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Attosecond X-ray pulses are the key to studying electron dynamics at their natural time scale involving specific electronic states. They are promising to build the conceptual bridge between physical and chemical photo-reaction processes. Free-electron lasers have demonstrated their capability of generating intense attosecond X-ray pulses. However, harnessing them for time-resolving experiments and investigations of nonlinear X-ray absorption mechanisms remains a cutting-edge challenge. We have characterised X-ray pulses with durations of down to 700$\,$attoseconds and peak powers up to 200$\,$GW at $\sim$ 1$\,$keV photon energy via angular streaking at the SQS instrument of the European XFEL. As direct application, we present results of nonlinear X-ray-matter interaction via state-specific spectroscopy on a transient system. Using the derived spectral and temporal information of each pulse, we deliberately steer the probability for formation of double-core vacancies in neon gas atoms through excitation or ionisation of the second inner-shell electron after K-shell ionisation. Our results advance the field of attosecond science with highly intense and fully characterised X-ray pulses to the site-specific investigation of electronic motion in transient media.

We present a near infrared (NIR) candidate star cluster catalog for the central kiloparsec of M82 based on new JWST NIRCam images. We identify star cluster candidates using the F250M filter, finding 1357 star cluster candidates with stellar masses $>10^4$ M$_\odot$. Compared to previous optical catalogs, nearly all (87%) of the candidates we identify are new. The star cluster candidates have a median intrinsic cluster radius of $\approx$1 pc and have stellar masses up to $10^6$ M$_\odot$. By comparing the color-color diagram to dust-free yggdrasil stellar population models, we estimate that the star cluster candidates have A$_{\rm V}\sim3-24$ mag, corresponding to A$_{\rm 2.5\mu m}\sim0.3-2.1$ mag. There is still appreciable dust extinction towards these clusters into the NIR. We measure the stellar masses of the star cluster candidates, assuming ages of 0 and 8 Myr. The slope of the resulting cluster mass function is $\beta=1.9\pm0.2$, in excellent agreement with studies of star clusters in other galaxies., Comment: Resubmitted to ApJL

In this paper we study the filamentary substructure of 3.3 $\mu$m PAH emission from JWST/NIRCam observations in the base of the M82 star-burst driven wind. We identify plume-like substructure within the PAH emission with widths of $\sim$50 pc. Several of the plumes extend to the edge of the field-of-view, and thus are at least 200-300 pc in length. In this region of the outflow, the vast majority ($\sim$70\%) of PAH emission is associated with the plumes. We show that those structures contain smaller scale "clouds" with widths that are $\sim$5-15 pc, and they are morphologically similar to the results of "cloud-crushing" simulations. We estimate the cloud-crushing time-scales of $\sim$0.5-3 Myr, depending on assumptions. We show this time scale is consistent with a picture in which these observed PAH clouds survived break-out from the disk rather than being destroyed by the hot wind. The PAH emission in both the midplane and the outflow is shown to tightly correlate with that of Pa$\alpha$ emission (from HST/NICMOS data), at the scale of both plumes and clouds, though the ratio of PAH-to-Pa$\alpha$ increases at further distances from the midplane. Finally, we show that the outflow PAH emission is suppressed in regions of the M82 wind that are bright in X-ray emission. Overall, our results are broadly consistent with a picture in which cold gas in galactic outflows is launched via hierarchically structured plumes, and those small scale clouds are more likely to survive the wind environment when collected into the larger plume structure., Comment: Submitted to MNRAS

The physical properties of galactic molecular outflows are important as they could constrain outflow formation mechanisms. We study the properties of the southwest (SW) outflow streamer including gas kinematics, optical depth, dense gas fraction, and shock strength in the central molecular zone of the starburst galaxy NGC 253. We image the molecular emission at a spatial resolution of $\sim$27 pc based on data from the ALCHEMI program. We trace the kinematics of molecular gas with CO(1-0) line. We constrain the optical depth of CO emission with CO/$^{13}$CO(1-0) ratio, the dense gas fraction with HCN/CO(1-0) ratio, as well as the shock strength with SiO(2-1)/$^{13}$CO(1-0) ratio. The CO/$^{13}$CO(1-0) integrated intensity ratio is $\sim$21 in the SW streamer region, which approximates the C/$^{13}$C isotopic abundance ratio. The higher integrated intensity ratio compared to the disk can be attributed to the optically thinner environment for CO(1-0) emission inside the SW streamer. The HCN/CO(1-0) and SiO(2-1)/$^{13}$CO(1-0) integrated intensity ratios both approach $\sim$0.2 in three giant molecular clouds (GMCs) at the base of the outflow streamers, which implies the higher dense gas fraction and enhanced strength of fast shocks in those GMCs than in the disk. The contours of those two integrated intensity ratios are extended towards the directions of outflow streamers, which connects the enhanced dense gas fraction and shock strength with molecular outflow. Moreover, the molecular gas with enhanced dense gas fraction and shock strength located at the base of the SW streamer shares the same velocity with the outflow. These phenomena suggest that the star formation inside the GMCs can trigger the shocks and further drive the molecular outflow., Comment: Accepted for publication in A&A, 14 pages, 11 figures

