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72 results on '"Matthieu Roy-Barman"'

1. Determining the geochemical fingerprint of the lead fallout from the Notre-Dame de Paris fire: Lessons for a better discrimination of chemical signatures

Author: Justine Briard, Sophie Ayrault, Matthieu Roy-Barman, Louise Bordier, Maxime L'Héritier, Aurélia Azéma, Delphine Syvilay, Sandrine Baron, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Archéologies et Sciences de l'Antiquité (ArScAn), Université Paris 1 Panthéon-Sorbonne (UP1)-Université Paris 8 Vincennes-Saint-Denis (UP8)-Université Paris Nanterre (UPN)-Ministère de la Culture et de la Communication (MCC)-Institut national de recherches archéologiques préventives (Inrap)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de recherche des monuments historiques (LRMH), Centre de Recherche sur la Conservation (CRC ), Muséum national d'Histoire naturelle (MNHN)-Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS)-Muséum national d'Histoire naturelle (MNHN)-Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS), Travaux et recherches archéologiques sur les cultures, les espaces et les sociétés (TRACES), École des hautes études en sciences sociales (EHESS)-Université Toulouse - Jean Jaurès (UT2J)-Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS), Université Paris 1 Panthéon-Sorbonne (UP1)-Université Paris 8 Vincennes-Saint-Denis (UP8)-Université Paris Nanterre (UPN)-Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS), École des hautes études en sciences sociales (EHESS)-Université Toulouse - Jean Jaurès (UT2J), and Université de Toulouse (UT)-Université de Toulouse (UT)-Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS)
Subjects: [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Environmental Engineering, Environmental Chemistry, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Pollution, Waste Management and Disposal
Abstract: On 2019, the fire of Notre-Dame de Paris cathedral ("NDdP") spread an unknown amount of lead (Pb) dust from the roof of the cathedral over Paris. No data describing the geochemical fingerprint of the roof lead, as well as no particle collected during the fire, were available: a post-hoc sampling was performed. To discriminate the potential environmental impact of the fire from multiple Pb sources in Paris, it was mandatory to define unequivocally the fire dust geochemical signature. A dedicated and in hindsight geochemistry-based strategy was developed to eliminate any source of potential contamination due to sampling substrates or previously deposited dust. Radiogenic Pb isotopic signatures (
Published: 2023
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2. Improved radiocesium purification in low-level radioactive soil and sediment samples prior to 135Cs/137Cs ratio measurement by ICP-MS/MS

Author: Anaelle Magre, Beatrice Boulet, Laurent Pourcelot, Matthieu Roy-Barman, Anne de Vismes Ott, Christophe Ardois, Laboratoire de métrologie de la radioactivité dans l'environnement (IRSN/PSE-ENV/SAME/LMRE), Service d'analyses et de métrologie de l'environnement (IRSN/PSE-ENV/SAME), Institut de Radioprotection et de Sûreté Nucléaire (IRSN)-Institut de Radioprotection et de Sûreté Nucléaire (IRSN), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'étude et d'expertise sur la radioactivité de l'environnement (IRSN/PSE-ENV/SEREN/LEREN), Service d'expertise et d'étude en radioprotection des populations et de la radioactivité dans l'environnement (IRSN/PSE-ENV/SEREN), Géochimie Des Impacts (GEDI), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Nuclear Energy and Engineering, Health, Toxicology and Mutagenesis, Public Health, Environmental and Occupational Health, Radiology, Nuclear Medicine and imaging, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Pollution, Spectroscopy, Analytical Chemistry
Abstract: International audience; The 135Cs/137Cs isotopic ratio allows to characterize the potential sources of radioactive contamination in the environment. This ratio is usually determined in highly contaminated environmental samples by combining selective radiochemistry with mass spectrometry measurement. In contrast, few data are available at the environmental level of 137Cs (
Published: 2022
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3. A global scavenging and circulation ocean model of thorium-230 and protactinium-231 with realistic particle dynamics (ProThorP 0.1).

Author: Marco van Hulten, Jean-Claude Dutay, and Matthieu Roy-Barman
Published: 2017

4. Decrease in 230Th in the Amundsen Basin since 2007: far-field effect of increased scavenging on the shelf?

Author: Ole Valk, Walter Geibert, Robert Lawrence Edwards, Matthieu Roy-Barman, William M. Smethie, Núria Casacuberta, Michiel M Rutgers van der Loeff, S. Bradley Moran, Ronja Paffrath, Viena Puigcorbé, Yanbin Lu, K. H. Lepore, and Sandra Gdaniec
Subjects: 0106 biological sciences, geography, geography.geographical_feature_category, 010504 meteorology & atmospheric sciences, Continental shelf, 010604 marine biology & hydrobiology, Geotraces, Particulates, 01 natural sciences, Salinity, Oceanography, Water column, Settling, Arctic, 13. Climate action, Environmental science, Scavenging, 0105 earth and related environmental sciences
Abstract: This study provides dissolved and particulate 230Th and 232Th results as well as particulate 234Th data collected during expeditions to the central Arctic Ocean (GEOTRACES, an international project to identify processes and quantify fluxes that control the distributions of trace elements; sections GN04 and GIPY11). Constructing a time series of dissolved 230Th from 1991 to 2015 enables the identification of processes that control the temporal development of 230Th distributions in the Amundsen Basin. After 2007, 230Th concentrations decreased significantly over the entire water column, particularly between 300 and 1500 m. This decrease is accompanied by a circulation change, evidenced by a concomitant increase in salinity. A potentially increased inflow of water of Atlantic origin with low dissolved 230Th concentrations leads to the observed depletion in dissolved 230Th in the central Arctic. Because atmospherically derived tracers (chlorofluorocarbon (CFC), sulfur hexafluoride (SF6)) do not reveal an increase in ventilation rate, it is suggested that these interior waters have undergone enhanced scavenging of Th during transit from Fram Strait and the Barents Sea to the central Amundsen Basin. The 230Th depletion propagates downward in the water column by settling particles and reversible scavenging.
Published: 2020
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5. 227Ac and 231Pa in the southeast sector of Southern Ocean (Bonus GoodHope – GEOTRACES cruise

Author: Matthieu Roy-Barman, Arnaud Dapoigny, and Martin Levier
Subjects: Oceanography, Geotraces, Cruise, Environmental science
Published: 2021
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6. Global Ocean Sediment Composition and Burial Flux in the Deep Sea

Author: Zanna Chase, Jörg Lippold, Samuel L Jaccard, Marina D Kravchishina, Matthieu Roy-Barman, Shaily Rahman, Adina Paytan, Alessandro Tagliabue, Lise Missiaen, Allison W Jacobel, Kassandra M Costa, Jean-Claude Dutay, Anna Sanchez-Vidal, Christopher R. German, Figen Mekik, Frank J. Pavia, Mariia V. Petrova, Eva María Calvo, Karen E. Kohfeld, L. L. Demina, Laura F. Robinson, Lars-Eric Heimbürger-Boavida, Jing Zhang, Marco van Hulten, Robert F. Anderson, Christopher T. Hayes, Allyson Tessin, Rut Pedrosa-Pàmies, Alan M. Shiller, Institut méditerranéen d'océanologie (MIO), Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Swiss Academy of Sciences, National Science Foundation (US), Russian Science Foundation, European Commission, Australian Research Council, and Agencia Estatal de Investigación (España)
Subjects: 0106 biological sciences, Atmospheric Science, mercury, 010504 meteorology & atmospheric sciences, Flux, barium, 010502 geochemistry & geophysics, 01 natural sciences, Deep sea, opal, marine atlas, carbon cycle, Paleoclimatology, Environmental Chemistry, 14. Life underwater, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, 550 Earth sciences & geology, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, General Environmental Science, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Global and Planetary Change, Ocean sediment, 010604 marine biology & hydrobiology, sediment burial, Data availability, Oceanography, 13. Climate action, Geology
Abstract: 25 pages, 11 figures, supporting information https://doi.org/10.1029/2020GB006769.-- Data Availability Statement: The new and compiled data reported here are available at the NOAA Paleoclimatology database (https://www.ncdc.noaa.gov/paleo/study/30512), Quantitative knowledge about the burial of sedimentary components at the seafloor has wide‐ranging implications in ocean science, from global climate to continental weathering. The use of 230Th‐normalized fluxes reduces uncertainties that many prior studies faced by accounting for the effects of sediment redistribution by bottom currents and minimizing the impact of age model uncertainty. Here we employ a recently compiled global data set of 230Th‐normalized fluxes with an updated database of seafloor surface sediment composition to derive atlases of the deep‐sea burial flux of calcium carbonate, biogenic opal, total organic carbon (TOC), nonbiogenic material, iron, mercury, and excess barium (Baxs). The spatial patterns of major component burial are mainly consistent with prior work, but the new quantitative estimates allow evaluations of deep‐sea budgets. Our integrated deep‐sea burial fluxes are 136 Tg C/yr CaCO3, 153 Tg Si/yr opal, 20Tg C/yr TOC, 220 Mg Hg/yr, and 2.6 Tg Baxs/yr. This opal flux is roughly a factor of 2 increase over previous estimates, with important implications for the global Si cycle. Sedimentary Fe fluxes reflect a mixture of sources including lithogenic material, hydrothermal inputs and authigenic phases. The fluxes of some commonly used paleo‐productivity proxies (TOC, biogenic opal, and Baxs) are not well‐correlated geographically with satellite‐based productivity estimates. Our new compilation of sedimentary fluxes provides detailed regional and global information, which will help refine the understanding of sediment preservation, This study was supported by the Past Global Changes (PAGES) project, which in turn received support from the Swiss Academy of Sciences and the US‐NSF. The work grew out of a 2018 workshop in Aix‐Marseille, France, funded by PAGES, GEOTRACES, SCOR, US‐NSF, Aix Marseille Université, and John Cantle Scientific, and the authors would like to acknowledge all attendees of this meeting. [...]. Christopher T. Hayes acknowledges support from US‐NSF awards 1658445 and 1737023. Some data compilation on Arctic shelf seas was supported by the Russian Science Foundation, grant number 20‐17‐00157. This work was also supported through project CRESCENDO (grant no. 641816, European Commission). Zanna Chase acknowledges support from the Australian Research Council’s Discovery Projects funding scheme (project DP180102357). Christopher R. German acknowledges US‐NSF awards 1235248 and 1234827, With the funding support of the ‘Severo Ochoa Centre of Excellence’ accreditation (CEX2019-000928-S), of the Spanish Research Agency (AEI)
Published: 2021
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7. Contrasted release of insoluble elements (Fe, Al, REE, Th, Pa) after dust deposition in seawater: a tank experiment approach

Author: Matthieu Bressac, Nathalie Leblond, Céline Ridame, Thibaut Wagener, Frédéric Gazeau, Lorna Folio, Karine Desboeufs, Cécile Guieu, Eric Douville, and Matthieu Roy-Barman
Subjects: 010504 meteorology & atmospheric sciences, Protactinium, chemistry.chemical_element, Thorium, Mineral dust, 01 natural sciences, chemistry, 13. Climate action, Environmental chemistry, Seawater, Seeding, Scavenging, Dissolution, Deposition (chemistry), 0105 earth and related environmental sciences
Abstract: The release of lithogenic elements (which are often assumed to be insoluble) such as Aluminum (Al), Iron (Fe), Rare Earth Elements (REE), Thorium (Th) and Protactinium (Pa) by Saharan dust reaching Mediterranean seawater was studied through tank experiments over 3 to 4 days under controlled conditions including control without dust addition and dust seeding under present and future climate conditions (+3 °C and −0.3 pH unit). Unfiltered surface seawater from 3 oligotrophic regions (Tyrrhenian Sea, Ionian Sea and Algerian Basin) were used. The maximum dissolution fractions were low for all seeding experiments: less than 0.3 % for Fe, 1 % for 232Th and Al, about 2–5 % for REE and less than 6 % for Pa. Different behaviors were observed: dissolved Al increased until the end of the experiments, Fe did not dissolve significantly and Th and light REE were scavenged back on the particles after a fast initial release. The constant 230Th/232Th ratio during the scavenging phase suggests that there is little or no further dissolution after the initial Th release. Quite unexpectedly, comparison of present and future conditions indicates that changes in temperature and/or pH influence the release of thorium and REE in seawater, leading to a lower Th release and a higher light REE release under increased greenhouse conditions.
Published: 2020

