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Your search keyword '"Martijn S. Bakker"' showing total 2 results
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2 results on '"Martijn S. Bakker"'

1. ChemInform Abstract: Base-Stabilized Nitrilium Ions as Convenient Imine Synthons

Author

Flip Holtrop, Tom van Dijk, Martijn S. Bakker, Koop Lammertsma, Martin Nieger, and J. Chris Slootweg

Subjects
chemistry.chemical_classification, chemistry.chemical_compound, chemistry, Base (chemistry), Imine, Synthon, General Medicine, Nitrilium, Combinatorial chemistry, Ion
Abstract

The simple method represents an efficient strategy for the synthesis of a wide range of substituted imines.

Published
2015
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2. Base-stabilized nitrilium ions as convenient imine synthons

Author

J. Chris Slootweg, Tom van Dijk, Flip Holtrop, Martijn S. Bakker, Koop Lammertsma, and Martin Nieger

Subjects
chemistry.chemical_classification, Base (chemistry), 010405 organic chemistry, Organic Chemistry, Synthon, Imine, 010402 general chemistry, 01 natural sciences, Biochemistry, Combinatorial chemistry, 0104 chemical sciences, Ion, Adduct, chemistry.chemical_compound, chemistry, Nucleophile, Pyridine, Organic chemistry, Physical and Theoretical Chemistry, Nitrilium
Abstract

A simple and efficient methodology is presented for the synthesis of a wide range of substituted imines. It is based on stabilizing readily available, but thermally labile, N-alkylnitrilium triflates with pyridine or DMAP to moderately air-stable adducts. These base-stabilized imine synthons react conveniently with phosphorus- and nitrogen-based nucleophiles to amidines and phosphaamidines.

Published
2015

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