We present new observations of the central 1 kpc of the M 82 starburst obtained with the James Webb Space Telescope (JWST) near-infrared camera (NIRCam) instrument at a resolution ~0.05"-0.1" (~1-2 pc). The data comprises images in three mostly continuum filters (F140M, F250M, and F360M), and filters that contain [FeII] (F164N), H2 v=1-0 (F212N), and the 3.3 um PAH feature (F335M). We find prominent plumes of PAH emission extending outward from the central starburst region, together with a network of complex filamentary substructure and edge-brightened bubble-like features. The structure of the PAH emission closely resembles that of the ionized gas, as revealed in Paschen alpha and free-free radio emission. We discuss the origin of the structure, and suggest the PAHs are embedded in a combination of neutral, molecular, and photoionized gas., Comment: Submitted to The Astrophysical Journal

Molecular lines are powerful diagnostics of the physical and chemical properties of the interstellar medium (ISM). These ISM properties, which affect future star formation, are expected to differ in starburst galaxies from those of more quiescent galaxies. We investigate the ISM properties in the central molecular zone of the nearby starburst galaxy NGC 253 using the ultra-wide millimeter spectral scan survey from the ALMA Large Program ALCHEMI. We present an atlas of velocity-integrated images at a 1".6 resolution of 148 unblended transitions from 44 species, including the first extragalactic detection of HCNH$^+$ and the first interferometric images of C$_3$H$^+$, NO, HCS$^+$. We conduct a principal component analysis (PCA) on these images to extract correlated chemical species and to identify key groups of diagnostic transitions. To the best of our knowledge, our dataset is currently the largest astronomical set of molecular lines to which PCA has been applied. The PCA can categorize transitions coming from different physical components in NGC 253 such as i) young starburst tracers characterized by high-excitation transitions of HC$_3$N and complex organic molecules (COMs) versus tracers of on-going star formation (radio recombination lines) and high-excitation transitions of CCH and CN tracing PDRs, ii) tracers of cloud-collision-induced shocks (low-excitation transitions of CH$_3$OH, HNCO, HOCO$^+$, and OCS) versus shocks from star-formation-induced outflows (high-excitation transitions of SiO), as well as iii) outflows showing emission from HOC$^+$, CCH, H$_3$O$^+$, CO isotopologues, HCN, HCO$^+$, CS, and CN. Our findings show these intensities vary with galactic dynamics, star formation activities, and stellar feedback., Comment: 65 pages, 39 figures. Accepted for publication in ApJS

We present a spatially-resolved excitation analysis for the central molecular zone (CMZ) of the starburst galaxy NGC 253 using the data from the ALMA Large program ALCHEMI, whereby we explore parameters distinguishing NGC 253 from the quiescent Milky Way's Galactic Center (GC). Non-LTE analyses employing a hierarchical Bayesian framework are applied to Band 3-7 transitions from nine molecular species to delineate the position-position-velocity distributions of column density ($N_\mathrm{H_2}$), volume density ($n_\mathrm{H_2}$), and temperature ($T_\mathrm{kin}$) at 27 pc resolution. Two distinct components are detected: a low-density component with $(n_\mathrm{H_2},\ T_\mathrm{kin})\sim(10^{3.3}\ \mathrm{cm}^{-3}, 85 K)$ and a high-density component with $(n_\mathrm{H_2},\ T_\mathrm{kin})\sim (10^{4.4}\ \mathrm{cm}^{-3}, 110\ \mathrm{K})$, separated at $n_\mathrm{H_2}\sim10^{3.8}\ \mathrm{cm}^{-3}$. NGC 253 has $\sim10$ times the high-density gas mass and $\sim3$ times the dense-gas mass fraction of the GC. These properties are consistent with their HCN/CO ratio but cannot alone explain the factor of $\sim30$ difference in their star formation efficiencies (SFEs), contradicting the dense-gas mass to star formation rate scaling law. The $n_\mathrm{H_2}$ histogram toward NGC 253 exhibits a shallow declining slope up to $n_\mathrm{H_2}\sim10^6\ \mathrm{cm}^{-3}$, while that of the GC steeply drops in $n_\mathrm{H_2}\gtrsim10^{4.5}\ \mathrm{cm}^{-3}$ and vanishes at $10^5\ \mathrm{cm}^{-3}$. Their dense-gas mass fraction ratio becomes consistent with their SFEs when the threshold $n_\mathrm{H_2}$ for the dense gas is taken at $\sim 10^{4.2\mbox{-}4.6}\ \mathrm{cm}^{-3}$. The rich abundance of gas above this density range in the NGC 253 CMZ, or its scarcity in the GC, is likely to be the critical difference characterizing the contrasting star formation in the centers of the two galaxies., Comment: 49 pages, 27 figures, 7 tables, accepted for publication in the Astrophysical Journal