8. Supplementary material to 'Contrasted release of insoluble elements (Fe, Al, REE, Th, Pa) after dust deposition in seawater: a tank experiment approach'

Author: Matthieu Roy-Barman, Lorna Folio, Eric Douville, Nathalie Leblond, Fréderic Gazeau, Matthieu Bressac, Thibaut Wagener, Céline Ridame, Karine Desboeufs, and Cécile Guieu
Published: 2020
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9. 14C in Urban Secondary Carbonate Deposits: a New Tool for Environmental Study

Author: Nadine Tisnérat-Laborde, Laurent Bergonzini, E Kaltnecker, A Noret, N Pelletier, Matthieu Roy-Barman, D Malnar, J. P. Dumoulin, P. Branchu, G Bultez, Marc Massault, E. Dumont, Edwige Pons-Branchu, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochrononologie Traceurs Archéométrie (GEOTRAC), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Interactions et dynamique des environnements de surface (IDES), Université Paris-Sud - Paris 11 (UP11)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Centre d'Etudes et d'Expertise sur les Risques, l'Environnement, la Mobilité et l'Aménagement - Direction Ile-de-France (Cerema Direction Ile-de-France), Centre d'Etudes et d'Expertise sur les Risques, l'Environnement, la Mobilité et l'Aménagement (Cerema), Centre National d'Études Spatiales [Toulouse] (CNES), Géochimie Des Impacts (GEDI), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), and Université Fédérale Toulouse Midi-Pyrénées-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)
Subjects: 010506 paleontology, Archeology, Earth science, urban hydrology, chemistry.chemical_element, Aqueduct, 010502 geochemistry & geophysics, 01 natural sciences, law.invention, Atmosphere, chemistry.chemical_compound, radiocarbon pulse bomb, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, law, Spring (hydrology), Radiocarbon dating, 0105 earth and related environmental sciences, geography, geography.geographical_feature_category, speleothems, Lamination (geology), chemistry, 13. Climate action, [SDE]Environmental Sciences, General Earth and Planetary Sciences, Carbonate, Carbon, Geology, Chronology
Abstract: Secondary carbonate deposits (similar to speleothems) in urban undergrounds, have been recently highlighted as powerful archives for reconstruction of the historical anthropogenic imprint on the environment. The precise chronology of these secondary carbonate deposits is a key issue for the accurate time reconstruction of environmental conditions. We present three 14C data sets for urban speleothem-like deposits that developed in contrasted man made environments. The first one was sampled in an underground technical gallery of the Palace of Versailles (France), and the other two in a manhole (Saint-Martin spring) of a historical underground aqueduct in Paris (France). The comparison of these records with the bomb peak and relative chronology (laminae counting) allowed us to identify: i) fast carbon transfer from the atmosphere to the urban underground; ii) a high proportion of dead carbon and a high damping effect in relation to possible old carbon stored within urban soils and/or the influence of local fossil carbon burning. This study also shows that the lamination of these deposits is bi-annual in these highly urbanized sites.
Published: 2018
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10. The Transpolar Drift as a Source of Riverine and Shelf-Derived Trace Elements to the Central Arctic Ocean

Author: Willard S. Moore, Carl H. Lamborg, Andrew R. Margolin, Tatiana Williford, Mak A. Saito, Elizabeth M. Jones, Randelle M. Bundy, Hans A. Slagter, Laramie T. Jensen, Robert F. Anderson, Jeroen E. Sonke, Sebastian M. Vivancos, Katlin L. Bowman, Benjamin Rabe, Mats A. Granskog, Alison M. Agather, Paul B. Henderson, Brian A. Haley, Chad R. Hammerschmidt, Frank J. Millero, Rob Middag, Jessica N. Fitzsimmons, Karl Kaiser, Aridane G. González, Rainer M. W. Amon, Mariko Hatta, Per Andersson, Lauren Kipp, Dennis A. Hansell, Robert Newton, Ryan J. Woosley, Micha J. A. Rijkenberg, Ole Valk, R. Lawrence Edwards, Laura M. Whitmore, Angelica Pasqualini, Jessica S. Dabrowski, Loes J. A. Gerringa, Yang Xiang, Matthew A. Charette, Ronald Benner, Martin Levier, Ronja Paffrath, David Kadko, Seth G. John, Jan van Ooijen, Michiel M Rutgers van der Loeff, Xianglei Li, Hélène Planquette, Dorothea Bauch, Robert Rember, Patrick Laan, Phoebe J. Lam, Colin A. Stedmon, Ursula Schauer, Katharina Pahnke, Heather E. Reader, Alan M. Shiller, Mariia V. Petrova, Adam Ulfsbo, Christopher I. Measures, Ruifeng Zhang, Peter Schlosser, Sandra Gdaniec, Robert M. Sherrell, Matthieu Roy-Barman, Lars Eric Heimburger-Boavida, Department of Marine Chemistry and Geochemistry (WHOI), Woods Hole Oceanographic Institution (WHOI), Dalhousie University [Halifax], Lamont-Doherty Earth Observatory (LDEO), Columbia University [New York], Texas A&M University [College Station], University of Southern Mississippi (USM), Department of Marine Sciences [Gothenburg], University of Gothenburg (GU), Tromsø department (IMR), Institute of Marine Research [Bergen] (IMR), University of Bergen (UiB)-University of Bergen (UiB), School of Oceanography [Seattle], University of Washington [Seattle], Department of earth and environmental sciences and the Lamont-Doherty earth observatory, Institute for Chemistry and Biology of the Marine Environment (ICBM), University of Oldenburg, Department of Earth Sciences [USC Los Angeles], University of Southern California (USC), Ocean Sciences Department, University of California [USA], University of California [Santa Cruz] (UC Santa Cruz), University of California (UC)-University of California (UC), Department of Oceanography [Honolulu], University of Hawai‘i [Mānoa] (UHM), Université de Toulon (UTLN), Institut méditerranéen d'océanologie (MIO), Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS), Helmholtz Centre for Ocean Research [Kiel] (GEOMAR), Department of Earth and Environmental Engineering [New York], Wright State University, Swedish Museum of Natural History (NRM), Department of Biological Sciences [Columbia], University of South Carolina [Columbia], University of California (UC), Department of Geology and Geophysics, University of Minnesota [Twin Cities] (UMN), University of Minnesota System-University of Minnesota System, Department of Geological Sciences [Stockholm], Stockholm University, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Royal Netherlands Institute for Sea Research (NIOZ), Laboratoire des Sciences de l'Environnement Marin (LEMAR) (LEMAR), Institut de Recherche pour le Développement (IRD)-Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER)-Université de Brest (UBO)-Institut Universitaire Européen de la Mer (IUEM), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Instituto de Oceanografía y Cambio Global (IOCAG), Université de Las Palmas de Gran Canaria [Espagne] (ULPGC), Norwegian Polar Institute, College of Earth, Ocean and Atmospheric Sciences [Corvallis] (CEOAS), Oregon State University (OSU), Rosenstiel School of Marine and Atmospheric Science (RSMAS), University of Miami [Coral Gables], Florida International University [Miami] (FIU), Texas A&M University [Galveston], University of British Columbia (UBC), Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung (AWI), DTU Aqua, National Institute of Aquatic Resources, Danmarks Tekniske Universitet = Technical University of Denmark (DTU), Memorial University of Newfoundland = Université Memorial de Terre-Neuve [St. John's, Canada] (MUN), International Arctic Research Center (IARC), University of Alaska [Fairbanks] (UAF), Arizona State University [Tempe] (ASU), Max Planck Institute for Chemistry (MPIC), Max-Planck-Gesellschaft, Géosciences Environnement Toulouse (GET), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Center for Global Change Science, Massachusetts Institute of Technology (MIT), Alfred Wegener Institute for Polar and Marine Research (AWI), Shanghai Jiao Tong University [Shanghai], Funding for Arctic GEOTRACES was provided by the U.S. National Science Foundation, Swedish Research Council Formas, French Agence Nationale de la Recherche and LabexMER, Netherlands Organization for Scientific Research, and Independent Research Fund Denmark, ANR-10-LABX-0019,LabexMER,LabexMER Marine Excellence Research: a changing ocean(2010), ANR-13-BS06-0014,GEOVIDE,GEOVIDE, Une étude internationale GEOTRACES le long de la section OVIDE en Atlantique Nord et en Mer du Labrador(2013), University of California [Santa Cruz] (UCSC), University of California-University of California, University of California, Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Technical University of Denmark [Lyngby] (DTU), Memorial University of Newfoundland [St. John's], Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), and Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)
Subjects: 010504 meteorology & atmospheric sciences, Geotraces, [SDE.MCG]Environmental Sciences/Global Changes, Flux, Oceanografi, hydrologi och vattenresurser, Oceanography, 01 natural sciences, Oceanography, Hydrology and Water Resources, Geochemistry and Petrology, Dissolved organic carbon, Arctic Ocean, Earth and Planetary Sciences (miscellaneous), 14. Life underwater, Water cycle, 0105 earth and related environmental sciences, Transpolar Drift, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Trace elements, ACL, Lead (sea ice), Trace element, Nutrients, Carbon, Geophysics, GEOTRACES, Arctic, 13. Climate action, Space and Planetary Science, Meteoric water, Environmental science, [SDE.BE]Environmental Sciences/Biodiversity and Ecology
Abstract: Data from GEOTRACES cruises GN01 (HLY1502) and GN04 (PS94) have been archived at the Biological & Chemical Oceanography Data Management Office (BCO-DMO; https://www.bco-dmo.org/deployment/638807) and PANGAEA (https://www.pangaea.de/?q=PS94&f.campaign%5B%5D=PS94) websites, respectively. The inorganic carbon data are available at the NOAA Ocean Carbon Data System (OCADS ; doi :10.3334/CDIAC/OTG.CLIVAR_ARC01_33HQ20150809). In addition to these national data archives, the data used in this paper is available as a supplementary downloadable excel file; International audience; A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river‐influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high‐resolution pan‐Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and ~25‐50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle‐reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (106 m3 s‐1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.
Published: 2020
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11. Seawater 227Ac Analysis by ID-Mc-ICPMS: A GEOTRACES Challenge

Author: Martin Levier, Matthieu Roy-Barman, Christophe Colin, and Arnaud Dapoigny
Published: 2020
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12. 230 Th Normalization: New Insights on an Essential Tool for Quantifying Sedimentary Fluxes in the Modern and Quaternary Ocean

