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Nereid, Neptune's third largest satellite, lies in an irregular orbit and is the only outer satellite in the system (apart from Triton) that can be spectroscopically characterized with the current generation of Earth-based telescopes. We report our results on spectral characterization of Nereid using its reflectance spectrum from 0.8-2.4 $\mu m$, providing the first measurements over the range of 0.8-1.4 $\mu m$. We detect spectral absorption features of crystalline water ice in close agreement with previous measurements. We show that model fits of simple intimate mixtures including water ice do not provide simultaneous matches to absorption band depths at 1.5 and 2.0 $\mu m$ when accounting for the spectral continuum. Possible solutions include invoking a more complex continuum, including both crystalline and amorphous water ice, and allowing for sub-micron sized grains. We show that mixtures including magnetite and the CM2 chondrite Murchison provide a flexible framework for interpreting spectral variation of bodies with neutral-sloped spectra like that of Nereid. Magnetite in particular provides a good match to the spectral continuum without requiring the presence of Tholin-like organics. We note that carbonaceous chondrites and their components may be useful analogs for the non-ice components of outer solar system bodies, consistent with recent findings by Fraser et al. (2019). Comparison to spectra of large TNOs and satellites of Uranus show that Nereid's low albedo, deep water bands, and neutral color is distinct from many other icy objects, but such comparisons are limited by incomplete understanding of spectral variability among $\sim$100km-sized icy bodies., Comment: 11 pages, 2 tables, 7 figures, accepted in PSJ

D-type asteroids represent a complex mystery related to the accretional history, composition, and dynamical migration of Outer Solar System objects. These spectrally featureless bodies have revealed few clues while raising many questions over four decades. D-types are dark, difficult to observe and perhaps contain unaltered primordial material. D-type asteroids are abundant in the outer belt, dominant in the Jupiter Trojans, and rare in the inner belt as well as near Earth space. Material spectrally similar to D-types is pervasive on other outer solar system bodies as well. The appearance of dark, spectrally red material in multiple classes of small bodies suggests some unknown geochemical and/or evolutionary connection(s) may exist between them. Our investigation focused on the visible near-infrared (VNIR) (0.7–2.45 μm) spectral distinctions of D-types based on heliocentric location. Twenty-five newly acquired spectra from NASA's Infrared Telescope Facility (IRTF) plus sixty-one IRTF VNIR spectra from the literature were combined into a single database and extensively analyzed with multiple orbital, observational, and spectral variables included in the examination. Twelve of the newly acquired spectra had not been imaged previously at IRTF. Pearson's correlation, simple and multiple regression, slope analysis, Monte Carlo modeling, as well as Principal Component Analysis (PCA) determined D-types show increased reddening with decreasing distance, with the segment from 1.5–2.45 μm, driving the overall trend for the full slope. Principal components show strong connection to the 0.7–1.35 μm slope and inclination of D-type Jupiter Trojans. Principal component combinations, magnitudes, and positive/negative direction relate strongly to both observed and derived differences in the D-type L4 and L5 Trojan population. The L5 population is less evolved spectrally and dynamically than L4 counterparts perhaps due to lower dynamical instabilities inside the L4 cloud.

Asteroids are the origin point for most meteorites impacting Earth. Terrestrial meteorite samples provide evidence of what actually occurred in the early solar system at the formation location of the meteorite, and when it occurred. The ability to connect a meteorite sample to an asteroid parent body provides its starting location as a meteoroid. To date, only a handful of chondritic meteorite types have been credibly connected to an asteroid parent. For the past two decades, D-type asteroids, a dark, spectrally reddish, and featureless taxonomic type have been speculated to be the parent body of the tiny family of ungrouped chondrites. These include the Tagish Lake Meteorite (TLM), a ~ 4 m meteorite “fall” in Canada's Yukon territory recovered in 2000. The quest to identify the TLM parent has been a baffling one as D-type asteroids are dominant among the Jovian Trojans, rare in main asteroid belt, and extremely rare in the inner asteroid belt as well as Near-Earth space. This study employed Near Infrared (NIR) spectra (0.7–2.45 μm) of 86 D-types and a variety of analysis techniques including visual analysis, slope analysis, curve fitting, Frechet analysis, dynamical analysis and Shkuratov radiative transfer theory to search for the TLM parent body. Sixteen TLM samples from the NASA Reflectance Experiment Laboratory (RELAB) plus five additional mineralogically well-constrained samples measured using X-ray diffraction (XRD) and Rietveld refinement were compared to D-type asteroid spectra. Our results indicate, out of several promising candidates, Near-Earth asteroid 17274 (2006 LC16), a ~ 3 km diameter Amor asteroid is a plausible parent body for TLM.