The Milky Way is a barred spiral galaxy with "bar lanes" that bring gas towards the Galactic Center. Gas flowing along these bar lanes often overshoots, and instead of accreting onto the Central Molecular Zone, it collides with the bar lane on the opposite side of the Galaxy. We observed G5, a cloud which we believe is the site of one such collision, near the Galactic Center at (l,b) = (+5.4, -0.4) with the ALMA/ACA. We took measurements of the spectral lines $^{12}$CO J=2-1, $^{13}$CO J=2-1, C$^{18}$O J=2-1, H$_2$CO J=3$_{03}$-2$_{02}$, H$_{2}$CO J=3$_{22}$-2$_{21}$, CH$_{3}$OH J=4$_{22}$-3$_{12}$, OCS J=18-17 and SiO J=5-4. We observed a velocity bridge between two clouds at $\sim$50 km/s and $\sim$150 km/sin our position-velocity diagram, which is direct evidence of a cloud-cloud collision. We measured an average gas temperature of $\sim$60 K in G5 using H$_2$CO integrated intensity line ratios. We observed that the $^{12}$C/$^{13}$C ratio in G5 is consistent with optically thin, or at most marginally optically thick $^{12}$CO. We measured 1.5 x 10$^{19}$ cm$^{-2}$(K km/s)$^{-1}$ for the local X$_{CO}$, 10-20x less than the average Galactic value. G5 is strong direct observational evidence of gas overshooting the Central Molecular Zone (CMZ) and colliding with a bar lane on the opposite side of the Galactic center., Comment: Accepted to ApJ. 27 pages, 19 figures

The inner 300-500 pc of the Milky Way has some of the most extreme gas conditions in our Galaxy. Physical properties of the Central Molecular Zone (CMZ), including temperature, density, thermal pressure, and turbulent pressure, are key factors for characterizing gas energetics, kinematics, and evolution. The molecular gas in this region is more than an order of magnitude hotter than gas in the Galactic disk, but the mechanism responsible for heating the gas remains uncertain. We characterize the temperature for 16 regions, extending out to a projected radius of $\sim$450 pc. We observe \am\, J,K=(1,1)-(6,6) inversion transitions from SWAG (Survey of Water and Ammonia in the Galactic Center) using the Australia Telescope Compact Array (ATCA), and ammonia lines (J,K) = (8,8)-(14,14) using the 100\,m Green Bank Telescope. Using these two samples we create full Boltzmann plots for every source and fit two rotational temperature components to the data. For the cool component we detect rotational temperatures ranging from 20-80\,K, and for the hot component we detect temperature ranging from 210-580\,K. With this sample of 16 regions, we identify some of the most extreme molecular gas temperatures detected in the Galactic center thus far. We do not find a correlation between gas temperature and Galactocentric radius, and we confirm that these high temperatures are not exclusively associated with actively star-forming clouds. We also investigate temperature and line widths and find (1) no correlation between temperature and line width and (2) the lines are non-thermally broadened indicating that non-thermal motions are dominant over thermal., Comment: 39 pages, 42 figures, 7 tables

Accurate, high throughput, and unbiased analysis of plutonium oxide particles is needed for analysis of the phenomenology associated with process parameters in their synthesis. Compared to qualitative and taxonomic descriptors, quantitative descriptors of particle morphology through scanning electron microscopy (SEM) have shown success in analyzing process parameters of uranium oxides. We utilize a VQ-VAE to quantitatively describe plutonium dioxide (PuO2) particles created in a designed experiment and investigate their phenomenology and prediction of their process parameters. PuO2 was calcined from Pu(III) oxalates that were precipitated under varying synthetic conditions that related to concentrations, temperature, addition and digestion times, precipitant feed, and strike order; the surface morphology of the resulting PuO2 powders were analyzed by SEM. A pipeline was developed to extract and quantify useful image representations for individual particles with the VQ-VAE to perform multiple classification tasks simultaneously. The reduced feature space could predict process parameters with greater than 80% accuracies for some parameters with a single particle. They also showed utility for grouping particles with similar surface morphology characteristics together. Both the clustering and classification results reveal valuable information regarding which chemical process parameters chiefly influence the PuO2 particle morphologies: strike order and oxalic acid feedstock. Doing the same analysis with multiple particles was shown to improve the classification accuracy on each process parameter over the use of a single particle, with statistically significant results generally seen with as few as four particles in a sample., Comment: 23 pages, 13 figures