Author: Laura F. Robinson, Paul Lerner, Allison W Jacobel, Sylvain Pichat, Kassandra M Costa, Adi Torfstein, George H. Rowland, Walter Geibert, Jörg Lippold, Alessandro Tagliabue, Samuel L Jaccard, Jean-Claude Dutay, Gideon M. Henderson, Stephanie S. Kienast, Alexandra R. Bausch, Claude Hillaire-Marcel, David McGee, Christoph Heinze, Gisela Winckler, Yuxin Zhou, Sharon S. Hoffmann, Robert F. Anderson, Figen Mekik, Christelle Not, Matthieu Roy-Barman, Frank J. Pavia, Lauren Kipp, Jerry F. McManus, Christopher T. Hayes, Franco Marcantonio, Lise Missiaen, Jennifer L. Middleton, Feifei Deng, David C Lund, Alfred Wegener Institute [Potsdam], Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung (AWI), Lamont-Doherty Earth Observatory (LDEO), Columbia University [New York], Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Scottish Association for Marine Science (SAMS), German Aerospace Center (DLR), Department of Earth Sciences [Oxford], University of Oxford [Oxford], Université du Québec à Montréal = University of Québec in Montréal (UQAM), Oeschger Centre for Climate Change Research (OCCR), University of Bern, Dalhousie University [Halifax], Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon), Max Planck Institute for Chemistry (MPIC), Max-Planck-Gesellschaft, Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Department of Oceanography [Cape Town], University of Cape Town, Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), University of Oxford, Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: Atmospheric Science, 010504 meteorology & atmospheric sciences, Pleistocene, Nepheloid layer, Paleontology, Last Glacial Maximum, 010502 geochemistry & geophysics, Oceanography, 01 natural sciences, chemistry.chemical_compound, chemistry, Continental margin, 13. Climate action, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Carbonate, Sedimentary rock, 14. Life underwater, Quaternary, 550 Earth sciences & geology, Holocene, Geology, [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography, 0105 earth and related environmental sciences
Abstract: International audience; 230 Th normalization is a valuable paleoceanographic tool for reconstructing high-resolution sediment fluxes during the late Pleistocene (last~500,000 years). As its application has expanded to ever more diverse marine environments, the nuances of 230 Th systematics, with regard to particle type, particle size, lateral advective/diffusive redistribution, and other processes, have emerged. We synthesized over 1000 sedimentary records of 230 Th from across the global ocean at two time slices, the late Holocene (0-5,000 years ago, or 0-5 ka) and the Last Glacial Maximum (18.5-23.5 ka), and investigated the spatial structure of 230 Th-normalized mass fluxes. On a global scale, sedimentary mass fluxes were significantly higher during the Last Glacial Maximum (1.79-2.17 g/cm 2 kyr, 95% confidence) relative to the Holocene (1.48-1.68 g/cm 2 kyr, 95% confidence). We then examined the potential confounding influences of boundary scavenging, nepheloid layers, hydrothermal scavenging, size-dependent sediment fractionation, and carbonate dissolution on the efficacy of 230 Th as a constant flux proxy. Anomalous 230 Th behavior is sometimes observed proximal to hydrothermal ridges and in continental margins where high particle fluxes and steep continental slopes can lead to the combined effects of boundary scavenging and nepheloid interference. Notwithstanding these limitations, we found that 230Th normalization is a robust tool for determining sediment mass accumulation rates in the majority of pelagic marine settings (>1,000 m water depth).
Published: 2020
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13. 231Pa and 230Th in the Arctic Ocean: Implications for boundary scavenging and 231Pa-230Th fractionation in the Eurasian Basin

Author: Arnaud Dapoigny, Lorna Foliot, Matthieu Roy-Barman, Martin Levier, Lise Missiaen, Sandra Gdaniec, Ole Valk, Michiel M Rutgers van der Loeff, Per Andersson, Carl-Magnus Mörth, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung (AWI), Géochrononologie Traceurs Archéométrie (GEOTRAC), Dept. of Geology and Geochemistry, Swedish Museum of Natural History (NRM), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: 010504 meteorology & atmospheric sciences, Nansen Basin, Geotraces, Structural basin, 010502 geochemistry & geophysics, 01 natural sciences, Sink (geography), Panoply, Geochemistry and Petrology, Arctic Ocean, 14. Life underwater, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Scavenging, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, geography, geography.geographical_feature_category, Thorium, Geology, Protactinium, Geokemi, Particulates, Oceanography, GEOTRACES, Geochemistry, Arctic, 13. Climate action, Boundary scavenging, Seawater
Abstract: 231Pa, 230Th and 232Th were analyzed in filtered seawater (n = 70) and suspended particles (n = 39) collected along a shelf-basin transect from the Barents shelf to the Makarov Basin in the Arctic Ocean during GEOTRACES section GN04 in 2015. The distribution of dissolved 231Pa and 230Th in the Arctic Ocean deviates from the linear increase expected from reversible scavenging. Higher 232Th concentrations were observed at the shelf, slope and in surface waters in the deep basin, pointing at lithogenic sources. Fractionation factors (FTh/Pa) observed at the Nansen margin were higher compared to FTh/Pa in the central Nansen Basin, possibly due to the residual occurrence of hydrothermal particles in the deep central Nansen Basin. Application of a boundary scavenging model quantitatively accounts for the dissolved and particulate 230Th distributions in the Nansen Basin. Modelled dissolved 231Pa distributions were largely overestimated, which was attributed to the absence of incorporation of water exchange with the Atlantic Ocean in the model. 231Pa/230Th ratios of the suspended particles of the Nansen Basin were below the 231Pa/230Th production ratio, but top-core sediments of the Nansen margin and slope have high 231Pa/230Th-ratios, suggesting that scavenging along the Nansen margin partly acts as a sink for the missing Arctic 231Pa.
Published: 2020
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14. Thorium isotopes in the Southeast Atlantic Ocean: Tracking scavenging during water mass mixing along neutral density surfaces

Author: Lorna Foliot, Louise Bordier, François Lacan, Sophie Ayrault, Matthieu Roy-Barman, Ester Garcia-Solsona, Catherine Pradoux, Catherine Jeandel, François Thil, Arnaud Dapoigny, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochrononologie Traceurs Archéométrie (GEOTRAC), Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), and Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS)
Subjects: Water mass, 010504 meteorology & atmospheric sciences, Thorium isotopes, Aquatic Science, 010502 geochemistry & geophysics, Oceanography, Atmospheric sciences, Isopycnal mixing, 01 natural sciences, Eddy diffusion, Continental margin, Settling, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, 14. Life underwater, Southern Ocean, Scavenging, marine particles, 0105 earth and related environmental sciences, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Isopycnal, isopycnal mixing, thorium isotopes, Southern ocean, Marine particles, 13. Climate action, Atlantic, Upwelling, Isotopes of thorium, Geology
Abstract: International audience; The distributions of dissolved and particulate thorium isotopes (230 Th and 232 Th) were established in samples from the BONUS GoodHope (BGH) IPY-GEOTRACES cruise in the SE Atlantic sector of the Southern Ocean (36°S-13°E to 57°S-0°, Feb.-Mar. 2008). The distribution of total (dissolved+particulate) 232 Th is dominated by the inputs from continental margins. The non-linear profiles of dissolved 230 Th are interpreted as due to the southward upwelling of the isopycnal surfaces. However, total 230 Th and 232 Th versus salinity plots illustrate departures from binary mixing and provides evidence for non-conservative behavior of both isotopes along the section. We propose a model for total 230 Th and 232 Th scavenging and mixing along isopycnal surfaces. We use this model to estimate particle settling speeds and isopycnal eddy diffusion coefficients along the BGH section. Data-model comparison suggests particle settling velocities in the range of 400-700 m/y and isopycnal eddy diffusivity of the order of 2000 m 2 /s.
Published: 2019
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15. Circulation changes in the Amundsen Basin from 1991 to 2015 revealed from distributions of dissolved 230Th

Author: Núria Casacuberta, Ole Valk, S. Bradley Moran, Ronja Paffrath, K. H. Lepore, Walter Geibert, William M. Smethie, Yanbin Lu, Viena Puigcorbé, Matthieu Roy-Barman, Michiel M Rutgers van der Loeff, Sandra Gdaniec, and Robert Lawrence Edwards
Subjects: Salinity, Water column, Oceanography, Settling, Arctic, 13. Climate action, Geotraces, Environmental science, Particulates, Structural basin, Scavenging
Abstract: This study provides dissolved and particulate 230Th and 232Th results as well as particulate 234Th data collected during expeditions to the central Arctic Ocean on ARK-XXIX/3 (2015) and ARK-XXII/2 (2007) (GEOTRACES sections GN04 and GIPY11, respectively). Constructing a time-series of dissolved 230Th from 1991 to 2015 enables the identification of processes that control the temporal development of 230Th distributions in the Amundsen Basin. After 2007, 230Th concentrations decreased significantly over the entire water column, particularly between 300 m and 1500 m. This decrease is accompanied by a circulation change, evidenced by a concomitant increase in salinity. Potentially increased inflow of water of Atlantic origin with low dissolved 230Th concentrations leads to the observed depletion in dissolved 230Th in the central Arctic. Because atmospherically derived tracers (CFC, 3He/3H) do not reveal an increase in ventilation rate, it is suggested that these interior waters have undergone enhanced scavenging of Th during transit from the Fram Strait and the Barents Sea to the central Amundsen Basin. The 230Th depletion propagates downward in the water column by settling particles and reversible scavenging. Taken together, the temporal evolution of Th distributions point to significant changes in the large-scale circulation of the Amundsen Basin.
Published: 2019
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16. Supplementary material to 'Circulation changes in the Amundsen Basin from 1991 to 2015 revealed from distributions of dissolved 230Th'

Author: Ole Valk, Michiel M. Rutgers van der Loeff, Walter Geibert, Sandra Gdaniec, S. Bradley Moran, Kate Lepore, Robert Lawrence Edwards, Yanbin Lu, Viena Puigcorbé, Nuria Casacuberta, Ronja Paffrath, William Smethie, and Matthieu Roy-Barman
Published: 2019
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17. Barium during the GEOTRACES GA-04S MedSeA cruise: The Mediterranean Sea Ba budget revisited

Author: Lorna Foliot, Sophie Ayrault, Pere Masqué, Maxi Castrillejo, Matthieu Roy-Barman, Jordi Garcia-Orellana, Edwige Pons-Branchu, Sandra Gdaniec, Louise Bordier, Martin Levier, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochrononologie Traceurs Archéométrie (GEOTRAC), Swedish Museum of Natural History (NRM), Universitat Autònoma de Barcelona (UAB), Institut de Ciencia i Tecnologia Ambientals (ICTA), National Oceanography Centre [Southampton] (NOC), University of Southampton, Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: Mediterranean climate, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, 010504 meteorology & atmospheric sciences, Evaporite, Geotraces, Geology, Mineral dust, 010502 geochemistry & geophysics, 01 natural sciences, 6. Clean water, Submarine groundwater discharge, Panoply, Oceanography, Mediterranean sea, 13. Climate action, Geochemistry and Petrology, Seawater, 14. Life underwater, Surface water, [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography, 0105 earth and related environmental sciences
Abstract: The distribution of barium (Ba) in seawater was determined in the main basins and straits of the Mediterranean Sea during the GEOTRACES GA-04S MedSeA cruise. In addition, the concentrations of Ba and radium (Ra) isotopes (228Ra) were determined in groundwaters discharging in the Mediterranean Sea. The dissolved Ba concentration increases from the inflowing Atlantic surface water (Ba ~ 45 nmol/kg) to the intermediate (Ba ~ 70 nmol/kg) and deep (Ba ~ 70–75 nmol/kg) Mediterranean Sea waters in general agreement with previously published profiles. We use these data to build a Ba budget of the Mediterranean Sea and to evaluate the role of different sources of Ba (dusts, rivers, sediments, submarine groundwater discharges, Messinian evaporites). Evaporation alone cannot account for the Ba concentration increase because salinity increases only by 8% between the Gibraltar Strait and the Eastern Basin, whereas the Ba concentration increases up to 75% between the Atlantic Water and the deep waters. Thus, the particulate Ba flux that maintains the Ba concentration gradient between the surface and the deep waters must be 10–100 times stronger than previously estimated and the net Ba loss at the Gibraltar Strait or out of the Western Basin must be balanced by external inputs to the Mediterranean Sea. Newly available data from Mediterranean rivers confirm that rivers are insufficient Ba sources to balance this budget. Using recent estimates of Saharan dust fluxes, we show that dust deposition is also a negligible Ba source, whereas it was previously considered as the main external source. Using Ba-228Ra data, we show for the first time that submarine groundwater discharges can significantly contribute to the Ba budget, but large uncertainties exist due to the high variability of the chemical composition of these groundwaters. The inputs from Messinian evaporites require to be further investigated. Ba transfer from the surface water to the intermediate and deep waters occurs through active particulate Ba cycling and/or Ba dissolution in the sediment. Our study suggests that the mean particulate Ba cycling is more intense than previously estimated. This article is part of a special issue entitled: “Cycles of trace elements and isotopes in the ocean – GEOTRACES and beyond” - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. Gonzalez.
Published: 2019
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18. Determination of low level of actinium 227 in seawater and freshwater by isotope dilution and mass spectrometry

