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Electrochemical energy storage and conversion devices are very unique and important for providing solutions to clean, smart, and green energy sectors particularly for stationary and automobile applications. They are broadly classified and overviewed with a special emphasis on rechargeable batteries (Li‐ion, Li‐oxygen, Li‐sulfur, Na‐ion, and redox flow batteries), electrocatalysts, and membrane electrolytes for fuel cells. The critical challenges for the development of sustainable energy storage systems are the intrinsically limited energy density, poor rate capability, cost, safety, and durability. Albeit huge advancements have been made to address these challenges, it is still long way to reach the energy demand, especially in the large‐scale storage and e‐mobility. A landscape of battery materials developments including the next generation battery technology is meticulously arrived, which enables to explore the alternate energy storage technology. Next generation energy storage systems such as Li‐oxygen, Li‐sulfur, and Na‐ion chemistries can be the potential option for outperforming the state‐of‐art Li‐ion batteries. Also, redox flow batteries, which are generally recognized as a possible alternative for large‐scale storage electricity, have the unique virtue of decoupling power and energy. In this overview, a systematic survey on the materials challenges and a comprehensive understanding of the structure–property–performance relationship of the storage and conversion devices is covered. Further, in‐depth detailing of various catalysts and membrane electrolytes that can be explored as a viable alternative for polymer electrolyte fuel cells as well as direction toward futuristic research areas is highlighted. This article is categorized under:Energy and Development > Science and MaterialsSustainable Energy > BioenergyEmerging Technologies > Energy Storage [ABSTRACT FROM AUTHOR]

Abstract: Seeking alternative olefin/paraffin separation techniques have been attracting great interest due to the high operating and capital costs of current commercially practiced separation processes. An olefin/paraffin separation scheme using membrane based facilitated transport/chemical absorption techniques offers great advantages such as reducing the operating and capital costs, as well as eliminating the operating drawbacks occurring in absorption processes such as flooding, foam formation, etc. Consequently, the utilization of a facilitated transport/chemical absorption scheme with a suitable membrane system for olefin/paraffin separation would be an attractive option for the replacement of the current separation technologies. A comprehensive review is presented for application of membranes for light olefin/paraffin separation. This article covers all types of membrane based facilitated transport/chemical absorption techniques which include various conventional liquid membranes configurations, membrane contactors and more advanced solid membrane electrolytes. The performance evaluation, shortcomings, and advantages are discussed in details. [Copyright &y& Elsevier]

All‐solid‐state flexible asymmetric supercapacitors (ASCs) are developed by utilization of graphene nanoribbon (GNR)/Co0.85Se composites as the positive electrode, GNR/Bi2Se3 composites as the negative electrode, and polymer‐grafted‐graphene oxide membranes as solid‐state electrolytes. Both GNR/Co0.85Se and GNR/Bi2Se3 composite electrodes are developed by a facile one‐step hydrothermal growth method from graphene oxide nanoribbons as the nucleation framework. The GNR/Co0.85Se composite electrode exhibits a specific capacity of 76.4 mAh g−1 at a current density of 1 A g−1 and the GNR/Bi2Se3 composite electrode exhibits a specific capacity of 100.2 mAh g−1 at a current density of 0.5 A g−1. Moreover, the stretchable membrane solid‐state electrolytes exhibit superior ionic conductivity of 108.7 mS cm−1. As a result, the flexible ASCs demonstrate an operating voltage of 1.6 V, an energy density of 30.9 Wh kg−1 at the power density of 559 W kg−1, and excellent cycling stability with 89% capacitance retention after 5000 cycles. All these results demonstrate that this study provides a simple, scalable, and efficient approach to fabricate high performance flexible all‐solid‐state ASCs for energy storage. [ABSTRACT FROM AUTHOR]