We analyze HCN and HNC emission in the nearby starburst galaxy NGC 253 to investigate its effectiveness in tracing heating processes associated with star formation. This study uses multiple HCN and HNC rotational transitions observed using ALMA via the ALCHEMI Large Program. To understand the conditions and associated heating mechanisms within NGC 253's dense gas, we employ Bayesian nested sampling techniques applied to chemical and radiative transfer models which are constrained using our HCN and HNC measurements. We find that the volume density $n_{\text{H}_{2}}$ and cosmic ray ionization rate (CRIR) $\zeta$ are enhanced by about an order of magnitude in the galaxy's central regions as compared to those further from the nucleus. In NGC 253's central GMCs, where observed HCN/HNC abundance ratios are lowest, $n \sim 10^{5.5}$ cm$^{-3}$ and $\zeta \sim 10^{-12}$ s$^{-1}$ (greater than $10^4$ times the average Galactic rate). We find a positive correlation in the association of both density and CRIR with the number of star formation-related heating sources (supernova remnants, HII regions, and super hot cores) located in each GMC, as well as a correlation between CRIRs and supernova rates. Additionally, we see an anticorrelation between the HCN/HNC ratio and CRIR, indicating that this ratio will be lower in regions where $\zeta$ is higher. Though previous studies suggested HCN and HNC may reveal strong mechanical heating processes in NGC 253's CMZ, we find cosmic ray heating dominates the heating budget, and mechanical heating does not play a significant role in the HCN and HNC chemistry., Comment: 33 pages, 23 figures, accepted for publication by the Astrophysical Journal

Centers of starburst galaxies may be characterized by a specific gas and ice chemistry due to their gas dynamics and the presence of various ice desorption mechanisms. This may result in a peculiar observable composition. We analyze abundances of $CO_2$, a reliable tracer of ice chemistry, from data collected as part of the ALMA large program ALCHEMI, a wide-frequency spectral scan toward the starburst galaxy NGC~253 with an angular resolution of 1.6$''$. We constrain the $CO_2$ abundances in the gas phase using its protonated form $HOCO^+$. The distribution of $HOCO^+$ is similar to that of methanol, which suggests that $HOCO^+$ is indeed produced from the protonation of $CO_2$ sublimated from ice. The $HOCO^+$ fractional abundances are found to be $(1-2)\times10^{-9}$ at the outer part of the central molecular zone (CMZ), while they are lower ($\sim10^{-10}$) near the kinematic center. This peak fractional abundance at the outer CMZ is comparable to that in the Milky Way CMZ, and orders of magnitude higher than that in Galactic disk star-forming regions. From the range of $HOCO^+/CO_2$ ratios suggested from chemical models, the gas-phase $CO_2$ fractional abundance is estimated to be $(1-20)\times10^{-7}$ at the outer CMZ, and orders of magnitude lower near the center. We estimate the $CO_2$ ice fractional abundances at the outer CMZ to be $(2-5)\times10^{-6}$ from the literature. A comparison between the ice and gas $CO_2$ abundances suggests an efficient sublimation mechanism. This sublimation is attributed to large-scale shocks at the orbital intersections of the bar and CMZ., Comment: 22 pages, 9 figures. Accepted for publication in the Astrophysical Journal

We present real-world data processing on measured electron time-of-flight data via neural networks. Specifically, the use of disentangled variational autoencoders on data from a diagnostic instrument for online wavelength monitoring at the free electron laser FLASH in Hamburg. Without a-priori knowledge the network is able to find representations of single-shot FEL spectra, which have a low signal-to-noise ratio. This reveals, in a directly human-interpretable way, crucial information about the photon properties. The central photon energy and the intensity as well as very detector-specific features are identified. The network is also capable of data cleaning, i.e. denoising, as well as the removal of artefacts. In the reconstruction, this allows for identification of signatures with very low intensity which are hardly recognisable in the raw data. In this particular case, the network enhances the quality of the diagnostic analysis at FLASH. However, this unsupervised method also has the potential to improve the analysis of other similar types of spectroscopy data.

We present ALMA data on the 3mm continuum emission, CO isotopologues (12CO, 13CO, C18O), and high-density molecular tracers (HCN, HCO+, HNC, HNCO, CS, CN, and CH3OH) in NGC4526. These data enable a detailed study of the physical properties of the molecular gas in a longtime resident of the Virgo Cluster; comparisons to more commonly-studied spiral galaxies offer intriguing hints into the processing of molecular gas in the cluster environment. Many molecular line ratios in NGC4526, along with our inferred abundances and CO/H2 conversion factors, are similar to those found in nearby spirals. One striking exception is the very low observed 12CO/13CO(1-0) line ratio, $3.4\pm0.3$, which is unusually low for spirals though not for Virgo Cluster early-type galaxies. We carry out radiative transfer modeling of the CO isotopologues with some archival (2-1) data, and we use Bayesian analysis with Markov chain Monte Carlo techniques to infer the physical properties of the CO-emitting gas. We find surprisingly low [12CO/13CO] abundance ratios of $7.8^{+2.7}_{-1.5}$ and $6.5^{+3.0}_{-1.3}$ at radii of 0.4 kpc and 1 kpc. The emission from the high-density tracers HCN, HCO+, HNC, CS and CN is also relatively bright, and CN is unusually optically thick in the inner parts of NGC4526. These features hint that processing in the cluster environment may have removed much of the galaxy's relatively diffuse, optically thinner molecular gas along with its atomic gas. Angular momentum transfer to the surrounding intracluster medium may also have caused contraction of the disk, magnifying radial gradients such as we find in [13CO/C18O]. More detailed chemical evolution modeling would be interesting in order to explore whether the unusual [12CO/13CO] abundance ratio is entirely an environmental effect or whether it also reflects the relatively old stellar population in this early-type galaxy., Comment: Version 2 is accepted in ApJ