Author: Martin Levier, Arnaud Dapoigny, Christophe Colin, and Matthieu Roy-Barman
Subjects: Actinium, 0106 biological sciences, Water mass, 010504 meteorology & atmospheric sciences, Analytical chemistry, chemistry.chemical_element, Isotope dilution, Oceanography, 01 natural sciences, Environmental water, Ocean gyre, TRACER, Environmental Chemistry, 0105 earth and related environmental sciences, Water Science and Technology, Detection limit, geography, geography.geographical_feature_category, Anion exchange chromatography, 010604 marine biology & hydrobiology, General Chemistry, Multi-collection mass spectrometry, chemistry, Environmental science, Seawater, Surface water
Abstract: By diffusing from the sediments into the ocean, 227Ac (half-life = 21.8 y) is a powerful tracer of vertical mixing in the deep ocean on decadal time scales. However, its use is limited by its very low concentration resulting in large volumes (hundreds of L) of water required for its analysis. We have developed a new method of 227 Ac analysis by isotope dilution and MC-ICPMS that significantly improves the measurement accuracy and reduces the sample size (10−30 L). After spiking water samples with 225Ac milked from a 229 Th solution, actinium isotopes are preconcentrated by manganese co-precipitation, purified by chromatographic methods and then measured by MC-ICPMS. The performance of the analytical method (accuracy, precision) was estimated with a homemade actinium standard solution. An internal quality control was carried out to validate the method by repeated measurements of 2 L of surface seawater doped with 227Ac (1000 ag/kg) and duplicates of the Vienne river water (6.1 ± 1.7 ag/kg and 4.1 ± 1.3 ag/kg). 231 Pa was also co-precipitated, purified during the chromatography and analysed by MC-ICPMS. The combined measurement of 227Ac and 231Pa from the same sample allows discriminating 227Ac supported by 231Pa decay from the 227 Ac released by remobilization from the sediments. The 227Ac concentrations measured on the first seawater samples of 29 L from the South China Sea water range from below the detection limit in surface water (~ 0.5 ag/kg for 30 L) to 3.4 ± 0.5 ag/kg at 2760 m depth (uncertainties are given in 2σn). The 227 Ac measured in the deep South China Sea waters entering through the Luzon strait are consistent with previous data obtained in the same water mass in the Pacific Ocean (PDW). Seawater from the southernmost station of Bonus GoodHope, in the Weddell Gyre , were also analysed, with 227Ac concentration ranging from 4.2 ± 0.4 ag/kg to 10.9 ± 1.0 ag/kg in good agreement with previous measurement in the Weddell Gyre by Geibert et al. (2002, 2008).
Published: 2021
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19. Rare earth and alkali elements in stalagmites, as markers of Mediterranean environmental changes during Termination I

Author: Edwige Pons-Branchu, Louise Bordier, L. Drugat, Eric Douville, Matthieu Roy-Barman, Lorna Foliot, Géochrononologie Traceurs Archéométrie (GEOTRAC), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: 010504 meteorology & atmospheric sciences, Alkali metals, [SDE.MCG]Environmental Sciences/Global Changes, Geochemistry, Speleothem, Termination I, Weathering, Stalagmite, Mediterranean, 010502 geochemistry & geophysics, 01 natural sciences, [SDV.EE.ECO]Life Sciences [q-bio]/Ecology, environment/Ecosystems, Geochemistry and Petrology, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Glacial period, Younger Dryas, Cerium anomaly, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Rare earth elements, ComputingMilieux_MISCELLANEOUS, Holocene, 0105 earth and related environmental sciences, geography, geography.geographical_feature_category, [CHIM.ORGA]Chemical Sciences/Organic chemistry, Bedrock, Geology, [SDE.ES]Environmental Sciences/Environmental and Society, 13. Climate action, [SDU.STU.CL]Sciences of the Universe [physics]/Earth Sciences/Climatology, [SDU.STU.ST]Sciences of the Universe [physics]/Earth Sciences/Stratigraphy, [SHS.ENVIR]Humanities and Social Sciences/Environmental studies, Environmental changes
Abstract: International audience; Speleothems represent a key source of information on climate variations in continental environments as they enable high temporal resolution reconstructions. The stalagmite salam3 presented in this study comes from the Salamandre Cave (SE France, Gard region). Its growth period, determined by 230Th/234U chronology and MOD-AGE extrapolation, falls between 10.91 ± 1.00 kyr BP and 13.43 ± 0.25 kyr BP, which corresponds to the transition between the last glacial period and the Holocene. This period is essential for the understanding of past and future climate variations.In this study, trace elements were measured along the growth axis of this stalagmite and results were compared with the elementary composition of bedrock and soil above the cave. Three periods were identified with high Li, Rb, Cs, Th and rare earth element (REE) concentrations, between 13.43 ± 0.25 and 13.11 ± 0.27, between 12.70 ± 0.34 and 12.30 ± 0.15 kyr, and between 11.31 ± 0.86 and 11.15 ± 0.87 kyr.Our results suggest that the alkali metals (alkalis) studied are either associated in the detrital phase with the clay and particle fraction (correlation with Th), or with the organic matter and colloids as complexed ligands (correlation with Mn). To attribute the origin of REE measured within the stalagmite, we compared their pattern with those of soil and bedrock, and two sources were deduced: i) periods with an enrichment in light REE and no cerium anomaly corresponding to mobilization from soil during weathering episodes such as the Bölling-Alleröd period; ii) from bedrock during a longer residence time of water in the epikarst such as during the Younger Dryas and the Holocene. Thus, as illustrated in this study, combined analysis of REE and alkalis can provide key information on soil weathering linked to climate/environmental change.
Published: 2019
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20. Thorium and protactinium isotopes as tracers of marine particle fluxes and deep water circulation in the Mediterranean Sea

Author: François Thil, Lorna Foliot, Pere Masqué, Matthieu Roy-Barman, Sandra Gdaniec, Arnaud Dapoigny, Jordi Garcia-Orellana, Per Andersson, Pierre Burckel, Carl-Magnus Mörth, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Department of Geological Sciences [Stockholm], Stockholm University, Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochrononologie Traceurs Archéométrie (GEOTRAC), Universitat Autònoma de Barcelona (UAB), Institut de Ciencia i Tecnologia Ambientals (ICTA), Swedish Museum of Natural History (NRM), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: 010504 meteorology & atmospheric sciences, Geotraces, Fractionation, 010502 geochemistry & geophysics, Oceanography, 01 natural sciences, Mediterranean sea, Settling, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Mediterranean Sea, Environmental Chemistry, 14. Life underwater, Scavenging, [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography, 0105 earth and related environmental sciences, Water Science and Technology, Ocean current, Thorium, Sediment, General Chemistry, Protactinium, Geokemi, particle fluxes, Geochemistry, 13. Climate action, Environmental science, Seawater
Abstract: 231Pa, 230Th and 232 Th were analyzed in unfiltered seawater samples (n = 66) and suspended particles (n = 19) collected in the Mediterranean Sea during the MedSeA-GA04-S cruise along the GEOTRACES section GA04S and used to investigate mechanisms controlling the distribution and fractionation of Pa and Th in an ocean margin environment. 231Pa and 230 Th are particle reactive radionuclides and are often used as tracers of processes such as boundary scavenging, particle transport and ocean circulation. The depth profiles of total 231Pa and 230Th concentrations in the Mediterranean Sea displayed non-linear shapes. Higher total 232Th concentrations were observed at the straits and in deep waters pointing at lithogenic sources. Fractionation factors FTh/Pa ranged from 1.4 to 9. Application of a box-model illustrated that 94% of the 231Pa and almost all of the 230Th (99.9%) produced in the Mediterranean Sea is removed to the sediment by scavenging. The negligible export of 230Th to the Atlantic Ocean, leads to a reevaluation of the mean settling speed of the filtered particles, which is now estimated to 500–1000 m/y. The low FTh/Pa fractionation factors are attributed to the efficient scavenging and lack of transport of 231Pa to the Atlantic Ocean.
Published: 2018
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21. A global scavenging and circulation ocean model of thorium-230 and protactinium-231 with realistic particle dynamics (NEMO-ProThorP 0.1)

Author: Marco van Hulten, Jean-Claude Dutay, and Matthieu Roy-Barman
Subjects: Computational Engineering, Finance, and Science (cs.CE), FOS: Computer and information sciences, Physics - Atmospheric and Oceanic Physics, 13. Climate action, Atmospheric and Oceanic Physics (physics.ao-ph), FOS: Physical sciences, 14. Life underwater, Computer Science - Computational Engineering, Finance, and Science
Abstract: In this paper, we set forth a 3-D ocean model of the radioactive trace isotopes Th-230 and Pa-231. The interest arises from the fact that these isotopes are extensively used for investigating particle transport in the ocean and reconstructing past ocean circulation. The tracers are reversibly scavenged by biogenic and lithogenic particles. Our simulations of Th-230 and Pa-231 are based on the NEMO-PISCES ocean biogeochemistry general circulation model, which includes biogenic particles, namely small and big particulate organic carbon, calcium carbonate and biogenic silica. Small and big lithogenic particles from dust deposition are included in our model as well. Their distributions generally compare well with the small and big lithogenic particle concentrations from recent observations from the GEOTRACES programme, except for boundary nepheloid layers for which, as up to today, there are no non-trivial, prognostic models available on a global scale. Our simulations reproduce Th-230 and Pa-231 dissolved concentrations: they compare well with recent GEOTRACES observations in many parts of the ocean. Particulate Th-230 and Pa-231 concentrations are significantly improved compared to previous studies, but they are still too low because of missing particles from nepheloid layers. Our simulation reproduces the main characteristics of the Pa-231/Th-230 ratio observed in the sediments, and supports a moderate affinity of Pa-231 to biogenic silica as suggested by recent observations, relative to Th-230. Future model development may further improve understanding, especially when this will include a more complete representation of all particles, including different size classes, manganese hydroxides and nepheloid layers. This can be done based on our model, as its source code is readily available., submitted to Geoscientific Model Development
Published: 2017

22. U–Th–REE–Hf bearing phases in Mediterranean Sea sediments: Implications for isotope systematics in the ocean

Author: Sophie Ayrault, Eric Robin, Sandra Marchandise, Matthieu Roy-Barman, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Laboratoire d'Etude des Matériaux par Microscopie Avancée (LEMMA ), Modélisation et Exploration des Matériaux (MEM), Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)
Subjects: Radiogenic nuclide, 010504 meteorology & atmospheric sciences, Geochemistry, Sediment, Mineralogy, Silt, 010502 geochemistry & geophysics, 01 natural sciences, Mediterranean sea, Allanite, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, 13. Climate action, Geochemistry and Petrology, Monazite, 14. Life underwater, Chemical composition, Geology, 0105 earth and related environmental sciences, Zircon
Abstract: International audience; The abundance, size and composition of micron-size U–Th–REE–Hf rich phases of marine clayey silt sediments from the Western Mediterranean Sea were determined using an automated scanning electron microscope equipped with an energy dispersive spectrometer. The minerals found in the sediment were monazite, allanite, florencite, xenotime and zircon. The size distribution and chemical composition of each phase were used to determine their contribution to the total content of the sediment in U, Th, REE, Y, Zr and Hf. Zircon accounts for most of the Zr and Hf of the sample. Xenotime and zircon account for most Y and HREE of the sample. However, the high Y–HREE–U–Th content of the zircons analyzed in this study (possibly due to xenotime overgrowth on zircon surface and alteration processes) contrasts with previous works and cannot be extended to any type of zircons. By contrast, only a small fraction (≈20–30%) of U, Th and LREE (such as Nd) are carried by U–Th–REE–Hf rich minerals (monazite mostly). It reflects the higher alterability of U–Th and LREE bearing phases compared to zircon and xenotime and implies that most U–Th and LREE are present in other phases at lower concentrations (possibly clays, organic matter or Fe–Mn oxides). The different size distributions of the different carriers can contribute to U–Th and LREE/HREE fractionation observed during the transport of these elements. Due to its very high physical and chemical resistance, zircon appears to be the main Hf carrier even in fine grained “zircon free type” sediments. By storing Lu and possibly releasing extremely radiogenic Hf, xenotime has an unforeseen role in the Lu–Hf systematics in marine sediment.
Published: 2014
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23. Marine Geochemistry : Ocean Circulation, Carbon Cycle and Climate Change

