Search

This paper lays the groundwork for a unifying approach to stochastic dominance testing under survey nonresponse that integrates the partial identification approach to incomplete data and design-based inference for complex survey data. We propose a novel inference procedure for restricted $s$th-order stochastic dominance, tailored to accommodate a broad spectrum of nonresponse assumptions. The method uses pseudo-empirical likelihood to formulate the test statistic and compares it to a critical value from the chi-squared distribution with one degree of freedom. We detail the procedure's asymptotic properties under both null and alternative hypotheses, establishing its uniform validity under the null and consistency against various alternatives. Using the Household, Income and Labour Dynamics in Australia survey, we demonstrate the procedure's utility in a sensitivity analysis of temporal poverty comparisons among Australian households.

Scanning X-ray nanodiffraction microscopy is a powerful technique for spatially resolving nanoscale structural morphologies by diffraction contrast. One of the critical challenges in experimental nanodiffraction data analysis is posed by the convergence angle of nanoscale focusing optics which creates simultaneous dependency of the far-field scattering data on three independent components of the local strain tensor - corresponding to dilation and two potential rigid body rotations of the unit cell. All three components are in principle resolvable through a spatially mapped sample tilt series however traditional data analysis is computationally expensive and prone to artifacts. In this study, we implement NanobeamNN, a convolutional neural network specifically tailored to the analysis of scanning probe X-ray microscopy data. NanobeamNN learns lattice strain and rotation angles from simulated diffraction of a focused X-ray nanobeam by an epitaxial thin film and can directly make reasonable predictions on experimental data without the need for additional fine-tuning. We demonstrate that this approach represents a significant advancement in computational speed over conventional methods, as well as a potential improvement in accuracy over the current standard.

Ptychography is a powerful imaging technique that is used in a variety of fields, including materials science, biology, and nanotechnology. However, the accuracy of the reconstructed ptychography image is highly dependent on the accuracy of the recorded probe positions which often contain errors. These errors are typically corrected jointly with phase retrieval through numerical optimization approaches. When the error accumulates along the scan path or when the error magnitude is large, these approaches may not converge with satisfactory result. We propose a fundamentally new approach for ptychography probe position prediction for data with large position errors, where a neural network is used to make single-shot phase retrieval on individual diffraction patterns, yielding the object image at each scan point. The pairwise offsets among these images are then found using a robust image registration method, and the results are combined to yield the complete scan path by constructing and solving a linear equation. We show that our method can achieve good position prediction accuracy for data with large and accumulating errors on the order of $10^2$ pixels, a magnitude that often makes optimization-based algorithms fail to converge. For ptychography instruments without sophisticated position control equipment such as interferometers, our method is of significant practical potential.

Coronal holes are recognized as the primary sources of heliospheric open magnetic flux (OMF). However, a noticeable gap exists between in-situ measured OMF and that derived from remote sensing observations of the Sun. In this study, we investigate the OMF evolution and its connection to solar structures throughout 2014, with special emphasis on the period from September to October, where a sudden and significant OMF increase was reported. By deriving the OMF evolution at 1au, modeling it at the source surface, and analyzing solar photospheric data, we provide a comprehensive analysis of the observed phenomenon. First, we establish a strong correlation between the OMF increase and the solar magnetic field derived from a Potential Field Source Surface (PFSS) model ($cc_{\mathrm{Pearson}}=0.94$). Moreover, we find a good correlation between the OMF and the open flux derived from solar coronal holes ($cc_{\mathrm{Pearson}}=0.88$), although the coronal holes only contain $14-32\%$ of the Sun's total open flux. However, we note that while the OMF evolution correlates with coronal hole open flux, there is no correlation with the coronal hole area evolution ($cc_{\mathrm{Pearson}}=0.0$). The temporal increase in OMF correlates with the vanishing remnant magnetic field at the southern pole, caused by poleward flux circulations from the decay of numerous active regions months earlier. Additionally, our analysis suggests a potential link between the OMF enhancement and the concurrent emergence of the largest active region in solar cycle 24. In conclusion, our study provides insights into the strong increase in OMF observed during September to October 2014., Comment: accepted in ApJ

