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The use of composite materials has shown steady growth in recent years due to their excellent specific mechanical properties and the possibility to reduce the weight of vehicles without impairing their safety and comfort. Continuous fibre-reinforced thermoplastic composites (CFRTP) show dynamic, acoustic, and damping properties far superior to steel and can be recycled and repaired. Their excellent properties make CFRTP good candidates for anti-vibration and shock absorbing components, however, out-of-plane mechanical properties hinder the anchoring to the vehicle's body by means of bolted connections. The results obtained in this study show how the maximum torque that can be applied without cracks or breakage phenomena is lower than in standard steel joints. Although the preload's value is admissible, this one is reduced over time due to relaxation phenomena associated with the viscoelastic behaviour of thermoplastic matrix. The results obtained can be improved with the integration of metal inserts in connections' areas. In this study, a case study of a gear mount replacing the steel core with CFRTP reinforced with inserts is carried out. The results show a reduction above 50% in weight, opening the possibility of lighter structures in the automotive sector.

Continuous Fibers-Reinforced Thermoplastic Composites (CFRTP) are presented as light materials, capable of offering a short production time with the possibility of being recycled. These properties make them ideal for automotive applications, aiming to reduce the consumption and emission of polluting gases. This article analyzed the dynamic tensile stress-compressive stress behavior of CFRTP in structural elements of the car with anti-vibration and damping functions. The data available in the literature on the reliable and usual compliance of the properties required for CFRTP, to be applied in the automotive structural elements, is scarce and insufficient. In order to analyze whether CFRTP feeds the demanding requirements of car manufacturers and if they provide advantages over the metal materials currently used, this article developed a method of reliable verification of their dynamic tensile and compression behavior. The methodology developed could be used as a guide to characterizing any combination of vulcanized rubber adhesive joints with CFRTP, regardless of the materials and additives used. The results obtained showed that there exists CFRTP that fits the requirements of the car manufacturers for this type of component and also offers dynamic advantages over the materials currently used as anti-vibration elements.

The synthesis and photophysical studies of two cationic Tröger's base (TB)-derived bis-naphthalimides 1 and 2 and the TB derivative 6, characterized by X-ray crystallography, are presented. The enantiomers of 1 and 2 are separated by cation-exchange chromatography on Sephadex C25 using sodium (-)-dibenzoyl-l-tartarate as the chiral mobile phase. The binding of enantiomers with salmon testes (st)-DNA and synthetic polynucleotides are studied by a variety of spectroscopic methods including UV/vis absorbance, circular dichroism, linear dichroism, and ethidium bromide displacement assays, which demonstrated binding of these compounds to the DNA grooves with very high affinity (K ∼ 10(6) M(-1)) and preferential binding of (-)-enantiomer. In all cases, binding to DNA resulted in a significant stabilization of the double-helical structure of DNA against thermal denaturation. Compound (±)-2 and its enantiomers possessed significantly higher binding affinity for double-stranded DNA compared to 1, possibly due to the presence of the methyl group, which allows favorable hydrophobic and van der Waals interactions with DNA. The TB derivatives exhibited marked preference for AT rich sequences, where the binding affinities follow the order (-)-enantiomer > (±) > (+)-enantiomer. The compounds exhibited significant photocleavage of plasmid DNA upon visible light irradiation and are rapidly internalized into malignant cell lines.