Author: Matthieu Roy-Barman, Catherine Jeandel, Matthieu Roy-Barman, and Catherine Jeandel
Subjects: Geochemistry, Chemical oceanography, Marine sediments
Abstract: Marine geochemistry uses chemical elements and their isotopes to study how the ocean works in terms of ocean circulation, chemical composition, biological activity and atmospheric CO2 regulation. This rapidly growing field is at a crossroad for many disciplines (physical, chemical and biological oceanography, geology, climatology, ecology, etc.). It provides important quantitative answers to questions such as: What is the deep ocean mixing rate? How much atmospheric CO2 is pumped by the ocean? How fast are pollutants removed from the ocean? How do ecosystems react to anthropogenic pressure? This text gives a simple introduction to the concepts, the methods and the applications of marine geochemistry with a particular emphasis on isotopic tracers. Overall introducing a very large number of topics (physical oceanography, ocean chemistry, isotopes, gas exchange, modelling, biogeochemical cycles), with a balance of didactic and indepth information, it provides an outline and a complete course in marine geochemistry. Throughout, the book uses a hands-on approach with worked out exercises and problems (with answers provided at the end of the book), to help the students work through the concepts presented. A broad scale approach is take including ocean physics, marine biology, ocean-climate relations, remote sensing, pollutions and ecology, so that the reader acquires a global perspective of the ocean. It also includes new topics arising from ongoing research programs. This textbook is essential reading for students, scholars, researchers and other professionals.
Published: 2016

24. The large-scale evolution of neodymium isotopic composition in the global modern and Holocene ocean revealed from seawater and archive data

Author: Alexander M Piotrowski, Kazuyo Tachikawa, Matthieu Roy-Barman, Christophe Colin, Yves Plancherel, Aloys Bory, Thomas Arsouze, Paolo Montagna, François Lacan, Xavier Giraud, Alexandra T. Gourlan, Emmanuelle Pucéat, Norbert Frank, Catherine Jeandel, Jean-Claude Dutay, Claire Waelbroeck, Laure Meynadier, Germain Bayon, Centre européen de recherche et d'enseignement de géosciences de l'environnement ( CEREGE ), Centre National de la Recherche Scientifique ( CNRS ) -Institut de Recherche pour le Développement ( IRD ) -Aix Marseille Université ( AMU ) -Collège de France ( CdF ) -Institut National de la Recherche Agronomique ( INRA ) -Institut national des sciences de l'Univers ( INSU - CNRS ), Laboratoire de Météorologie Dynamique (UMR 8539) ( LMD ), Université Pierre et Marie Curie - Paris 6 ( UPMC ) -Institut national des sciences de l'Univers ( INSU - CNRS ) -École polytechnique ( X ) -École des Ponts ParisTech ( ENPC ) -Centre National de la Recherche Scientifique ( CNRS ) -Département des Géosciences - ENS Paris, École normale supérieure - Paris ( ENS Paris ) -École normale supérieure - Paris ( ENS Paris ), Unité de Mécanique ( UME ), École Nationale Supérieure de Techniques Avancées ( Univ. Paris-Saclay, ENSTA ParisTech ), Unité de recherche Géosciences Marines (Ifremer) ( GM ), Institut Français de Recherche pour l'Exploitation de la Mer ( IFREMER ), Laboratoire d’Océanologie et de Géosciences (LOG) - UMR 8187 ( LOG ), Université du Littoral Côte d'Opale-Université de Lille-Centre National de la Recherche Scientifique ( CNRS ), Géosciences Paris Sud ( GEOPS ), Université Paris-Sud - Paris 11 ( UP11 ) -Centre National de la Recherche Scientifique ( CNRS ), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] ( LSCE ), Université de Versailles Saint-Quentin-en-Yvelines ( UVSQ ) -Commissariat à l'énergie atomique et aux énergies alternatives ( CEA ) -Université Paris-Saclay-Centre National de la Recherche Scientifique ( CNRS ), Institute of Environmental Physics [Heidelberg] ( IUP ), Universität Heidelberg [Heidelberg], Institut de Physique du Globe de Paris ( IPGP ), Université Pierre et Marie Curie - Paris 6 ( UPMC ) -Institut national des sciences de l'Univers ( INSU - CNRS ) -IPG PARIS-Université Paris Diderot - Paris 7 ( UPD7 ) -Université de la Réunion ( UR ) -Centre National de la Recherche Scientifique ( CNRS ), GEOMAR - Helmholtz Centre for Ocean Research [Kiel] ( GEOMAR ), GEOMAR LEGOS, Laboratoire d'études en Géophysique et océanographie spatiales ( LEGOS ), Université Paul Sabatier - Toulouse 3 ( UPS ) -Centre National d'Etudes Spatiales ( CNES ) -Institut national des sciences de l'Univers ( INSU - CNRS ) -Observatoire Midi-Pyrénées ( OMP ) -Centre National de la Recherche Scientifique ( CNRS ) -Université Paul Sabatier - Toulouse 3 ( UPS ) -Centre National d'Etudes Spatiales ( CNES ) -Institut national des sciences de l'Univers ( INSU - CNRS ) -Observatoire Midi-Pyrénées ( OMP ) -Centre National de la Recherche Scientifique ( CNRS ), Istituto di Science Marine - ISMAR (Italy), Biogéosciences [Dijon] ( BGS ), AgroSup Dijon - Institut National Supérieur des Sciences Agronomiques, de l'Alimentation et de l'Environnement-Université de Bourgogne ( UB ) -Centre National de la Recherche Scientifique ( CNRS ), University of Oxford [Oxford], Centre européen de recherche et d'enseignement des géosciences de l'environnement (CEREGE), Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Collège de France (CdF (institution))-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS)-Institut National de la Recherche Agronomique (INRA), Laboratoire de Météorologie Dynamique (UMR 8539) (LMD), Département des Géosciences - ENS Paris, École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-École des Ponts ParisTech (ENPC)-École polytechnique (X)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC), Unité de Mécanique (UME), École Nationale Supérieure de Techniques Avancées (ENSTA Paris), Unité de recherche Géosciences Marines (Ifremer) (GM), Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER), Laboratoire d’Océanologie et de Géosciences (LOG) - UMR 8187 (LOG), Institut national des sciences de l'Univers (INSU - CNRS)-Université du Littoral Côte d'Opale (ULCO)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Géosciences Paris Sud (GEOPS), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Modélisation du climat (CLIM), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institute of Environmental Physics [Heidelberg] (IUP), Institut des Sciences de la Terre (ISTerre), Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-Institut national des sciences de l'Univers (INSU - CNRS)-Institut de recherche pour le développement [IRD] : UR219-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Institut de Physique du Globe de Paris (IPGP), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-IPG PARIS-Université Paris Diderot - Paris 7 (UPD7)-Université de La Réunion (UR)-Centre National de la Recherche Scientifique (CNRS), Istituto di Science Marine (ISMAR ), Consiglio Nazionale delle Ricerche (CNR), Biogéosciences [UMR 6282] [Dijon] (BGS), Centre National de la Recherche Scientifique (CNRS)-Université de Bourgogne (UB)-AgroSup Dijon - Institut National Supérieur des Sciences Agronomiques, de l'Alimentation et de l'Environnement, Géochimie Des Impacts (GEDI), Paléocéanographie (PALEOCEAN), Institut de Recherche pour le Développement (IRD)-Institut National de la Recherche Agronomique (INRA)-Aix Marseille Université (AMU)-Collège de France (CdF (institution))-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-École polytechnique (X)-École des Ponts ParisTech (ENPC)-Centre National de la Recherche Scientifique (CNRS)-Département des Géosciences - ENS Paris, École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL), Géosciences Marines (GM), Institut national des sciences de l'Univers (INSU - CNRS)-Université du Littoral Côte d'Opale (ULCO)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD [France-Nord]), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Universität Heidelberg [Heidelberg] = Heidelberg University, Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Université de La Réunion (UR)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS), National Research Council of Italy | Consiglio Nazionale delle Ricerche (CNR), Biogéosciences [UMR 6282] (BGS), Université de Bourgogne (UB)-Centre National de la Recherche Scientifique (CNRS), University of Oxford, Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Collège de France (CdF)-Institut national des sciences de l'Univers (INSU - CNRS)-Aix Marseille Université (AMU)-Institut National de la Recherche Agronomique (INRA), École normale supérieure - Paris (ENS Paris)-École normale supérieure - Paris (ENS Paris), Université de Lille-Université du Littoral Côte d'Opale-Centre National de la Recherche Scientifique (CNRS), Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS), Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-PRES Université de Grenoble-Institut de recherche pour le développement [IRD] : UR219-Institut national des sciences de l'Univers (INSU - CNRS)-Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-Université Joseph Fourier - Grenoble 1 (UJF), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National d'Études Spatiales [Toulouse] (CNES)-Observatoire Midi-Pyrénées (OMP), Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS), Istituto di Scienze Marine [Bologna] (ISMAR), Consiglio Nazionale delle Ricerche (CNR)-Consiglio Nazionale delle Ricerche (CNR), Department of Earth Sciences [Cambridge, UK], University of Cambridge [UK] (CAM), Department of Earth Sciences [Oxford], Work supported by NEOSYMPA project (CYBER/LEFE) and from the German Science Foundation through the project DFG-NEOGLACIAL (FR-1341/3-1 and 3-2)., Université de Bourgogne (UB)-AgroSup Dijon - Institut National Supérieur des Sciences Agronomiques, de l'Alimentation et de l'Environnement-Centre National de la Recherche Scientifique (CNRS), Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Institut des Sciences de la Terre ( ISTerre ), Université Joseph Fourier - Grenoble 1 ( UJF ) -Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux ( IFSTTAR ) -Institut national des sciences de l'Univers ( INSU - CNRS ) -Institut de recherche pour le développement [IRD] : UR219-PRES Université de Grenoble-Université Savoie Mont Blanc ( USMB [Université de Savoie] [Université de Chambéry] ) -Centre National de la Recherche Scientifique ( CNRS ) -Université Grenoble Alpes ( UGA ), Université Paul Sabatier - Toulouse 3 ( UPS ) -Centre National d'Etudes Spatiales ( CNES ) -Institut national des sciences de l'Univers ( INSU - CNRS ) -Observatoire Midi-Pyrénées ( OMP ) -Centre National de la Recherche Scientifique ( CNRS ), ISMAR-CNR, Department of Earth Sciences, University of Cambridge, and Université de Bourgogne ( UB ) -AgroSup Dijon - Institut National Supérieur des Sciences Agronomiques, de l'Alimentation et de l'Environnement-Centre National de la Recherche Scientifique ( CNRS )
Subjects: Geochemistry & Geophysics, RARE-EARTH-ELEMENTS, 010504 meteorology & atmospheric sciences, sub-01, ANTARCTIC INTERMEDIATE WATER, MN OXYHYDROXIDE COATINGS, 010502 geochemistry & geophysics, 01 natural sciences, law.invention, law, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Dissolved organic carbon, Predicted seawater εNd, Radiocarbon dating, Holocene, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, [ SDU.STU.OC ] Sciences of the Universe [physics]/Earth Sciences/Oceanography, Geology, LAST GLACIAL MAXIMUM, Oceanography, Physical Sciences, Seawater-archive comparison, MERIDIONAL OVERTURNING CIRCULATION, [ SDU ] Sciences of the Universe [physics], 0406 Physical Geography And Environmental Geoscience, Water mass, NORTH-ATLANTIC DEEP, Water mass tracer, [object Object], Geochemistry and Petrology, Nd isotopes, TRACER, 0402 Geochemistry, WESTERN PACIFIC-OCEAN, 14. Life underwater, PARTICULATE MATERIAL DISSOLUTION, [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography, 0105 earth and related environmental sciences, Science & Technology, Predicted seawater epsilon(Nd), SEA SEDIMENTS IMPLICATIONS, [ SDU.STU.GC ] Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Salinity, 0403 Geology, 13. Climate action, [SDU]Sciences of the Universe [physics], Seawater, Hydrography, Data compilation, CENTRAL ARCTIC-OCEAN
Abstract: International audience; Neodymium isotopic compositions (143Nd/144Nd or εNd) have been used as a tracer of water masses and lithogenic inputs to the ocean. To further evaluate the faithfulness of this tracer, we have updated a global seawater εNd database and combined it with hydrography parameters (temperature, salinity, nutrients and oxygen concentrations), carbon isotopic ratio and radiocarbon of dissolved inorganic carbon. Archive εNd data are also compiled for leachates, foraminiferal tests, deep-sea corals and fish teeth/debris from the Holocene period (< 10,000 years).At water depths ≥ 1500 m, property-property plots show clear correlations between seawater εNd and the other variables, suggesting that large-scale water mass mixing is a primary control of deepwater εNd distribution. At ≥ 200 m, basin-scale seawater T-S-εNd diagrams demonstrate the isotopic evolution of different water masses. Seawater and archive εNd values are compared using property-property plots and T-S-εNd diagrams. Archive values generally agree with corresponding seawater values although they tend to be at the upper limit in the Pacific. Both positive and negative offsets exist in the northern North Atlantic. Applying multiple regression analysis to deep (≥ 1500 m) seawater data, we established empirical equations that predict the main, large-scale, deepwater εNd trends from hydrography parameters. Large offsets from the predicted values are interpreted as a sign of significant local/regional influence. Dominant continental influence on seawater and archive εNd is observed mainly within 1000 km from the continents. Generally, seawater and archive εNd values form gradual latitudinal trend in the Atlantic and Pacific at depths ≥ 600 m, consistent with the idea that Nd isotopes help distinguish between northern/southern sourced water contributions at intermediate and deep water depths.
Published: 2017
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25. Urbanization impact on sulfur content on groundwater revealed by the study of urban speleothem-like deposits: case study in Paris, France