Many nano and quantum devices, with their sizes often spanning from millimeters down to sub-nanometer, have intricate low-dimensional, non-uniform, or hierarchical structures on surfaces and interfaces. Since their functionalities are dependent on these structures, high-resolution surface-sensitive characterization becomes imperative to gain a comprehensive understanding of the function-structure relationship. We thus developed hard X-ray ptychographic reflectometry imaging, a new technique that merges the high-resolution two-dimensional imaging capabilities of hard X-ray ptychography for extended objects, with the high-resolution depth profiling capabilities of X-ray reflectivity for layered structures. The synergy of these two methods fully leverages both amplitude and phase information from ptychography reconstruction to not only reveal surface topography and localized structures such as shapes and electron densities, but also yields statistical details such as interfacial roughness that is not readily accessible through coherent imaging solely. The hard X-ray ptychographic reflectometry imaging is well-suited for three-dimensional imaging of mesoscopic samples, particularly those comprising planar or layered nanostructures on opaque supports, and could also offer a high-resolution surface metrology and defect analysis on semiconductor devices such as integrated nanocircuits and lithographic photomasks for microchip fabrications., Comment: 43 pages, 11 figures

Artificial intelligence (AI) is being ubiquitously adopted to automate processes in science and industry. However, due to its often intricate and opaque nature, AI has been shown to possess inherent vulnerabilities which can be maliciously exploited with adversarial AI, potentially putting AI users and developers at both cyber and physical risk. In addition, there is insufficient comprehension of the real-world effects of adversarial AI and an inadequacy of AI security examinations; therefore, the growing threat landscape is unknown for many AI solutions. To mitigate this issue, we propose one of the first red team frameworks for evaluating the AI security of maritime autonomous systems. The framework provides operators with a proactive (secure by design) and reactive (post-deployment evaluation) response to securing AI technology today and in the future. This framework is a multi-part checklist, which can be tailored to different systems and requirements. We demonstrate this framework to be highly effective for a red team to use to uncover numerous vulnerabilities within a real-world maritime autonomous systems AI, ranging from poisoning to adversarial patch attacks. The lessons learned from systematic AI red teaming can help prevent MAS-related catastrophic events in a world with increasing uptake and reliance on mission-critical AI.

Upgrades to advanced scientific user facilities such as next-generation x-ray light sources, nanoscience centers, and neutron facilities are revolutionizing our understanding of materials across the spectrum of the physical sciences, from life sciences to microelectronics. However, these facility and instrument upgrades come with a significant increase in complexity. Driven by more exacting scientific needs, instruments and experiments become more intricate each year. This increased operational complexity makes it ever more challenging for domain scientists to design experiments that effectively leverage the capabilities of and operate on these advanced instruments. Large language models (LLMs) can perform complex information retrieval, assist in knowledge-intensive tasks across applications, and provide guidance on tool usage. Using x-ray light sources, leadership computing, and nanoscience centers as representative examples, we describe preliminary experiments with a Context-Aware Language Model for Science (CALMS) to assist scientists with instrument operations and complex experimentation. With the ability to retrieve relevant information from facility documentation, CALMS can answer simple questions on scientific capabilities and other operational procedures. With the ability to interface with software tools and experimental hardware, CALMS can conversationally operate scientific instruments. By making information more accessible and acting on user needs, LLMs could expand and diversify scientific facilities' users and accelerate scientific output.