Superconducting photoelectron injectors are a promising technique for generating high brilliant pulsed electron beams with high repetition rates and low emittances. Experiments such as ultra-fast electron diffraction, experiments at the Terahertz scale, and energy recovery linac applications require such properties. However, optimization of the beam properties is challenging due to the high amount of possible machine parameter combinations. In this article, we show the successful automated optimization of beam properties utilizing an already existing simulation model. To reduce the amount of required computation time, we replace the costly simulation by a faster approximation with a neural network. For optimization, we propose a reinforcement learning approach leveraging the simple computation of the derivative of the approximation. We prove that our approach outperforms common optimization methods for the required function evaluations given a defined minimum accuracy.

The complex physical, kinematic, and chemical properties of galaxy centres make them interesting environments to examine with molecular line emission. We present new $2-4$" (${\sim}75{-}150$ pc at $7.7$ Mpc) observations at 2 and 3 mm covering the central $50$" (${\sim}1.9$ kpc) of the nearby double-barred spiral galaxy NGC 6946 obtained with the IRAM Plateau de Bure Interferometer. We detect spectral lines from ten molecules: CO, HCN, HCO$^+$, HNC, CS, HC$_3$N, N$_2$H$^+$, C$_2$H, CH$_3$OH, and H$_2$CO. We complemented these with published 1mm CO observations and 33 GHz continuum observations to explore the star formation rate surface density ${\Sigma_{\mathrm{SFR}}}$ on 150 pc scales. In this paper, we analyse regions associated with the inner bar of NGC 6946 $-$ the nuclear region (NUC), the northern (NBE), and southern inner bar end (SBE) and we focus on short-spacing corrected bulk (CO) and dense gas tracers (HCN, HCO$^+$, and HNC). We find that HCO$^+$ correlates best with ${\Sigma_{\mathrm{SFR}}}$, but the dense gas fraction ($f_{\mathrm{dense}}$) and star formation efficiency of the dense gas (${\mathrm{SFE_{dense}}}$) fits show different behaviours than expected from large-scale disc observations.The SBE has a higher ${\Sigma_{\mathrm{SFR}}}$, $f_{\mathrm{dense}}$, and shocked gas fraction than the NBE. We examine line ratio diagnostics and find a higher CO(2-1)/CO(1-0) ratio towards NBE than for the NUC. Moreover, comparison with existing extragalactic datasets suggests that using the HCN/HNC ratio to probe kinetic temperatures is not suitable on kiloparsec and sub-kiloparsec scales in extragalactic regions. Lastly, our study shows that the HCO$^+$/HCN ratio might not be a unique indicator to diagnose AGN activity in galaxies., Comment: 38 pages, 23 figures, accepted for publication in A&A

We present the ALMA detection of molecular outflowing gas in the central regions of NGC4945, one of the nearest starbursts and also one of the nearest hosts of an active galactic nucleus (AGN). We detect four outflow plumes in CO (3-2) at ~0.3" resolution that appear to correspond to molecular gas located near the edges of the known ionized outflow cone and its (unobserved) counterpart behind the disk. The fastest and brightest of these plumes has emission reaching observed line-of-sight projected velocities of over 450 km/s beyond systemic, equivalent to an estimated physical outflow velocity v>600 km/s for the fastest emission. Most of these plumes have corresponding emission in HCN or HCO+ (4-3). We discuss a kinematic model for the outflow emission where the molecular gas has the geometry of the ionized gas cone and shares the rotation velocity of the galaxy when ejected. We use this model to explain the velocities we observe, constrain the physical speed of the ejected material, and account for the fraction of outflowing gas that is not detected due to confusion with the galaxy disk. We estimate a total molecular mass outflow rate dMmol/dt~20 Msun/yr flowing through a surface within 100 pc of the disk midplane, likely driven by a combination of the central starburst and AGN., Comment: 20 pages, 12 figures, accepted by The Astrophysical Journal on September 28, 2021