Author: Edwige Pons-Branchu, Andy Phillips, André Guillerme, Philippe Branchu, Jean-Luc Michelot, Emmanuel Dumont, Eric Douville, Mathieu Fernandez, Matthieu Roy-Barman, Liliane Jean-Soro, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Eau et Environnement (IFSTTAR/GERS/EE), PRES Université Nantes Angers Le Mans (UNAM)-Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR), Histoire des technosciences en société (HT2S), Conservatoire National des Arts et Métiers [CNAM] (CNAM), Centre d'Etudes et d'Expertise sur les Risques, l'Environnement, la Mobilité et l'Aménagement - Direction Ouest (Cerema Direction Ouest), Centre d'Etudes et d'Expertise sur les Risques, l'Environnement, la Mobilité et l'Aménagement (Cerema), Géosciences Paris Sud (GEOPS), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS), GNS Science [Lower Hutt], GNS Science, Géochrononologie Traceurs Archéométrie (GEOTRAC), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-PRES Université Nantes Angers Le Mans (UNAM), HESAM Université - Communauté d'universités et d'établissements Hautes écoles Sorbonne Arts et métiers université (HESAM)-HESAM Université - Communauté d'universités et d'établissements Hautes écoles Sorbonne Arts et métiers université (HESAM), Centre d'Etudes et d'Expertise sur les Risques, l'Environnement, la Mobilité et l'Aménagement - Equipe-projet TEAM (Cerema Equipe-projet TEAM), Laboratoire de Chimie - UMR5182 (LC), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Interactions et dynamique des environnements de surface (IDES), Université Paris-Sud - Paris 11 (UP11)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon)-Institut de Chimie du CNRS (INC), and HESAM Université (HESAM)-HESAM Université (HESAM)
Subjects: Pollution, Paris, Environmental Engineering, Gypsum, 010504 meteorology & atmospheric sciences, Water table, media_common.quotation_subject, Geochemistry, Speleothem, Aqueduct, 010501 environmental sciences, engineering.material, 01 natural sciences, Panoply, [SHS.HISPHILSO]Humanities and Social Sciences/History, Philosophy and Sociology of Sciences, chemistry.chemical_compound, δ34S, Urbanization, 11. Sustainability, Environmental Chemistry, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Waste Management and Disposal, Groundwater, 0105 earth and related environmental sciences, media_common, Hydrology, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, geography, geography.geographical_feature_category, 6. Clean water, Speleothems, chemistry, 13. Climate action, [SDU]Sciences of the Universe [physics], engineering, Carbonate, France, Water Pollutants, Chemical, Geology, Sulfur, Environmental Monitoring
Abstract: International audience; Speleothem-like deposits that develop underground in urban areas are an archive of the environmental impact of anthropic activities that has been little studied so far. In this paper, the sulfate content in shallow groundwater from northern Paris (France) is compared with the sulfur content in two 300-year-old urban carbonate deposits that grew in a historical underground aqueduct. The present-day waters of the aqueduct have very high sulfur and calcium contents, suggesting pollution from gypsum dissolution. However, geological gypsum levels are located below the water table. Sulfur content was measured by micro-X-ray fluorescence in these very S-rich carbonate deposits (0.5 to 1% of S). A twofold S increase during the second half of the 1800s was found in both samples. These dates correspond to two major periods of urbanization above the site. We discus three possible S sources: anthropic sources (industries, fertilizers…), volcanic eruptions and input within the water through gypsum brought for urbanization above the studied site (backfill with quarry waste) since the middle of the 19th century. For the younger second half of the studied section, S input from gypsum brought during urbanization was confirmed by the study of isotopic sulfur composition (δ34S = + 15.2‰ at the top). For the oldest part, several sulfur peaks could be related to early industrial activity in Paris, that caused high local air pollution, as reported in historical archives but also to historical gypsum extraction. This study provides information on the origin and timing of the very high SO42 − levels measured nowadays within the shallow groundwater, thus demonstrating the interest in using carbonate deposits in urban areas as a proxy for the history of urbanization or human activities and their impact on water bodies.
Published: 2017
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26. Variable reactivity of particulate organic matter in a global ocean biogeochemical model

Author: Olivier Aumont, Marco van Hulten, Matthieu Roy-Barman, Jean-Claude Dutay, Christian Éthé, Marion Gehlen
Published: 2017
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27. A reactivity continuum of particulate organic matter in a global ocean biogeochemical model

Author: Matthieu Roy-Barman, Marco van Hulten, Jean-Claude Dutay, Christian Ethé, Marion Gehlen, Olivier Aumont, Nucleus for European Modeling of the Ocean (NEMO R&D ), Laboratoire d'Océanographie et du Climat : Expérimentations et Approches Numériques (LOCEAN), Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Muséum national d'Histoire naturelle (MNHN)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Muséum national d'Histoire naturelle (MNHN), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and European Project: 641816,H2020,H2020-SC5-2014-two-stage,CRESCENDO(2015)
Subjects: [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, 0106 biological sciences, 010504 meteorology & atmospheric sciences, Continuum (measurement), Particulate organic matter, 010604 marine biology & hydrobiology, [PHYS.PHYS.PHYS-GEO-PH]Physics [physics]/Physics [physics]/Geophysics [physics.geo-ph], Biogeochemical model, 01 natural sciences, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, 13. Climate action, Environmental chemistry, Environmental science, 14. Life underwater, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences
Abstract: The marine biological carbon pump is dominated by the vertical transfer of Particulate Organic Carbon (POC) from the surface ocean to its interior. The efficiency of this transfer plays an important role in controlling the amount of atmospheric carbon that is sequestered in the ocean. Furthermore, the abundance and composition of POC is critical for the removal of numerous trace elements by scavenging, a number of which such as iron are essential for the growth of marine organisms, including phytoplankton. Observations and laboratory experiments have shown that POC is composed of numerous organic compounds that can have very different reactivities. Yet, this variable reactivity of POC has never been extensively considered, especially in modeling studies. Here, we introduced in the global ocean biogeochemical model NEMO-PISCES a description of the variable composition of POC based on the theoretical Reactivity Continuum Model proposed by (Boudreau and Ruddick, 1991). Our model experiments show that accounting for a variable lability of POC increases POC concentrations in the ocean’s interior by one to two orders of magnitude. This increase is mainly the consequence of a better preservation of small particles that sink slowly from the surface. Comparison with observations is significantly improved both in abundance and in size distribution. Furthermore, the amount of carbon that reaches the sediments is increased by more than a factor of two, which is in better agreement with global estimates of the sediment oxygen demand. The impact on the major macro-nutrients (nitrate and phosphate) remains modest. However, iron (Fe) distribution is strongly altered, especially in the upper mesopelagic zone as a result of more intense scavenging: Vertical gradients in Fe are milder in the upper ocean which appears to be closer to observations. Thus, our study shows that the variable lability of POC can play a critical role in the marine biogeochemical cycles which advocates for more dedicated in situ and laboratory experiments.
Published: 2016
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28. CO2 Exchanges between the Ocean and the Atmosphere

Author: Matthieu Roy-Barman and Catherine Jeandel
Subjects: Atmosphere, Environmental science, Atmospheric sciences
Published: 2016
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29. Thermohaline Circulation

Author: Matthieu Roy-Barman and Catherine Jeandel
Published: 2016
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30. Radioactive and Radiogenic Isotopes

Author: Catherine Jeandel and Matthieu Roy-Barman
Subjects: Geochemistry, Radiogenic Isotopes
Published: 2016
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31. Stable Isotopes

Author: Matthieu Roy-Barman and Catherine Jeandel
Published: 2016
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32. Ocean History and Climate Evolution

Author: Catherine Jeandel and Matthieu Roy-Barman
Subjects: Oceanography, Effects of global warming, Climatology, Environmental science, Climate model, Climate state
Published: 2016
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33. The Little World of Marine Particles

Author: Matthieu Roy-Barman and Catherine Jeandel
Published: 2016
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34. Advection–Diffusion Models

Author: Catherine Jeandel and Matthieu Roy-Barman
Subjects: Materials science, Advection, Mechanics, Diffusion (business)
Published: 2016
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35. Marine Geochemistry

Author: Catherine Jeandel and Matthieu Roy-Barman
Subjects: 010504 meteorology & atmospheric sciences, Ocean current, Global warming, Climate change, 010501 environmental sciences, 01 natural sciences, Carbon cycle, Oceanography, Effects of global warming, Ocean fertilization, Climatology, Climate model, Geology, 0105 earth and related environmental sciences
Published: 2016
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36. Development and Limitations of Biological Activity in Surface Waters

Author: Matthieu Roy-Barman and Catherine Jeandel
Subjects: Chemistry, Environmental chemistry, Development (differential geometry), Biological activity
Published: 2016
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37. Seawater Is More than Salted Water

Author: Catherine Jeandel and Matthieu Roy-Barman
Subjects: Environmental chemistry, Environmental science, Seawater
Published: 2016
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38. Box Models

Author: Matthieu Roy-Barman and Catherine Jeandel
Published: 2016
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39. A Few Bases of Descriptive and Physical Oceanography

Author: Matthieu Roy-Barman and Catherine Jeandel
Subjects: Engineering, business.industry, Mathematics education, Physical oceanography, business
Published: 2016
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40. Manganese in the world ocean: a first global model

Author: Andreas Sterl, Jean-Claude Dutay, Rob Middag, Marion Gehlen, Marco van Hulten, Matthieu Roy-Barman, Hein J W de Baar, and Alessandro Tagliabue
Subjects: 010504 meteorology & atmospheric sciences, chemistry, Earth science, Environmental science, chemistry.chemical_element, Manganese, 010501 environmental sciences, 01 natural sciences, Global model, 0105 earth and related environmental sciences
Abstract: Dissolved manganese (Mn) is a biologically essential element. Moreover, its oxidised form is involved in the removal of itself and several other trace elements from ocean waters. Recently, a large number of highly accurate Mn measurements has been obtained in the Atlantic, Indian and Arctic Oceans as part of the GEOTRACES programme. The goal of this study is to combine these new observations with state-of-the-art modelling to give new insights into the main sources and redistribution of Mn throughout the ocean. To this end, we simulate the distribution of dissolved Mn using a global-scale circulation model. Our model reproduces observations accurately and provides the following insights: – The high surface concentrations of manganese are caused by the combination of photoreduction and sources to the upper ocean. The most important sources are dust, then sediments, and, more locally, rivers. – Results show that surface Mn in the Atlantic Ocean moves downwards into the North Atlantic Deep Water, but because of strong removal rates the Mn does not propagate southwards. – There is a mostly homogeneous background concentration of dissolved Mn of about 0.10 nM to 0.15 nM throughout most of the deep ocean. The model reproduces this by means of a threshold on particulate manganese oxides of 25 pM, suggesting that a minimal concentration of particulate Mn is needed before aggregation and removal become efficient. – The observed sharp hydrothermal signals are produced by assuming both a high source and a strong removal of Mn near hydrothermal vents.
Published: 2016
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41. Supplementary material to 'Manganese in the world ocean: a first global model'