Coherent X-ray scattering (CXS) techniques are capable of interrogating dynamics of nano- to mesoscale materials systems at time scales spanning several orders of magnitude. However, obtaining accurate theoretical descriptions of complex dynamics is often limited by one or more factors -- the ability to visualize dynamics in real space, computational cost of high-fidelity simulations, and effectiveness of approximate or phenomenological models. In this work, we develop a data-driven framework to uncover mechanistic models of dynamics directly from time-resolved CXS measurements without solving the phase reconstruction problem for the entire time series of diffraction patterns. Our approach uses neural differential equations to parameterize unknown real-space dynamics and implements a computational scattering forward model to relate real-space predictions to reciprocal-space observations. This method is shown to recover the dynamics of several computational model systems under various simulated conditions of measurement resolution and noise. Moreover, the trained model enables estimation of long-term dynamics well beyond the maximum observation time, which can be used to inform and refine experimental parameters in practice. Finally, we demonstrate an experimental proof-of-concept by applying our framework to recover the probe trajectory from a ptychographic scan. Our proposed framework bridges the wide existing gap between approximate models and complex data.

A plethora of coronal models, from empirical to more complex magnetohydrodynamic (MHD) ones, are being used for reconstructing the coronal magnetic field topology and estimating the open magnetic flux. However, no individual solution fully agrees with coronal hole observations and in situ measurements of open flux at 1~AU, as there is a strong deficit between model and observations contributing to the known problem of the missing open flux. In this paper we investigate the possible origin of the discrepancy between modeled and observed magnetic field topology by assessing the effect on the simulation output by the choice of the input boundary conditions and the simulation set up, including the choice of numerical schemes and the parameter initialization. In the frame of this work, we considered four potential field source surface based models and one fully MHD model, different types of global magnetic field maps and model initiation parameters. After assessing the model outputs using a variety of metrics, we conclude that they are highly comparable regardless of the differences set at initiation. When comparing all models to coronal hole boundaries extracted by extreme ultraviolet (EUV) filtergrams we find that they do not compare well. This miss-match between observed and modeled regions of open field is a candidate contributing to the open flux problem.

The manipulation and control of nanoscale magnetic spin textures is of rising interest as they are potential foundational units in next-generation computing paradigms. Achieving this requires a quantitative understanding of the spin texture behavior under external stimuli using in situ experiments. Lorentz transmission electron microscopy (LTEM) enables real-space imaging of spin textures at the nanoscale, but quantitative characterization of in situ data is extremely challenging. Here, we present an AI-enabled phase-retrieval method based on integrating a generative deep image prior with an image formation forward model for LTEM. Our approach uses a single out-of-focus image for phase retrieval and achieves significantly higher accuracy and robustness to noise compared to existing methods. Furthermore, our method is capable of isolating sample heterogeneities from magnetic contrast, as shown by application to simulated and experimental data. This approach allows quantitative phase reconstruction of in situ data and can also enable near real-time quantitative magnetic imaging.

Flare frequency distributions represent a key approach to addressing one of the largest problems in solar and stellar physics: determining the mechanism that counter-intuitively heats coronae to temperatures that are orders of magnitude hotter than the corresponding photospheres. It is widely accepted that the magnetic field is responsible for the heating, but there are two competing mechanisms that could explain it: nanoflares or Alfv\'en waves. To date, neither can be directly observed. Nanoflares are, by definition, extremely small, but their aggregate energy release could represent a substantial heating mechanism, presuming they are sufficiently abundant. One way to test this presumption is via the flare frequency distribution, which describes how often flares of various energies occur. If the slope of the power law fitting the flare frequency distribution is above a critical threshold, $\alpha=2$ as established in prior literature, then there should be a sufficient abundance of nanoflares to explain coronal heating. We performed $>$600 case studies of solar flares, made possible by an unprecedented number of data analysts via three semesters of an undergraduate physics laboratory course. This allowed us to include two crucial, but nontrivial, analysis methods: pre-flare baseline subtraction and computation of the flare energy, which requires determining flare start and stop times. We aggregated the results of these analyses into a statistical study to determine that $\alpha = 1.63 \pm 0.03$. This is below the critical threshold, suggesting that Alfv\'en waves are an important driver of coronal heating., Comment: 1,002 authors, 14 pages, 4 figures, 3 tables, published by The Astrophysical Journal on 2023-05-09, volume 948, page 71