Molecular abundances are sensitive to UV-photon flux and cosmic-ray ionization rate. In starburst environments, the effects of high-energy photons and particles are expected to be stronger. We examine these astrochemical signatures through multiple transitions of HCO$^+$ and its metastable isomer HOC$^+$ in the center of the starburst galaxy NGC 253 using data from the ALMA large program ALCHEMI. The distribution of the HOC$^+$(1-0) integrated intensity shows its association with "superbubbles", cavities created either by supernovae or expanding HII regions. The observed HCO$^+$/HOC$^+$ abundance ratios are $\sim 10-150$, and the fractional abundance of HOC$^+$ relative to H$_2$ is $\sim 1.5\times 10^{-11} - 6\times 10^{-10}$, which implies that the HOC$^+$ abundance in the center of NGC 253 is significantly higher than in quiescent spiral-arm dark clouds in the Galaxy and the Galactic center clouds. Comparison with chemical models implies either an interstellar radiation field of $G_0\gtrsim 10^3$ if the maximum visual extinction is $\gtrsim 5$, or a cosmic-ray ionization rate of $\zeta \gtrsim 10^{-14}$ s$^{-1}$ (3-4 orders of magnitude higher than that within clouds in the Galactic spiral-arms) to reproduce the observed results. From the difference in formation routes of HOC$^+$, we propose that a low-excitation line of HOC$^+$ traces cosmic-ray dominated regions, while high-excitation lines trace photodissociation regions. Our results suggest that the interstellar medium in the center of NGC 253 is significantly affected by energy input from UV-photons and cosmic rays, sources of energy feedback., Comment: 57 pages, 32 figures, accepted for publication in ApJ

X-ray free-electron lasers (XFELs) as the world's brightest light sources provide ultrashort X-ray pulses with a duration typically in the order of femtoseconds. Recently, they have approached and entered the attosecond regime, which holds new promises for single-molecule imaging and studying nonlinear and ultrafast phenomena such as localized electron dynamics. The technological evolution of XFELs toward well-controllable light sources for precise metrology of ultrafast processes has been, however, hampered by the diagnostic capabilities for characterizing X-ray pulses at the attosecond frontier. In this regard, the spectroscopic technique of photoelectron angular streaking has successfully proven how to non-destructively retrieve the exact time-energy structure of XFEL pulses on a single-shot basis. By using artificial intelligence techniques, in particular convolutional neural networks, we here show how this technique can be leveraged from its proof-of-principle stage toward routine diagnostics even at high-repetition-rate XFELs, thus enhancing and refining their scientific accessibility in all related disciplines., Comment: This version includes Supplementary Information

We present a supermassive black hole (SMBH) mass measurement in the Seyfert 1 galaxy NGC7469 using Atacama Large Millimeter/submillimeter Array (ALMA) observations of the atomic-${\rm [CI]}$(1-0) and molecular-$^{12}$CO(1-0) emission lines at the spatial resolution of $\approx0.3$" (or $\approx$ 100 pc). These emissions reveal that NGC7469 hosts a circumnuclear gas disc (CND) with a ring-like structure and a two-arm/bi-symmetric spiral pattern within it, surrounded by a starbursting ring. The CND has a relatively low $\sigma/V\approx0.35$ ($r\sim0.5$") and $\sim0.19$ ($r>0.5"$), suggesting that the gas is dynamically settled and suitable for dynamically deriving the mass of its central source. As is expected from X-ray dominated region (XDR) effects that dramatically increase an atomic carbon abundance by dissociating CO molecules, we suggest that the atomic [CI](1-0) emission is a better probe of SMBH masses than CO emission in AGNs. Our dynamical model using the ${\rm [CI]}$(1-0) kinematics yields a $M_{\rm BH}=1.78^{+2.69}_{-1.10}\times10^7$M$_\odot$ and $M/L_{\rm F547M}=2.25^{+0.40}_{-0.43}$ (M$_\odot$/L$_\odot$). The model using the CO(1-0) kinematics also gives a consistent $M_{\rm BH}$ with a larger uncertainty, up to an order of magnitude, i.e.\ $M_{\rm BH}=1.60^{+11.52}_{-1.45}\times10^7$M$_\odot$. This newly dynamical $M_{\rm BH}$ is $\approx$ 2 times higher than the mass determined from the reverberation mapped (RM) method using emissions arising in the unresolved broad-line region (BLR). Given this new $M_{\rm BH}$, we are able to constrain the specific RM dimensionless scaling factor of $f=7.2^{+4.2}_{-3.4}$ for the AGN BLR in NGC7469. The gas within the unresolved BLR thus has a Keplerian virial velocity component and the inclination of $i\approx11.0^\circ$$_{-2.5}^{+2.2}$, confirming its face-on orientation in a Seyfert 1 AGN by assuming a geometrically thin BLR model., Comment: 22 pages, 16 figures, 7 tables. Accepted for publication on MNRAS