Author: Marco van Hulten, Jean-Claude Dutay, Rob Middag, Hein de Baar, Matthieu Roy-Barman, Marion Gehlen, Alessandro Tagliabue, and Andreas Sterl
Published: 2016
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42. Lead contamination of the Seine River, France: Geochemical implications of a historical perspective

Author: Marie Françoise Le Cloarec, Philippe Bonté, Sophie Ayrault, Christa Göpel, Matthieu Roy-Barman, Cindy Rianti Priadi, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Institut de Physique du Globe de Paris (IPGP (UMR_7154)), Institut national des sciences de l'Univers (INSU - CNRS)-Université de La Réunion (UR)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité), This work has been made possible thanks to funding from the Piren-Seine 569 programme coordinated by J.-M. Mouchel., Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut de Physique du Globe de Paris (IPGP), and Institut national des sciences de l'Univers (INSU - CNRS)-IPG PARIS-Université de La Réunion (UR)-Centre National de la Recherche Scientifique (CNRS)-Université de Paris (UP)
Subjects: Pollution, Paris, Environmental Engineering, 010504 meteorology & atmospheric sciences, [SDE.MCG]Environmental Sciences/Global Changes, Health, Toxicology and Mutagenesis, media_common.quotation_subject, Drainage basin, industrial lead, 010501 environmental sciences, History, 21st Century, 01 natural sciences, Isotopes, Rivers, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, River mouth, Environmental Chemistry, Broken Hill, isotope, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Weather, 0105 earth and related environmental sciences, media_common, geography, geography.geographical_feature_category, Lead (sea ice), Public Health, Environmental and Occupational Health, Environmental engineering, Sediment, Seine, General Medicine, General Chemistry, History, 20th Century, Contamination, urban lead, 6. Clean water, Isotopic composition, Lead, 13. Climate action, Environmental chemistry, [SDE]Environmental Sciences, Waste water treatment plant, Environmental science, France, Rio 38 Tinto, Gasoline, Water Pollutants, Chemical
Abstract: International audience; Four sediment cores collected in the Seine River basin and dated between 1916 and 2003 were analyzed for lead concentrations and isotopic composition. In all four cores, the measured Pb concentration (up to 460 mg kg$^{-1}$) lies significantly above the natural background (27–40 mg kg$^{-1}$), although a significant decrease (down to 75 mg kg$^{-1}$) was observed during the second half of the 20th century which can be explained by the reduction of lead emissions. The $^{206}$Pb/$^{207}$Pb ratio measured in these samples indicates that the main source of Pb used in the Paris conurbation is characterized by a “Rio Tinto” signature (defined as $^{206}$Pb/$^{207}$Pb = 1.1634 $\pm$ 0.0001). A high contribution, up to 25%, from the leaded gasoline (characterized by 206Pb/207Pb = 1.08 $\pm$ 0.02) is revealed in the Seine River downstream Paris, indicating that lead from the leaded gasoline is preferentially released to the river.The dominating Pb signature in the Paris conurbation that is currently sampled through incinerators fumes (206Pb/207Pb = 1.1550 $\pm$ 0.0005) and waste water treatment plant ($^{206}$Pb/$^{207}$Pb = 1.154 $\pm$ 0.002), represents a mixture of highly recycled lead from the Rio Tinto mine and lead from leaded gasoline (imprinted by the low 206Pb/207Pb of the Broken Hill mine). This signature is called “urban” rather than “industrial”, because it is clearly distinct from the Pb that is found in areas contaminated by heavy industry, i.e. the heavy industries located on the Oise River which used lead from European ores characterized by high $^{206}$Pb/$^{207}$Pb ratios ($\sim$1.18–1.19) and possibly a minor amount of North American lead ($^{206}$Pb/$^{207}$Pb ratios > 1.20). The “urban” signature is also found in a rural area upstream of Paris in the 1970’s. At the Seine River mouth in 2003, Pb with an urban signature represents 70% of the total Pb sediment content, with the 30% remaining corresponding to natural Pb.
Published: 2012
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43. GEOTRACES intercalibration of230Th,232Th,231Pa, and prospects for10Be

Author: Alexander L. Thomas, Laura F. Robinson, Martin Q. Fleisher, J.A. Hoff, S. Bradley Moran, R. Lawrence Edwards, Matthieu Roy-Barman, Michiel M Rutgers van der Loeff, Robert F. Anderson, and Roger Francois
Subjects: 010504 meteorology & atmospheric sciences, Geotraces, Ocean Engineering, Particulates, Contamination, 010502 geochemistry & geophysics, 01 natural sciences, 6. Clean water, Chemical oceanography, law.invention, Water column, law, Environmental chemistry, Internal consistency, Environmental science, Seawater, Filtration, 0105 earth and related environmental sciences
Abstract: Nineteen labs representing nine nations participated in the GEOTRACES intercalibration initiative that determined concentrations of 232Th, 230Th, 231Pa or 10Be in seawater, suspended particles or sediments. Results generally demonstrated good agreement among labs that analyzed marine sediments. Two sets of seawater samples, aliquots of particulate material filtered in situ, and/or aliquots of biogenic sediments were distributed to participating labs. Internal consistency among participating labs improved substantially between the first and second set of seawater samples. Contamination was a serious problem for 232Th. Standard Niskin™ bottles introduced no detectable contamination, whereas sample containers, reagents and labware were implicated as sources of contamination. No detectable differences in concentrations of dissolved 232Th, 230Th or 231Pa were observed among samples of seawater filtered through Nuclepore ™, Supor ™ or QMA™ (quartz) filters with pore diameters ranging between 0.4 and 1.0 μm. Isotope yield monitors equilibrate with dissolved Th in seawater on a time scale of much less than one day. Samples of filtered seawater acidified to a pH between 1.7 and 1.8 experienced no detectable loss of dissolved Th or Pa during storage for up to three years. The Bermuda Atlantic Time Series station will serve as a GEOTRACES baseline station for future intercalibration of 232Th and 230Th concentrations in seawater. Efforts to improve blanks and standard calibration are ongoing, as is the development of methods to determine concentrations of particulate nuclides, tests of different filtration methods, and an increasing awareness of the need to define protocols for reporting uncertainties.
Published: 2012
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44. Influence of intense scavenging on Pa-Th fractionation in the wake of Kerguelen Island (Southern Ocean)

Author: P. van Beek, Matthieu Roy-Barman, C. Venchiarutti, Marc Souhaut, Rémi Freydier, Catherine Jeandel, GEOMAR LEGOS, Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Laboratoire des Mécanismes et Transfert en Géologie (LMTG), Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Université de Toulouse (UT)-Université de Toulouse (UT)-Observatoire Midi-Pyrénées (OMP)
Subjects: 0106 biological sciences, 010504 meteorology & atmospheric sciences, Nepheloid layer, lcsh:Life, Flux, Biogenic silica, 010502 geochemistry & geophysics, WATER-COLUMN, 01 natural sciences, Water column, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, lcsh:QH540-549.5, 14. Life underwater, Scavenging, Ecology, Evolution, Behavior and Systematics, ATLANTIC-OCEAN, 0105 earth and related environmental sciences, Earth-Surface Processes, THORIUM ISOTOPES, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, geography, Plateau, geography.geographical_feature_category, Advection, 010604 marine biology & hydrobiology, FRACTIONATION, lcsh:QE1-996.5, PHYTOPLANKTON BLOOM, PARTICLE COMPOSITION, LITHOGENIC CLAYS, EQUATORIAL PACIFIC, Particulates, 6. Clean water, lcsh:Geology, lcsh:QH501-531, NATURAL IRON FERTILIZATION, PA-231/TH-230, Oceanography, 13. Climate action, lcsh:Ecology, COMMUNITY STRUCTURE, Geology
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Roy-Barman, M. Freydier, R. van Beek, P. Souhaut, M. Jeandel, C. IPEV (Institut Paul Emile Victor); INSU/CNRS; LEGOS (Toulouse); CNRS-INSU We thank the captain and crew of the R/V Marion Dufresne, the PI of KEOPS project Stephane Blain and the chief scientist Bernard Queguiner. We would like to thank Lionel Scouarnec and Christophe Guillerm (INSU) for their help with the in-situ pumps. We are grateful to Jean-Louis Reyss who enabled us to achieve the gamma measurements at LSM. We are especially thankful to Roger Francois and Walter Geibert for providing the Pa spikes allowing us to achieve this study. We thank Catherine Pradoux for her help in the clean laboratory. We are very grateful to the two anonymous reviewers for their critical and fruitful comments. This work was supported by the IPEV (Institut Paul Emile Victor), the INSU/CNRS and the LEGOS (Toulouse).The publication of this article is financed by CNRS-INSU. 0 COPERNICUS GESELLSCHAFT MBH GOTTINGEN BIOGEOSCIENCES; Dissolved and particulate excess (230)Th and (231)Pa concentrations (noted (230)Th(xs) and (231)Pa(xs) respectively) and (231)Pa(xs)/(230)Th(xs) activity ratios were investigated on and out of the Kerguelen plateau (Southern Ocean) in the framework of the Kerguelen Ocean and Plateau compared Study project in order to better understand the influence of particle flux and particle chemistry and advection on the scavenging of (231)Pa. In the wake of Kerguelen, particulate (231)Pa(xs) is relatively abundant compared to its content in the dissolved phase. This, together with the low fractionation observed between (230)Th and (231)Pa (F(Th/Pa) ranging from 0.06 +/- 0.01 to 1.6 +/- 0.2) reflects the domination of the biogenic silica in the particle pool. Along the eastern escarpment of the Kerguelen plateau, the strong (231)Pa(xs) horizontal gradient in the deep waters highlights the intense removal of (231)Pa at depth, as already observed for (230)Th(xs). This local boundary scavenging was attributed to re-suspension of opal-rich particles by nepheloid layers, resulting in fractionation factors F(Th/Pa)
Published: 2011
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45. Improved U–Th dating of carbonates with high initial 230Th using stratigraphical and coevality constraints

Author: Matthieu Roy-Barman, Edwige Pons-Branchu, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochrononologie Traceurs Archéométrie (GEOTRAC), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), and Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)
Subjects: Isochron, U-Th dating, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, 010506 paleontology, geography, geography.geographical_feature_category, Stratigraphy, STRUTages, Speleothem, Geology, 010502 geochemistry & geophysics, 01 natural sciences, Panoply, Paleontology, Earth and Planetary Sciences (miscellaneous), isochron, stratigraphical, coeval constraints, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, coral, speleothem, 0105 earth and related environmental sciences
Abstract: International audience; With high precision measurements now achievable by MC-ICPMS, the uncertainty on the initial 230 Th content can be the major source of uncertainty for U-Th ages of carbonates. The initial 230 Th content is usually derived from the 232 Th content of the sample and the initial 230 Th/ 232 Th ratio calculated using isochron techniques or using stratigraphical constraints along the speleothem growth axis. These two methods are based on different hypotheses and have not been couple previously. Here, we present a new algorithm called STRUTages that combines stratigraphical and coevality constraints in order to obtain the best estimate on the initial 230 Th/ 232 Th ratio of each sample. STRUTages and isochron results are compared on a suite of speleothems and a coral core. Comparison of the U-Th and growth-band counted ages of the coral core demonstrates the validity of the STRUTages approach. An Octave (Matlabcompatible) script allowing the use of stratigraphical and coevality constraints is provided.
Published: 2016
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46. Three centuries of heavy metal pollution in Paris (France) recorded by urban speleothems