Understanding and interpreting dynamics of functional materials \textit{in situ} is a grand challenge in physics and materials science due to the difficulty of experimentally probing materials at varied length and time scales. X-ray photon correlation spectroscopy (XPCS) is uniquely well-suited for characterizing materials dynamics over wide-ranging time scales, however spatial and temporal heterogeneity in material behavior can make interpretation of experimental XPCS data difficult. In this work we have developed an unsupervised deep learning (DL) framework for automated classification and interpretation of relaxation dynamics from experimental data without requiring any prior physical knowledge of the system behavior. We demonstrate how this method can be used to rapidly explore large datasets to identify samples of interest, and we apply this approach to directly correlate bulk properties of a model system to microscopic dynamics. Importantly, this DL framework is material and process agnostic, marking a concrete step towards autonomous materials discovery.

To study nanostructures on substrates, surface-sensitive reflection-geometry scattering techniques such as grazing incident small angle x-ray scattering are commonly used to yield an averaged statistical structural information of the surface sample. Grazing incidence geometry can probe the absolute three-dimensional structural morphology of the sample if a highly coherent beam is used. Coherent Surface Scattering Imaging (CSSI) is a powerful yet non-invasive technique similar to Coherent X-ray Diffractive Imaging (CDI) but performed at small angles and grazing-incidence reflection geometry. A challenge with CSSI is that conventional CDI reconstruction techniques cannot be directly applied to CSSI because the Fourier-transform-based forward models cannot reproduce the dynamical scattering phenomenon near the critical angle of total external reflection of the substrate-supported samples. To overcome this challenge, we have developed a multislice forward model which can successfully simulate the dynamical or multi-beam scattering generated from surface structures and the underlying substrate. The forward model is also demonstrated to be able to reconstruct an elongated 3D pattern from a single shot scattering image in the CSSI geometry through fast-performing CUDA-assisted PyTorch optimization with automatic differentiation., Comment: 12 pages, 4 figures, 1 table

Annually-resolved measurements of the radiocarbon content in tree-rings have revealed rare sharp rises in carbon-14 production. These 'Miyake events' are likely produced by rare increases in cosmic radiation from the Sun or other energetic astrophysical sources. The radiocarbon produced is not only circulated through the Earth's atmosphere and oceans, but also absorbed by the biosphere and locked in the annual growth rings of trees. To interpret high-resolution tree-ring radiocarbon measurements therefore necessitates modelling the entire global carbon cycle. Here, we introduce 'ticktack', the first open-source Python package that connects box models of the carbon cycle with modern Bayesian inference tools. We use this to analyse all public annual 14C tree data, and infer posterior parameters for all six known Miyake events. They do not show a consistent relationship to the solar cycle, and several display extended durations that challenge either astrophysical or geophysical models., Comment: Accepted Proceedings of the Royal Society A. 19 pages 6 figures body, 12 pages appendices which are supplementary material in the published version

Coherent microscopy techniques provide an unparalleled multi-scale view of materials across scientific and technological fields, from structural materials to quantum devices, from integrated circuits to biological cells. Driven by the construction of brighter sources and high-rate detectors, coherent X-ray microscopy methods like ptychography are poised to revolutionize nanoscale materials characterization. However, associated significant increases in data and compute needs mean that conventional approaches no longer suffice for recovering sample images in real-time from high-speed coherent imaging experiments. Here, we demonstrate a workflow that leverages artificial intelligence at the edge and high-performance computing to enable real-time inversion on X-ray ptychography data streamed directly from a detector at up to 2 kHz. The proposed AI-enabled workflow eliminates the sampling constraints imposed by traditional ptychography, allowing low dose imaging using orders of magnitude less data than required by traditional methods.