We present ALMA observations of CO isotopologues and high-density molecular tracers (HCN, HCO+, CN, etc.) in NGC 7465, an unusually gas-rich early-type galaxy that acquired its cold gas recently. In the inner 300 pc, the molecular gas kinematics are misaligned with respect to all other galaxy components; as the gas works its way inward it is torqued into polar orbits about the stellar kinematically-decoupled core (KDC), indicating that the stellar KDC is not related to the current gas accretion event. The galaxy also exhibits unusually high 12CO/13CO line ratios in its nucleus but typical 13CO/C18O ratios. Our calculations show that this result does not necessarily indicate an unusual [12CO/13CO] abundance ratio but rather that 12CO (1-0) is optically thin due to high temperatures and/or large linewidths associated with the inner decoupled, misaligned molecular structure. Line ratios of the higher-density tracers suggest that the densest phase of molecular gas in NGC 7465 has a lower density than is typical for nearby galaxies, possibly as a result of the recent gas accretion. All of the observed molecular properties of NGC 7465 are consistent with it having acquired its molecular (and atomic) gas from a spiral galaxy. Further detailed studies of the CO isotopologues in other early-type galaxies would be valuable for investigating the histories of those that may have acquired their gas from dwarfs. Finally, these ALMA data also show an unidentified line source that is probably a background galaxy similar to those found at z=1-3 in blind CO surveys., Comment: 26 pages, accepted for publication in the Astrophysical Journal

Young massive clusters play an important role in the evolution of their host galaxies, and feedback from the high-mass stars in these clusters can have profound effects on the surrounding interstellar medium. The nuclear starburst in the nearby galaxy NGC253 at a distance of 3.5 Mpc is a key laboratory in which to study star formation in an extreme environment. Previous high resolution (1.9 pc) dust continuum observations from ALMA discovered 14 compact, massive super star clusters (SSCs) still in formation. We present here ALMA data at 350 GHz with 28 milliarcsecond (0.5 pc) resolution. We detect blueshifted absorption and redshifted emission (P-Cygni profiles) towards three of these SSCs in multiple lines, including CS 7$-$6 and H$^{13}$CN 4$-$3, which represents direct evidence for previously unobserved outflows. The mass contained in these outflows is a significant fraction of the cluster gas masses, which suggests we are witnessing a short but important phase. Further evidence of this is the finding of a molecular shell around the only SSC visible at near-IR wavelengths. We model the P-Cygni line profiles to constrain the outflow geometry, finding that the outflows must be nearly spherical. Through a comparison of the outflow properties with predictions from simulations, we find that none of the available mechanisms completely explains the observations, although dust-reprocessed radiation pressure and O star stellar winds are the most likely candidates. The observed outflows will have a very substantial effect on the clusters' evolution and star formation efficiency., Comment: Accepted to ApJ

NGC 4945 is a nearby (3.8 Mpc) galaxy hosting a nuclear starburst and Seyfert Type 2 AGN. We use the Atacama Large Millimeter/submillimeter Array (ALMA) to image the 93 GHz (3.2 mm) free-free continuum and hydrogen recombination line emission (H40$\alpha$ and H42$\alpha$) at 2.2 pc (0.12'') resolution. Our observations reveal 27 bright, compact sources with FWHM sizes of 1.4 - 4.0 pc, which we identify as candidate super star clusters. Recombination line emission, tracing the ionizing photon rate of the candidate clusters, is detected in 15 sources, 6 of which have a significant synchrotron component to the 93 GHz continuum. Adopting an age of ~5 Myr, the stellar masses implied by the ionizing photon luminosities are $\log_{10}$($M_{\star}$/M$_{\odot}$) $\approx$ 4.7 - 6.1. We fit a slope to the cluster mass distribution and find $\beta = -1.8 \pm 0.4$. The gas masses associated with these clusters, derived from the dust continuum at 350 GHz, are typically an order of magnitude lower than the stellar mass. These candidate clusters appear to have already converted a large fraction of their dense natal material into stars and, given their small free-fall times of ~0.05 Myr, are surviving an early volatile phase. We identify a point-like source in 93 GHz continuum emission which is presumed to be the AGN. We do not detect recombination line emission from the AGN and place an upper limit on the ionizing photons which leak into the starburst region of $Q_0 < 10^{52}$ s$^{-1}$., Comment: accepted for publication in ApJ. 27 pages, 11 figures, 6 tables

We compare molecular gas properties in the starbursting center of NGC253 and the Milky Way Galactic Center (GC) on scales of ~1-100 pc using dendograms and resolution-, area- and noise-matched datasets in CO (1-0) and CO (3-2). We find that the size-line width relations in NGC253 and the GC have similar slope, but NGC253 has larger line widths by factors of ~2-3. The $\sigma^2/R$ dependency on column density shows that, in the GC, on scales of 10-100 pc the kinematics of gas over $N>3\times10^{21}$ cm$^{-2}$ are compatible with gravitationally bound structures. In NGC253 this is only the case for column densities $N>3\times10^{22}$ cm$^{-2}$. The increased line widths in NGC253 originate in the lower column density gas. This high-velocity dispersion, not gravitationally self-bound gas is likely in transient structures created by the combination of high average densities and feedback in the starburst. The high densities turns the gas molecular throughout the volume of the starburst, and the injection of energy and momentum by feedback significantly increases the velocity dispersion at a given spatial scale over what is observed in the GC., Comment: 13 pages, 3 figures, 4 tables; accepted for publication in the Astrophysical Journal