Author: Sophie Ayrault, Wolfgang Borst, Louise Bordier, Emmanuel Dumont, Philippe Branchu, Eric Douville, Edwige Pons-Branchu, Matthieu Roy-Barman, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS), Géochrononologie Traceurs Archéométrie (GEOTRAC), Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS), Centre d'Etudes et d'Expertise sur les Risques, l'Environnement, la Mobilité et l'Aménagement - Direction Ile-de-France (Cerema Direction Ile-de-France), Centre d'Etudes et d'Expertise sur les Risques, l'Environnement, la Mobilité et l'Aménagement (Cerema), Centre d'Economie et de Sociologie Rurales Appliquées à l'Agriculture et aux Espaces Ruraux (CESAER), Institut National de la Recherche Agronomique (INRA)-AgroSup Dijon - Institut National Supérieur des Sciences Agronomiques, de l'Alimentation et de l'Environnement, Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochimie Des Impacts (GEDI), AgroSup Dijon - Institut National Supérieur des Sciences Agronomiques, de l'Alimentation et de l'Environnement-Institut National de la Recherche Agronomique (INRA), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: Pollution, Geologic Sediments, Paris, Environmental Engineering, 010504 meteorology & atmospheric sciences, media_common.quotation_subject, Geochemistry, Speleothem, 010501 environmental sciences, 01 natural sciences, Natural (archaeology), Mining, Anthropogenic pollution, Metals, Heavy, Environmental Chemistry, Coal, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Waste Management and Disposal, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, media_common, Hydrology, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, geography, geography.geographical_feature_category, business.industry, Mean value, Urbanization, Metal pollution, Isotopic composition, 13. Climate action, business, Environmental Pollution, Geology, Environmental Monitoring
Abstract: The first record of urban speleothems used to reconstruct the history of heavy metal pollution of shallow groundwaters is presented. Two speleothems grew during the last 300 years in an underground aqueduct in the north-eastern part of Paris. They display high Pb, Mn V, Cu, Cd and Al concentrations since 1900 due to the urbanization of the site which triggered anthropogenic contamination of the water feeding the speleothems. Surprisingly, these heavy metal concentrations are also high in the oldest part. This early pollution could come from the use of Parisian waste as fertilizers in the orchards and vineyards cultivated above the aqueduct before urbanization. Lead isotopes were measured in these carbonates as well as in lead artifacts from the 17th–18th centuries (206Pb/207Pb = 1.180 +/− 0.003). The mean 206Pb/207Pb ratio, for one of the speleothems is 1.181 +/− 0.003 unvarying with time. These lead signatures are close to those of coal and old lead from northern European mines, lower than the natural background signature. It confirms that the high metal concentrations found come from anthropogenic pollution. Conversely, the lead isotopic composition of the second speleothem presents two temporal trends: for the oldest levels, the mean value (1.183 +/− 0.003) is similar to the first speleothem. For the youngest part, a lower value (1.172 +/− 0.005) is recorded, evidencing the contribution of a new lead source at the beginning of the industrial revolution. Pb isotopes were also measured in recent samples from a nearby superficial site. The first sample is a recent (AD 1975 +/− 15 years) deposit (206Pb/207Pb = 1.148 +/− 0.003), and the second, a thin subactual layer (206Pb/207Pb = 1.181 +/− 0.002). These data are compatible with the adding of anthropogenic sources (leaded gasoline and industrial lead from Rio Tinto ore).
Published: 2015
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47. 234Th sorption and export models in the water column: A review

Author: Matthew A. Charette, Nicolas Savoye, Ken O. Buesseler, Matthieu Roy-Barman, Marc Elskens, J. Kirk Cochran, George A. Jackson, Claudia R. Benitez-Nelson, Sabine Schmidt, Adrian B. Burd, Analytical, Environmental and Geo- Chemistry, Vrije Universiteit Brussel (VUB), Environnements et Paléoenvironnements OCéaniques (EPOC), Observatoire aquitain des sciences de l'univers (OASU), Université Sciences et Technologies - Bordeaux 1-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Sciences et Technologies - Bordeaux 1-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-École pratique des hautes études (EPHE), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS), University of South Carolina [Columbia], Stony Brook University [SUNY] (SBU), State University of New York (SUNY), Department of Marine Chemistry and Geochemistry (WHOI), Woods Hole Oceanographic Institution (WHOI), Texas A&M University [College Station], Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Université Sciences et Technologies - Bordeaux 1 (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Sciences et Technologies - Bordeaux 1 (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-École Pratique des Hautes Études (EPHE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: 0106 biological sciences, 010504 meteorology & atmospheric sciences, Meteorology, Physical oceanography, Oceanography, Atmospheric sciences, 01 natural sciences, Pacific ocean, Water column, Particle dynamics, Environmental Chemistry, 14. Life underwater, 0105 earth and related environmental sciences, Water Science and Technology, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, model, $^{234}$Th, 010604 marine biology & hydrobiology, Sorption, General Chemistry, scavenging, Field (geography), particle dynamics, High flux, 13. Climate action, [SDE]Environmental Sciences, export, Geology
Abstract: Over the past few decades, the radioisotope pair of 238U / 234Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to 234Th. It is focused on the models associated with 234Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / 234Th ratios (Buesseler et al.), 234Th speciation (Santschi et al.) and present and future applications of 234Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, O., this issue. An Introduction to the application and future use of 234Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current 234Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate 234Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of 234Th export, especially during high flux events (> ca. 800 dpm m− 2 d− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of 234Th as a tracer of particle dynamics and flux in more complicated regimes.
Published: 2006
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48. Thorium isotopes as tracers of particles dynamics and deep water circulation in the Indian sector of the Southern Ocean (ANTARES IV)

Author: Matthieu Roy-Barman, Pavel P. Povinec, Laurent Coppola, S. Mulsow, Catherine Jeandel, Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Instituto de Geociencias, Universidad Austral de Chile, Marine Environment Laboratories [Monaco] (IAEA-MEL), International Atomic Energy Agency [Vienna] (IAEA), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), and Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)
Subjects: Biogeochemical cycle, 010504 meteorology & atmospheric sciences, 010502 geochemistry & geophysics, Oceanography, 01 natural sciences, Water column, Settling, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Environmental Chemistry, 14. Life underwater, 0105 earth and related environmental sciences, Water Science and Technology, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Polar front, North Atlantic Deep Water, General Chemistry, Thorium-230, Marine particles, Thorium-234, 13. Climate action, Environmental science, Subtropical front, Southern Indian Ocean, Surface water, Isotopes of thorium
Abstract: Dissolved and particulate samples were collected to study the distribution of thorium isotopes ( 234 Th, 232 Th and 230 Th) in the water column of the Indian sector of the Southern Ocean (from 42°S to 47°S and from 60°E to 66°E, north of the Polar Front) during Austral summer 1999. Vertical profiles of excess 230 Th ( 230 Th xs ) increases linearly with depth in surface water (0–100 m) and a model was applied to estimate a residence time relative to the thorium scavenging ( τ scav ). Low τ scav in the Polar Front Zone (PFZ) are found, compared to those estimated in the Subtropical Front Zone (STZ). Changes in particle composition between the PFZ and STZ could influence the 230 Th xs scavenging efficiency and explain this difference. An innovative coupling between 234 Th and 230 Th xs was then used to simultaneously constrain the settling velocities of small (0.6–60 μm) and large (above 60 μm) particles. Although the different hydrological and biogeochemical regimes visited during the ANTARES IV cruise did not explain the spatial variation of sinking velocity estimates, our results indicate that less particles may reach the seafloor north (60 ± 2 m d − 1 , station 8) than south of the Agulhas Return Current (119 ± 23 and 130 ± 5 m d − 1 at stations 3 and 7, respectively). This information is essential for understanding particle transport and by extension, carbon export. In the deep water column, the 230 Th xs concentrations did not increase linearly with depth, probably due to lateral transport of North Atlantic Deep Water (NADW) from the Atlantic to the Indian sector, which renews the deep waters and decreases the 230 Th xs concentrations. A specific 230 Th xs transport model is applied in the deep water column and allows us to assess a “travel time” of NADW ranging from 2 to 15 years.
Published: 2006
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49. What did we learn about ocean particle dynamics in the GEOSECS–JGOFS era?

Author: Matthieu Roy-Barman, Catherine Jeandel, Christopher R. German, Phoebe J. Lam, Robert M. Sherrell, Frank Dehairs, Michiel M Rutgers van der Loeff, Sven Kretschmer, Chemistry, Analytical and Environmental Chemistry, Earth System Sciences, Analytical, Environmental & Geo-Chemistry, Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung (AWI), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Vrije Universiteit Brussel (VUB), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), and Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)
Subjects: [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Geotraces, Sampling (statistics), Geology, Particle (ecology), Aquatic Science, Residence time (fluid dynamics), Panoply, Oceanography, Settling, 13. Climate action, Sediment trap, Environmental science, Seawater, 14. Life underwater, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Nansen bottle, ComputingMilieux_MISCELLANEOUS
Abstract: Particles determine the residence time of many dissolved elements in seawater. Although a substantial number of field studies were conducted in the framework of major oceanographic programs as GEOSECS and JGOFS, knowledge about particle dynamics is still scarce. Moreover, the particulate trace metal behavior remains largely unknown. The GEOSECS sampling strategy during the 1970s focused on large sections across oceanic basins, where particles were collected by membrane filtration after Niskin bottle sampling, biasing the sampling toward the small particle pool. Late in this period, the first in situ pumps allowing large volume sampling were also developed. During the 1990s, JGOFS focused on the quantification of the “exported carbon flux” and its seasonal variability in representative biogeochemical provinces of the ocean, mostly using sediment trap deployments. Although scarce and discrete in time and space, these pioneering studies allowed an understanding of the basic fate of marine particles. This understanding improved considerably, especially when the analysis of oceanic tracers such as natural radionuclides allowed the first quantification of processes such as dissolved-particle exchange and particle settling velocities. Because the GEOTRACES program emphasizes the importance of collecting, characterizing and analyzing marine particles, this paper reflects our present understanding of the sources, fate and sinks of oceanic particles at the early stages of the program.
Published: 2015
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50. Remanence of lead pollution in an urban river system : a multi-scale temporal and spatial study in the Seine River basin, France

Author: Matthieu Roy-Barman, Philippe Bonté, Olivier Evrard, Cindy Rianti Priadi, P. Le Pape, Sophie Ayrault, Cécile Quantin, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géosciences Paris Sud (GEOPS), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS), Géochimie Des Impacts (GEDI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), ISIS EGIS EAU Indonésie, Université de Bandung, Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
Subjects: Paris, 010504 meteorology & atmospheric sciences, Health, Toxicology and Mutagenesis, Drainage basin, [SDU.STU]Sciences of the Universe [physics]/Earth Sciences, 010501 environmental sciences, Structural basin, 01 natural sciences, Panoply, Spatio-Temporal Analysis, Rivers, Urbanization, Water Pollution, Chemical, Environmental Chemistry, Humans, Industry, 0105 earth and related environmental sciences, Hydrology, geography, geography.geographical_feature_category, Sediment, General Medicine, Particulates, Contamination, Pollution, 6. Clean water, Current (stream), Lead, 13. Climate action, [SDE]Environmental Sciences, Environmental science, Combined sewer, Particulate Matter, France, Water Pollutants, Chemical, Environmental Monitoring
Abstract: International audience; Total lead (Pb) concentration and Pb isotopic ratio ((206)Pb/(20)7Pb) were determined in 140 samples from the Seine River basin (France), covering a period of time from 1945 to 2011 and including bed sediments (bulk and size fractionated samples), suspended particulate matter (SPM), sediment cores, and combined sewer overflow (CSO) particulate matter to constrain the spatial and temporal variability of the lead sources at the scale of the contaminated Seine River basin. A focus on the Orge River subcatchment, which exhibits a contrasted land-use pattern, allows documenting the relation between hydrodynamics, urbanization, and contamination sources. The study reveals that the Pb contamination due to leaded gasoline that peaked in the 1980s has a very limited impact in the river nowadays. In the upstream Seine River, the isotopic ratio analysis suggests a pervasive contamination which origin (coal combustion and/or gasoline lead) should be clarified. The current SPM contamination trend follows the urbanization/industrialization spatial trend. Downstream of Paris, the lead from historical use originating from the Rio Tinto mine, Spain ((206)Pb/(207)Pb = 1.1634 ± 0.0001) is the major Pb source. The analysis of the bed sediments (bulk and grain size fractionated) highlights the diversity of the anthropogenic lead sources in relation with the diversity of the human activities that occurred in this basin over the years. The "urban" source, defined by waste waters including the CSO samples ((206)Pb/(207)Pb = 1.157 ± 0.003), results of a thorough mixing of leaded gasoline with "historical" lead over the years. Finally, a contamination mixing scheme related to hydrodynamics is proposed.
Published: 2014
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