We report near-infrared (0.7-2.5 micron) reflectance spectra for each of the six target asteroids of the forthcoming NASA Discovery-class mission Lucy. Five Jupiter Trojans (the binary (617) Patroclus system, (3548) Eurybates, (21900) Orus, (11351) Leucus, and (15094) Polymele) are well-characterized, with measurable spectral differences. We also report a survey-quality spectrum for main belt asteroid (52246) Donaldjohanson. We measured a continuum of spectral slopes including "red" (Orus, Leucus), "less red" (Eurybates, Patroclus-Menoetius) and intermediate (Polymele), indicating a range of compositional end-members or geological histories. We perform radiative transfer modeling of several possible surface compositions. We find that the mild-sloped spectra and low albedo of Patroclus and Eurybates imply similar compositions. Eurybates (~7 wt.% water ice) and Patroclus (~4 wt.% water ice) are consistent with a hydrated surface. Models for Orus and Leucus are consistent with each other and require a significantly more reddening agent (e.g. iron-rich silicates or tholin-like organics). Polymele has a linear spectrum like Patroclus, but a higher albedo more closely aligned with Orus/Leucus, defying simple grouping. Solar system formation models generally predict that the Jovian Trojans accreted in the outer solar system. Our observations and analysis are generally consistent with this expectation, although not uniquely so., Comment: Accepted by AJ. 10 Figures, 5 Tables

Salt-rich deposits may be more widespread on planetary surfaces than is generally appreciated. Remote observations, laboratory studies of meteorites, and cosmochemical constraints all point towards widespread occurrences of salts (including halides, sulfates, and (bi)carbonates) on asteroids, icy bodies, Mars, and elsewhere. We have investigated the mid-infrared (1.8–25 μm) reflectance spectral properties of mixtures of chondritic (ordinary, enstatite and carbonaceous) meteorites with potassium bromide; a mid-infrared transmissive salt like all halides. Our results demonstrate that halide-chondrite mixtures provide spectral signatures that either reveal the presence of transmissive materials or provide evidence for highly porous regolith. Previously, the nature of the surfaces of the asteroids 624 Hektor and 21 Lutetia was inferred using a limited range of spectra from halide-chondrite mixtures. Here, we provide an extensive dataset of halide-chondrite mixtures to encompass a wider set of possible surface compositions.

D-type asteroids are a prime example of the many dark, low-albedo asteroids which do not reflect sufficient light to reveal detectable mineral absorptions. While D-type asteroids are relatively rare in the inner solar system and the main asteroid belt, they are dominant among the Jovian Trojans. In this study, we have applied Shkuratov radiative transfer modeling to laboratory spectra of meteorites for which mineral abundances have been measured using X-ray diffraction (XRD) and Rietveld refinement. The general agreement of radiative transfer and XRD estimates of mineral abundances demonstrates the applicability of the radiative transfer approach to featureless, low-albedo spectra. Shkuratov modeling was then applied to new spectral observations of D-type asteroids, along with numerous previously published spectra. The surface mineral abundances of 81 D-type objects, including NASA's Lucy Mission target (21900) Orus, were modeled using assemblages that are plausible based on meteorite analogues. Modeling results reveal D-types are composed of: low-iron olivine; magnesium saponite-dominant phyllosilicates; opaques such as pyrrhotite and tholin; as well as traces of water-ice and other constituents. Subtle compositional differences in model mineralogies exist between Trojan and non-Trojan D-types as well as between L4 and L5 Trojans suggesting differing formational as well as evolutional conditions have affected these bodies.