We present extremely deep upper limits on the radio emission from 4U~1957+11, an X-ray binary that is generally believed to be a persistently accreting black hole that is almost always in the soft state. We discuss a more comprehensive search for Type I bursts than in past work, revealing a stringent upper limit on the burst rate, bolstering the case for a black hole accretor. The lack of detection of this source at the 1.07 $\mu$Jy/beam noise level indicates jet suppression that is stronger than expected even in the most extreme thin disk models for radio jet production -- the radio power here is 1500--3700 times lower than the extrapolation of the hard state radio/X-ray correlation, with the uncertainties depending primarily on the poorly constrained source distance. We also discuss the location and velocity of the source and show that it must have either formed in the halo or with a strong asymmetric natal kick., Comment: 6 page, 2 figures, accepted to Monthly Notices of the Royal Astronomical Society Letters

We used the Atacama Large Millimeter/submillimeter Array (ALMA) to map $^{12}$CO($J$ = 1-0), $^{12}$CO($J$ = 2-1), $^{12}$CO($J$ = 3-2), $^{13}$CO($J$ = 2-1), and [CI]($^3P_1$-$^3P_0$) emission lines around the type 1 active galactic nucleus (AGN) of NGC 7469 ($z = 0.0164$) at $\sim 100$ pc resolutions. The CO lines are bright both in the circumnuclear disk (central $\sim 300$ pc) and the surrounding starburst (SB) ring ($\sim 1$ kpc diameter), with two bright peaks on either side of the AGN. By contrast, the [CI]($^3P_1$-$^3P_0$) line is strongly peaked on the AGN. Consequently, the brightness temperature ratio of [CI]($^3P_1$-$^3P_0$) to $^{13}$CO(2-1) is $\sim 20$ at the AGN, as compared to $\sim 2$ in the SB ring. Our local thermodynamic equilibrium (LTE) and non-LTE models indicate that the enhanced line ratios (or CI enhancement) are due to an elevated C$^0$/CO abundance ratio ($\sim 3-10$) and temperature ($\sim 100-500$ K) around the AGN as compared to the SB ring (abundance ratio $\sim 1$, temperature $\lesssim 100$ K), which accords with the picture of the X-ray-dominated Region (XDR). Based on dynamical modelings, we also provide CO(1-0)-to- and [CI]($^3P_1$-$^3P_0$)-to-molecular mass conversion factors at the central $\sim 100$ pc of this AGN as $\alpha_{\rm CO} = 4.1$ and $\alpha_{\rm CI} = 4.4~M_\odot$ (K km s$^{-1}$ pc$^2$)$^{-1}$, respectively. Our results suggest that the CI enhancement is potentially a good marker of AGNs that could be used in a new submillimeter diagnostic method toward dusty environments., Comment: 25 pages, 12 figures, 8 tables. Accepted for publication in ApJ. Minor updates in a replacement

We present submillimeter spectra of the (proto-)super star cluster (SSC) candidates in the starbursting center of the nearby galaxy NGC 253 identified by Leroy et al. (2018). The 2.5pc resolution of our ALMA cycle 3 observations approach the size of the SSCs and allows the study of physical and chemical properties of the molecular gas in these sources. In the 14 SSC sources and in the frequency ranges 342.0-345.8 GHz and 353.9-357.7 GHz we detect 55 lines belonging to 19 different chemical species. The SSCs differ significantly in chemical complexity, with the richest clusters showing 19 species and the least complex showing 4 species. We detect HCN isotopologues and isomers (H$^{13}$CN, HC$^{15}$N, H$^{15}$NC), abundant HC$_3$N, SO and S$^{18}$O, SO$_2$, and H$_2$CS. The gas ratios CO/HCN, CO/HCO$^+$ are low, ~1-10, implying high dense gas fractions in the SSCs. Line ratio analyses suggests chemistry consistent with photon-dominated regions and mechanical heating. None of the SSCs near the galaxy center show line ratios that imply an X-ray dominated region, suggesting that heating by any (still unknown) AGN does not play a major role. The gas temperatures are high in most sources, with an average rotational temperature of ~130 K in SO$_2$. The widespread existence of vibrationally excited HCN and HC$_3$N transitions implies strong IR radiation fields, potentially trapped by a greenhouse effect due to high continuum opacities., Comment: 20 pages, 4 figures, 6 tables; accepted for publication in the Astrophysical Journal