de Freitas reports financial support was provided by Brazilian National Council for Scientific and Technological Development (CNPq). The authors declare that they have no conflicts of interest in relation to this study. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

This study examined the sediment metal fractions and availability to infer bioaccumulation in marine harbor benthic organisms. Total metals were analyzed using atomic absorption spectrometry and inductively coupled plasma-optical emission spectrometry for chemical fractions and organisms. The results showed similar metal concentrations and distribution driven by rivers and harbor pollution. We found significant differences in metal accumulation in marine benthic groups, highest in scavenger species. Their metal concentrations in decreasing order were 1.97-4568, 0.10-1260, 1.64-159, and 0.105-112 μg g -1 dw for hermit crabs, forams, bivalves, and polychaetes. Moreover, certain organisms, such as tusk shells, sea pens, bivalves, forams, and isopods, may exhibit selective metal accumulation. Biota-sediment accumulation factors (>1) were highest for essential metals like Cu, Zn, and Mn, while toxic metals like As, Cr, Co, and Ni increased. This concurrent assessment provides more comprehensive data for metal bioaccumulation in marine benthic ecosystems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Background: Industrial facilities across the United States (US) release millions of pounds of toxic chemicals, including metals. Exposure to toxic metals has been associated with adverse health outcomes, but there is limited evidence on the association between living near metal-releasing facilities and the body burden of emitted compounds., Objective: To investigate the association between residential proximity to toxic metal-emitting industrial facilities and toenail metal concentrations and to evaluate whether associations differed by race., Methods: In a sample of 1556 non-Hispanic Black (32.5%) and non-Hispanic White (67.5%) women from the Sister Study, we used the US Environmental Protection Agency Toxics Release Inventory to identify metal-emitting facilities within 3, 5, and 10 km of participants' baseline residences. We measured toenail concentrations (μg/g) of arsenic, cadmium, cobalt, chromium, and lead. Using multivariable linear regression, we examined associations between residential proximity to and emissions from metal-emitting facilities and toenail metal concentrations, stratifying by race. We explored modification of race-stratified associations by neighborhood deprivation, using the Area Deprivation Index (ADI)., Results: Black participants were more likely to reside within 3 km of chromium-releasing facilities and 5 and 10 km of all observed metal-emitting sites. Living near metal-releasing facilities was not associated with higher toenail metal concentrations overall. Among Black women, higher chromium emissions exposure was associated with higher toenail chromium levels (β Tertile3vs.non-exposed  = 2.36 μg/g, 95% CI = 0.63, 4.10). An association with lead was observed among Black women residing in the most deprived areas (≥75th ADI percentile: β = 3.08 μg/g, 95% CI = 1.46, 4.71). No associations were observed for White participants., Conclusions: Despite low exposure prevalence, our findings suggest that living near chromium- and lead-releasing facilities, especially at shorter distances, may be associated with higher corresponding toenail metal levels among Black women, particularly those residing in the most disadvantaged areas., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Published by Elsevier Inc.)

The optimization of alternative materials in concrete production continues to garner considerable attention in order to meet sustainability goals and supplement natural materials. Portland limestone cement (PLC) and municipal solid waste incineration (MSWI) bottom ash (BA) have been proposed separately as green cement and coarse aggregate supplement in low-strength concrete production, creating sustainable products and alternative disposal scenario for a waste material. This study discusses the impact of advanced ash processing techniques on aggregates and presents the performance of concrete incorporating both of these products with PLC for the first time. Two sources of MSWI BA were investigated, one as-produced (TMR) and one processed with novel advanced metals recovery (AMR). The AMR process reduced total Al content in ash compared to TMR (20,500 vs 17,000 mg/kg), though not aluminum oxide content, as the AMR process targets metallic aluminum. A composition study on both aggregates supports a reduction in ferrous and non-ferrous metals following the AMR process. All control and test mixes met 28-day compressive strength requirements (17 Mpa). Both AMR and TMR MSWI BA-amended concretes yielded compressive strengths below control specimens (no ash) ranging from 17 to 23 MPa, with little to no difference observed dependent on MSWI BA processing. The life-cycle discussion supports benefits deriving from supplementing naturally mined materials and recovering ferrous and nonferrous metals with the AMR process., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Timothy G. Townsend, Christopher C. Ferraro, Kate D. Weiksnar, Ethan J. Marks, Margaret J. Deaderick, Isabella Mejia-Ruiz report financial support was provided by Solid Waste Authority of Palm Beach County. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Enteral nutrition formulas are products that provide macro and micronutrients to patients who cannot receive their nutrition orally. In this study, the levels of 23 metals known to have potential health risks were determined by inductively coupled plasma mass spectrometry in a total of 28 enteral nutrition formula. Metal exposure was calculated according to three different daily energy intake scenarios (Scenario 1 = 50% oral nutrition + 50% enteral nutrition formula, Scenario 2 = 25% oral nutrition + 75% enteral nutrition formula and Scenario 3 = 100% enteral nutrition formula) and evaluated in terms of non-carcinogenic health risks. The mean levels of Fe, Co, Ni, Cu, Zn, Mo, Se, Li, Be, V, As, Sr, Ag, Cd, Sb, Ba, La, Hg and Pb in the samples analyzed were determined 12,000 ± 3300, 64 ± 1.6, 10 ± 13, 1300 ± 400, 8500 ± 2500, 75 ± 30, 61 ± 21, 0.34 ± 0.36, 0.05 ± 0.08, 7.3 ± 2, 1.6 ± 0.6, 457 ± 166, 0.02 ± 0.1, 0.14 ± 0.12, 0.01 ± 0.1, 74 ± 103, 0.63 ± 0.4, 0.05 ± 0.03 and 0.14 ± 0.7 μg/L. These metals were considered safe in terms of non-carcinogenic health risks when analyzed individually. However, when the target hazard quotient values of all metals were evaluated together, hazard index values were higher than the reference value of 1, for both men and women, indicating potential health risks., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The agro-food surplus is considered the most abundant renewable resource, interesting for the economic and environmental impact, with a possible employment in different productive fields such as supplement in animal feed. For a safe and effective enhancement of agro-food wastes it is needed a toxicological analysis before of their employment, to avoid potential risks to animals, humans and environment. The purpose of this study was to evaluate the metals content (Cu, Fe, Zn, Mg, Na, K, Ca, Mn, Se, Zn, Co, Ni, V, Sb, Mo, Cr and Pb, Cd, As, Ba), in agro-food wastes through ICP-MS analysis. The results obtained showed the presence of metals analysed with a significant content of essential micro and macro-elements; with regard to toxic metals, only strawberries and fennel samples showed Pb levels above the MRL. These data confirm, from the toxicological point of view, a possible and safe reuse of the most of all agro-food wastes, as raw material at low cost and rich of essential nutrients and particularly as supplement in animal feed.